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化学交联模压一步法制备改性PVC泡沫塑料 总被引:9,自引:0,他引:9
以聚氯乙烯(PVC)为主体材料,加入丁腈橡胶(NBR)进行共混改性,采用高温共混、化学交联模压一步法来制备改性PVC泡沫塑料。探讨增塑剂邻苯二甲酸二辛酯(DOP)、丁腈橡胶、发泡剂偶氮二甲酰胺(AC)和戊次甲基四受(H)、交联剂过氧化二异丙苯(DCP)、填料碳酸钙(CaCO3)等的用量对PVC泡沫塑料性能的影响。实验表明,当选择PVC100份、NBR60份、DOP60份、AC4.0份、DCP1份, 相似文献
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探讨了用烷基改性酚醛树脂(R131)作多功能配合剂制造NBR/PVC并用胶砂浆泵衬胶的方法。NBR/PVC并用胶砂浆泵衬胶的配方确定为:NBR70;PVC30;R131 7.0;硫黄 1.1;共硫化剂DMG 2.5;活性剂 3.5;促进剂DM/CZ 2.7;防老剂4010NA/D 1.2;中超耐磨炭黑 46;增塑剂DOP 5.0;石蜡 0.6。R131在胶料混炼时分段加入。砂浆泵部件的制备工艺是: 相似文献
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含有活性添加剂的M-8_B1和M-8_T2K的两种油品对NBR-18O形密封圈有一定的副作用,通过调整NBR胶料硫化体系(硫黄0.3;促进剂CZ1.5;促进剂M0.5;硫化剂DCP2.0)和补强剂炭黑的用量(高耐磨炭黑55;喷雾炭黑40).可以使其满足抗两种油品侵蚀的性能要求。另外,在NBR胶料中添加25份耐寒增塑剂(邻苯二甲酸二丁酯10;癸二酸二辛酯15).可提高胶料的耐低温性能,并使脆性温度降至-65℃以下。 相似文献
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介绍了望远镜橡塑装饰包皮的胶料配方设计、生产工艺和产品性能。望远镜橡塑装饰包皮胶料的主体材料采用NBR/PVC(并用比83/17)并用体系;硫化体系由硫黄(1-25 份) 和促进剂TMTD(0-29 份)、促进剂DM(0-42 份)、促进剂M(0-42 份)组成;增塑剂选用增塑剂DBP(8-3 份);黑色胶料的防老剂选用防老剂2246(1-6 份),非黑色胶料的防老剂选用防老剂264(2-0 份);黑色胶料的补强填充剂选用HAF/GPF(并用比83/17) 并用体系,非黑色胶料的补强填充剂选用白炭黑/ 陶土( 并用比75/17)并用体系。NBR 的塑炼采用低温、小辊距和低容量的三段塑炼法;NBR与PVC的共混采用常温共混工艺;混炼胶的威氏塑性值控制在0-28~0-30 之间;制品在平板硫化机上硫化完毕后,再在160~170 ℃的烘箱中热处理15~30 min。胶料物理性能良好,成品性能满足设计要求。 相似文献
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在氯化聚乙烯(CPE)和NBR中加入促进剂NA22首先对CPE进行动态硫化,然后加入硫黄对NBR进行静态硫化制备了CPE/NBR共混物。考察了促进剂NA22用量、CPE/NBR共混比以及动态硫化温度对共混物性能的影响。结果表明,动态硫化是解决CPE与NBR相容性问题的有效手段;促进剂NA22存在饱和点,用量以2份为宜;CPE用量增大,动态硫化共混物交联密度则略有升高;动态硫化温度提高(160~180℃),交联密度增大。 相似文献
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本文研究了聚碳酸酯(Lexan OQ2720)注塑制品退火后的力学及动态力学性能的变化。结果表明,制品的应力集中情况有明显改善,力学性能除断裂伸长率外都产生了较高提升,拉伸强度提高了14.86%,弯曲强度提高了12.7%,弯曲模量提高了21.27%,冲击强度提高了17.93%;动态力学分析结果表明,,注塑制品的内部存在应力。经退火后,注塑制品内部取向、缠结的分子链得到充分松弛,制品储能模量随温度的变化呈线性规律,内部链段的状态稳定,热变形温度得到了提高。而未退火试样的储能模量随温度变化起伏不定,内部链段的状态比较活跃。动态频率对制品中应力有一定响应能力,响应频率范围约为30-60Hz,随着频率扫描温度的升高,由于应力集中降低,频率对应力响应能力不断降低。 相似文献
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采用浇注机浇注的方法制备了可作为抛光垫材料使用的硬质多孔聚氨酯脲弹性体,借助万能拉力机、DMA、DSC等手段对材料性能进行表征。实验结果表明:调整硬段含量在一定范围时,可获得不同性能、多种抛光需求的抛光垫;与2,4–TDI相比,2,6–TDI的增加有助于与MOCA形成规整的硬段结晶,阻尼峰向高温处移动,但由于产物是完全线性结构,材料的储能模量反而有所降低;KEL值(能量损耗因子)用于表征材料的抛光性能时,少量的交联有助于获得较好的抛光效果。 相似文献
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In the present article, a series of commercial‐grade polypropylenes (PP) filled with different contents of short basalt fibers were studied. This composite material presented deterioration of both mechanical characteristics, for example, stress and strain at yield with increasing of the fiber content. On the other hand, the impact strength was fourfold higher than that of unfilled PP. A poor adhesion between the PP matrix and the basalt fibers was detected. This is why interfacial interactions were promoted by the adding of poly(propylene‐g‐maleic anhydride) (PP‐g‐MA). It was observed that the tensile properties of the obtained materials and their impact strengths increased significantly with increasing of the amount of PP‐g‐MA in the blend. The adhesion improvement was confirmed by scanning electron microscopy as well. Fourier transform infrared spectroscopy was applied to assess if any chemical interactions in the system PP/PP‐g‐MA/basalt fibers exist. Dynamic mechanical thermal analysis data showed an increase of the storage modulus with increasing fiber content. The conclusion was made that the modification of the PP matrix led to a higher stiffness but its value remained constant, irrespective of the PP‐g‐MA content. With increasing fiber content, damping in the β‐region decreased, but increase of the coupling agent content restored its value back to that of PP. The loss modulus spectra presented a strong influence of fiber content on the α‐relaxation process of PP. The position of the peaks of the above‐mentioned relaxation processes are discussed as well. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 74: 523–531, 1999 相似文献
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Influence of the grafting topology of hydrophobic silica surfaces on the mechanical properties of silicone high consistency rubbers
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David Mariot Anne‐Sophie Caro‐Bretelle Patrick Ienny François Ganachaud 《Polymer International》2015,64(9):1128-1134
Silica‐filled rubber materials exhibit stress softening and hysteresis under cyclic loadings. These phenomena are usually associated with both the Payne and Mullins effects. To better characterize these properties, five model silicas were produced and used in industrial‐like high consistency rubber (HCR) formulations: the native (hydrophilic) silica and four chemically modified silicas for which both the content of surface silanols and the nature of the grafted silicone chains differ. Silica ? polydimethylsiloxane HCR elastomer with constant silica content and optimal dispersion was tested via static (uniaxial tensile tests, cyclic and monotonic) and dynamic tests. The Payne and Mullins effects as well as the ultimate properties were evaluated as a function of particle surface treatment. It was found that the Payne amplitude decreases with the content of grafted chains, whereas the Mullins effect and ultimate strain decrease with an increase in molar mass between crosslinks. Finally, the ultimate strength is optimal as long as silica is surface treated, albeit independent of surface grafting topology. © 2015 Society of Chemical Industry 相似文献
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报道了PMMA/USPU共聚物的力学性能。研究结果表明,USPU对PMMA具人显著的增韧必增强作用。共聚物的模量-组成关系符合Davies模型,表明共聚物中PMMA相和USPU相之间呈互为连续的形态。 相似文献
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研究了反式-1,4-聚异戊二烯(TPI)结晶性对不同用量过氧化二异丙苯(DCP)硫化的TPI性能的影响。结果表明,拉伸前后TPI试样的XRD曲线上结晶峰有明显不同。TPI预拉伸冷冻试样的拉伸性能与冷冻前后原始试样的差异明显。随着DCP用量的增加,500mm/min和50mm/min拉伸速率下测得的拉伸强度之间的差异变得越来越小;同一压缩率时,试样的压缩强度不断降低。在tanδ-温度曲线上,随着交联密度的提高,TPI低温损耗峰的tanδ值不断增大,而其高温损耗峰的tanδ值呈下降趋势。 相似文献
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The mechanical properties of functionally graded polymeric composites (FGPCs) with varying carbon black loading and the effect of stacking sequence in styrene butadiene rubber (SBR) matrix were studied. For a given average amount of nanofiller, the modulus of FGPCs for any given stacking sequence of layers is higher when compared with its uniformly dispersed polymeric composites (UDPCs) counterpart. Tensile strength, elongation at break, and tear strength either increase or decrease depending on the stacking sequence and average loading of the filler in FGPCs. In addition, the smoother gradation (i.e., lesser difference in the amounts of CB content in adjacent layers) and a wide gap of difference in CB content in a stack has a profound effect on the modulus and tensile strength of FGPCs. Dynamic mechanical analysis shows lesser damping in FGPCs than UDPCs. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
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Weidian Shen Jian Sun Jhiqiang Liu Wenjing Mao J. David Nordstrom Paul D. Ziemer Frank N. Jones 《Journal of Coatings Technology and Research》2004,1(2):117-125
This study illustrates the capabilities of a nanoindentation/nanoscratch tester to assess mechanical and tribological properties
of coating films. Properties such as hardness, elastic modulus, mar and scratch resistance, and critical force for cracking
can be accurately measured. Operation of the Nano-Indenter is described in detail. A scanning probe microscope (SPM) is shown
to be a valuable supplement to the Nano-Indenter. Well-characterized thermoset acrylic clearcoats and thermoplastic latex
films were studied. For the first time, operating parameters are described for measurement of relatively soft coatings, such
as films cast from a latex with a glass transition temperature (Tg) of 8°C. Thus, the method is made available for study of most types of coatings. The method can easily discriminate between
coatings with different Tgs and crosslink densities. Once operating parameters are established, it takes about 10 minutes for an indentation test and
10 minutes for a scratch test with the Nano-Indenter, and with further automation this time could be reduced. Each indentation
test accurately measures hardness and elastic modulus as a function of depth within the coating, and each scratch test provides
additional insight into the material’s behavior. The method is sensitive to small changes in polymer composition and formulation,
and results are highly reproducible.
Presented at the 81st Annual Meeting of the Federation of Societies for Coatings Technology, November 12–14, 2003, in Philadelphia,
PA. 相似文献