共查询到19条相似文献,搜索用时 78 毫秒
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《煤炭加工与综合利用》2015,(10)
结合我国柴油生产及使用中存在的问题,对甲醇制高十六烷值清洁柴油组分的优势进行了分析,指出燃用含DMMn配方的柴油,可大幅度减少污染物排放,是一种具有较好发展前景的柴油添加剂。 相似文献
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随着柴油质量标准的不断升级,催化裂化柴油因十六烷值低、芳烃含量高等特点,加工难度日趋增大。研究学者针对提高催化裂化柴油十六烷值开发出加氢改质、加氢转化、加氢处理-催化裂化组合、加氢裂化掺炼催化柴油等技术,各类技术在产品结构、产品质量、改造难度等方面各具特色。炼油企业可根据自身的需求选择适宜的技术,以实现柴油质量升级。某企业在应用了加氢裂化掺炼催化柴油技术、加氢处理-催化裂化组合技术后,柴油十六烷值有所提升,车用柴油比例由60%提升至94%,在每月加工1万t外购催化柴油的情况下,车用柴油比例仍维持80%以上。 相似文献
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柴油十六烷值改进剂的新工艺 总被引:1,自引:0,他引:1
以异戊醇和50%HNO3为原料,50%H2SO4为催化剂,尿素为反应稳定剂,合成了柴油十六烷值改进剂——硝酸异戊酯。通过实验确定了反应的最佳条件:在沸腾条件下,H2SO4:HNO3(mol:mol)为2:1,HNO3:异戊醇(mol:mol)1.3:1,加入尿素为HNO3的3%左右,可得到收率和纯度都较高的硝酸异戊酯,反应平稳安全。产品经红外光谱、密度及折光率分析证明为硝酸异戊酯。 相似文献
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Geokinetics crude shale oil, a distillate and processing intermediates sampled during four-stage catalytic hydroprocessing of the distillate were analysed for total nitrogen, basic nitrogen and olefinic and aromatic contents. Successive hydroprocessing stages yielded products containing 80, 46, 16 and 2% of the nitrogen content in the feedstock. Total nitrogen, basic nitrogen and aromatic contents were also reduced. Apparent relative reactivities of aromatic hydrocarbons and nitrogen-containing compounds are in agreement with reactivities observed in model compound studies. Hydrodenitrogenation of nitrogen-containing compounds occurred concurrently with hydrogenation of non-nitrogen-containing aromatic hydrocarbons. Hydroprocessing conditions necessary for essentially complete removal of nitrogen yielded a refined oil with low aromatic content. 相似文献
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A method of Structural Group Analysis (SGA) was used to characterize feed and liquid products from catalytic hydroprocessing using a commercial Ni-Mo catalyst. Comparison of the structural profiles revealed significant changes in the concentration of various structural groups. SGA is a promising tool for investigating chemical changes in complex reacting systems. 相似文献
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Karanja (Pongamia pinnata) oil, a non-edible high viscosity (27.84 cSt at 40 °C) straight vegetable oil, was blended with conventional diesel in various proportions to evaluate the performance and emission characteristics of a single cylinder direct injection constant speed diesel engine. Diesel and karanja oil fuel blends (5%, 10%, 15%, and 20%) were used to conduct short-term engine performance and emission tests at varying loads (0%, 20%, 40%, 60%, 80%, and 100%). Tests were carried out over the entire range of engine operation and engine performance parameters such as fuel consumption, thermal efficiency, exhaust gas temperature, and exhaust emissions (smoke, CO, CO2, HC, NOx, and O2) were recorded. The brake specific energy consumption (BSEC), brake thermal efficiency (BTE), and exhaust emissions were evaluated to determine the optimum fuel blend. Higher BSEC was observed at full load for neat petro-diesel. A fuel blend of 10% karanja oil (KVO10) showed higher BTE at a 60% load. Similarly, the overall emission characteristics were found to be best for the case of KVO10 over the entire range of engine operation. 相似文献
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The conversion of the esters included in refined cottonseed oil into hydrocarbon molecules compatible with petroleum diesel, which are named renewable diesel, has been studied at conventional hydrotreatment conditions. The vegetable oil was fed in mixture with desulphurized petroleum diesel to the hydrotreater containing a conventional CoMo/Al2O3 hydrotreatment catalyst. Conversion of esters was determined in the temperature range of 305-345 °C, at 30 bar and for 5 h−1 < WHSV < 25 h−1. Catalyst deactivation was followed for a period of 450 h in operation. A simple kinetic model of ester conversion suitable for scale-up and simulation studies has been tested. 相似文献
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Pavel Šimá?ek David Kubi?ka Iva Kubi?ková František Homola Milan Pospíšil Josef Chudoba 《Fuel》2011,90(7):2473-3322
Hydroprocessing of neat sunflower oil was carried out at 360-420 °C and 18 MPa over a commercial hydrocracking catalyst in a bench scale fixed bed reactor. In the studied experimental range, products consisted exclusively of hydrocarbons that differed significantly in composition. While the concentration of n-alkanes exceeded 67 wt.% in the reaction products collected at 360 °C, it decreased to just 20 wt.% in the product obtained at 420 °C. Consequently, the fuel properties of the latter product were very similar to those of standard (petroleum-derived) diesel fuel. Particularly, it exhibited excellent low-temperature properties (cloud point −11 °C; CFPP −14 °C). Reaction products obtained at 400 and 420 °C were blended into petroleum-derived diesel fuel in three concentration levels ranging from 10 to 50 wt.% and the fuel properties of these mixtures were evaluated. Diesel fuel mixtures containing the product of sunflower oil hydrocracking at 420 °C showed very good low-temperature properties including cloud point (−8 °C) and CFPP (−15 °C) that was further lowered to −25 °C due to addition of flow improvers. 相似文献
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Temperature effect on the viscosities of palm oil and coconut oil blended with diesel oil 总被引:1,自引:0,他引:1
One of the major difficulties in using crude vegetable oils as substitute fuels in diesel engines is their relatively high
viscosities. Increasing the temperature of the crude vegetable oil, blending it with diesel oil, or the combination of both
offers a simple and effective means of controlling and lowering the viscosities of vegetable oils. This work reports viscosity
data, determined with a rotational bob-and-cup viscometer, for crude palm oil and cononut oil blended with diesel oil over
the temperature range of 20–80°C and for different mixture compositions. All the test oil samples showed a time-independent
newtonian type of flow behavior. The reduction of viscosity with increasing liquid temperature followed an exponential relationship,
with the two constants of the equation being a function of the volume percentage of the vegetable oil in the mixture. A single
empirical equation was developed for predicting the viscosity of these fuel mixtures under varying temperatures and blend
compositions. 相似文献
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多产柴油催化剂CC-20D与助剂CA-100在催化裂化装置上的混合应用 总被引:1,自引:0,他引:1
本文介绍了多产柴油催化剂CC-20D与高效助辛并增产液化气助剂CA-100在克拉玛依石化厂重催装置上的混合应用情况。结果表明CC-20D具有增产柴油效果明显。抗污染能力强。产品选择性好等优点;CA-100提高辛烷值和增产液化气能力强。使用CC-20D并配合使用3%的CA-100时,柴油产率提高3.27wt%,液化气提高1.9wt%,总液收提高1.81wt%,汽油RON提高1.7,MON提高0.8,创造了较好的经济效益。 相似文献