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对中国石油辽河石化公司0.6 Mt/a连续重整装置催化剂再生单元注氯系统出现的异常情况:再生注氯泵入口杂质聚集、再生注氯泵安全阀内漏、再生注氯泵入口管线冬季冻凝所引起的再生注氯异常情况进行分析并得出相应的结论及应对措施及建议。 相似文献
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重整催化剂再生过程中注氯量的调节 总被引:4,自引:0,他引:4
对重整催化剂再生过程氧氯化进行分析,提出了重整催化剂再生时注氯量的调节依据,根据近期内提升时第一反应器床层和出口温度的变化情况,得出了催化剂再生时水氯平衡的调节原则。 相似文献
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Chlorsorb氯吸附技术与碱洗技术的应用对比 总被引:1,自引:0,他引:1
介绍了传统碱洗技术与Chlorsorb氯吸附技术在连续重整装置中的工业应用情况,提出Chlorsorb氯吸附系统,流程简化、操作简单、操作成本较低,避免了催化剂再生单元因为碱洗系统堵塞而被迫停工的可能,同时也避免产生含碱、含盐废水的现象。但Chlorsorb氯吸附技术在国内的应用尚在起步阶段,其脱氯效果及对催化剂的影响还有待进一步考察。 相似文献
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根据连续重整装置不同部位的工艺特点,探讨了ET系列脱氯剂在连续重整装置的预加氢高温脱氯、重整产氢低温脱氯及连续重整再生循环气高温脱氯中的应用。结果表明:ET系列脱氯剂能较好地脱除重整进料、重整产氢和再生循环气中的氯化氢,较好地消除了氯化氢对装置的腐蚀隐患。 相似文献
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本文从离心式重整循环氢压缩机长期运行、氯腐蚀与氯结盐、重整催化剂活性3个方面分析了对固定床半再生重整装置长周期运行的影响:指出了固定床半再生重整装置长周期运行应努力的方向。 相似文献
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O.N. Cardoso 《Chemical engineering science》2003,58(18):4159-4172
Axial solid dispersion promoted by Taylor bubbles in a batch liquid column was studied. A mechanistic model was developed to predict the axial solid dispersion. The model is based on the upward transport of particles inside closed wakes of non-interacting Taylor bubbles. The model predictions are compared with experimental data. The experimental data were obtained in a test tube of internal diameter. The particle volumetric distribution was measured by several differential pressure transducers placed along the column. Two classes of glass beads, mean diameter 180 and , were suspended in aqueous glycerol solutions, with glycerol percentage ranging from 40% (v/v) to 100% (v/v). The amount of particles in the column was such that the volumetric particle fractions were 0.1, 0.2 and 0.3, supposing homogeneous liquid-solid suspension. The air flow rate ranged from 90×10−6 to at PTN conditions. The obtained experimental data are in good agreement with the model predictions for laminar wakes, i.e., closed wakes with internal recirculation and without vortex shedding. The experimental data show a higher upward particle transport for wakes in the transition laminar-turbulent regime; closed wakes with internal recirculation and vortex shedding. The upward particle transport is higher for increasing air flow rate, decreasing particle diameter and increasing amount of particles in the column. 相似文献
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López C.M. Machado F.J. Méndez B. Pinto M. Sazo V. Goldwasser J. Ramírez M.M. 《Topics in Catalysis》2000,10(1-2):65-71
The skeletal isomerization of 1butene was performed over a series of silicoaluminophosphate molecular sieves with AEL structure (SAPO11). The results were compared with those obtained over an aluminophosphate molecular sieve (AlPO411). The three SAPO11 samples, with different acidic properties, were synthesized by either varying the chemical composition of the synthesis gel or by varying the preparation time of the aforementioned gel. The catalytic results indicate that irrespective of how the acidity of the SAPO11 samples is changed (viz., independently of the method elected to modify the acidic properties of the samples), a close parallelism between the selectivity towards the skeletal isomerization and the number of (moderate + strong) Brønsted acid sites (sites retaining pyridine above 623 K) was observed for the SAPO11 solids. These results, definitively, indicate the participation of these acid sites in the skeletal isomerization process. 相似文献
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Studies of chemoreception in crustaceans have shown that flesh-eating species can detect amino acids, nucleotides and derivatives, and amines, while most herbivorous and omnivorous species are additionally sensitive to carbohydrates. We used extracellular recording techniques to evaluate the effectiveness of a range of nitrogen-containing compounds (mostly amino acids), bile acids, and carbohydrates in stimulating chemoreceptor cells present in the second and third pereopods of the omnivorous crayfish Procambarus clarkii. When applied at a final concentration of 100 M, effective stimuli were trehalose, leucine, cellobiose, glycine, sucrose, maltose, and ammonium (from most to least effective). The other 17 compounds tested, many chosen because they are potent stimuli for other crustaceans, were ineffective stimuli for P. clarkii. Concentration–response functions were determined for three single cells that were sensitive to ammonium, for five multiunit fibers sensitive to glycine, and for six multiunit fibers sensitive to leucine. Thresholds ranged from 10 nM to 10 M, functions were generally linear when plotted against the log of the stimulus concentration, and there was little evidence of saturation. While P. clarkii is sensitive to only seven of 24 compounds tested, the compounds that proved stimulatory should serve as cues for location and identification of food items preferred by this omnivorous crustacean. 相似文献
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Sequestration of Host Plant Glucosinolates in the Defensive Hemolymph of the Sawfly Athalia rosae 总被引:1,自引:1,他引:0
Caroline Müller Niels Agerbirk Carl Erik Olsen Jean-Luc Boevé Urs Schaffner Paul M. Brakefield 《Journal of chemical ecology》2001,27(12):2505-2516
Interactions between insects and glucosinolate-containing plant species have been investigated for a long time. Although the glucosinolate–myrosinase system is believed to act as a defense mechanism against generalist herbivores and fungi, several specialist insects use these secondary metabolites for host plant finding and acceptance and can handle them physiologically. However, sequestration of glucosinolates in specialist herbivores has been less well studied. Larvae of the turnip sawfly Athalia rosae feed on several glucosinolate-containing plant species. When larvae are disturbed by antagonists, they release one or more small droplets of hemolymph from their integument. This reflex bleeding is used as a defense mechanism. Specific glucosinolate analysis, by conversion to desulfoglucosinolates and analysis of these by high-performance liquid chromatography coupled to diode array UV spectroscopy and mass spectrometry, revealed that larvae incorporate and concentrate the plant's characteristic glucosinolates from their hosts. Extracts of larvae that were reared on Sinapis alba contained sinalbin, even when the larvae were first starved for 22 hr and, thus, had empty guts. Hemolymph was analyzed from larvae that were reared on either S. alba, Brassica nigra, or Barbarea stricta. Leaves were analyzed from the same plants the larvae had fed on. Sinalbin (from S. alba), sinigrin (B. nigra), or glucobarbarin and glucobrassicin (B. stricta) were present in leaves in concentrations less than 1 mol/g fresh weight, while the same glucosinolates could be detected in the larvae's hemolymph in concentrations between 10 and 31 mol/g fresh weight, except that glucobrassicin was present only as a trace. In larval feces, only trace amounts of glucosinolates (sinalbin and sinigrin) could be detected. The glucosinolates were likewise found in freshly emerged adults, showing that the sequestered phytochemicals were transferred through the pupal stage. 相似文献
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环保型阻燃湿法合成革的研制 总被引:1,自引:0,他引:1
用液态的磷酸酯阻燃剂对涤/棉配比基布进行浸渍处理,处理量占基布质量的5 %(干重比),可使基布达到美国FMVSS-302阻燃标准的B级阻燃效果。通过6种阻燃剂在聚氨酯树脂中的不同配比试验,考察了不同阻燃剂组合及其用量对聚氨酯树脂阻燃性能的影响。结果表明,氢氧化铝/间苯二酚双/磷酸酯(12/2/2 ,质量份,下同)复合阻燃剂配方体系所制试样燃烧速度为0 mm /min,阻燃效果可达到A级;将其涂覆于阻燃处理的基布上即可制得环保型阻燃合成革,阻燃性能可以通过多国的阻燃标准。 相似文献
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A. B. Filonow 《Journal of chemical ecology》1999,25(7):1555-1565
The fungus, Botrytis cinerea, causes decay in apples in postharvest storage. Conidia of B. cinerea on polycarbonate membranes were incubated on filter paper disks saturated with water or suspensions of yeasts (2 × 106 CFU/filter) and then exposed for 24 hr at 22°C to 0–16 l of ethyl, butyl, or hexyl acetates injected into the headspaces of 500-cc glass jars. Germination of conidia was increased by exposure to 4–16 l of ethyl acetate compared to the no-ester controls. Conidia were stimulated to germinate by 4 l of butyl acetate and 8 l of hexyl acetate, but greater volumes were toxic to germination. The yeasts Cryptococcus laurentii and Sporobolomyces roseus were more effective at reducing the stimulatory effect than Saccharomyces cerevisiae. Acetate esters also stimulated germination of conidia on polycarbonate membranes on apples inside jars. Cryptococcus laurentii or S. roseus suppressed this effect more than S. cerevisiae. Germination of conidia on a membrane on water inside a 3.9-liter jar containing an apple was 2.5-fold greater than the no-apple control. Butyl acetate increased Botrytis infection of apple wounds. Butyl and hexyl acetate were detected by GLC in the headspace of Golden Delicious apples. Results indicated that some acetate esters produced by apple stimulated germination of B. cinerea conidia, and this effect was suppressed by yeasts. 相似文献
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通过降低聚合温度,调整复合引发剂配比、链转移剂用量,加入抗“鱼眼”剂等方法进一步优化了工艺配方,制备出“鱼眼”数少、树脂质量好的聚合度为800的PVC树脂。 相似文献
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通过分析注射过程中PVC熔体在模具内的流动过程,指出了PVC-U管件制品“白斑”形成的原因,提出了在生产过程中消除“白斑”的方法,主要有调整工艺条件及配方、改进模具设计等。 相似文献