Effects of rare earth on inclusions and corrosion resistance of 10PCuRE weathering steel

The types,morphologies and distributions of nonmetallic inclusions in Cu-P weathering steels with and without rare earth were analyzed through a quantitative image analyzer,scanning electron microscopy(SEM)and energy dispersive spectroscopy(EDS)attached to SEM.Solid-soluble content of rare earth in the steels was analyzed by non-aqua electroanalysis and ICP.The results showed that rare earth modified the types and the morphologies of inclusions in the weathering steels.The small spherical rare earth oxysulfides and rare earth sulphides replaced the elongated MnS inclusions in the RE weathering steels.The rare earth inclusions dispersedly distributed and most inclusions were smaller than 2 μm in size.The optimum content of RE was 0.0065%-0.016% for 10PCuRE weathering steels containing about0.002% oxygen and 0.004% sulfur.Solid-soluble content of rare earth in steels was(14-20)x 10-6,which can act as a micro-alloying element.The corrosion resistance of 10PCuRE weathering steels and Q235 were studied by dry-wet cyclic immersion test.Their corrosion rates were obtained respectively.The polarization curves and pitting corrosion behaviors of weathering steels with and without rare earth were measured by electrochemical methods.The corrosion resistance of Cu-P weathering steels was improved by adding an appropriate amount of rare earth.Less and fewer rare earth inclusions largely decreased pitting susceptibility and rate of pit propagation.The pitting potential and the resistance against pitting corrosion of the RE weathering steel were significantly improved due to the modification of rare earth to inclusions.     

Lanthanide NIR luminescence for telecommunications, bioanalyses and solar energy conversion

Present-day advanced technologies heavily rely on the exciting magnetic and spectroscopic properties of lanthanide ions. In particular, their ability to generate well-characterized and intense near-infrared (NIR) luminescence is exploited in any modern fiber-optic telecommunication network. In this feature article, we first summarize the whereabouts underlying the design of highly luminescent NIR molecular edifices and materials. We then focus on describing the main trends in three applications related to this spectral range: telecommunications, biosciences, and solar energy conversion. In telecommunications, efforts concentrate presently on getting easily processable polymer-based waveguide amplifiers. Upconversion nanophosphors emitting in the visible after NIR excitation are now ubiquitous in many bioanalyses while their application to bio-imaging is still in its early stages; however, highly sensitive NIR-NIR systems start to be at hand for both in vitro and in vivo imaging, as well as dual probes combining magnetic resonance and optical imaging. Finally, both silicon-based and dye-sensitized solar cells benefit from the downconversion and upconversion capabilities of lanthanide ions to harvest UV and NIR solar light and to boost the overall quantum efficiency of these next-generation devices.     

Evaluation of D113 cation exchange resin for the removal of Eu(Ⅲ) from aqueous solution

Batch adsorption experiments were conducted for the adsorption of Eu(Ⅲ) ions from aqueous solution by D113 resin. The results indicated that D113 resin could adsorb Eu(Ⅲ) ion effectively from aqueous solution. The adsorption was strongly dependent on pH of the medium with enhanced adsorption as the pH turned from 3.50 to 7.00 and the optimal adsorption condition was in HAc-NaAc medium with pH value of 6.50. The maximum uptake capacity of Eu(Ⅲ) ions was 290.9 mg/g D113 at 298 K, at an initial pH value of 6.50. The overall adsorption process was best described by Lagergren-first-order kinetics. When Freundlich and Langmuir isotherms were tested, the latter had a better fit with the experimental data. The thermodynamic parameters such as free energy (G) which were all negative, indicated that the adsorption of Eu(Ⅲ) ions onto D113 resin was spontaneous and the positive value of enthalpy (H) showed that the adsorption was endothermic in nature. Thomas model was applied to experimental column data to determine the characteristic parameters of column useful for process design. Furthermore, Eu(Ⅲ) could be eluted by using 3.0 mol/L HCl solution and the D113 resin could be regenerated and reused.     

Phase structure and temperature dependent luminescence properties of Sr2LiSiO4F: Eu2+ and Sr2MgSi2O7: Eu2+ phosphors

Green-emitting Sr2LiSiO4F:Eu2+ and blue-emitting Sr2MgSi2O7:Eu2+ phosphors were synthesized by the conventional high temperature solid-state route,respectively.Their structures and photoluminescenee properties were comparatively investigated.It was found that the mixture phases of Sr2MgSi2O7 and SrF2 were obtained when a part of Sr2+ in Sr2LiSiO4F was replaced by some amount of Mg2+ in order to design the possible SrMgLiSiO4F:Eu2+ phosphor.Based on the photoluminescence analysis,Sr2LiSiO4F:Eu2+ phosphor exhibited a green broad emission band of main peak at 513 nm under the excitation of 365 nm,while the Sr2MgSi2O7:Eu2+ and SrMgLiSiO4F:Eu2+ phosphor showed blue emission centered at 467 nm.The temperature dependent photoluminescence properties and room temperature decay time for the three kinds of phosphors were also discussed in this paper.     

Er3+-substituted W-type barium ferrite: preparation and electromagnetic properties

Er3+-substituted W-type barium ferrites Ba1-xErx(Zn0.3Co0.7)2Fe16O27(x=0.00,0.05,0.10,0.15,0.20)were synthesized by polymer adsorbent combustion method.Samples were characterized by X-ray diffraction analysis(XRD),X-ray fluorescence(XRF),scanning electron microscopy(SEM)and network analyzer to investigate the relationships among Er3+concentration,crystal structure,surface mcrphology and electromagnetic properties.All the XRD patterns showed pure phase of W-type barium ferrite when x≤0.15,while the impurity phase of ErFeO3 appeared when x=0.20.The pure W-type barium ferrite showed a hexagonal flake shape.In addition,the microwave electromagnetic properties of samples were analyzed in the frequency range of 2-18 GHz.It was indicated that the electromagnetic properties were significantly improved when Er3+doping content was 0.10.The reasons were also discussed using electromagnetic theory.The optimized ferrite exhibited excellent microwave absoption performance.The maximum of reflection loss(RL)reached about-27.4 dB and RL was below-10dB at the frequency range from 8.4 GHz to 18 GHz,when the thickness was 2.6 mm.     

EXAFS investigation and luminescent properties of nanosized Tb: Lu2O3 phosphors

Nanosized terbium doped Lu2O3 phosphors were synthesized via a modified co-precipitation processing.The as-prepared Tb:Lu2O3 phosphors was consisted of well crystallized nanosized sphere particles with a diameter of about 30 nnx Local structure of Tb ions in Lu2O3 lattice was investigated by an analytical approach based on Fourier transformation of the extended X-ray absorption fine structure(EXAFS) data.X-ray near edge structure (XANES) spectra suggested that all Tb ions doped were tervalonce.EXAFS results indicated that Tb ions have entered the Lu2O3 cubic lattice by means of solid solution.The coordination number and first shell Tb-O distance dropped with the increasing of Tb concentration.Emission spectra of the phosphors was shown to be typical for Tb3+ with main components at 542,550 and 490 nm,derived from irradiative relaxation of 5D4 level.The emission intensity decreased severely with the increasing of Tb concentration from 1 mol.% to 15 tool.%,suggesting a significant concentration quenching above 1 mol.% Tb.The reduction of emission intensity was interpreted by higher distortion derived relaxation among the surface state resident Tb3+ ions.     

Multi-Pass Simulation of Heavy Plate Rolling Including Intermediate Forced Cooling

Thermomechanical Controlled Processing (TMCP) including accelerated cooling after the final hot rolling pass is a well-established technology,widely applied in HSLA steel plate production.However,there are still certain limitations,especially for thicker plate.The rolling schedule includes a long holding period (HP) after the roughing stage to allow the temperature to fall sufficiently for optimised TMCP during finishing.Intermediate Forced Cooling (IFC) applied during the HP can increase productivity by decreasing the required hold time,can restrict austenite grain growth,and can also improve the subsequent strain penetration in thick plate with further metallurgical benefits.Multi-pass plane strain compression (PSC) tests have been performed on the thermomechanical compression (TMC) machine at Sheffield University including different severities of IFC.Clearly it is impossible to simulate all aspects of the temperature and strain gradients present in thick plates in laboratory specimens,and most of the tests were conducted at temperatures and strains calculated by Finite Element modelling as relevant to specific positions through the plate thickness.However,some aspects of the gradients were addressed with tests using cold platens.The results have indeed shown that IFC can shorten the HP and reduce austenite grain growth and its variation across thick plate.     

Overview of Particles and Bubbles in Continuously Cast Steel

This paper gives an overview of phenomena associated with particles and bubbles in continuously cast steel. During steel processing from deoxidation to solidification the inclusion population undergoes changes with opportunities of removal. Flotation is an important separation mechanism. Inclusion particles may accumulate in the solidifying strand, thus forming enriched bands, which depend on the type of casting machine. Bubbles are created during inert gas injection. They also change in size, can float out, but also form accumulation bands. The interaction of bubbles and particles is discussed. Internal structure that recently has been observed on the inner surface of bubbles will be reviewed.     

烦恼 快乐 艺术——池莉“人生三部曲”解读

池莉的"人生三部曲"--<烦恼人生>、<不谈爱情>、<太阳出世>诉尽了普普通通的市民烦恼,小说中主人公被柴米油盐、吃喝拉撒、老婆孩子等琐事所烦着,从而构成他们的"烦恼人生".然而池莉通过自己的艺术创作,以积极的人生态度,又让读者体会到生活本身的快乐,"烦恼人生"中包含着"快乐人生".     

属性块在工程图形中的研究与应用

介绍了在工程图形中用属性块标注表面粗糙度的方法.采用属性块不仅能避免大量重复性的工作,还能节省大量的存储空间,具有提高绘图速度、质量,便于修改,资源共享等应用价值.     

Drawdown due to Temporally Varying Pumping Discharge: Inversely Estimating Aquifer Parameters

A ramp kernel method is proposed for accurately calculating the drawdown due to any temporal variation in pumping discharge. The use of the ramp kernels assumes the linear variation between the two consecutive measured pumping discharges. The prior studies assume a rectangular variation between the two consecutive measured pumping discharges. In the rectangular variation, a uniform pumping rate is assumed during a time span. An analytical equation for calculating the ramp kernel is derived. An optimization method is used with the proposed ramp kernels for inversely estimating the aquifer parameters from drawdown due to an arbitrary unsteady pumping discharge. Unlike the prior methods, the proposed method accurately identifies the parameters even when the sampling interval for the drawdown and pumping discharge is longer than that needed for assuming a linear variation. The proposed method outperforms the prior method. Application of the proposed method is illustrated using examples.     

Below-Average Bidding Method

The low-bid method, typically used for competitive bidding in the United States, may result in a contract with a firm that submits either accidentally or deliberately an unrealistically low-bid price. Such an occurrence hurts both the owner and the contractor by promoting disputes, increased costs, and schedule delays. To address this problem, other countries have adopted bidding methods based on the average of the bids submitted. One such approach is the below-average method where the winning bid is closest to but below the average of all bids. A competitive bidding model for the below-average-bid method is presented and its merits relative to the average-bid method and the low-bid method are explored. The below-average-bid process is investigated analytically and through Monte Carlo simulation. The results of bidding models for the below-average, the average, and the low-bid methods are presented in four easy-to-use nomograms which allow contractors to determine the optimal lump-sum bid price for each method without the need for complicated analysis. A comparison of the three methods provides information and insights to help owners with the difficult choice of a suitable bidding method for the project at hand.     

Failure Resistance of Historic Stone Bridge Structure of Charles Bridge. II: Susceptibility to Floods

The paper is a follow-up to the first part devoted to an analogical problem investigated with a view to the degradation of the stone structure due to the effects of nonstress load, and it deals with the probability problem of the bridge structure collapse under the effect of an extreme flood wave. The paper presents the results of the numerical analysis of the response of the historic stone bridge structure of Charles Bridge of the 14th century to the flood wave effect simulated by angular rotation, subsidence, and shifting in the footing bottom of a bridge pier. Special focus is on the effect of interventions into the stone bridge structure dating back to the last major overhaul of 1967–1975, particularly, on the effect of the reinforced concrete slab (tie plate) connecting the opposite bridge breast walls increasing the rigidity of the breast walls and their structurally efficient connection to the vaults of the bridge arches. The numerical analyses performed point out the prevailing negative effects of the implemented interventions in terms of structural rigidity of the stone bridge structure exposed to the effect of a flood wave.     

Case Study of Fluvial Modeling of River Responses to Dam Removal

A plan was made to remove Matilija Dam on the Ventura River. With dam removal, the delta in the reservoir and the downstream channel were expected to undergo major changes in morphology. The FLUVIAL-12 model was employed to simulate reservoir and river channel responses after dam removal. As a first step, the model was calibrated using the Ventura River data to establish its validity. In calibration, the model was used to simulate the fluvial processes starting from the time of dam completion. The simulated sediment deposition above the Matilija Dam matches closely with the deposits measured by the U.S. Bureau of Reclamation. A large amount of sediment was stored in the reservoir; some of the stored sediment would be transported downstream after dam removal. An important consequence of dam removal is the major increase of sediment release to the river channel downstream. The sediment supply to the downstream reach is not only from the stored sediment in the reservoir but also from natural sediment inflow from the upstream watershed. Therefore, sediment supply to the downstream reach will exceed the natural sediment flow before the dam presence. This situation tends to overload the downstream reach with sediment, resulting in excessive deposition. The amount of sediment release from the area above the removed dam is closely related to the changes in reservoir morphology. It is necessary to model changes in the channel bed profile and channel width during erosion in order to determine the amount of sediment removal. The amount of sediment release may not be simulated using an erodible-bed model but it may be determined using an erodible boundary model.     

Addition of Cobalt to Lead Anodes Used for Oxygen Evolution—A Literature Review

A review of the literature dealing with the effect of cobalt on lead-based anodes for oxygen evolution during electrolysis of sulfuric acid solutions verifies that the presence of cobalt at the anode–electrolyte interface, either as constituent of the anode material or as ions in the electrolyte, catalyzes the evolution of oxygen and reduces the corrosion of the anodes and the contamination by lead of metal cathodes produced during electrowinning. However, due to harmful effects of cobalt ions on the cathodic reaction in some processes, these benefits are limited to the electrowinning of copper. Efforts to develop a way of introducing cobalt at the anode–electrolyte interface without interfering with the cathodic reactions are reviewed in this paper. The use of lead–cobalt alloy anodes has had limited success due to issues arising from the low solubility of cobalt in lead, segregation during casting of the alloys, and nonuniform distribution of cobalt which affects the integrity of the anodes. This has been overcome in part lately by inclusion of cobalt into only the surface layer of a lead or lead alloy substrate, by thermal treatment of a cobalt salt to form a catalytic cobalt oxide surface species, or by electrodeposition of composite lead–cobalt oxide anodes. The last approach in particular has been actively investigated by several groups, but to our knowledge it is yet to find application in the industry. The review also critically examines the likely reaction mechanisms involved.     

Stability of I-Walls in New Orleans during Hurricane Katrina

Failures of I-walls during Hurricane Katrina were responsible for many breaches in the flood protection system in New Orleans. Six breaches were examined in detail by Task Group 7 of the Interagency Performance Evaluation Taskforce. Four of these failures and breaches, which occurred before the water levels reached the top of the wall, were not caused by overtopping erosion. The failure of the I-wall at the 17th Street Canal resulted from shear through the weak foundation clay. The south failure of the London Avenue I-wall was caused by subsurface erosion, which carried massive amounts of sand inland, and removed support for the wall, leading to catastrophic instability. At the north breach on London Avenue, the failure was caused by high pore pressures, combined with a lower friction angle in the loose sand, which resulted in gross instability of the I-wall under the water pressure load from the storm surge. Looking back, with the benefit of 20-20 hindsight, these stability and erosion failures can be explained in terms of modern soil mechanics, exploration techniques, laboratory test procedures, and analysis methods. An important factor in all of the cases investigated was development of a gap behind the wall as the water rose against the wall and caused it to deflect. Formation of the gap increased the load on the wall, because the water pressures in the gap were higher than the earth pressures that had acted on the wall before the gap formed. Where the foundation soil was clay, formation of a gap eliminated the shearing resistance of the soil on the flood side of the wall, because the slip surface stopped at the gap. Where the foundation soil was sand, formation of the gap opened a direct hydraulic connection between the water in the canal and the sand beneath the levee. This hydraulic short circuit made seepage conditions worse, and erosion due to underseepage more likely. It also increased the uplift pressures on the base of the levee and marsh layer landward of the levee, reducing stability. Because gap formation has such important effects on I-wall stability, and because gaps behind I-walls were found in many locations after the storm surge receded, the presence of the gap should always be assumed in I-wall design studies.     

Experimental Study and Numerical Simulation on Concrete Box Culverts in Trenches

Concrete culverts in trenches have been widely used in expressways. Problems frequently take place because of improperly estimated vertical earth pressures on culverts. Different codes have been used in China to estimate the design load on culverts. In this study, a full-scale experiment and FEM simulation were conducted to evaluate the variation of vertical earth pressures and soil arching in backfill and to examine the accuracy of the methods recommended by different design codes including the prevailing Chinese General Code for Design of Highway Bridges and Culverts based on the linear earth pressure theory. The measured vertical earth pressures from the experiment were compared with those from the current theoretical methods. The variations of foundation pressure and settlement were also analyzed. The FEM simulation investigated the key influencing factors on the vertical earth pressures including the height of the embankment fill, the width of the trench, the slope angle of the trench, the dimensions of the culvert, the properties of the backfill, and the elastic modulus of the foundation soil. This research reveals that soil arch formed when the backfill on the culvert reached a certain height, but it was unstable. The coefficient of the vertical earth pressure on the top of the culvert was significantly different from that recommended by the Chinese General Code for Design of Highway Bridges and Culverts.     

New Orleans Levee System Performance during Hurricane Katrina: London Avenue and Orleans Canal South

Hurricane Katrina was one of the worst natural disasters in U.S. history. The effects of the hurricane were particularly devastating in the city of New Orleans. Most of the damage was due to the failure of the levee system that surrounds the city to protect it from flooding. This paper presents the results of centrifuge models conducted at Rensselaer Polytechnic Institute and the U.S. Army Corps of Engineers simulating the behavior of the levees at London Avenue North and South that failed during Hurricane Katrina. Those levees failed without being overtopped by the storm surge. Also included are the results of a centrifuge model of one levee section at Orleans Canal South, which did not fail during the hurricane. The key factor of the failure mechanism of the London Avenue levees was the formation of a gap between the flooded side of the levee and the sheetpile. This gap triggered a reduction of the strength at the foundation of the protected side of the levee. The results are fully consistent with field observations.     

Leaching Behavior of Lead, Chromium (III), and Zinc in Cement/Metal Oxides Systems

This paper reports the study of the leaching behavior of cement/metal oxides mixtures containing lead, chromium (III) and zinc oxides. A fractional factorial design of experiments (24?1) was carried out considering four factors, the concentration of ZnO, Cr2O3, PbO, and Fe2O3 in the formulations. Iron oxide was also included in the experimental design as it is usually the main constituent of industrial wastes from thermal processes, where lead, chromium and zinc oxides are also found. After 56 days of curing, samples were subjected to the Acid Neutralization Capacity Test and the concentrations of Cr, Zn, and Pb were determined in the leachate at different pH after filtering. The output variables for the analysis of the experimental data were the concentration of metals at initial pH (in water), at pH 9, 7, and 4, and the acid neutralization capacity of the samples at pH 9. The analysis of the results indicates that the immobilization of Zn and Pb in Portland cement is poor; these metals behave as their amphoteric hydroxides. However, the leaching of Cr (III) is in the range found in the control sample, indicating that the stabilization of Cr (III) is successful.     

Coherent Structures in the Flow Field around a Circular Cylinder with Scour Hole

Large-eddy simulation (LES) and laboratory-flume visualizations were used to investigate coherent structures present in the flow field around a circular cylinder located in a scour hole. The bathymetry corresponds to equilibrium scour conditions and is fixed in LES. The flow parameters in the simulation correspond to the experimental conditions in which the approach flow is fully turbulent. Detailed consideration is given to the interaction of the horseshoe vortex (HV) system within the scour hole with the detached shear layers formed from the cylinder, and the near bed turbulence. It is found that the overall structure of the HV system varies considerably in space and time, though a large, relatively stable, primary necklace vortex is present at practically all times inside the scour hole. The simulation captures the presence of bimodal chaotic oscillations inside the HV system, as well as the sharp increase in the resolved turbulent kinetic energy levels and pressure fluctuations reported in prior experimental investigations. High levels of the mean bed shear stress are observed beneath the primary necklace vortex, especially over the region where the bimodal oscillations are strong, as well as beneath the small junction vortex at the base of the cylinder. It is also found that the detachment and advection of patches of vorticity from the downstream part of the legs of the necklace vortices can induce large instantaneous bed shear stress values. When the critical bed shear stress value for sediment entrainment on a flat surface is adjusted for bed slope effects, the LES simulation correctly predicts that the distribution of the mean bed shear stress is consistent with equilibrium scour conditions.