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酯化法合成聚酰亚胺泡沫塑料的研究 总被引:2,自引:0,他引:2
以3,3',4,4'-二苯酮四酸二酐、3,3',4,4'-二苯醚四酸二酐、4,4'一二胺基二苯甲烷、4,4'-二胺基二苯醚和4,4'-二胺基二苯砜为单体,甲醇和四氢呋喃混合溶剂,采用酯化法制备了5种聚酰亚胺(PI)泡沫塑料.红外光谱分析证实,由二酐的二酸二酯和二胺反应生成了聚酯铵盐前驱体(PEAS),且通过微波辐照发泡方法由PEAS粉末成功制得了PJ泡沫塑料.结果表明,5种PI泡沫塑料平均密度为11 kg/m<'3>,阻燃性能和耐高温性能优异,四元共聚型的P14和P15泡沫塑料压缩永久形变最小、耐高温性能最佳. 相似文献
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聚酰亚胺泡沫塑料开发研究概述 总被引:9,自引:0,他引:9
介绍了聚酰亚胺泡沫塑料的6种合成方法和制备工艺中所应注意的几个方面(发泡方法、泡孔大小和形状控制等)。并综述了聚酰亚胺泡沫塑料的高低温性、高抗拉强度、高弹性模量、耐辐射性、高介电性能等优异的性能及其在透波材料、阻尼材料、耐高温材料、低放气材料、低温材料、复合材料、介电材料等方面的应用。聚酰亚胺泡沫塑料的发展还应有更广阔的空间。 相似文献
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喷雾干燥法制备粉末橡胶及其硫化性能研究 总被引:1,自引:2,他引:1
以超声分散的炭黑悬浮液填充天然胶乳,采用喷雾干燥法制备粒径小于5μm的粉末橡胶。结果表明,对于固形物质量分数约为0.1的炭黑/天然胶乳悬浮液,当喷雾干燥机的浆料进口温度约180℃、进给量约15%、吸气量为100%时,粉末橡胶制备过程较为顺利且制得的粉末橡胶颗粒细小、尺寸均匀;在相同的硫化条件下,与机械混炼法相比,喷雾干燥法制得的粉末橡胶硫化性能显著改善,硫化曲线的转矩峰值提高约1倍;粉末橡胶对氧化锌、硬脂酸、硫黄、促进剂CZ和DM的需求量更大,当以上小料用量均提高至普通机械混炼胶料2倍时,粉末橡胶硫化曲线的转矩峰值大幅度提高,由约30 N.m提高至约60 N.m,比普通机械混炼胶料提高约3倍。 相似文献
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本文论述了以烷基苯磺酸钠代替国外Pluconics F-108表面活性剂,在水分散体系中制备乙烯-醋酸乙烯共聚物(EVA)粉末的方法。结果表明:EVA颗粒在水分散体系中以无机碱类和无机盐类作为助分散剂,使用国产普通烷基苯磺酸钠,在高速搅拌状态下,可以制得粒度分布范围较窄,粒径在40~200目的球状粉末。该粉末与深冷法加工的粉末相比,具有外形呈球状,粒度均匀的特点,因此更适合于热熔粘合衬芯布的加工上。 相似文献
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爆炸法生产网化聚氨酯泡沫塑料 总被引:3,自引:0,他引:3
以聚醚多元醇、聚合物多元醇、甲苯二异氰酸酯及多种添加剂为原料,采用水发泡,制成块状软质聚氨酯泡沫塑料;将其放入网化箱中,充入氢气与氧气,混合均匀后,引爆,制得网状泡沫塑料,介绍了块泡生产的基本配方,爆炸法网化工艺过程,对氢气与氧气的用量及混合时间进行了讨论,并介绍了网化泡沫的物理性能。 相似文献
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A polyimide powder was prepared from 3,3′,4,4′-biphenyl tetracarboxylic dianhydride (BPDA) and 4,4′-oxydianiline (ODA). Polyimide powder having low molecular weight was prepared by imidizing low-molecular-weight polyamic acid. The molecular weight of this polyimide powder increased on heating in a solid state. The molecular weight increased with the decrease of crystallinity of polyimide. © 1996 John Wiley & Sons, Inc. 相似文献
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In this article, the foaming processes of polyimide foams and its reinforced foams were observed by a self‐made visualization device at different heating rates ranging from 10°C/min to 120°C/min. Contributing factors such as chemical structure of polyimide, fillers, and heating rate were investigated to determine the effects on the inflation onset temperature and morphological change of polyimide foam precursor powders. The results showed that the powder might grow into a single bubble mesostructure at a lower heating rate or a multibubble mesostructure at a higher heating rate. Because of the filling of reinforcing fillers, the inflation morphology of reinforced polyimide foam precursor powders show a different change trend with the increase of temperature compared to the pure polyimide foam precursor powders. For all kinds of polyimide foam precursor powders investigated in this article, the inflation morphologies showed a similar variation trend with different heating rates, and the final inflation degrees were slightly different. The inflation onset temperatures of all polyimide foam precursor powders studied decreased with increasing heating rate. POLYM. COMPOS., 2010. © 2008 Society of Plastics Engineers 相似文献
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A new high‐temperature resistance polyimide foam was synthesized from 2,3,3′,4′‐biphenyltetracarboxylic dianhydride (α‐BPDA) and p‐phenylenediamine (p‐PDA). The structures and foaming process of polyimide precursor powders were characterized by wide‐angle X‐ray diffractometer (WXRD) and the self‐made visualization device, respectively. The imidization degree, thermal mechanical properties and thermal stability of the polyimide foams with different post‐treatment temperatures were also measured by fourier transform infrared spectrometer spectrum (FTIR), dynamic thermal mechanical anaylsis (DMTA), and thermogravimetric analysis (TGA). Results showed that the inflation onset temperatures of polyimide precursor powders ranged from 122 to 135°C with varying the heating rate. And the increase in the imidization degree, glass transition temperatures (Tg) and temperatures for 5 wt% mass loss of high‐temperature resistance polyimide foams can be achieved with increasing post‐treatment temperature. It was quite surprising to find that Tg of high‐temperature resistance polyimide foam post‐treated at 420°C was up to above 450°C, and the char yield at 800°C was more than 60%. POLYM. ENG. SCI., 2010. © 2010 Society of Plastics Engineers 相似文献
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Preparation and properties of rigid polyimide foams derived from dianhydride and isocyanate 总被引:1,自引:0,他引:1
A series of rigid polyimide (PI) foams were synthesized via the reaction of a first solution with a second solution. The first solution was isocyanate‐terminated polyimide prepolymers; the second solution contained deionized water and surfactant. The effect of different water contents and isocyanate index on the structures and properties of rigid PI foams were investigated. The apparent density, hardness, compressive strength, and the 5% weight loss temperatures (T5%) decreased with the increase of water content. With the increase of isocyanate index, the apparent density and the T5% values decreased, whereas the glass transition temperatures (Tg) increased and the hardness, compressive strength first increased and then decreased. The rigid PI foams composed of closed‐cells were confirmed by scanning electron microscopy. The maximum compressive strength of rigid PI foams prepared was up to 1.31 MPa. Moreover, excellent thermal stability was presented with the T5% values were all above 360°C and the residual weights of the foams (Rw) were more than 50% at 800°C. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
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《中国胶粘剂》2019,(10)
先将石墨粉预处理,后采用化学镀法与配制的镀液制备镍包石墨粉,最后加入聚酰亚胺树脂超声制备镍包石墨粉聚酰亚胺导电胶。对合成的镍包石墨粉进行SEM(扫描电镜)表征,探讨超声时间对剪切强度的影响、使用温度和填料含量对体积电阻率的影响、固化温度对电导率的影响以及导电胶在镀铜基板和镀锌基板上接触电阻的比较。研究结果表明:化学镀温度为80℃时,镍包石墨粉包覆效果良好;超声时间15 min、固化温度170℃、填料含量8%制备的导电胶性能较佳,且导电胶使用温度不宜超过200℃;导电胶在镀铜基板上的老化表现优于镀锌基板。制备的镍包石墨粉聚酰亚胺导电胶基本达到了作为导电胶的使用需求,进一步研究应用具有一定的市场前景。 相似文献
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A novel polyimide/silver (PI/Ag) foam was prepared by isocyanate foaming and direct ion exchange between Ag+ ions from silver nitrate and the H+ ions in the carboxyl (–COOH) groups of the polyamide molecular chain. The microstructures, chemical and phase composition of the PI/Ag foams were tested by SEM, FT-IR and XRD. The properties were tested by TG, DSC and UV spectrophotometer. The effects of different Ag contents on the microstructures and properties were analysized. SEM results showed that the PI/Ag foams had present the opened-cells type. With the increase in the Ag+ ions contents, both the amount of silver particles and the UV reflectivity of the PI/Ag foams increased, as the size of silver particles decreased. FT-IR test results show that the introduction of the silver nano-particles have no significant effect on the chemical structure of the PI foams. XRD results indicate that the silver nano-particles are face-centered cubic structure and have good crystalline properties. Thermal tests results show that the PI/Ag foams maintain the excellent thermal stability. Based on the above experimental results, the reaction mechanism during the foaming and curing process were also analysized. 相似文献
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Preparation of polyimide composite membranes by a chemical vapor deposition and polymerization process (CVDP) was studied for the development of pervaporation or gas separation membranes. Hexafluoroisopropylidene-2,2-bis [phethalic acid anhydride] (6F-dianhydride) (6FDA) and 4,4′-diaminodiphenyl ether (ODA) were used as monomers and were simultaneously deposited on an asymmetric polyimide membrane in vacuum of 10−6 Torr. The deposited layer of the monomers was converted to polyimide by heating at 250°C at 3 h in an ordinary vacuum oven, and its separation performance for water-ethanol and CO2−N2 systems was characterized. 相似文献