月桂酸钠对天然胶乳与丁苯胶乳并用胶乳性能的影响

研究了月桂酸钠的不同用量对天然胶乳与丁苯胶乳并用胶乳胶体性能与胶膜的物理机械性能的影响.结果表明:随着月桂酸钠在并用胶乳中用量的增加,并用胶乳的黏度下降,表面张力的变化不大;月桂酸钠在并用胶乳中的用量为0.2％,NRL/SBRL为90/10时,并用胶乳胶膜的物理机械性能最好.     

丁苯胶乳与苯乙烯接枝共聚物的结构与性能

ＳＢＲ－ｇ－ｓ由丁苯胶乳与苯乙烯接枝改性制成。一种ＳＢＲ－ｇ－ｓ乳胶粒子具有核一壳结构,另一种是ＰＳ均聚物：在固体ＳＢＲ－ｇ－ｓ中,ＰＳ在含量不高于３５％时为分散相,含量为５％时为近连续相。ＳＢＲ－ｇ－ｓ接枝率的最高极限经为３５％。     

过氧化物预硫化天然胶乳硫化过程胶乳胶膜的热分析

用热重法-微商热重法(TG—DTG)和差热分祈(DTA)研究了用过氧化物预硫化胶乳过程中，硫化时间不同时胶乳胶膜热氧降解的过程。结果表明，过氧化物预硫化胶乳胶膜的起始降解温度、DTG峰顶温度和DTG峰的终止温度、起始放热温度和DTA峰顶温度均随硫化过程发生变化。     

非离子丁苯胶乳改性乳化沥青性能研究

采用自主研发生产的非离子丁苯胶乳作为改性剂,对不同基质沥青进行改性,考察改性乳化沥青的各项性能.并在高速公路进行推广应用,取得较好效果,为非离子丁苯胶乳改性乳化沥青在路面上的应用提供借鉴.     

丁苯胶乳接枝醋酸乙烯酯共聚改性的研究

为了改善丁苯胶乳(SB)与水泥的相容性,采用醋酸乙烯酯(VAc)单体与SB进行乳液接枝共聚。研究了单体浓度、引发剂和乳化剂的用量、反应温度、反应时间等对接枝率的影响,确定了最佳的接枝反应条件为:[VAc]=5.0mol/L;[(NH4)2SO3]=9.4×10-3mol/L;乳化剂C12H25SO3Na含量为4%(按单体质量计),温度80℃,时间3h。以IR测定了未接枝的的SB和接枝物的结构,比较二者的IR谱图,在1815.44cm-1、1753.91cm-1处有强吸收峰,表明接枝物含有羰基,从而证明VAc接枝到SB上。以SEM观察了胶乳的成膜性,接枝聚合物的成膜性远优于未接枝的SB膜;其拉伸强度显著提高。     

丁苯胶乳对路用沥青改性效果的研究

研究了 2种性质不同的丁苯胶乳对路用沥青的改性效果 ,并对改性机理进行了初步探讨 ,提出了 2种产品的应用设想。     

废丁苯胶乳/废聚酯纤维高强高模复合材料的制备与性能

采用液相高剪切混合、共沉预处理技术改善纤维在橡胶基体中的分散及其界面结合,制备了废丁苯胶乳/废聚酯纤维高强高模复合材料,并系统研究了复合材料的硫化特性、力学性能、动态力学性能和断面微观形貌。结果表明,当纤维的质量分数为60%时,复合材料具有最佳的力学性能,其拉伸强度为23.2 MPa,而未填充纤维的硫化胶强度仅为9.3MPa;同时,室温下材料的储能模量提高了约19倍。     

喷墨打印纸及其丁苯胶乳的合成

本文介绍了近年来几种照相级高光防水彩喷纸与普通纸型高速印刷喷墨打印纸的发明,以及喷墨打印纸用丁苯胶乳制造的技术要旨。指出,引进吸收、参考借鉴喷墨打印记录材料领域的国际先进专利技术,是以引进一消化吸收一再创新的模式继续推进我国喷墨打印记录材料领域的技术进步,增强企业核心竞争力的重要环节。     

细乳液聚合法合成大粒径羧基丁苯胶乳

采用新型的细乳液聚合技术,制备大粒径羧基丁苯胶乳。考察了制备工艺参数对反应动力学及产物性能的影响。研究发现,乳化剂浓度对细乳液稳定性及聚合动力学有较大影响。以HS作为乳化剂,能得到稳定的细乳液体系。随HS浓度增大,聚合体系的反应速率增大,胶乳粒子粒径减小。助稳定剂十六烷(HD)的加入对细乳液体系影响较大。随着HD浓度增大,转化率先降低后升高,乳胶粒径先升高后降低;功能单体衣康酸(IA)的加入使细乳液体系更加稳定。     

天然乳胶制品性能的影响因素研究进展

天然胶乳具有优异的综合性能,适宜制备各种乳胶制品。乳胶制品被广泛应用于日常生产生活中。制品性能受多种因素共同影响。从原材料、硫化工艺过程和后硫化处理3方面因素对胶乳制品性能的影响研究进展进行了阐述。最后指出探究各因素与性能间的关系对提高制品性能具有重要意义。     

Investigations on the addition of styrene butadiene rubber in natural rubber and dichlorocarbene modified styrene butadiene rubber blends

This paper focuses on the use of styrene butadiene rubber (SBR) as a viscosity modifier in novel blends of natural rubber (NR) and dichlorocarbene modified styrene butadiene rubber (DCSBR). The processing characteristics, vulcanisation kinetics, stress-strain behaviour, mechanical properties and low temperature transition of the blends have been examined in order to analyse the influence of SBR in the blends. The change in cross-link density values from stress strain behaviour and equilibrium swelling data has been correlated with the technological properties of the blends. The excellent mechanical properties and the increased cross-link density in blends in the presence of 5—10 phr of styrene butadiene rubber reveals the viscosity modifying action of SBR in NR/DCSBR blends. The variation in viscosities of these blends with the addition of SBR is reflected in the DSC thermograms. The resulting blends show very high resistance to thermal ageing as compared to those without SBR.     

改性淀粉/丁苯橡胶复合材料的制备及性能研究

采用固相法制备了玉米淀粉接枝马来酸酐(MAH)和苯乙烯(St)的共聚物Starch-g-MAH-St(SMS)。采用机械共混法制备了接枝改性淀粉/丁苯橡胶(SMS/SBR)复合材料,研究了复合材料的力学性能、热空气老化性能、动态力学性能以及微观形态。结果表明,SMS/SBR复合材料的力学性能优于未改性淀粉/SBR复合材料和纯SBR。当苯乙烯和MAH单体用量都为原淀粉质量的10 %且SMS的用量为20 g/100 g SBR时,SMS/SBR复合材料的力学性能最佳。经100℃ 热空气老化48 h后,复合材料的拉伸强度仍可达10 MPa。与纯 SBR硫化胶相比,SMS/SBR复合材料的玻璃化转变温度(T_g)降低。微观形态分析显示,淀粉经改性后粒子尺寸减小,在SBR 中的分散性得到了改善,与SBR基体的相容性得到了提高。      

Influence of carbon blacks on butadiene rubber/high styrene rubber/natural rubber with nanosilica: Morphology and wear

The effect of fillers on morphology and wear characteristics are studied in butadiene rubber (PBR)/high styrene rubber (HSR)/natural rubber (NR) blends with different types of carbon black. SAF N110 with SRF N774 type of carbon black shows a significant effect on curing studies and mechanical properties by reacting at the interface between PBR, HSR and NR matrix. Blends containing the same carbon blacks show high abrasion resistant properties against Du-Pont abrader, DIN abrader and different mining rock surfaces and also is found to be the toughest rubber against all types of rock.     

Effect of expanded graphite and modified graphite flakes on the physical and thermo-mechanical properties of styrene butadiene rubber/polybutadiene rubber (SBR/BR) blends

The aim of the present research work is to develop expanded graphite (EG) and isocyanate modified graphite nanoplatelets (i-MG) filled SBR/BR blends, which can substitute natural rubber (NR) in some application areas. The present study investigated the effect of i-MG on the physical, mechanical and thermo-mechanical properties of polybutadiene rubber (BR), styrene butadiene rubber (SBR) and SBR/BR blends in the presence of carbon black (CB). Graphite sheets were modified to enhance its dispersion in the rubber matrices, which resulting in an improvement in the overall physical and mechanical properties of the rubber vulcanizates. Compounds based on 50:50 of BR and SBR with ∼3 wt% nanofillers with CB were fabricated by melt mixing. The morphology of the filled rubber blends was investigated by wide angle X-ray diffraction (WAXD) and high resolution transmission electron microscopic (HR-TEM) analyses. The intercalated and delaminated structures of the nanofiller loaded rubber blends were observed. Scanning electron microscopic (SEM) analysis of the cryo-fractured surfaces of the rubber compounds showed more rough and tortuous pathway of the fractured surfaces compared to the fractured surfaces of the only CB loaded rubber composites. Filled rubber compounds exhibit increase in the ΔS (torque difference) value, reduced scorch and cure time compared to their respective controls. Dynamic mechanical thermal analysis (DMTA) of the filled rubber compounds shows an increase in the storage modulus compared to the controls. Isocyanate modified graphite nanoplatelets (i-MG) containing rubber compounds in the presence of CB showed an increase in the mechanical, dynamic mechanical, hardness, abrasion resistance and thermal properties compared to the alone CB filled rubber vulcanizates.     

聚乙烯/废天然橡胶的老化和力学性能研究

通过汞灯辐射试验对制备的聚乙烯/废天然橡胶共混物进行了紫外老化试验,研究了防老剂4010对聚乙烯/废天然橡胶的紫外老化性能的影响。结果表明:老化初期聚乙烯/废天然橡胶(60/40)的拉伸强度提高,老化中后期聚乙烯/废天然橡胶拉伸强度下降。防老剂4010的加入提高了聚乙烯/废天然橡胶的紫外老化性能。     

白炭黑补强环氧化溶聚丁苯橡胶

为探究环氧化对白炭黑(SiO₂粒子)在溶聚丁苯橡胶(SSBR)基体中分散性的作用,首先,以SSBR和环氧化溶聚丁苯橡胶(ESSBR)为基体,白炭黑为补强填料,分别制备了SiO₂/SSBR、SiO₂/ESSBR混炼胶和硫化胶;然后,采用FTIR、SEM和其他测试方法研究了材料的结构、形貌、硫化特性、耐磨性能、准静态力学性能和动态力学性能。结果表明:随环氧度从0增大到14.73%,生胶的门尼黏度增大。ESSBR分子链中的环氧基团与SiO₂粒子表面的硅羟基反应形成稳定的化学键,抑制SiO₂粒子团聚,促进其均匀分散;当环氧度为6.87%时, SiO₂粒子在ESSBR中的分散性最好。随环氧度增大, SiO₂/ESSBR硫化胶的拉伸强度先增大后减小、耐磨性能先增强后减弱、断裂伸长率降低、100%和300%定伸强度增大、玻璃化转变温度升高、0℃时的损耗因子显著增大、抗湿滑性增强、60℃时的损耗因子略有增加且滚动阻力增大。因此, SSBR硫化胶经环氧化改性后综合性能提高,当其环氧度在6.87%~8.51%范围内时, SiO₂/ESSBR硫化胶的综合性能最优。      

Structure and properties of polylactide/natural rubber blends

Polylactide, PLA, is a biodegradable thermoplastic polyester derived from biomass that has restricted packaging applications due to its high brittleness and poor crystallisation behaviour. Here, new formulations based on natural rubber–PLA blends have been developed. The processing windows, temperature, time, and rotor rate, and the rubber content have been optimised in order to obtain a blend with useful properties. The rubber phase was uniformly dispersed in the continuous PLA matrix with a droplet size range from 1.1 to 2.0 μm. The ductility of PLA has been significantly improved by blending with natural rubber, NR. The elongation at break improved from 5% for neat PLA to 200% by adding 10 wt% NR. In addition, the incorporation of NR not only increased the crystallisation rate but also enhanced the crystallisation ability of PLA. These materials are, therefore, very promising for industrial applications.     

Effect of fillers on natural rubber/high styrene rubber blends with nano silica: Morphology and wear

The blends of high styrene rubber (HSR) and natural rubber (NR) with nano silica were prepared using a blending technique in presence of different types of carbon black. The effect of filler on morphological and wear characteristics was studied. ISAF (Intermediate Super Abrasion Furnace) type of carbon black have showed a significant effect on optimum cure time, cure rate index and mechanical properties by reacting at the interface between HSR and NR matrix. All the samples show only one melting peak on the DSC curve; this is attributed to the same backbone structure of the matrix and the carbon black reinforcement. The samples containing 30 wt.% of HSR with ISAF type of carbon black has shown maximum heat buildup, lower swelling and lower compression set value. Blends containing ISAF type of carbon black with 30 wt.% of HSR showed high abrasion resistant properties against Du-Pont abrader, DIN abrader and different mining rock surfaces and also is found to be the toughest rubber against all types of rock. Coal is main abrader against the rubber under this study.     

Effect of fillers and nitrile blended PVC on natural rubber/high styrene rubber with nanosilica blends: Morphology and wear

The blends of high styrene rubber (HSR) and natural rubber (NR) with nitrile blended PVC (NVC) and nanosilica are prepared by using a blending technique in presence of different types of carbon black. The effect of filler on morphological and wear characteristics is studied. ISAF type of carbon black have showed a significant effect on optimum cure time, cure rate index and mechanical properties by reacting at the interface between NVC, HSR and NR matrix. All the samples show only one melting peak on the DSC curve; this is attributed to the same backbone structure of the matrix and the carbon black reinforcement. The samples containing 20 wt.% of NVC with ISAF N234 type of carbon black has shown maximum heat buildup and lower compression set value. Blends containing ISAF type of carbon black with 20 wt.% of NVC shows high abrasion resistant properties against Du-Pont abrader, DIN abrader and different mining rock surfaces and also is found to be the toughest rubber against all types of rock. Coal is identified the main abrader against the rubber blends under this study.