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1.
A miniaturized ceramic differential scanning calorimeter (MC-DSC) with integrated oven and crucible is presented. Despite its small size of only 11 mm × 39 mm × 1.5 mm, all functions of a conventional DSC apparatus are integrated in this novel device - including the oven. The MC-DSC is fully manufactured in thick-film and green glass ceramic tape-based low temperature co-fired ceramics (LTCC) technology. Therefore, production costs are considered to be low. Initial results using indium as a sample material show a good dynamic performance of the MC-DSC. Full width at half maximum of the melting peak is 2.4 °C (sample mass approx. 11 mg, heating rate approx. 50 °C/min). Repeatability of the indium melting point is within ±0.02 °C. The melting peak area increases linearly with the sample mass up to at least 26 mg. Simulations of a strongly simplified finite element model of the MC-DSC are in a good agreement with measurement results allowing a model-based prediction of its basic characteristics.  相似文献   

2.
Stream temperature is an important indicator of water quality, particularly in regions where endangered fish populations are sensitive to elevated water temperature. Regional assessment of stream temperatures from the ground is limited by sparse sampling in both space and time. Remotely sensed thermal-infrared (TIR) images are able to make spatially distributed measurements of the radiant skin temperature of streams. We quantify and discuss the accuracy and uncertainty limits to recovering stream temperatures in the Pacific Northwest for a range of stream widths (10-500 m), and TIR pixel sizes (5-1000 m) from remotely sensed airborne and satellite TIR images. Among locations with more than three pixels across the stream, the image temperature overestimated the in-stream temperature on average by 1.2 °C, which is 7% of the in-stream temperature (standard error (SE) of 0.2 °C, n = 21). The corresponding uncertainty (band weighted standard deviation in image temperature) for these locations averaged ± 0.3 °C (SE < 0.1 °C, n = 21) which is 2% of in-stream temperatures. This overestimation by the image temperatures is likely to be due to thermal stratification between the stream surface and the location of the in-stream temperature measurements deeper in the water column. For streams with one to three pixels across, mixing with bank elements increased the overestimation by image temperatures to 2.2 °C (SE = 0.3 °C, n = 23) on average (13% of in-stream temperatures), and the uncertainty increased to ± 0.4 °C (SE = 0.1 °C, n = 23) which is 2% of in-stream temperatures. For a fraction of a pixel across the stream the overestimation by image temperatures was 7.6 °C (SE = 1.2 °C, n = 23) on average (45% of in-stream temperatures), and the uncertainty was ± 0.5 °C (SE = 0.1 °C, n = 23) which is 3% of in-stream temperatures. These results show that reliable satellite TIR measurement of stream temperatures is limited to large rivers (∼180-m across for Landsat ETM+), unless novel unmixing algorithms are used effectively.  相似文献   

3.
Copper (II) oxide (CuO)/multiwall carbon nanotube (MWNT) thin film based ethanol-sensors were fabricated by dispersing CVD-prepared MWNTs in varying concentration over DC magnetron sputtered-CuO films. The responses of these sensors as a function of MWNT concentrations and temperatures were measured, and compared. The sensing response was the maximum at an operating temperature near 400 °C for all the samples irrespective of the MWNTs dispersed over them. At optimum operating temperature (Topt) of 407 ± 1 °C, the response is linear for 100-700 ppm range and tends to saturate at higher concentrations. In comparison with bare CuO sample, the response of CuO/MWNT sensing films increased up to 50% in the linear range. The response improvement for 2500 ppm of ethanol was up to 90% compared to bare CuO sample. In addition, the sensing response time also reduced to around 23% for lowest ethanol concentration at Topt. However, a decrease in the sensor response was observed on films with very high concentrations of MWNTs.  相似文献   

4.
Impervious surface area (ISA) from the Landsat TM-based NLCD 2001 dataset and land surface temperature (LST) from MODIS averaged over three annual cycles (2003-2005) are used in a spatial analysis to assess the urban heat island (UHI) skin temperature amplitude and its relationship to development intensity, size, and ecological setting for 38 of the most populous cities in the continental United States. Development intensity zones based on %ISA are defined for each urban area emanating outward from the urban core to the non-urban rural areas nearby and used to stratify sampling for land surface temperatures and NDVI. Sampling is further constrained by biome and elevation to insure objective intercomparisons between zones and between cities in different biomes permitting the definition of hierarchically ordered zones that are consistent across urban areas in different ecological setting and across scales.We find that ecological context significantly influences the amplitude of summer daytime UHI (urban-rural temperature difference) the largest (8 °C average) observed for cities built in biomes dominated by temperate broadleaf and mixed forest. For all cities combined, ISA is the primary driver for increase in temperature explaining 70% of the total variance in LST. On a yearly average, urban areas are substantially warmer than the non-urban fringe by 2.9 °C, except for urban areas in biomes with arid and semiarid climates. The average amplitude of the UHI is remarkably asymmetric with a 4.3 °C temperature difference in summer and only 1.3 °C in winter. In desert environments, the LST's response to ISA presents an uncharacteristic “U-shaped” horizontal gradient decreasing from the urban core to the outskirts of the city and then increasing again in the suburban to the rural zones. UHI's calculated for these cities point to a possible heat sink effect. These observational results show that the urban heat island amplitude both increases with city size and is seasonally asymmetric for a large number of cities across most biomes. The implications are that for urban areas developed within forested ecosystems the summertime UHI can be quite high relative to the wintertime UHI suggesting that the residential energy consumption required for summer cooling is likely to increase with urban growth within those biomes.  相似文献   

5.
MODIS-derived surface temperature of the Great Salt Lake   总被引:1,自引:0,他引:1  
The surface temperature of Utah's hypersaline Great Salt Lake is examined between 2000 and 2007 using 3345 images from the Moderate Resolution Imaging Spectroradiometer (MODIS) on board the NASA Earth Observing System Terra and Aqua platforms. This study shows the utility of using a multi-year record of the easily accessible and fully processed MODIS thermal imagery to monitor spatial, diurnal, seasonal, and annual variations in the surface water temperature (SWT) of lakes where long-term in situ measurements are rarely available. A cloud-free Terra image is available on average every day during the summer and early fall, every other day during spring and late fall, and every third day during the winter. MODIS-derived lake SWT exhibits a cool bias (~ − 1.5 °C) relative to in situ temperature observations gathered from three buoys and a slowly-moving watercraft.The dominant SWT signal is the annual cycle (with a range of 26 °C and peak temperature in mid-July) while the diurnal range is as large as 4 °C during the spring season. Year-to-year variations in SWT are largest during the fall with over 1 °C anomalously warm (cold) departures from the 8-year monthly medians observed during fall 2001 (2006). The MODIS imagery provides an updated SWT climatology for operational weather forecasting applications (e.g., lake-effect snow storm prediction) as well as for input into operational and research numerical weather prediction models.  相似文献   

6.
Hierarchical SnO2 microspheres were synthesized by a hydrothermal method at 140 °C using stannic chloride hydrate and sodium hydroxide as starting materials. The individual hierarchical SnO2 microsphere ranged from 700 to 900 nm in diameter. After these microspheres were heated at 600 °C for 2 h, the spheres were cross-linked into clusters by short SnO2 nanorods as revealed by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Most importantly, SnO2 hierarchical microsphere sensor exhibits excellent selectivity and fast response to ethanol. Response and recovery times were 0.6 s and 11 s when the sensor was exposed to 50 ppm ethanol at an operating temperature of 300 °C. Thus, hierarchical structures play a significant role in the field of gas sensing.  相似文献   

7.
SnCl2 (solution) was spin coated on soda lime glass and Al2O3 substrate to obtain nano-particulate tin oxide film, directly by sintering at 550 °C for 40 minutes (min). The surface morphology and crystal structure of the tin oxide films were analyzed using atomic force microscopy (AFM) and X-ray diffraction (XRD). The size of SnO2 nanostructure was determined from UV-vis and found to be ?3 nm. These films were tested for sensing H2 concentration of 0.1-1000 ppm at optimized operating temperature of 265 °C. The results showed that sensitivity (Rair/Rgas per ppm) goes on increasing with decreasing concentration of test gas, giving concentration dependent changes. Special studies carried out at low concentration levels (0.1-1 and 1-10 ppm) of H2, give high sensitivity (200 × 10−3/ppm) for lowest concentration (0.1-1 ppm) of H2. The selectivity for H2 against relative humidity (RH), CO2, CO and LPG gases is also good. The sensor, at operating temperature of 200 °C, is showing nearly zero response to 300 ppm of H2, and offering response to acetone vapour of 11 ppm. Selectivity for acetone against RH% and CO2 was also studied. These sensors can be used as H2 sensor at an operating temperature of 265 °C, and as an acetone sensor at the operating temperature of 200 °C.  相似文献   

8.
Transparency sheets, coated with copper on both sides by means of thermal evaporation in vacuum, are patterned by direct chemical etching to realize sensing platforms having copper heaters on the backside, and resistances having calibrated temperature coefficient on the topside. The mechanical and thermal stability of these structures was demonstrated up to 70 °C. Bending tests also show that the metallic patterns do maintain unaltered performances after more than 104 bending cycles. Resistance measurements show that the resistance on the patterned copper structures linearly increases with the temperature in the range between room temperature and 70 °C, while above this temperature an irreversible damage occurs. Experimental investigations demonstrate that the heaters on the backside of the sensing platforms allow to obtain a quite uniform temperature distribution on the top side over an area larger than 1 cm2.Coating the flexible sensing platform by doped polyaniline and carbon nanotubes embedded in a polymer host, a chemoresistive system operating at low temperature is developed, which allows to perform tests at constant temperature, with the temperature being set and monitored by using the heater and the patterned resistance, respectively. The sensing performances of the films are evaluated by means of electrical measurements performed while exposing the samples to different relative humidity levels, and to calibrate ammonia pulses.  相似文献   

9.
An experimental site was set up in a large, flat and homogeneous area of rice crops for the validation of satellite derived land surface temperature (LST). Experimental campaigns were held in the summers of 2002-2004, when rice crops show full vegetation cover. LSTs were measured radiometrically along transects covering an area of 1 km2. A total number of four thermal radiometers were used, which were calibrated and inter-compared through the campaigns. Radiometric temperatures were corrected for emissivity effects using field emissivity and downwelling sky radiance measurements. A database of ground-based LSTs corresponding to morning, cloud-free overpasses of Envisat/Advanced Along-Track Scanning Radiometer (AATSR) and Terra/Moderate Resolution Imaging Spectroradiometer (MODIS) is presented. Ground LSTs ranged from 25 to 32 °C, with uncertainties between ± 0.5 and ± 0.9 °C. The largest part of these uncertainties was due to the spatial variability of surface temperature. The database was used for the validation of LSTs derived from the operational AATSR and MODIS split-window algorithms, which are currently used to generate the LST product in the L2 level data. A quadratic, emissivity dependent split-window equation applicable to both AATSR and MODIS data was checked as well. Although the number of cases analyzed is limited (five concurrences for AATSR and eleven for MODIS), it can be concluded that the split-window algorithms work well, provided that the characteristics of the area are adequately prescribed, either through the classification of the land cover type and the vegetation cover, or with the surface emissivity. In this case, the AATSR LSTs yielded an average error or bias of − 0.9 °C (ground minus algorithm), with a standard deviation of 0.9 °C. The MODIS LST product agreed well with the ground LSTs, with differences comparable or smaller than the uncertainties of the ground measurements for most of the days (bias of + 0.1 °C and standard deviation of 0.6 °C, for cloud-free cases and viewing angles smaller than 60°). The quadratic split-window algorithm resulted in small average errors (+ 0.3 °C for AATSR and 0.0 °C for MODIS), with differences not exceeding ± 1.0 °C for most of the days (standard deviation of 0.9 °C for AATSR and 0.5 °C for MODIS).  相似文献   

10.
P-type CuO nanorods with the breadth of 15-20 nm and the length of 60-80 nm, have been synthesized using a microwave-assisted hydrothermal (MH) method. The band gap of CuO nanorods was calculated to be 2.75 eV based on the UV-vis absorption spectrum of the product. The gas sensing property of the CuO nanorods to several organic vapors was tested in temperatures ranging from 160 °C to 300 °C. The response of the CuO sensor to ethanol (1000 ppm) was 9.8 at the working temperature of 210 °C. The response time and the recovery time were within the range of 13-42 s and 17-51 s, respectively. Further measurements exhibited stronger response to ethanol than to other target gases. The enhanced gas sensing performance of the sensor to ethanol may be attributed to the small size of the CuO particles.  相似文献   

11.
IDS (InterDendritic Solidification) is a thermodynamic–kinetic–empirical tool for simulation of solidification phenomena of steels including phase transformations from melt down to room temperature. In addition, important thermophysical material properties (enthalpy, thermal conductivity, density, etc.) are calculated. The model has been developed in the Laboratory of Metallurgy, Helsinki University of Technology, Finland, since 1984. IDS includes two main modules, the IDS module and the ADC (Austenite DeComposition) module. IDS module simulates the solidification phenomena from liquid down to 1000 °C and ADC the austenite decomposition down to room temperature. Both modules have their own recommended composition ranges. The IDS module is based on the so-called sharp interface concept. The ADC is mainly statistical based on empirical CCT (Continuous Cooling Transformation) diagrams. IDS tool is also coupled with the thermodynamic programmer's library, called ChemApp, developed by a German company, GTT-Technologies. This coupled package is used to simulate among other things multiphase inclusions during solidification. The present paper summarises the features of the IDS tool including the coupling with the ChemApp library.  相似文献   

12.
This work presents the design and the thermal behavior characterization of an innovative self-test portable surface acoustic wave platform for chemical detection under high temperature. Before the forthcoming deposition of the sensitive coating, the thermal behavior of the bare LGS acoustic platform has been focused on. The system includes a (0°, 140°, 25°) crystallographic cut langasite (LGS) piezoelectric substrate, a ceramic heater, and a platform with RF connections for remote measurements. The packaging consists in a hermetic stainless steel cell, which enables safe gas detection. Its thermal behavior was successfully investigated in the temperature range 25-500 °C thanks to the integrated heater, without using an external furnace. Finite element modeling aided the development of this platform structure by predicting the thermal behavior of each of its parts and their cross-influences. The structure of the platform was specifically designed so that 500 °C could be reached on the LGS acoustic device while the temperature on the PCB connections should not exceed 50 °C. Then, the temperature-dependence on the waves generated by the acoustic transducers has been investigated through numerical modeling by resolving the wave propagation equations with several sets of LGS constants. Corresponding simulations showed good agreement with experiments, Thermal cycling up to 350 °C highlighted satisfactory hardiness and response-reproducibility of the system towards thermal stress, after a first burn effect.  相似文献   

13.
Nanostructured porous tungsten oxide materials were synthesized by the means of electrochemical etching (anodization) of tungsten foils in aqueous NaF electrolyte. Formation of the sub-micrometer size mesoporous particles has been achieved by infiltrating the pores with water. The obtained colloidal anodic tungsten oxide dispersions have been used to fabricate resistive WO3 gas sensors by drop casting the sub-micrometer size mesoporous particles between Pt electrodes on Si/SiO2 substrate followed by calcination at 400 °C in air for 2 h. The synthesized WO3 films show slightly nonlinear current-voltage characteristics with strong thermally activated carrier transport behavior measured at temperatures between −20 °C and 280 °C. Gas response measurements carried out in CO, H2, NO and O2 analytes (concentration from 1 to 640 ppm) in air as well as in Ar buffers (O2 only in Ar) exhibited a rapid change of sensor conductance for each gas and showed pronounced response towards H2 and NO in Ar and air, respectively. The response of the sensors was dependent on temperature and yielded highest values between 170 °C and 220 °C.  相似文献   

14.
The estimation of near surface air temperature (Ta) is useful for a wide range of applications such as agriculture, climate related diseases and climate change studies. Air temperature is commonly obtained from synoptic measurements in weather stations. In Africa, the spatial distribution of weather stations is often limited and the dissemination of temperature data is variable, therefore limiting their use for real-time applications. Compensation for this paucity of information may be obtained by using satellite-based methods. However, the derivation of near surface air temperature (Ta), from the land surface temperature (Ts) derived from satellite is far from straight forward. Some studies have tried to derive maximum Ta from satellites through regression analysis but the accuracy obtained is quite variable according to the study. The main objective of this study was to explore the possibility of retrieving high-resolution Ta data from the Moderate Resolution Imaging Spectroradiometer (MODIS) Ts products over different ecosystems in Africa. First, comparisons between night MODIS Ts data with minimum Ta showed that MODIS nighttime products provide a good estimation of minimum Ta over different ecosystems (with (ΔTs − Ta) centered at 0 °C, a mean absolute error (MAE) = 1.73 °C and a standard deviation = 2.4 °C). Secondly, comparisons between day MODIS Ts data with maximum Ta showed that (ΔTs − Ta) strongly varies according to the seasonality, the ecosystems, the solar radiation, and cloud-cover. Two factors proposed in the literature to retrieve maximum Ta from Ts, i.e. the Normalized Difference Vegetation Index (NDVI) and the Solar Zenith Angle (SZA), were analyzed. No strong relationship between (ΔTs − Ta) and (i) NDVI and (ii) SZA was observed, therefore requiring further research on robust methods to retrieve maximum Ta.  相似文献   

15.
In order to further understand the different contributions to NOx sensing mechanism as well as the importance of electrode geometry, solid state potentiometric sensors with varying La2CuO4 sensing electrode thicknesses were studied. These sensors (with a Pt counter electrode) showed a dependence of NO2 sensitivity which decreased with increasing thickness in the temperature range of 550-650 °C. They also showed NO sensitivity that was independent of thickness at 400 °C and 600 °C, but varied at temperatures between. This behavior was attributed to multiple mechanistic contributions explained by Differential Electrode Equilibria.  相似文献   

16.
The α-Fe2O3 nanorods were successfully synthesized without any templates by calcining the α-FeOOH precursor in air at 300 °C for 2 h and their LPG sensing characteristics were investigated. The α-FeOOH precursor was prepared through a simple and low cost wet chemical route at low temperature (40 °C) using FeSO4·7H2O and CH3COONa as starting materials. The formation of α-FeOOH precursor and its topotactic transformation to α-Fe2O3 upon calcination was confirmed by X-ray diffraction measurement (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM) analysis. The α-Fe2O3 nanorods exhibited outstanding gas sensing characteristics such as, higher gas response (∼1746-50 ppm LPG at 300 °C), extremely rapid response (∼3-4 s), relatively slow recovery (∼8-9 min), excellent repeatability, good selectivity and lower operating temperature (∼300 °C). Furthermore, the α-Fe2O3 nanorods are able to detect up to 5 ppm for LPG with reasonable response (∼15) at the operating temperature of 300 °C and they can be reliably used to monitor the concentration of LPG over the range (5-60 ppm). The experimental results clearly demonstrate the potential of using the α-Fe2O3 nanorods as sensing material in the fabrication of LPG sensors. Plausible LP G sensing mechanism of the α-Fe2O3 nanorods is also discussed.  相似文献   

17.
Nanostructured TiO2-ZrO2 thin films and powders were prepared by a straightforward aqueous particulate sol-gel route. Titanium (IV) isopropoxide and zirconium (IV) acetate hydrate were used as precursors, and hydroxypropyl cellulose was used as a polymeric fugitive agent in order to increase the specific surface area. X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy revealed that the powder were crystallised at the low temperature of 500 °C, containing anatase-TiO2 and tetragonal-ZrO2 phases. Furthermore, it was found that ZrO2 retarded the anatase-to-rutile transformation up to 900 °C. The activation energies for crystallite growth of TiO2 and ZrO2 components in the binary system were calculated 10.16 and 3.12 kJ/mol, respectively. Transmission electron microscope (TEM) image showed that one of the smallest crystallite sizes was obtained for TiO2-ZrO2 binary mixed oxide, being 5 nm at 500 °C. Field emission scanning electron microscope (FESEM) analysis revealed that the deposited thin films had nanostructured morphology with the average grain size of 20 nm at 500 °C and 36 nm at 900 °C. Thin films produced under optimised conditions showed excellent microstructural properties for gas sensing applications. They exhibited a remarkable response towards low concentrations of CO and NO2 gases at low operating temperature of 150 °C, resulted in an increase of thermal stability of sensing films as well as a decrease in the power consumption. Furthermore, calibration curves revealed that TiO2-ZrO2 sensor follows the power law, S = A[gas]B (where S is sensor response, coefficients A and B are constants and [gas] is gas concentration) for the two types of gases, and it has excellent capability for the detection of low gas concentrations.  相似文献   

18.
This paper presents a new high temperature dynamic viscosity sensor for in situ condition monitoring of engine lubricants. The sensor is used to measure the variation in the quality factor of a vibrating piezoelectric cantilever beam due to viscous damping. The sensor was used to measure the dynamic viscosity of various single and multi-grade engines oils up to 180 cP from 25 °C to 60 °C. The sensor is capable of detecting degradation and dilution of engine oil for both new and used samples of 5W-30 and 10W-40 and diluted SAE 30 engine oils. All of the viscosity measurements presented are within 0.13-9.8% of the results obtained using the standard Walther equation at various temperatures. An equation relating dynamic viscosity of an oil sample to the quality factor of the beam is presented. The quality factor measurement circuit presented in this research can be implemented in automotive applications for in situ condition monitoring of lubricant viscosity.  相似文献   

19.
Simple regression algorithms were developed to quantify spatio-temporal dynamics of minimum and maximum air temperatures (Tmin and Tmax, respectively) and soil temperature for a depth of 0-5 cm (Tsoil-5cm) across complex terrain in Turkey using Moderate Resolution Imaging Spectroradiometer (MODIS) data at a 500-m resolution. A total of 762 16-day MODIS composites (127 images × 6 bands) between 2000 and 2005 were averaged over a monthly basis to temporally match monthly Tmin, Tmax, and Tsoil-5cm from 83 meteorological stations. A total of 60 (28 temporally averaged plus 32 time series-based) linear regression models of Tmin, Tmax, and Tsoil-5cm were developed using best subsets procedure as a function of a combination of 12 explanatory variables: six MODIS bands of blue, red, near infrared (NIR), middle infrared (MIR), normalized difference vegetation index (NDVI), and enhanced vegetation index (EVI); four geographical variables of latitude, longitude, altitude, and distance to sea (DtS); and two temporal variables of month, and year. The best multiple linear regression models elucidated 65% (RMSE = 5.9 °C), 65% (RMSE = 5.1 °C), and 57% (RMSE = 6.9 °C) of variations in Tmin, Tmax, and Tsoil-5cm, respectively, under a wide range of Tmin (−34 to 25 °C), Tmax (0.2-47 °C) and Tsoil-5cm (−9 to 40 °C) observed at the 83 stations.  相似文献   

20.
Piezoresistors of polycrystalline silicon were obtained by the aluminum induced crystallization (AIC) process-route. Tri-layer samples with the layer sequence Si/Al/Si were deposited by means of e-beam evaporation. The Si layer thickness was held constant at 300 nm, whereas the Al thickness was varied between 25 and 125 nm. The annealing was performed in vacuum at temperatures between 330 and 660 °C for up to 6 h. The piezoresistors exhibit gauge factors (GFs) of 4.5 up to 17, with temperature coefficients of resistance (TCR) between −0.4 and −0.1%/K and temperature coefficients of GF (TCGF) between −0.1 and 0.4%/K. These values depend on the annealing conditions applied and the Al layer thickness of the sample. Complementary measurements on a bi-layer system of Al/Si = 300 nm/300 nm were performed after annealing under vacuum conditions and a subsequent wet-etch removal of the Al top-layer. GFs up to 24, TCRs of −0.4 to −0.2%/K, and TCGFs of −0.2 to 0.2%/K were determined for these samples. As piezoresistive AIC-silicon is obtained using much lower process temperatures, compared to common high temperature processes, the process route presented becomes interesting for sensor applications on temperature sensitive substrates.  相似文献   

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