薄板坯连铸连轧流程低碳铝镇静钢组织细化的原因

薄板坯连铸连轧流程生产的低碳Al镇静钢普遍存在组织偏细，强度偏高的现象，这为高强度带钢生产提供了有利条件，但也为冷轧基料生产带来了一定的困难。国内外已对薄板坯连铸连轧流程生产的低碳Al镇静钢组织细化原因进行了大量的分析和研究，得到了一些认识。本研究表明，薄板坯连铸出坯后已有AIN沉淀析出，经均热后仍有约0．0030％的AIN未溶解。这些AIN微细沉淀对抑制奥氏体再结晶晶粒长大、抑制相变铁素体晶粒长大起到一定作用，使钢带组织细化；另外，薄板坯连铸连轧流程轧后冷却段长度偏短，冷却强度偏高也是造成组织细化，强度偏高的主要原因。     

薄板坯流程连铸连轧过程中的细晶化现象分析

研究了薄板坯连铸连轧工艺的铸坯凝固组织特征和钢带的组织演变规律。通过化学相分析、微观组织分析研究发现，微细AIN粒子在薄板坯连铸过程中可沉淀析出，铸坯经20～30min均热后AIN仅部分溶解。对AIN析出的热力学和动力学分析也证实了AIN在铸坯上沉淀析出的合理性。这些在连轧开始前原始奥氏体中析出的AIN沉淀是抑制变形奥氏体再结晶晶粒长大，细化奥氏体组织，并最终使钢带组织细化的主要原因；同时，薄板坯连铸连轧流程冷却辊道短、冷却强度大等因素也是导致薄板坯连铸连轧过程中Al镇静钢组织细化的主要原因。     

低碳铝镇静钢中AlN的沉淀析出

 利用热处理和化学相分析对薄板坯连铸连轧低碳铝镇静钢中AlN的沉淀析出行为进行了试验研究。结果显示,在薄板坯连铸连轧的低碳铝镇静钢中仅有很少量的氮被固定为AlN,大部分氮仍为自由氮,其原因是在薄板坯连铸连轧流程中的连铸出坯、均热、连轧和层流冷却等阶段,AlN在钢中很少沉淀析出。在热轧钢板卷取后的缓慢空冷过程中可以沉淀析出少量的AlN,这些AlN不能起到细化晶粒的作用。     

薄板坯连铸连轧流程V微合金化技术研究

本文基于薄板坯连铸连轧流程物理冶金特征,系统地研究了V的析出规律和V微合金钢的强化机理.结果表明,均热前铸坯中有大量细小V析出物,均热过程中部分析出物溶解,颗粒略有长大;铸坯中的细小析出物对抑制变形奥氏体再结晶晶粒长大有明显的作用,使试验钢具有晶粒尺寸为3～4μm的超细晶组织;组织超细化是导致薄板坯连铸连轧流程V微合金钢强度提高的主要原因.采用薄板坯连铸连轧流程V微合金化技术开发了屈服强度550MPa级HSLAS-F80高强钢,其组织均匀、晶粒超细化、强度高、成型性能和焊接性能优良.     

薄板坯连铸连轧的低碳铝镇静钢中AlN作用的试验研究

 对薄板坯连铸连轧的低碳铝镇静钢中AlN的作用进行了初步的试验研究。研究结果显示：当低碳铝镇静钢中酸溶铝含量在0.005%～0.043%时,钢中AlN的沉淀析出对热轧板材的晶粒度及力学性能没有明显影响,据此可以推测AlN的沉淀析出不是薄板坯连铸连轧低碳铝镇静钢晶粒细化的原因。在薄板坯连铸连轧的低碳铝镇静钢中仅沉淀析出很少量的AlN,这些AlN仅能起到很微弱的沉淀强化作用,因此AlN也不是低碳铝镇静钢中起沉淀强化作用的主要析出相。但是这些少量AlN的沉淀析出对热轧板材再加热时的晶粒长大却有明显影响：随钢中酸溶铝含量的增加,即随钢中AlN含量的增加,钢的晶粒粗化温度不断提高。     

珠钢电炉-薄板坯连铸连轧流程VN微合金钢组织性能研究

阐述了珠钢电炉-薄板坯连铸连轧流程VN微合金钢钒的析出规律、微观组织特征和强化机理。研究表明：在电炉-薄板坯连铸连轧流程采用VN微合金化,铸坯中析出以钒（C,N）为主,并有少量TiN或（Ti,V）（C,N）复合析出,平均粒度大约为40nm,热连轧开始前铸坯中大量存在的钒（C,N）能够抑制后续热连轧过程中变形奥氏体再结晶晶粒长大,使铁索体组织超细化;强化机制以细晶强化为主、沉淀强化为辅;采用VN微合金化技术开发的550MPa级VN微合金钢组织细化至3．0—4．0μm,产品具有良好的综合性能。     

CSP流程VN微合金钢的冶金学特征

在薄板坯连铸连轧生产中，微合金元素的溶解与析出过程，以及微合金元素与变形奥氏体再结晶、γ-a相变间的关系与传统厚板坯连轧有较大的差异，这为薄板坯连铸连轧流程生产微合金钢带来了一定的困难。研究表明，V～N的冶金学特征比较适合于CSP技术的特定工艺流程。对0．05％C—1.5％Mn-0．12％V-0．020％N钢，连铸出坯后已有大量微细V（CN）析出，均热后仅有部分沉淀溶解。这些铸坯中的微细沉淀对抑制变形奥氏体再结晶晶粒长大有十分重要的作用。在工业试生产中，铁素体晶粒尺寸为3～4pm的V—N微合金化超细晶粒钢已经试制成功，在CSP流程V—N微合金钢中，V的沉淀强化作用也显著提高了试验钢的强度水平。通过对VN微合金钢的超细组织控制和沉淀强化控制，在CSP流程上可生产屈服强度达550MPa级的低碳贫珠光体高强度钢。     

薄板坯连铸连轧流程试制取向硅钢抑制剂的析出特点

 在实验室模拟薄板坯连铸连轧流程试制取向硅钢的基础上,通过大量的透射电镜观察和分析检测,得到了脱碳退火后钢中形成的析出物的情况,确定了钢中的主抑制剂为Cu2S,同时还存在少量的辅助抑制剂AlN以及以复合析出物形式存在的微量的MnS。研究了Cu2S主抑制剂在薄板坯连铸连轧流程生产取向硅钢的析出特点,分析了实验用钢中Cu2S抑制力。结果表明,Cu2S作为薄板坯连铸连轧流程生产普通取向硅钢的主抑制剂有足够的抑制能力,能够满足CGO钢二次再结晶的要求。     

低温高磁感取向硅钢连铸与均热过程AlN与MnS析出的热力学

针对薄板坯连铸连轧流程结合"获得抑制剂法"所制备的低温高磁感取向硅钢,通过热力学计算研究了AlN与MnS在连铸与均热过程中的析出规律与行为。计算结果表明,连铸过程中AlN在凝固后的高温α相中便可能析出,而MnS仅可能在凝固后的α+γ两相区内析出。钢中AlN与MnS在均热过程中均处于部分固溶与部分析出的状态。后续高温渗氮处理后初次晶粒的异常长大并不明显,表明渗氮处理前钢中固有抑制剂的数量相对充足。     

薄板坯连铸连轧生产取向电工钢模拟实验

 在实验室条件下模拟薄板坯连铸连轧流程试制了取向电工钢。结果表明,实验室条件下模拟薄板坯连铸连轧流程生产取向电工钢是可行的。试制的电工钢成品磁感较好,铁损偏高。实验中,铸坯中柱状晶发达,有穿晶出现,铸坯心部有少量等轴晶。热轧板和常化板晶粒尺寸沿板厚方向有明显变化,组织沿板厚方向可分为表面脱碳层、过渡层、中心层。中间退火后晶粒细小,脱碳退火后晶粒细小均匀。试验中,常化和产品厚度对产品磁性能的影响不明显。     

China's Major Non-ferrous Metals Imports & Exports

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Zinc Production by Province in 2014

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80% of Chinese Firms Purchasing Overseas Mines Ended up in the Red

<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic     

Copper Processing Profit Dropped Sharply,Copper Consumption Will Face Impact in the Second Half of the Year

正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field,     

Central Geological Prospecting Fund Newly Added 16.47 Million Tonnes of Bauxite in 2013

正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF     

Manufacturers of Copper Tube for Central Air Conditioner Use Face Mounting Pressure in the Final Quarter of the Year

正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure     

Xinjiang Ranks No.1 in Production of Primary Aluminum in China

正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year,     

Shenhuo Coal Industry and Electricity Power Completed800,000 t/a Aluminum Project in Xinjiang

正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform.     

Guangdong Metal Transaction Center has Become the Second Largest Precious Metal Transaction Platform Nationwide

正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness.     

Seven Rare Earth Projects Involving Close to 3 Billion Yuan Investment Landed In the HighTech Zone

正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully.