An inter-laboratory stability study of roll-to-roll coated flexible polymer solar modules

A large number of flexible polymer solar modules comprising 16 serially connected individual cells was prepared at the experimental workshop at Risø DTU. The photoactive layer was prepared from several varieties of P3HT (Merck, Plextronics, BASF and Risø DTU) and two varieties of ZnO (nanoparticulate, thin film) were employed as electron transport layers. The devices were all tested at Risø DTU and the functional devices were subjected to an inter-laboratory study involving the performance and the stability of modules over time in the dark, under light soaking and outdoor conditions. 24 laboratories from 10 countries and across four different continents were involved in the studies. The reported results allowed for analysis of the variability between different groups in performing lifetime studies as well as performing a comparison of different testing procedures. These studies constitute the first steps toward establishing standard procedures for an OPV lifetime characterization.     

Improvement in long-term stability of dye-sensitized solar cell for outdoor use

To improve the intrinsic stability of the component of dye-sensitized solar cells (DSCs), we have fabricated the unit cell using solvent-free ionic liquid electrolyte. The degradation in the continuous 1 sun light soaking test at 60 °C over 15,000 h was effectively suppressed, compared with the cell using γ-butyrolactone electrolyte. The lifetime for outdoor use was estimated over 15 years from acceleration factor based on the outdoor exposure test. To confirm the stability of the DSC under practical outdoor use, we fabricated the solar light using the DSC modules, rechargeable batteries and bright light emitting diode (LED). The solar lights have been emitting a bright white light at night using the electricity from batteries charged by the DSC modules during the daytime in any weather condition for a half year.     

透明隔热膜对改善光伏组件温度和发电效率的研究

针对太阳光中的近红外光导致光伏组件温升,进而影响光伏组件发电效率的问题,开展了透明隔热膜在降低组件温度并提高发电效率方面的研究。首先,纳米氧化锡锑(ATO)透明隔热膜具有反射红外光,透射可见光的特点。基于此特点,在实验室将自制的纳米ATO隔热涂料涂布在光伏组件专用玻璃上,在分光光度计下检测样品的可见光、近红外光透过率;其次,分别在太阳能模拟器、室外日光下测试隔热性能以及光伏组件的功率特性。实验测试结果表明:实验室自制的纳米ATO透明隔热膜可有效降低光伏组件的工作温度,从而提高其发电效率和使用寿命。     

Characterization of microspherical semi-transparent solar cells and modules

Microspherical solar cells and modules have been fabricated. The spherical nature of these semi-transparent devices allows the microspherical cells to harvest both directly incident and diffuse components of sunlight thereby improving the solar energy conversion efficiency. Indoor and outdoor characterizations of these three dimensional semi-transparent cells and modules are carried out using a Lambertian reflector in order to assess the maximum efficiency of the devices. In the absence of the reflector the cell efficiency is 13.5% under standard illumination (100 mW cm⁻², A.M. 1.5, 25 °C). However, this is significantly enhanced in the presence of the reflector. Microspherical modules with the reflector are directly compared to similar semi-transparent modules comprised of traditional planar devices, in outdoor tests at low light intensity (2.5–25 mW cm⁻²) to further demonstrate the benefits of the design particularly at low angle of incident radiation.     

Flexible, long-lived, large-area, organic solar cells

We report herein large area (>10 cm²), interconnected organic solar cell modules both on glass substrates as well as on flexible ultra-high barrier foils, reaching 1.5% and 0.5% overall power conversion efficiency under AM1.5 conditions. Series connection is described, as these modules consist of up to three cells. Using our flexible barrier material, a shelf lifetime of polythiophene-based solar cells of 6000 h could be realized. Furthermore, we compare the photovoltaic performance of efficient conjugated polymer:fullerene solar cell modules with established technologies. Under typical indoor-office lighting, our modules are competitive with these systems.     

Effect of spectral irradiance distribution on the outdoor performance of amorphous Si//thin-film crystalline Si stacked photovoltaic modules

Effects of spectral irradiance distributions on the outdoor performance of amorphous Si//thin-film crystalline Si stacked photovoltaic (PV) modules installed at Shiga-prefecture in Japan have been investigated. Outdoor solar spectrum measurements revealed that more than 95% of annual total spectra were blue-rich compared to AM1.5 standard solar spectrum. The outdoor performance of the modules had a higher spectral dependence than that of polycrystalline Si modules. Also, the peak of the histogram of annual spectral indexes well corresponded to the peak of the outdoor performance. The results indicate that the actual spectral irradiance distribution is important in designing stacked PV modules.     

CdTe/CdS Solar cells on flexible molybdenum substrates

Development of CdTe/CdS solar cells on flexible metallic substrates is highly interesting due to the light weight and flexible nature of the solar modules. We have deposited CdTe films onto flexible molybdenum substrates using close-spaced sublimation technique and the CdTe/CdS junction was developed by depositing a thin layer of CdS onto the CdTe substrate from a chemical bath. The devices were characterized by Current–voltage (I–V) and photocurrent spectroscopy techniques. Prior to the deposition of the transparent conducting layer, the devices were annealed in air at different temperatures and found that the devices annealed at 400°C have better photovoltaic parameters. The efficiency of a typical device under 60 mW cm⁻² illumination was estimated as 3.5%.     

A simple method for quantifying spectral impacts on multi-junction solar cells

A method to quantify spectral effects on the electric parameters of multi-junction solar cells is presented. The method is based on measuring the short circuit current of at least two monitor cells. Ideally these monitor cells have the same spectral responses as the subcells in the investigated multi-junction solar cell. In contrast to the subcells, the current of the individual monitor cells can be measured separately. This allows conclusions to be drawn about the spectral impact on the current mismatch of the multi-junction solar cell. A spectrometric evaluation method is then applied.The method has been tested experimentally with three concentrator modules using III-V triple-junction solar cells. These modules were measured outdoors for several months under variable solar spectral conditions. In parallel, the IV curves of the modules and the current of two component cells were measured. A spectral parameter Z was derived from the monitor cell current signals, which was correlated to the short circuit current and the fill factor of the modules. A linear correlation was found between Z and the normalized short circuit current of the concentrator modules. Translation equations were derived from the linear correlation. These enable the calculation of a module’s short circuit current under any spectral conditions. In particular, the short circuit currents of the modules were derived for direct normal irradiance of 850 W/m² and spectral conditions corresponding to the AM1.5d low AOD spectrum. This is an important step towards comparing the performance of modules which show strong spectral sensitivity. Future rating methods can benefit from the presented simple method for quantifying spectral impacts on multi-junction solar cells. Furthermore, the method can be of interest for tuning the spectrum of pulsed solar simulators.     

Spectral effects on amorphous silicon solar module fill factors

The outdoor operation and monitoring of amorphous silicon (a-Si) solar modules present unique features when compared to the more traditional and quite well understood operation of the crystalline silicon (c-Si) technology. The peculiarities of a-Si contrast to such extent with those of c-Si solar cells that in the field, while the former performs better during summer, the latter is more efficient in winter. Concepts usually applied to describe phenomena in c-Si devices are often inadequate to describe the performance of a-Si cells. When looking at module performance, the fill factor (FF) can be regarded as one of the characteristic photovoltaic quantities of major interest. Under outdoor illumination, cells are seasonally exposed to different solar spectral contents and intensities, which vary considerably from summer to winter. The FF depends on both the quality (spectrum) and quantity (irradiation) of the incident light. In this context, we report results showing spectral effects on the FF of amorphous silicon solar modules deployed outdoors. While “blue” spectra improved the FF of a-Si devices, the contrary was observed for “red” spectra. The voltage-dependent spectral response of a-Si devices is also described and quantified. Our results reveal that a-Si modules can perform quite well at low irradiations and mainly diffuse spectra. We, thus, conclude that in system sizing programmes, the performance of a-Si modules should be treated more precisely with respect to spectra, to reveal their true operational characteristics and advantages.     

Solar module using dye-sensitized solar cells with a polymer electrolyte

Dye-sensitized TiO₂ solar cells assembled with a polymer electrolyte were investigated, aiming at the construction of an 8 V solar module. The individual solar cells were assembled with 4.5 cm² active area and were characterized under outdoor conditions, exhibiting an average efficiency of 0.9% per cell (at 12:00 noon). The solar module was built by connecting 13 cells in series. The integrated average daily power was estimated to be 183 mW. The present paper discusses the performance of the individual cells and the module.     

Impact of spectral irradiance distribution and temperature on the outdoor performance of amorphous Si photovoltaic modules

Performance of photovoltaic (PV) modules is evaluated under the standard test condition, which rarely meets actual outdoor conditions. Environmental conditions greatly affect the output energy of PV modules. The impact of environmental factors, especially solar spectrum distribution and module temperature, on the outdoor performance of amorphous Si (a-Si) and multicrystalline Si (mc-Si) PV modules is characterized. The results show that the output energy of a-Si modules mainly depends on spectrum distribution and is higher under blue-rich spectrum. In contrast, the output energy of mc-Si module is sensitive to module temperature but not to spectrum distribution.     

Field and laboratory studies of the stability of amorphous silicon solar cells and modules

If photovoltaic solar cells and modules are to be used as a major source of power generation it is important to have a good knowledge and understanding of their long-term performance under different climatic and operating conditions. A number of studies of the long-term performance of commercially available photovoltaic modules manufactured using different technologies have now been reported in the literature. These have shown clear differences in the seasonal and long term performance and stability of different solar cell techniques. In addition to general module engineering factors that result in a loss of performance in all modules some types of solar cells, such as those made from thin film amorphous silicon (a-Si:H), also suffer specific losses in performance due to fundamental material changes, such as photodegradation or the Staebler–Wronski effect (SWE). A field evaluation of the long term performance of state-of-the-art crystalline and amorphous silicon photovoltaic modules in Australian conditions is currently being undertaken at Murdoch University. The initial results from this monitoring program are reported. This paper also reports on laboratory and field studies being undertaken on the nature of the Staebler–Wronski effect in amorphous silicon solar cells and how the stability of these cells is affected by different operating conditions. Based on a mechanism for the SWE in a-Si:H solar cells developed as a result of our research we propose a number of possible ways to reduce the Staebler–Wronski effect in a-Si:H solar cells.     

Optical properties, durability, and system aspects of a new aluminium-polymer-laminated steel reflector for solar concentrators

A newly developed aluminium-polymer-laminated steel reflector for use in solar concentrators was evaluated with respect to its optical properties, durability, and reflector performance in solar thermal and photovoltaic systems. The optical properties of the reflector material were investigated using spectrophotometer and scatterometry. The durability of the reflector was tested in a climatic test chamber as well as outdoors in Älvkarleby (60.5°N, 17.4°E), Sweden. Before ageing, the solar weighted total and specular reflectance values were 82% and 77%, respectively, and the reflector scattered light isotropically. After 1 year's outdoor exposure, the total and specular solar reflectance had decreased by less than 1%. However, after 2000 h in damp heat and 1000 W/m² simulated solar radiation, the optical properties had changed significantly: The light scattering was anisotropic and the total and specular solar reflectance values had decreased to 75% and 42%, respectively. The decrease was found to be due to degradation of the protective polyethylene terephthalate (PET) layer, caused by UV radiation and high temperature. The conclusions are that the degradation is climate dependent and that PET is not suitable as a protective coating under extreme conditions, such as those in the climatic test chamber. However, the results from outdoor testing indicate that the material withstands exposure in a normal Swedish climate.     

Fabrication technology for large-area a-Si solar cells

The fabrication process technology for large-area a-Si photovoltaic (PV) modules and their performance are reviewed. Our present technology enables us to provide 10% efficient large-area submodules with a stabilized efficiency of 8.5%. To study the practicability of the a-Si solar panels, we carried out an outdoor test for our a-Si modules. The results show that the a-Si solar PV modules generate power very efficiently in outdoor systems. The advantage of the a-Si modules under outdoor uses is presented and discussed.     

Fabrication of flexible CdTe solar modules with monolithic cell interconnection

CdTe solar cells and modules have been manufactured on polyimide (PI) substrates. Aluminum doped zinc oxide (ZnO:Al) was used as a transparent conductive oxide (TCO) front contact, while a thin high resistive transparent layer of intrinsic zinc oxide (i-ZnO) was used between the front contact and the CdS layer. The CdS and CdTe layers were evaporated onto the ZnO:Al/i-ZnO coated PI films in a high vacuum evaporation system followed by a CdCl₂ activation treatment and a Cu–Au electrical back contact deposition. In some cases prior to the cell deposition, the PI film was coated with MgF₂ on the light facing side and the effects on the optical and electrical properties of TCO and solar cells were investigated. The limitations on current density of solar cells due to optical losses in the PI substrate were estimated and compared to the experimentally achieved values. Flexible CdTe solar cells of highest efficiencies of 12.4% and 12.7% were achieved with and without anti-reflection MgF₂ coating, respectively.Laser scribing was used for patterning of layers and monolithically interconnected flexible solar modules exhibiting 8.0% total area efficiency on 31.9 cm² were developed by interconnection of 11 solar cells in series.     

Microcrystalline/micromorph silicon thin-film solar cells prepared by VHF-GD technique

Hydrogenated microcrystalline silicon prepared at low temperatures by the glow discharge technique is examined here with respect to its role as a new thin-film photovoltaic absorber material. XRD and TEM characterisations reveal that microcrystalline silicon is a semiconductor with a very complex morphology. Microcrystalline p–i–n cells with open-circuit voltages of up to 560–580 mV could be prepared. “Micromorph” tandem solar cells show under outdoor conditions higher short-circuit currents due to the enhanced blue spectra of real sun light and therefore higher efficiencies than under AM1.5 solar simulator conditions. Furthermore, a weak air mass dependence of the short-circuit current density could be observed for such micromorph tandem solar cells. By applying the monolithic series connection based on laser patterning a first micromorph mini-module (total area of 23.6 cm²) with 9% cell conversion efficiency could be fabricated.     

Experimental characterisation of a novel heat exchanger for a solar hot water application under indoor and outdoor conditions

The performance of a novel heat exchanger unit (‘Solasyphon’) developed for a solar hot water system was experimentally investigated under indoor and outdoor operating conditions. The ‘Solasyphon’ can be easily integrated to an existing single-coil hot water cylinder avoiding the need for costly twin-coil solar hot water storage. A series of tests were conducted under controlled indoor and real outdoor conditions to test and compare the performance of the ‘Solasyphon’ system with a traditional twin-coil (‘coil’) system. The analysis was based upon experimental data collected under various operating conditions including different primary supply temperatures (solar simulated); heating from ambient, heating with a partially stratified storage from ambient and finally under no draw-off and standard draw-off patterns. The outdoor testing was carried out on both systems separately over Summer/Autumn conditions in Northern Ireland. The results showed that the ‘Solasyphon’ system is more effective compared to a traditional twin-coil system for a domestic application where intermittent hot water demand is predominant and under a transient solar input particularly on intermediate or poor solar days. The ‘Solasyphon’ delivered solar heated water directly to the top of the storage producing a stratified supply at a useable temperature. The twin-coil system was found to be more efficient than the ‘Solasyphon’ system under a prolonged heating period.     

Modeling of the I–V curves of the PV modules using linear interpolation/extrapolation

Translation of the I–V curves of solar cells and modules for irradiance G and device temperature T is investigated. A new translation procedure based on the linear interpolation/extrapolation is proposed, in order to translate the I–V curves to target conditions of G and T. The accuracy of the method is investigated based on the indoor and outdoor experimental I–V curves of various kinds of photovoltaic (PV) cells and modules. The calculated the I–V curves over a wide range of G and T well agree with experimental results for various kinds of PV cells and modules. These results indicate that the translation of the I–V curve based on the method is effective for estimating the performance of the PV devices under various climatic conditions.     

Large-area CIGS modules: Pilot line production and new developments

Thin-film solar modules based on Cu(In,Ga)Se₂ (CIGS) promise to become a lower-cost alternative to polycrystalline silicon. The ZSW and Wuerth Solar are developing and running industrial processes suitable for the mass production of CIGS modules. Yield and output in the Wuerth Solar pilot line are steadily improving, with average module efficiencies exceeding 10%. New developments at the ZSW include doubling the length of the linear evaporation source to increase the throughput and adjusting the processes to enable production of flexible modules. New calculations regarding module design for optimized performance are presented as well as results from outdoor testing of Wuerth Solar modules.     

Light trapping, a new approach to spectrum splitting

In this paper, a novel type of light trap is introduced. It enables photovoltaic conversion with separate solar cells optimized for different frequency bands, which are covered by spectrally selective mirrors. Sunlight is coupled into a transparent medium and converted to diffuse radiation by randomization. It is well known that under these conditions light intensity is enhanced by a factor of 2n² inside the medium. The unidirectional radiation at the aperture is however only n². Two types of light trap are presented. The first one employs concentrated radiation incident on a small volume light trap. It is shown that efficiency depends on the ratio (solar cell area)/(input area). A more detailed analysis shows that under regular conditions part of the light is absorbed directly after entering the trap which results in higher efficiencies. We show that a trapping efficiency above 90% is obtainable.The second type of trap is based on a photonic structure covering the surface of the medium. It has high angular selectivity and broad spectral transmission. An analysis of efficiency and loss mechanisms is presented. If both types of trap are combined even higher efficiency is possible. Consequences for solar cell technology are investigated. It is further shown that the light trapping principle can also be applied to large area stationary modules.