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介绍硫化剂DCP、共硫化剂TAIC(异氰脲三烯丙酯)和HVA2(N,N′间亚苯基双马来酰亚胺)、分散剂硬脂酸及卤素和无卤阻燃剂对EPDM阻燃电缆胶料性能的影响。硫化剂DCP用量为3份左右、共硫化剂TAIC/HVA2并用(并用比为1/0.5)、硬脂酸用量较大、卤素或有机氮阻燃剂用量适中,则EPDM阻燃电缆胶料的物理和电性能较好。 相似文献
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本研究耐辐射无卤阻燃绝缘EPDM电缆胶料的主要配合为:生胶为乙烯含量较高的1,4-己二烯型电绝缘级EPDM(100份);阻燃剂为氢氧化铝/氢氧化镁/三氧化二锑并用体系(95~100份),其中氢氧化铝和氢氧化镁用硬脂酸锌进行表面处理;补强填充剂为煅烧陶土、LEE白滑粉、PY-Ⅱ型水白云母粉和钛白粉并用体系(105~115份);硫化剂为2,5-二甲基-2,5-二(叔丁基过氧化)己烷(4~5份),共硫化剂为三羟甲基丙烷三甲基丙烯酸酯和N,N′-间亚苯基双马来酰亚胺并用体系(1.6~1.8份)。胶料和成品的物理机械性能、介电性能、阻燃性能和耐环境性能(耐热性、耐蒸汽性和耐辐射性)达到IEC502(1994)和IEC18A(1981)(CO)标准。 相似文献
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采煤机(屏蔽型)电缆的半导电橡胶屏蔽层的胶料配方为:乙烯-醋酸乙烯酯共聚物(EVA)90;氯化聚乙烯(CPE)10;过氧化二异丙苯1-3;三聚异氰酸三烯丙酯2-5;20#机油15.0;固体石蜡8.0;环氧酯类增塑剂适量;乙炔炭黑40-60;高耐磨炭黑30;轻质碳酸钙适量:抗氧剂300#1.5;硬脂酸盐1.0,含胶率45%。EVA.CPE在开炼机上共混,胶料混炼可在开炼机上或密炼机中进行,本胶料与线芯绝缘胶料是一次挤出成型进入硫化管中硫化的。胶料及成品性能均满足GB7594—87和GB12972.1—91标准。 相似文献
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研制出了一种耐环境性较好的彩色低烟低卤氯磺化聚乙烯(CSM)/EPDM电缆护套胶料。得出的胶料优化配方为:CSM/EPDM(85~90)/(15~10);硫化体系(硫化剂DCP/共硫化剂HVA2/共硫化剂TAIC)65~70;补强填充剂(LEE白滑粉/煅烧陶土/轻质碳酸钙)100~110;三盐基马来酸铅35~40;金红石型钛白粉30~40;耐辐射剂(二苯胺类/磷酸苯酯类)15~20;阻燃剂(氢氧化铝/氢氧化镁/三氧化二锑)100~115;其它20~40。胶料及电缆成品性能满足IEC502(1994)标准及核电站使用要求。 相似文献
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含有活性添加剂的M-8_B1和M-8_T2K的两种油品对NBR-18O形密封圈有一定的副作用,通过调整NBR胶料硫化体系(硫黄0.3;促进剂CZ1.5;促进剂M0.5;硫化剂DCP2.0)和补强剂炭黑的用量(高耐磨炭黑55;喷雾炭黑40).可以使其满足抗两种油品侵蚀的性能要求。另外,在NBR胶料中添加25份耐寒增塑剂(邻苯二甲酸二丁酯10;癸二酸二辛酯15).可提高胶料的耐低温性能,并使脆性温度降至-65℃以下。 相似文献
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简介了挂车制动阀橡胶膜片(以下简称膜片) 的研制。膜片的胶料配方确定为:NBR(牌号N240S) 100;氧化锌 5;硬脂酸 1;防老剂 3;喷雾炭黑+ 高耐磨炭黑 80 ;增塑剂DOS 10;硫黄 0-3 ;促进剂 2-5 ,合计 201-8。硫化胶性能符合德国WABCO公司的JED7080 M0 标准。膜片的骨架材料选用厚度为(0-26±0-03) mm 的聚酯帆布。产品通过中国重型汽车集团公司技术中心的台架试验。 相似文献
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利用霉变玉米胚组织研制了对二甲基亚硝胺(DMNA)、二乙基亚硝胺(DE-NA)和甲基苄基亚硝胺(MBNA)等选择性响应的新型组织传感器。该传感器灵敏度高,重现性好,选择性好,其线性范围2.0×10-6~2.0×10-3mol·L-1,检测下限1.3×10-7mol·L-1,斜率为59.2(30°C,pH7.5)。 相似文献
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主要探讨了EPDM/CPE并用比、阻燃剂(Sb2O3、十溴联苯醚)的配比、填料品种及用量、硫化剂DCP及助交联剂TAIC等因素对EPDM/CPE并用胶料力学性能、阻燃性能及电性能的影响,结果表明:选择EPDM40,CPE60.3PbO1.2,2PbO1.2,DCP2~3,TAIC1,滑石粉30,Sb2O310~15,ZR-1020~30,SA1,ZnO5,可制得综合性能较好的EPDM/CPE并用胶 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Cheng-Le Zhao Shane Porzio Alan Smith Haiyan Ge H. T. Davis L. E. Scriven 《Journal of Coatings Technology and Research》2006,3(2):109-115
Despite its industrial importance, the subject of freeze-thaw (F/T) stability of latex coatings has not been studied extensively.
There is also a lack of fundamental understanding about the process and the mechanisms through which a coating becomes destabilized.
High pressure (2100 bar) freezing fixes the state of water-suspended particles of polymer binder and inorganic pigments without
the growth of ice crystals during freezing that produce artifacts in direct imaging scanning electron microscopy (SEM) of
fracture surfaces of frozen coatings. We show that by incorporating copolymerizable functional monomers, it is possible to
achieve F/T stability in polymer latexes and in low-VOC paints, as judged by the microstructures revealed by the cryogenic
SEM technique. Particle coalescence as well as pigment segregation in F/T unstable systems are visualized. In order to achieve
F/T stability in paints, latex particles must not flocculate and should provide protection to inorganic pigment and extender
particles. Because of the unique capabilities of the cryogenic SEM, we are able to separate the effects of freezing and thawing,
and study the influence of the rate of freezing and thawing on F/T stability. Destabilization can be caused by either freezing
or thawing. A slow freezing process is more detrimental to F/T stability than a fast freezing process; the latter actually
preserves suspension stability during freezing.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004 in Chicago,
IL. Tied for first place in The John A. Gordon Best Paper Competition. 相似文献
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Ethanol and (−)-α-Pinene: Attractant Kairomones for Bark and Ambrosia Beetles in the Southeastern US
In 2002–2004, we examined the flight responses of 49 species of native and exotic bark and ambrosia beetles (Coleoptera: Scolytidae
and Platypodidae) to traps baited with ethanol and/or (−)-α-pinene in the southeastern US. Eight field trials were conducted
in mature pine stands in Alabama, Florida, Georgia, North Carolina, and South Carolina. Funnel traps baited with ethanol lures
(release rate, about 0.6 g/day at 25–28°C) were attractive to ten species of ambrosia beetles (Ambrosiodmus tachygraphus, Anisandrus sayi, Dryoxylon onoharaensum, Monarthrum mali, Xyleborinus saxesenii, Xyleborus affinis, Xyleborus ferrugineus, Xylosandrus compactus, Xylosandrus crassiusculus, and Xylosandrus germanus) and two species of bark beetles (Cryptocarenus heveae and Hypothenemus sp.). Traps baited with (−)-α-pinene lures (release rate, 2–6 g/day at 25–28°C) were attractive to five bark beetle species
(Dendroctonus terebrans, Hylastes porculus, Hylastes salebrosus, Hylastes tenuis, and Ips grandicollis) and one platypodid ambrosia beetle species (Myoplatypus flavicornis). Ethanol enhanced responses of some species (Xyleborus pubescens, H. porculus, H. salebrosus, H. tenuis, and Pityophthorus cariniceps) to traps baited with (−)-α-pinene in some locations. (−)-α-Pinene interrupted the response of some ambrosia beetle species
to traps baited with ethanol, but only the response of D. onoharaensum was interrupted consistently at most locations. Of 23 species of ambrosia beetles captured in our field trials, nine were
exotic and accounted for 70–97% of total catches of ambrosia beetles. Our results provide support for the continued use of
separate traps baited with ethanol alone and ethanol with (−)-α-pinene to detect and monitor common bark and ambrosia beetles
from the southeastern region of the US. 相似文献
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Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
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中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
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中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献