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利用溶胶-凝胶法制备了低含量Ni掺杂的TiO2光催化剂粉体,考察了催化剂在甲基橙水溶液中的重复使用性能,并用XRD、XPS和N2吸附-脱附等手段对催化剂进行了表征分析。结果表明,当掺杂Ni物质的量分数为0.3%和焙烧温度400 ℃时,制备的Ni/TiO2的光催化降解甲基橙水溶液的活性高于纯TiO2的光催化降解活性。Ni/TiO2光催化剂在水溶液体系重复使用过程中,催化活性急剧下降,重复使用性能较差。Ni掺杂使TiO2上产生具有较低结合能的低价钛离子如Ti3+,使表面缺陷(或氧空位)增加。比表面积和氧空位增加可能是Ni掺杂提高TiO2光催化活性的主要原因。Ni流失可能是Ni/TiO2在水溶液体系中重复使用性能较差的原因。 相似文献
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采用溶胶-凝胶法在玻璃纤维上涂层TiO2光催化剂,并掺杂Fe3+和Ce3+修饰TiO2光催化剂,进行了间歇式光催化降解气相苯实验,结果表明掺杂Fe3+和Ce3+均可以提高TiO2光催化剂的活性,其中0.2% Fe3+/TiO2光催化剂活性最好.借助XRD、SEM和XPS等表征手段来分析修饰前后的催化剂表面的物理化学性质变化,研究表面性质的变化对于光催化性能的影响.表征结果显示载体玻璃纤维表面均匀分布了粒径为40~60 nm的锐钛型TiO2微粒,0.2%Fe3+和Ce3+掺杂后催化剂表面Ti3+浓度增大,表面羟基浓度减小.催化剂表面的Ti3+会与被吸附氧气反应形成Ti4+并同时产生活性组分O-2,氧化剂O-2在光催化降解苯反应过程中起着重要作用. 相似文献
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掺杂铁纳米TiO2的制备及其光催化性能研究 总被引:7,自引:3,他引:7
分别采用水热法和溶胶-凝胶法制备了纳米级TiO2和不同掺铁量的TiO2纳米粒子。通过纯TiO2和掺铁TiO2分别作光催化剂时甲基橙溶液在紫外光下的光催化降解试验发现,溶胶-凝胶法掺杂铁离子可以有效地提高TiO2光催化活性,而水热法掺杂铁使TiO2的光催化活性明显降低。Fe/TiO2摩尔比为0.01%~0.1%,随掺杂量的增大,TiO2光催化活性逐渐降低。 相似文献
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掺镧纳米TiO2的光催化性能研究 总被引:5,自引:1,他引:5
研究了掺镧纳米TiO2的物理特性及光催化活性,探讨了它们之间的关系,通过对甲基橙和罗丹明两种不同结构物质的降解实验,发现掺镧纳米TiO2光催化性能具有广泛性。用于实际印染废水处理,再次验证掺镧能提高TiO2的光催化效能,掺镧摩尔分数为0.02%时光催化效果最好。 相似文献
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以钛酸丁酯为前驱物,在离子液体(1-丁基-3-甲基咪唑六氟磷酸盐)、水和无水乙醇所组成的混合溶剂中采用溶胶-凝胶法及微波干燥,制备了硫掺杂纳米TiO2光催化剂。采用XRD对催化剂的结构进行了表征,以甲基橙为模拟污染物,高压汞灯和卤钨灯为光源,考察了掺杂量、微波干燥等因素对硫掺杂TiO2光催化剂活性的影响。结果表明,硫掺杂TiO2催化剂活性高于未掺杂TiO2催化剂;且当硫脲与钛酸丁酯物质的量比为5.0,在家用微波炉于功率210 W干燥25 min,再在马弗炉600 ℃焙烧处理2 h制备的催化剂,具有最佳的光催化降解效果。 相似文献
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过渡金属离子掺杂纳米TiO2的相变与光催化活性 总被引:4,自引:0,他引:4
采用溶胶-凝胶法制备了掺杂Mo6+、Cr3+、Fe3+的改性纳米TiO2光催化剂,并分别在550℃和580℃下对其进行了热处理,考察了热处理温度对掺杂纳米TiO2相变和光催化活性的影响.通过光催化降解染料罗丹明B实验,对在不同热处理温度下Mo6+、Cr3+、Fe3+改性以及不同Mo6+掺杂量的TiO2光催化活性进行了评价,发现掺杂离子对TiO2光催化活性的影响与其对TiO2相转变的作用是一致的,即抑制相转变的同时也提高了光催化活性.实验结果也进一步表明,Mo6+掺杂量为0.05%(摩尔分数)时的TiO2具有最佳光催化活性. 相似文献
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Chien‐Te Hsieh Meng‐Hsuan Lai Ching Pan 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2010,85(8):1168-1174
BACKGROUND: In this study, visible‐light‐derived photocatalytic activity of metal‐doped titanium dioxide nanosphere (TS) stacking layers, prepared by chemical vapor deposition (CVD), was investigated. The as‐grown TS spheres, having an average diameter of 100–300 nm, formed a layer‐by‐layer stacking layer on a glass substrate. The crystalline structures of the TS samples were of anatase‐type. RESULTS: Ultraviolet (UV) absorption confirmed that metallic doping (i.e. Co and Ni) shifted the light absorption of the spheres to the visible‐light region. With increasing dopant density, the optical band gap of the nanospheres became narrower, e.g. the smallest band gap of Co‐doped TS was 2.61 eV. Both Ni‐ and Co‐doped TS catalysts showed a photocatalytic capability in decomposing organic dyes under visible irradiation. In comparison, Co‐doped TiO2 catalyst not only displays the adsorption capacity, but also the photocatalytic activity higher than the N‐doped TiO2 catalyst. CONCLUSION: This result can be attributed to the fact that the narrower band gap easily generates electron–hole pairs over the TS catalysts under visible irradiation, thus, leading to the higher photocatalytic activity. Accordingly, this study shed some light on the one‐step efficient CVD approach to synthesize metal‐doped TS catalysts for decomposing dye compounds in aqueous solution. Copyright © 2010 Society of Chemical Industry 相似文献
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Linhui Yu Yangming Lin Jing Huang Sen Lin Danzhen Li 《Journal of the American Ceramic Society》2017,100(1):333-342
Carbon‐doped TiO2 nanomaterials have been successfully synthesized via an effective two‐step procedure involving hydrothermal method and followed by a low‐temperature calcination treatment process, through which a controllable amount of carbonate‐like species could be incorporated into TiO2. First‐principles calculations suggest the TiO2 doped with carbon in form of carbonate‐like species can effectively extend the adsorption of the material from ultraviolet region to visible light. And it is experimentally found that carbon‐doped TiO2 nanomaterials exhibit much higher photocatalytic activity than reference P25 and TiO2?xNx catalysts toward the liquid‐phase degradation of organic pollutants under visible light (420 nm < λ < 800 nm) irradiation. The presence of synergic effect between carbonate‐like doping and anatase TiO2 is believed to play an essential role in affecting the photocatalytic reactivity, and the response to the visible light is ascribed to the narrowed band gap energy controlled by carbon doping. Moreover, the roles of active species in the photocatalytic process are compared using different types of active species scavengers. Meanwhile, the degradation mechanism of the photocatalysis is proposed. It is hoped that our work could provide valuable information on the design of carbonate‐like doped semiconductor with more excellent properties and set the foundation for the further industrial application. 相似文献
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Xiangxin Yang Chundi Cao Keith Hohn Larry Erickson Ronaldo Maghirang Dambar Hamal Kenneth Klabunde 《Journal of Catalysis》2007,252(2):296-302
C-doped and C- and V-doped TiO2 photocatalysts were prepared by a sol–gel process. Both catalysts showed high activity for the degradation of acetaldehyde under visible irradiation (>420 nm). The co-doped TiO2 catalysts also were highly active in the dark; 2.0% V-containing co-doped TiO2 had the highest activity, comparable with the activity under visible light irradiation. The catalysts were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS), and N2 adsorption–desorption. The results suggest that vanadium ions were introduced both on the surface and into the bulk of TiO2. A free electron, induced by the formation of V5+ in the sublayers of TiO2 during calcination at 500 °C in air, was delocalized and promoted into the conduction band by thermal energy and further transferred to O2, generating a superoxide radical anion (O−2) that is responsible for degradation of acetaldehyde in the dark. In addition to functioning as a photosensitizer that shifts the optical response of TiO2 from the ultraviolet (UV) to the visible light region, the doped elemental carbon increased the surface area and improved the dispersion of vanadium. 相似文献
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Rodrigo T. Bento Olandir V. Correa Marina F. Pillis 《Journal of the European Ceramic Society》2019,39(12):3498-3504
Titanium dioxide ceramic coatings have been used as catalysts in green technologies for water treatment. However, without the presence of a dopant, its photocatalytic activity is limited to the ultraviolet radiation region. The photocatalytic activity and the structural characteristics of undoped and sulfur-doped TiO2 films grown at 400 °C by metallorganic chemical vapor deposition (MOCVD) were studied. The photocatalytic behavior of the films was evaluated by methyl orange dye degradation under visible light. The results suggested the substitution of Ti4+ cations by S6+ ions into TiO2 structure of the doped samples. SO42? groups were observed on the surface. S-TiO2 film exhibited good photocatalytic activity under visible light irradiation, and the luminous intensity strongly influences the photocatalytic behavior of the S-TiO2 films. The results supported the idea that the sulfur-doped TiO2 films grown by MOCVD may be promising catalysts for water treatment under sunlight or visible light bulbs. 相似文献
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To enhance the photocatalytic activity of TiO2, V and Zn co-doped TiO2 films were synthesized by the sol–gel method. The experimental results indicated that the films were composed of round-like nano-particles or aggregates. V and Zn codoping could not only obviously increase the specific surface area of TiO2 but also result in the narrowed band gap of TiO2 sample. The photocatalytic activities of the TiO2 films were evaluated by the photocatalytic decomposition of organic dyes in aqueous solution. Compared with un-doped TiO2 film or single doped TiO2 film, V and Zn co-doped TiO2 film exhibited excellent photocatalytic activities under both UV light and visible light. The improvement mechanism by V and Zn codoping was also discussed. 相似文献
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Nanoparticles of TiO2 were synthesised by sol–gel technique and photo deposition of about 1% noble metal (M/TiO2, M = Ag, Au, and Pt) on TiO2 was carried out. The catalysts were characterised by XRD, TEM, BET, FT-IR, and UV–Visible spectroscopy. Using commercial TiO2 (P-25 Degussa), the conditions such as dye concentration, catalyst weight and pH were optimized for complete decolourisation of textile dye tartazine (TAZ) under UV and visible irradiations. Among the catalysts tested, the synthesised TiO2 showed better photocatalytic activity than TiO2 (P-25 Degussa). Whereas, M/TiO2 catalysts showed remarkable photocatalytic activity towards the decolourisation of TAZ even under visible irradiation. This enhanced activity of M/TiO2 catalyst may be attributed to the trapping of conduction band electrons by noble metals. 相似文献
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S–N co-doped anatase nanosized TiO2 photocatalyst was successfully prepared by simple sol–gel method. The samples were characterized by XRD, XPS, UV–Vis. From the results of UV–Vis, a red shift of the absorption edge was brought out owing to the S and N codoping. XPS and UV–Vis studies revealed that N and S were in situ codoped in the lattice of TiO2 and the absorbance in visible light region decreased with the calcination temperature increased. The photocatalytic activity was evaluated by the photocatalytic oxidation of penicillin solution under visible light irradiation. The results show that visible-light induced photocatalytic activities of the as-prepared TiO2 powders were improved by S–N copoing. The high activity of S–N co-doped TiO2 can be related to the results of the synergetic effects of strong absorption in the UV–Vis region, red shift in adsorption edge. 相似文献
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Sol−gel synthesis based on the self-assembling template method has been applied to synthesize Li–Y doped and co-doped TiO2 not only to improve simultaneously the structural and electronic properties of TiO2 nanomaterials but also to achieve Li–Y doping of titania with high photocatalytic reactivity. The characterization of the samples was performed by GXRD, GSDR, FT-IR, and Raman spectroscopy. According to the GXRD patterns, all the observed reflections can be indexed using the anatase form of TiO2, Which is confirmed by ground state diffuse reflectance and micro-Raman spectra. The Li–Y doped titania materials immobilized as nanostructured thin films on glass substrates exhibit high photocatalytic efficiency for the degradation of toluidine and benzoic acid under visible light irradiation. The development of these visible light-activated nanocatalysts has the potential of providing environmentally benign routes for water treatment. 相似文献