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用注塑成型方法制备了抗冲嵌段共聚聚丙(烯PP-B)试样,研究了工艺条件的改变对PP-B力学性能的影响。结果表明:注射速率和模具温度与PP-B弯曲强度、弯曲模量成正相关,而与冲击强度、拉伸强度的关系较为复杂;模具温度的升高有利于结晶度的提高,PP-B刚性上升,韧性下降;注射速率改变引起的剪切、拉伸流动使熔体发生取向流动,从而使沿取向方向上的强度升高,垂直取向方向上的强度降低;保压压力对PP-B性能的影响主要是通过熔体非晶部分在保压阶段的分子定向作用来实现的,随着保压时间的延长,PP-B塑件密度提高缺,陷减少拉,伸强度弯、曲模量呈增大趋势。 相似文献
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采用红外光谱仪、核磁共振谱仪、凝胶渗透色谱仪、差示扫描量热仪、扫描电子显微镜及动态流变仪研究汽车保险杠用抗冲共聚聚丙烯的结构与性能。结果表明,国产料与进口料的结构基本相同,性能已达到甚至超过进口料,可代替进口料使用。 相似文献
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利用扫描电子显微镜(SEM),研究了溶剂刻蚀时间、刻蚀溶剂种类(正庚烷、正辛烷、邻二甲苯)、外力作用(超声与不超声)对所观察到的抗冲共聚聚丙烯(IPC)相形貌的影响。研究结果表明:对具有不同相对分子质量的乙烯-丙烯无规共聚物(EPR)的IPC,溶剂刻蚀时间会对观察到的相形貌产生较大影响;利用正庚烷、正辛烷作为刻蚀溶剂,均仅观察到1种相态结构,而以邻二甲苯作为刻蚀溶剂,可以观察到4种核壳分散相态结构。 相似文献
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介绍了兰州石化聚丙烯装置,开发与生产高抗冲共聚产品SP179的主要工艺参数、产品结构和性能。同时确定了聚丙烯环管工艺生产超高抗冲产品的技术指标,最后对SP179产品做出了全面的性能测试。 相似文献
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可控流变共聚PP的制备工艺及力学性能 总被引:1,自引:0,他引:1
用可控流变法降解共聚聚丙烯(PP)获得可控流变共聚PP。考察了基础树脂、过氧化物加入量、工艺参数对最终产品力学性能的影响。研究发现:在QP73N加入少量过氧化物便能显著改善流动性;根据基础树脂和最终产品的熔体流动指数可确定过氧化物的加入量;各种工艺参数对流变性能的影响由大到小依次为:温度、喂料转速、主机转速;喂料转速与主机转速之比越小,熔体流动指数越高;对降解产品力学性能的各项指标影响最大的因素都是挤出温度,其次是喂料转速和主机转速。 相似文献
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注塑成型工艺对透明PP光学性能的影响 总被引:1,自引:0,他引:1
采用不同的工艺条件注塑成型无规共聚透明聚丙烯(PP),测试透光率、雾度和表面光泽度,分析了成型工艺参数对制品光学性能的影响。所选透明PP的最佳注塑工艺为:加工温度220~230℃,模具温度40~60℃。在保证制品顺利成型的情况下应尽量采用较小的注塑压力。注塑速率和注塑时间对制品的光学性能影响较小。 相似文献
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Dynamic injection processing experiments have been carried out on polypropylene using the self‐made electromagnetic dynamic plastics injection molding machine, and the effects of the vibration force field on mechanical properties of molding samples are studied, namely, the influence of vibration frequency and vibration amplitude on the mechanical properties of samples are researched by using tensile testing, impact testing, differential scanning calorimeter (DSC) and scanning electronic micrograph (SEM) techniques. The results show that the tensile strength and impact strength are both enhanced and the melting point shifts toward the higher temperature, which facilitates the perfection of crystal. The best vibration parameters for processing polypropylene using electromagnetic dynamic plastics injection molding machine are that frequency is from 3 to 9 Hz and amplitude is from 0.1 to 0.4 mm. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 972–976, 2006 相似文献
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Impact-resistant polypropylene copolymer (IPC) samples with various pre-shear histories were prepared by a Brabender Rheometer. The influence of pre-shearing on crystallization of IPC, including isothermal and nonisothermal crystallization behaviors was investigated by differential scanning calorimetry (DSC) and polarized optical microscopy (POM). The results of nonisothermal crystallization showed that compared with as-received IPC, the temperatures referred to the peak of crystallization exotherm, Tp, were prominently elevated for pre-sheared IPC. In isothermal crystallization experiment, combining Avrami Method and Hoffman-Lauritzen Model, it was found that the half-time of crystallization (t1/2) of pre-sheared IPC was greatly shortened and the calculated fold surface free energy (σe) within the isothermal temperatures investigated showed a large reduction. Morphological development during isothermal crystallization observed by POM clearly confirmed that the enhancement in crystallization is mainly due to the fast formation of nuclei during crystallization. Besides, using successive self-nucleation and annealing (SSA) thermal fractionation technique, changes in chain structures induced by pre-shearing were obtained. The relaxation behavior of pre-sheared IPC was also evaluated and it was found that the shear-induced enhancement in crystallization could be relaxed to various extents under annealing conditions. 相似文献
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Polypropylene/sawdust composites have been prepared according to a statistical experimental design, with varying sawdust and compatibilizer (maleic anhydride grafted PP) concentrations. To investigate process conditions, composites were first extruded in a twin screw extruder coupled to a Haake torque rheometer, without degassing, and then reextruded in a Werner Pfleiderer twin screw extruder, with two degassing zones. Process conditions were analyzed according to statistical techniques. Effect of the variables on mechanical properties was assessed through flexural modulus, tensile strength, and percent elongation at break and morphology was assessed by scanning electron microscopy. Comparison between the extruded and reextruded compounds indicated the need to reduce moisture, prior to and during processing, as well as the need of effective mixing of the compounds. Sawdust concentration showed to be the variable which affected most all properties assessed. Increase in sawdust concentration resulted in increased composite stiffness. The presence of the compatibilizer caused a slight increase in tensile strength and reduction in percent elongation at break, indicating improved adhesion at the PP/sawdust interface. The reprocessed compounds were also analyzed by differential scanning calorimetry. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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The goal of the present work is the examination of maleic anhydride (MAn) grafted impact-resistant polypropylene (I-PP), consisting of amorphous rubber and semicrystalline matrix. A special instrument to separate the rubber from the matrix is preparative temperature rising elution fractionation (TREF). Investigations of the isolated fractions permit conclusions on the course of the grafting reaction and side reactions during the modification. The present work has shown that the fractionation is just as possible in the modified products as in the raw material. It has also shown that a grafting reaction occurs mainly in the rubber phase of this two-phase polypropylene. During the grafting reaction, only small degrees of radical degradation of the homopolymeric polypropylene matrix could be detected. © 1997 John Wiley & Sons, Inc. 相似文献