Magnetic field enhanced radio frequency ion source and its application for Siincorporation diamond-like carbon film preparation

Various ion sources are key components to prepare functional coatings,such as diamond-like carbon(DLC)films.In this article,we present our trying of surface modification on basis of Si-incorporation diamond-like carbon(Si-DLC)produced by a magnetic field enhanced radio frequency ion source,which is established to get high density plasma with the help of magnetic field.Under proper deposition process,a contact angle of 111°hydrophobic surface was achieved without any surface patterning,where nanostructure SiC grains appeared within the amorphous microstructure.The surface property was influenced by ion flow parameters as well as the resultant surface microstructure.The magnetic field enhanced radio frequency ion source developed in this paper was useful for protective film applications.     

国外最新消息

美国NRG能源公司将建造更多的核电厂美国NRG能源公司执行总裁David Crane表示,公司将拥有更多的核电厂,包括计划在得克萨斯州建造的两座机组。(编译自路透社2007年11月6日报道)     

《原子能科学技术》征稿简则

须包括题目、作者姓名、作者单位、城市名、省名和邮政编码,并应写成叙述性文摘(含有研究目的、方法、结果和结论);关键词3～8个。3)文稿应采用阿拉伯数字进行分级编号。引言不编号,也不写引言字样。4)基金项目名称及项目编号、作者简介(第1作者姓名(出生年—)、性别(民族,汉族略)、籍贯、职称、学位、从事     

国外最新消息

切尔诺贝利核电机组完成最后一次卸料工作2008年4月23日,切尔诺贝利核电厂完成了其3号机组的最后一次卸料工作。此次卸料工作的完成,意味着切尔诺贝利核电厂已完成了所有的机组卸料工作。(编译自世界核新闻网站2008年4月24日报道)     

国际原子能机构成员国

1957年阿富汗、阿尔巴尼亚、阿根廷、澳大利亚、奥地利、白俄罗斯、巴西、保加利亚、加拿大、古巴、丹麦、多米尼加共和国、埃及、萨尔瓦多、埃塞俄比亚、法国、德国、希腊、危地马拉、海地、罗马教廷、匈牙利、冰岛、印度、印度尼西亚、以色列、意大利、日本、大韩民国、摩纳哥、摩洛哥、缅甸、荷兰、新西兰、挪威、巴基斯坦、巴拉圭、秘鲁、波兰、葡萄牙、罗马尼亚、俄罗斯联邦、塞尔维亚和黑山、南非、西班牙、斯里兰卡、瑞典、瑞士、泰国、突尼斯、土耳其、乌克兰、英国、美国、委内瑞拉、越南1958年比利时、厄瓜多尔、芬兰、伊朗伊斯兰共和国、卢森堡、墨西哥、菲律宾、苏丹     

茜素红的辐射降解研究

用60Co γ射线辐照茜素红水溶液,研究该染料的辐射降解特性.通过对辐照前后茜素红的紫外可见光谱、脱色率、总有机碳(Total organic carbon,TOC)去除率的研究.探讨了吸收剂量、初始浓度、溶液pH值、H2O2加入量、在不同气体饱和条件下对茜素红溶液降解和矿化效果的影响.结果表明,辐射技术能有效降解茜素红染料,在空气饱和双氧水浓度为4mmol/L的条件下,吸收剂量为7.5kGy时,茜素红脱色率可达98%,TOC去除率可达70%.     

前言

由中国文物保护技术协会释光与电子自旋共振测定年代专业委员会(挂靠在上海博物馆)和中国国家地震局地质研究所共同主办的全国第十次释光(Luminescence)与电子自旋共振(ESR)测定年代学术讨论会于2006年11月6-10日在杭州的浙江省地震局培训中心召开.来自内地和香港的大学、中国科学院及部委研究所和文博系统32个单位的专家、学者出席了讨论会.这次讨论会共有27篇论文在会上作了交流,内容涉及热释光(TL)、光释光(OSL)和电子自旋共振测定年代的理论、方法和技术;考古和地质样品年代的测定及其应用;陶瓷器古剂量的测定;释光特性与矿藏成因;热释光、光释光测量仪器研制和改进等.本选编辑录了其中13篇论文予以发表.     

一株耐辐射菌的分离与初步鉴定

对新疆古尔班通古特沙漠土样中分离到的一株耐辐射菌RL2进行了多相分类鉴定.结果发现,此菌为革兰氏阳性,球形,菌落为淡红色;菌株的(G C)mol%含量为71.62%;16S rDNA序列分析表明,菌株RL2的16S rDNA基因序列与D.radiodurans DSM20539T同源性最高(97.2%).通过表型及系统进化树分析,确定RL2菌种分类应归于Deinococcus菌属,并可能是该菌属中的-个新种.     

Activated persulfate by DBD plasma and activated carbon for the degradation of acid orange Ⅱ

In this study, the effect of activated peroxydisulfate(PDS) by dielectric barrier discharge(DBD) plasma and activated carbon(HGAC) on the removal of acid orange Ⅱ(AOⅡ) was investigated. The effects of applied voltage, PDS dosage, HGAC dosage, initial pH value, and inorganic anions on the removal rate of AOⅡ were discussed. The main free radicals degrading azo dyes during the experiment were also studied. Experimental results show that the removal rate of AOⅡ in DBD/HGAC/PDS synergistic system is much higher than that in the single system. With the applied voltage of 16 kV, HGAC dosage of 1 g l-1, PDS and AOⅡ molar ratio of 200:1, initial pH value of 5.4 and concentration of AOⅡ solution of 20 mg l-1, the removal rate of AOⅡ reached 97.6% in DBD/HGAC/PDS process after 28 min of reaction.Acidic and neutral conditions are beneficial for AOⅡ removal. Sulfate and hydroxyl radicals play an important role in the removal of AOⅡ. Inorganic anions are not conducive to the removal of AOⅡ.     

高温熔盐试验回路系统设计及验证研究

钍基熔盐堆核能系统（TMSR）计划建设热功率2 MW的液态燃料熔盐堆。在熔盐泵、换热器、冷冻阀等设备原理样机研制基础上,需要设计并建造高温氟盐回路对上述设备进行运行考验。首先设定熔盐-空气换热器换热功率为200 kW,根据经典热量方程及预定流速法确定系统流量为15 m3/h、管径为DN50（公称直径为50 mm）。采用Fluent数值计算确定系统压损为155 kPa,考虑一定裕量后熔盐泵扬程确定为20 m。为解决管道在高温工况下热应力集中问题,除熔盐泵固定安装外,加热器及换热器设计采用了万向球移动支承结构以增加系统柔性。自建成以来,回路累计运行超过4000 h,相关设备及系统结构设计得到验证。系统实际压损为110~120 kPa,仍需采用差压计进行实测验证。熔盐杂质含量分析表明,系统运行后Cr、Mo等杂质元素含量提高了2个数量级,说明存在材料腐蚀。回路内水氧含量控制水平需要在100 μL/L设计限值基础上进一步提高。      

The protective performance of a molten salt frozen wall in the process of fluoride volatility of uranium

The fluoride volatility method(FVM) is a technique tailored to separate uranium from fuel salt of molten salt reactors. A key challenge in RD of the FVM is corrosion due to the presence of molten salt and corrosive gases at high temperature. In this work, a frozen-wall technique was proposed to produce a physical barrier between construction materials and corrosive reactants.The protective performance of the frozen wall against molten salt was assessed using FLiNaK molten salt with introduced fluorine gas, which was regarded as a simulation of the FVM process. SS304, SS316 L, Inconel 600 and graphite were chosen as the test samples. The extent of corrosion was characterized by an analysis of weight loss and scanning electron microscope studies. All four test samples suffered severe corrosion in the molten salt phase with the corrosion resistance as: Inconel 600 SS316 L graphite SS304. The presence of the frozen wall could protect materials against corrosion by molten salt and corrosive gases, and compared with materials exposed to molten salt, the corrosion rates of materials protected by the frozen wall were decreased by at least one order of magnitude.     

石墨慢化通道式熔盐堆的稳态热工水力计算模型

针对石墨慢化通道式熔盐堆的堆芯结构,基于COMSOL Multiphysics程序和MATLAB程序建立了堆芯稳态热工水力学计算模型。该模型对堆芯内固体区域的温度分布采用三维热传导方程进行模拟,对通道内熔盐温度采用一维单相流体模型进行计算。固体区域与熔盐通过熔盐通道壁面的对流换热边界建立热耦合。该模型基于平行通道压力损失相等的原则,分配堆芯内各熔盐通道的流量。通过对比RELAP5程序的计算结果,验证了模型对温度和流量分配计算的正确性。针对2 MWt 液态燃料熔盐堆的一种概念设计,分析了堆芯内三维温度分布和通道间流量分配。该模型可精确计算通道式熔盐堆堆芯内稳态温度分布和流量分配,对堆芯的热工水力学设计具有重要意义。     

熔盐冷冻壁应用中关键工艺影响因素研究

在熔盐堆燃料干法处理流程中,处理设备面临着严重的材质腐蚀问题。熔盐冷冻壁技术被视为保护相关设备耐受化学腐蚀的有效方法,而冷冻壁厚度的稳定控制是干法处理流程应用冷冻壁技术实现处理工艺目的的关键。基于自行研制的冷冻壁实验装置,模拟了干法处理中熔盐冷冻壁的应用工况,考察了导热油进口温度、熔盐初始温度、加热器功率、冷冻壁初始厚度对冷冻壁厚度变化的影响,得到了各个因素的影响规律,并总结了最佳的应用工艺条件。利用热流量的变化分析了冷冻壁厚度变化的原因:热流量越大,冷冻壁厚度减小量越大,达到平衡时,热流量越大,冷冻壁平衡厚度越小。通过实验数据拟合得到了线热流密度与冷冻壁平衡厚度的关系式,平均相对误差11.2%。     

Corrosion behavior of Hastelloy-N alloys in molten salt fluoride in Ar gas or in air

The effects of air on the corrosion of Hastelloy-N alloys in molten salt coolant containing fission product elements were investigated to determine the safety of structural materials in high-temperature reactors cooled with fluoride salt. Corrosion tests of Hastelloy-N in the molten fluoride salt FLiNaK in an alumina crucible and a graphite crucible under argon gas or air were performed at 773–923 K for 100 h. The depth of corrosive attack, as well as the extent of chromium and molybdenum depletion, increased with increasing temperature. The extent of Hastelloy-N corrosion in molten salt under air was significantly greater than under argon gas. The effect of adding the impurity cesium iodide to molten salt containing nuclear waste fuel on the corrosion behavior was negligible.     

一体化小型氟盐冷却高温堆瞬态特性分析

根据下一代核能系统的发展目标,提出了采用自然循环的一体化小型氟盐冷却高温堆的概念。利用修改后的RELAR5-MS系统分析程序,建立了一体化小型氟盐冷却高温堆模型,并得到其稳态特性参数。在此基础上,对其在满功率运行状态下的反应性引入事故和失热阱事故进行了分析。分析计算表明,在反应性事故工况下,由于自然循环的存在,堆芯冷却剂流量随着堆芯温度发生动态变化,最终达到新的稳态,燃料棒和冷却剂温度均处于安全限值范围内。在失热阱事故下,反应堆负反馈的特性使得堆芯功率逐渐降低并实现自动停堆,即使不考虑余热排出系统的作用,燃料组件和冷却剂温度上升缓慢,在140 h内,燃料棒和冷却剂温度均处于全限值范围内。结果表明,一回路采用自然循环冷却的一体化小型氟盐冷却高温堆具有良好的固有安全性。     

高温原位氟化熔盐红外吸收光谱装置研制

钍基熔盐堆是第四代核能系统的候选堆型之一,熔盐由于优异的传热性能与中子特性,被作为冷却剂和燃料盐载体在堆内运行,其微观结构对其物理化学性质有重大影响,因此,研究熔盐结构对熔盐制备净化、腐蚀控制以及熔盐堆的设计、建造和安全运行都有重要的指导作用。红外吸收光谱(Infrared Absorption Spectroscopy,IR)是研究熔盐结构的有力工具之一,但标准仪器无法实现高温(500oC)熔盐的测量。本研究在解决了样品加热、环境气氛控制以及腐蚀等难题后,研制了一套适用于高温氟化熔盐实验的高温原位红外吸收光谱装置。该装置中,加热炉为左右两开式,可以直接放进标准红外光谱仪样品仓内;样品池为组装式,主体是能够耐氟化熔盐腐蚀的镍基哈氏合金,窗片为单晶Si C或金刚石;样品池整体呈倒"T"型,上端密封盖带有进气口和出气口,可实现抽真空或通惰性气体的操作。该装置可以实现25-600oC温度范围测量,波段范围覆盖近红外和中红外(14 700-400 cm~(-1))。通过使用常温水和高温亚硝酸钠的红外光谱实验对该装置的可靠性进行了验证。利用该装置,我们成功地获得了高温氟锂铍(FLi Be)熔盐的红外吸收光谱。     

Acoustic characterization of a CANDU primary heat transport pump at the blade-passing frequency

In this paper, we examine the acoustics of a single-stage, double-volute CANDU heat transport pump based on a full-scale experimental investigation. We estimate the strength of source variables (acoustic pressure and velocity) and establish the pump characteristics as an acoustic source at the blade-passing frequency. We conduct this analysis by first assessing the resonance effects in the test loop, and then decomposing the measured signal into the components associated with pump action and loop acoustics with the use of a simple pump model. The pump model is based on a linear superposition of pressure wave transmission and excitation. The results of this analysis indicate that the pump source variables are nearly free of acoustic resonance effects in the test loop. The source pressure and velocity are each estimated at approximately 10 kPa (zero-to-peak). The results also indicate that the pump may act as both a pressure and a velocity source. At the loop resonance, the pump acoustic behavior is exclusively governed by the pressure term. This observation leads to the conclusion that the maximum amplification of pressure pulsations in a reactor heat transport system may be predicted by modeling the pump as a pressure source.     

熔盐自然循环回路热损失功率实验及计算

熔盐自然循环回路是为研究熔盐的自然循环特性,支持先进熔盐堆非能动安全系统设计而建造的实验装置。熔盐在回路中的热量损失对于自然循环的建立和保持具有重要的影响。本文以熔盐储罐为代表部件,通过实验得到了其热量损失的数据,并利用数值模拟的方法,计算了不同温度下储罐各部分的热损失,分析了储罐热损失规律,拟合得到了热损失随温度及时间的变化关系。对比熔盐在不同温度下热损失的实验值和计算值,发现两者吻合良好,相对误差均小于10%。分析结果表明,内插式电加热器是储罐主要热损失途径之一,并导致了熔盐的温度分层。     

Activation product transport in a FLiBe-vanadium alloy-HT9 system

An assessment is made of the gamma radiation hazards likely to be found around a fusion reactor heat transfer and tritium breeding loop which employs a vanadium alloy for the blanket and first wall structure and the ferritic-steel HT9 for the remainder of the loop. The coolant/tritium breeding fluid is the molten metallic salt FLiBe. Since the radiation levels near the primary loop components are found to be less than 100 mR/h 3–5 days after shutdown after three years of continuous full power operation, limited hands-on maintenance could be allowed. The very short half-lives of the predominant corrosion products make this result possible and make such a system very attractive.