共查询到19条相似文献,搜索用时 328 毫秒
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从物理和化学2方面分析了SCR催化剂的失活原因,在综述了目前国内外废弃SCR催化剂再生和回收处理研究进展的基础上,提出利用废弃SCR催化剂生产新SCR催化剂的新工艺。 相似文献
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随着SCR技术在燃煤电厂中的大规模应用,作为SCR技术核心的脱硝催化剂,由于受到锅炉烟气物理和化学方面的作用,性能逐渐下降,从而失活成为废旧脱硝催化剂。废旧脱硝催化剂一部分可以进行再生,但剩余大部分不可再生,废旧脱硝催化剂已被列为危险固体废弃物,如简单填埋处置,不仅浪费资源,而且可能对周边生态环境带来危害,因此开展废旧脱硝催化剂的回收利用的研究就显得尤为重要,文章就简述了近些年来废旧脱硝催化剂回收利用情况。 相似文献
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选择性催化还原(SCR)是目前应用最为广泛的烟气脱硝技术,催化剂是整个SCR脱硝系统的核心。在实际应用过程中,催化剂存在各种失活问题,其中砷中毒是催化剂失活的重要原因之一。本文详细阐述了SCR脱硝催化剂砷中毒的物理和化学失活机理,其中物理失活是由于As2O3在催化剂表面沉积、氧化造成催化剂孔道堵塞所致,而化学失活是由于砷氧化物破坏催化剂酸位点、改变活性基团形态、降低催化剂氨吸附及氧化还原能力所致。然后,系统介绍了抗砷中毒SCR脱硝催化剂的研发路线以及现有抗砷中毒催化剂优化改进的主要技术手段,主要包括调整催化剂孔隙结构、优化催化剂化学配方和烟气侧砷氧化物吸附固化等,其中MoO3是优选的催化剂活性助剂,金属元素(如Bi、In、Sn、Mg)是主要的抗砷助剂,钙基物质是典型的烟气侧砷氧化物吸附添加剂。最后,对砷中毒废弃催化剂的再生技术进行了简要介绍,包括湿法清洗、热还原法、复合再生等,在实际工业应用中,主要以物理清扫、湿法清洗配合活性组分添加的复合再生方式实现中毒催化剂再生。本文可对未来抗砷中毒SCR脱硝催化剂的研发与优化提供重要支撑。 相似文献
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The recent developments on the effect of H2O on deNOx performance of a variety of SCR catalysts selectively removing NOx by hydrocarbons in excess oxygen have been reviewed. In particular, the water tolerance of the catalyst is summarized to
illustrate a common deactivation behavior of SCR catalyst for the reduction of NO by hydrocarbons under wet feed gas mixture.
Earlier proposals elucidating the possible cause of the catalyst deactivation under wet conditions are discussed, focusing
mainly on the catalyst characteristics. A promising way, which can improve the water tolerance and the hydrothermal stability
of zeolite-based SCR catalyst, is also described. 相似文献
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SCR deactivation in a full-scale cofired utility boiler 总被引:3,自引:0,他引:3
Joshua R. Strege Christopher J. Zygarlicke Bruce C. Folkedahl Donald P. McCollor 《Fuel》2008,87(7):1341-1347
The Energy and Environmental Research Center installed a portable slipstream selective catalytic reduction (SCR) reactor in the convective pass of a utility boiler cofiring wood waste and Powder River Basin (PRB) coal. Catalyst sections were removed after 43, 128, and 171 days of operation. SCR catalytic activity was determined for each section, and a sample of one section was examined under a scanning electron microscope to look for signs of catalyst blinding and/or poisoning. The catalyst deactivated at an apparently inverse rate with an initial deactivation rate of 18% every 1000 h. The major mode of deactivation appeared to be pore blocking by combined alkali and calcium sulfate deposition and growth. 相似文献
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选择性催化还原(SCR)脱硝技术是目前主流的氮氧化物脱除技术,其核心是催化剂。凹凸棒石成本低廉,性能优越,适合用作SCR催化剂的载体,而且以凹凸棒石为载体的催化剂显示出良好的低温选择性和稳定性,具有很好的应用前景。本文总结了凹凸棒石低温SCR脱硝催化剂的研究进展,阐述了活性组分、制备方法、前体物种、活性组分负载量、煅烧温度、元素掺杂等因素对催化剂脱硝活性的影响,同时简要介绍了导致此类催化剂失活的原因以及失活催化剂的再生方法,并指出在凹凸棒石负载型低温脱硝催化剂上进行的SCR脱硝反应遵循E-R机理,最后指出此类催化剂的未来研究方向主要是进一步提高现有催化剂的低温催化活性和抗中毒能力,实现工业化应用。 相似文献
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V_2O_5-WO_3/TiO_2 SCR催化剂的失活机理及分析 总被引:3,自引:0,他引:3
催化剂是SCR烟气脱硝技术的核心,减缓催化剂的失活速率,延长催化剂的寿命对于降低SCR系统的运行成本有着非常重要的意义.描述了国内外文献中涉及的SCR催化剂的失活现象,列举了导致催化剂失活的各项因素,比较了碱金属、碱土金属、As和P及HCl等物质的影响规律及因素,并在此基础上总结了各类文献中提到的中毒机理:碱金属通过减少Bronsted酸性位的数量和削弱Bronsted酸性位的酸性导致催化剂中毒,碱土金属则能够在催化剂表面沉积进而造成孔结构的堵塞,催化剂的砷中毒是由气态的砷的化合物不断聚积,堵塞进入催化剂活性位的通道引起的,而磷对于催化剂的影响体现在其能够减小活性位的数量上.针对特定的失活机理,可以通过优化催化剂的特性来减缓催化剂的失活速率. 相似文献
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Joshua R. Strege Christopher J. Zygarlicke Bruce C. Folkedahl Donald P. McCollor 《Fuel》2006,85(17-18):2439-2444
Samples of ash collected from a full-scale utility boiler cofiring 80% wood waste with 20% Powder River Basin (PRB) coal were mixed with ground selective catalytic reduction (SCR) catalyst and exposed to simulated flue gas. Changes in mass were recorded with time, and mass gains were found to be highest without SCR catalyst present. Ash samples were analyzed before and after testing to determine what mechanisms had led to mass gain. The ash had reacted with gas-phase SO2 to form solid sulfates. Mass gain by sulfation would likely cause ash particles to grow and cover catalyst pores in the field, leading to catalyst deactivation and reduced NOx control. 相似文献