形变对Ti44Ni47Nb9宽滞后形状记忆合金应力诱发马氏体相变行为的影响

采用差示扫描量热仪(DSC)系统研究了在(M8 30℃)温度下拉伸形变对Ti44Ni47Nb9形状记忆合金应力诱发马氏体(SIM)相变行为的影响．DSC测量表明,SIM相变为一微观不均匀过程,当形变量达到约14％时,SIM相变过程结束．在形变试样的第一次加热过程中,SIM的逆转变开始温度A′s和相变潜热均随着形变量的增加先增加后略有降低;而逆转变温度间隔随着形变量的增加略有增加,但和热诱发马氏体相比,SIM的逆转变温度间隔明显变窄．此宽滞后现象为一次性效应．在随后加热循环中的相变潜热、第一次冷却过程中马氏体相变开始温度以及第二次加热过程中逆转变开始温度均随着形变的增加而缓慢降低．     

Ti-Ni-Nb宽滞后形状记忆合金的应力诱发马氏体相变行为

用在（Ms＋30℃）温度下的拉伸实验和差示扫描量热仪（DSC）较系统地研究了Ti44Ni47Nb9宽滞后形状记忆合金应力诱发马氏体的相变行为。研究结果表明：当形变量达到14％左右时，应力诱发马氏体相变过程基本完成。应力诱发马氏体的逆相变温度间隔要比热诱发马氏体约小一个数量级。形变对该合金应力诱发马氏体的逆转变开始温度、逆转变温度间隔以及相变潜热均有明显影响，随着拉伸变形量的增加而增加。而在随后的冷却循环中，相变潜热和马氏体相变开始温度均随着形变的增加缓慢降低。     

Ti—Ni—Nb宽滞后记忆合金的研究进展

Ｔｉ－Ｎｉ－Ｎｂ形状记忆合金由于其较宽的相变滞后和优良的形状记忆性能,是一眼有前任的管接头和紧固件用材。本文论述了Ｔｉ－Ｎｉ－Ｎｂ合金滞后加宽的工程意义,介绍了近十年来Ｔｉ－Ｎｉ－Ｎｂ合金显微组织,马氏体相变,力学行为,应变恢复率,低温热容和机械加工特性等方面的研究进展及发展趋势。     

应力诱发马氏体相变滞后的研究

用Landau-Devonshire自由能理论可描述形状记忆合金伪弹性行为随温度变化的规律:温度上升,滞后环位置提高,滞后面积减小;到达临界温度T_c后,滞后全部消失。可是对CuZnAl单晶系统测定结果显示:滞后环位置随温度升高而升高,但滞后面积在一定温度范围内,却基本不变。对滞后环内变化规律的研究结果指出,滞后大小取决于应力诱发马氏体量的多少,马氏体量越多,则滞后面积越大。     

富钛的Ti51Ni47Si2形状记忆合金的马氏体相变

近等原子TiNi合金具有优异的形状记忆效应和超弹性,因此,在工程和医疗及牙科方面得到了广泛的应用。影响TiNi合金形状记忆性能的因素除了热循环、热处理、冷轧外,添加第三元素对其相变也有重要影响,如用钒、锆、铁及钴元素取代镍后,马氏体转变温度(Ms)降低,而用金、钯及铂部分取代镍后会显著增加Ms点。TiNiFe、TiNiAl及TiNiCo合金相变顺序为高温立方相B2→三角晶系中间相(R)→斜方晶系(B19);而对于TiNiCu、TiNiPd合金而言,相变顺序则为B2→B19→B19′(B19′为低温单斜晶系)。 采用射频溅射法制备的TiNi薄膜变形大,回复力强,被认…     

Co—Ni合金磁诱发马氏体相变的热力学分析

从应力诱发马氏体相变热力学角度出发,分析了外磁场作用下具有高磁晶各向能的Co-Ni合金磁诱发马氏体相变热力学,并建立了新的数学模型。     

Ti-50.1Ni形状记忆合金相变与形变行为

用热重分析仪、X射线衍射仪和拉伸试验研究了退火温度、变形温度对Ti-50.1Ni形状记忆(SME)合金丝的相变、形变的影响.Ti-50.1Ni合金加热氧化过程中温度超过600℃后氧化加剧,故退火温度不宜超过600℃.该合金奥氏体相变开始温度(As)高于室温,室温相为马氏体,呈SME特性.350～600℃退火态Ti-50.1Ni合金在室温下均呈SME.     

DAMPING PROPERTIES OF MARTENSITE AND MARTENSITIC TRANSFORMATION IN CuZnAl ALLOYS

The internal friction of alloys in martensite state is believed to be an M/M interface one,which can be explained by an expression deduced from the theory of dislocation internal fric-tion.The internal friction during martensitic transformation consists of two parts,includingthose of the M/M interface and of the phase transformation.The latter is further composedof two portions,the major one produced by reverse martensitic transformation and the otherfrom stress-induced martensite.It was also found that the degradation of damping propertiesof the CuZnAl alloys is related to the dislocation,which is introduced from the exciting pro-cess,and tends to be of stable value after certain excitements.     

DEFORMATION OF CuZnAl SHAPE MEMORY ALLOYS IN MARTENSITIC STATE

Plastic deformation of three CuZnAl shape memory alloys in martensitic state was investi-gated by means of optical and electron metallography,dilatometry and electric resistiviy de-termination.Two of the alloys are in martensitic state at ambient temperature,and theA_f temperature of the third one is far below the ambient temperature.The effect ofdeformation of alloys in martensitic state on the course and temperature of transformation aswell as the hysteresis of transformation cycles has been analyzed and the “effect of the firstcycle” has also been discussed.     

Cu—Zn—Al形状记忆合金在马氏体状态的塑性变形

采用光学显微镜、电子显微镜、电阻和膨胀方法研究了三种Cu-Zn-Al形状记忆合金在马氏体状态的塑性变形对马氏体转变温度、相变过程及转变循环滞后的影响。其中两种合金相变温度较高,在室温下即为马氏体状态。第三种合金A_f温度远低于室温。讨论了“第一次循环效应”的可能机制。     

CuZnAl合金的马氏体及其相变的阻尼性能SCIEI

本文研究了CuZnAl合金在马氏体及马氏体相变时的阻尼性能。结果表明,在马氏体状态的内耗是一种M/M界面内耗,利用位错内耗理论的表达式可解释其变化规律。在马氏体相变区的内耗,包括M/M界面内耗及相变内耗两级分,其中相变内耗又由马氏体逆转变产生的内耗及应力诱发马氏体内耗两部分组成,并且前者占主导地位、合金阻尼性能的衰减与激振过程中引入的位错有关,并在一定振动次数后趋向一稳定值。     

Ni-Ti形状记忆合金中母相(?)马氏体可逆转变过程的研究SCIEI

用透射电镜对Ni-Ti形状记忆合金中母相?马氏体可逆转变进行了动态观察。利用高分辨电子显微术研究了该合金相变温度上下的结构变化。结果表明,马氏体与奥氏体的取向关系为:[111]_A∥[110]_M,[110]_A∥[001]_M,(110)_A∥(001)_M,(110)_A与(010)_M间夹角为6.5°左右;马氏体的晶体缺陷多为孪晶和层错,新发现有孪晶而为(100)的孪晶。     

REVERSIBLE TRANSFORMATION BETWEEN MATRIX AND MARTENSITE IN Ni-Ti SHAPE MEMORY ALLOYS

The reversible transformation between matrix and martensite in Ni-Ti shape memory alloyshas been dynamically observed under TEM.The orientation relation between martensite andaustenite as well as the structural change near the transition temperature has been also studiedwith the help of HREM SADP.The results show that the orientation relation betweenmartensite and austenite is[(?)11]_A//[(?)10]_M,[110]_A//[001]_M,(110)_A//(001)_M and theangle between((?)110)_A and(010)_M is about 6.5°.The crystal defects of martensite are foundto be twin and stacking fault,and the twin plane as(100).     

MARTENSITIC TRANSFORMATION AND THERMAL STABILITY IN Cu-Al-Co AND Cu-Al-Zr ALLOYS

Cu-Al-Co and Cu-Al-Zr alloys were explored with Co or Zr additions in Cu-Al alloys for high temperature shape memory alloys. Samples were quenched after homogenized at 850℃ for 48h. It was found that both Cu-Al-Co and Cu-Al-Zr show AlCus martensitic phase at room temperature and exhibit martensitic transformation temperatures higher than 200℃, showing the potentials for developing as high temperature shape memory alloys. Thermal cycles were performed by DSC instrument on both Cu-Al-Co and Cu-Al-Zr alloys. The results show that Cu-Al-Co loses its martensitic transformation after five thermal cycles, and Cu-Al-Zr exhibits no martensitic transformation in the second thermal cycle.     

THERMODYNAMICS OF MARTENSITIC TRANSFORMATION IN Fe-Mn-C AND Fe-Ni-C ALLOYS

A Central Atom Model is introduced and the LFG and Hsu models are modified in order toevaluate the driving force for the martensitic transformation in Fe-Mn-C and Fe-Ni-C al-loys.The results show that the relationship between the driving force and the yield strength ofaustenite at Ms temperature,σ_(0.2)~γ/M_s,fits Hsu's formula;ΔG~=2.1σ_(0.2)~γ/M_s+907J/mol.The M_s temperatures of Fe-Mn-C and Fe-Ni-C alloys are also calculated.Thecalculated results are in good agreement with experimental values.     

DSC STUDY OF MARTENSITIC TRANSFORMATION KINETICS IN A Cu－Zn－Al－Mn－Ni SHAPE MEMORY ALLOY

ＤＳＣＳＴＵＤＹＯＦＭＡＲＴＥＮＳＩＴＩＣＴＲＡＮＳＦＯＲＭＡＴＩＯＮＫＩＮＥＴＩＣＳＩＮＡＣｕ－Ｚｎ－Ａｌ－Ｍｎ－ＮｉＳＨＡＰＥＭＥＭＯＲＹＡＬＬＯＹＧＥＮＧＧｕｉｌｉ;ＢＡＩＹｕｊｕｎ;ＰＥＮＧＱｉｆｅｎｇ（ＩｎｓｔｉｔｕｔｅｆｏｒＭａｔｅｒｉａ...     

DEFORMATION BEHAVIOUR OF Cu－Zn－Al ALLOYS AND ITS EFFECT ON TRANSFORMATION HYSTERESIS

ＤＥＦＯＲＭＡＴＩＯＮＢＥＨＡＶＩＯＵＲＯＦＣｕ－Ｚｎ－ＡｌＡＬＬＯＹＳＡＮＤＩＴＳＥＦＦＥＣＴＯＮＴＲＡＮＳＦＯＲＭＡＴＩＯＮＨＹＳＴＥＲＥＳＩＳＷａｎｇＭｉｎｇｐｕ；ＸｕＧｅｎｙｉｎ；ＹｉｎＺｈｉｍｉｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｅｒｉａｌ...