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1.
Qiang Li Wanjing Wang Zhongshi Yang Makoto Kobayashi Masato Suzuki Junya Osuo Akiko Hamada Katsushi Matsuoka Rie Kurata Jing Wu Chunyi Xie Liping Zhao Kenji Okuno Yasuhisa Oya Guang-Nan Luo 《Fusion Engineering and Design》2011,86(9-11):1689-1692
The doped graphite tiles bolted to the active cooling heat sink, made of GBST1308 (1% B4C, 2.5% Si, 7.5% Ti) coated with SiC, are now being used as the only plasma facing material (PFM) for the EAST device since the campaign of 2008. From the plasma density and fueling point of view, it is important to study thoroughly the hydrogen isotope retention in this kind of SiC-coated doped graphite. D2+ implantations into the SiC coated doped graphite were performed at Shizuoka University. The chemical states of Si and C were studied by means of X-ray photoelectron spectroscopy (XPS), and the thermal desorption behavior of deuterium was analyzed by thermal desorption spectroscopy (TDS). It was found that deuterium was trapped by both C and Si in the SiC coatings. In the previous studies, Oya et al. reported the deuterium retention behavior in polycrystalline β-SiC. In this paper, difference of retention behavior in β-SiC and SiC coating will be also discussed. 相似文献
2.
Jing Wu Zhongshi Yang Fang Ding Wanjing Wang Guang-Nan Luo Masao Matsuyama 《Fusion Engineering and Design》2012,87(7-8):1399-1404
Tritium exposure experiments were carried out for three kinds of EAST SiC coated doped-graphite (SiC/C) samples, one from the original graphite tiles without being irradiated, and the other two from erosion and deposition areas of first wall after the 2009 campaign in EAST. β-ray-induced X-ray spectrometry (BIXS) was used to characterize the exposed samples. It is showed that the significant amount of tritium was absorbed in the surface of deposition sample in comparison with that of original sample, which was also supported by the results of imaging plate (IP) measurements. In addition, it was found that drastic decrease in tritium retention appeared by lowering exposure temperature, and the trapped tritium was maintained stably with time. Computer simulation is used to analyze the details of depth profile of tritium in different kinds of samples. 相似文献
3.
Deuterium retention in plasma spray tungsten coatings exposed to low-energy, high flux D plasma 总被引:1,自引:0,他引:1
V.Kh. Alimov H. Nakamura O.V. Ogorodnikova K. Isobe 《Journal of Nuclear Materials》2011,414(3):479-484
Two types of porous plasma spray tungsten coatings deposited onto stainless steel and graphite substrates were exposed to low-energy (76 eV ), high-flux (1022 D/m2 s) D plasma to ion fluences of (3-4) × 1026 D/m2 at various temperatures. Deuterium retention in the W coatings was examined by thermal desorption spectroscopy and the D(3He,p)4He nuclear reaction, allowing determination of the D concentration at depths up to 7 μm. The relatively high D concentration (above 0.1 at.%) at depths of several micrometers observed after D plasma exposure at 340-560 K can be related to accumulation of D2 molecules in pores, while at temperatures above 600 K deuterium is accumulated mainly in the form of D atoms chemisorbed on the inner pore surfaces. At exposure temperatures above 500 K, the D retention in the plasma spray W coating on graphite substrate increases significantly due to trapping of diffusing D atoms at carbon dangling bonds located at the edge of a graphite crystallite. 相似文献
4.
Z. Tian 《Journal of Nuclear Materials》2010,399(1):101-107
Deuterium retention in two types of polycrystalline tungsten (PCW) was studied as a function of incident ion fluence, ion energy, and specimen temperature. (i) D retention at 300 K, as a function of D+ fluence, demonstrated a trend to saturation in both the Rembar hot-rolled thin foil and Plansee tungsten plate. At 500 K, new D retention results for the Plansee PCW showed an increasing trend with increasing incident D+ fluence without any indication of saturation, in agreement with previous results for Rembar PCW [A.A. Haasz, J.W. Davis, M. Poon, R.G. Macaulay-Newcombe, J. Nucl. Mater. 258-263 (1998) 889-895]. Even when the incident D+ fluence was increased to 8 × 1025 D+/m2, which is in the fluence range of plasma devices, there was still no sign of saturation. (ii) The temperature dependence results for the Plansee PCW show a decreasing trend in D retention as the temperature is increased from 300 to 500 K. These results differ from previous studies of Rembar PCW [A.A. Haasz, J.W. Davis, M. Poon, R.G. Macaulay-Newcombe, J. Nucl. Mater. 258-263 (1998) 889-895], but are similar to those seen for single crystal tungsten [M. Poon, A.A. Haasz, J.W. Davis, R.G. Macaulay-Newcombe, J. Nucl. Mater. 313-316 (2003) 199]; an explanation for the different behaviour is suggested. (iii) Varying the D+ energy from 100 to 500 eV/D+ plays a minor role in the amount of D retained, suggesting that D retention in W depends more on the W structure, incident ion fluence and specimen temperature, rather than on the incident ion energy when the energy is below the threshold for damage formation (∼960 eV for D on W). 相似文献
5.
W. Sato H. Ueno H. Miyoshi D. Kameda K. Shimada S. Suda A. Shinohara K. Asahi 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2008,266(2):316-322
The online time-differential perturbed angular correlation (TDPAC) method was applied to a study of the physical states of a probe 19F, the β− decay product of 19O (t1/2 = 26.9 s), implanted in highly oriented pyrolytic graphite. The observed magnitude of the electric field gradient at the probe nucleus, ∣Vzz∣ = 2.91(17) × 1022 V m−2, suggests that the incident 19O atoms are stabilized at an interlayer position with point group C3v. Exhibiting observed TDPAC spectra having a clear sample-to-detector configuration dependence, we demonstrate the applicability of the present online method with a short-lived radioactive 19O beam. 相似文献
6.
Xu Gao Ryosuke Sasaki Lichun Zheng Sun-joong Kim Shin-ya Kitamura 《Journal of Nuclear Science and Technology》2018,55(4):400-409
The control blade and the fuel rod installed in channel box melt in steam during severe accident of a boiling water reactor. In order to clarify the melting phenomena and relocation of the structural material in the core of the reactor, interaction and melting behavior among B4C, 304 grade of stainless steel (SST), and Zircaloy-4 in atmosphere containing H2/H2O at 1473 K are investigated. The results showed that the reaction at the interface between B4C and SST under H2O atmosphere was slow and an oxidation was observed after 3600 s. Under H2O/H2 atmosphere, the concentration of B and C in the SST increased and the SST melted. Despite the atmosphere, an oxide layer formed on the surface of Zircaloy-4, and thus the reactions proceeded slowly when the Zircaloy-4 was contacted with B4C and SST. Under H2O atmosphere, continuous oxidation happened to SST, and SST was partially melted. Under H2 atmosphere, the SST was also melted due to the diffusion of B and C from the B4C. In addition, the oxidation of B4C affected the oxidation behavior of SST and Zircaloy, and thus the oxidation and the hydroxylation of B4C in a severe accident was discussed thermodynamically. 相似文献
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8.
R. Pugno K. Schmid R. Doerner D. Nishijima J. Roth 《Journal of Nuclear Materials》2008,375(2):168-172
ITER strike-plates are foreseen to be of carbon-fiber-composite (CFC). In this study the CFC bulk deuterium retention in ITER-relevant conditions is investigated. DMS 701 (Dunlop) CFC targets were exposed to plasma in PISCES-B divertor plasma simulator. Samples were exposed to both pure deuterium plasma and beryllium-seeded plasma at high fluences (up to ) and high surface temperature (1070 K). The deuterium contents of the exposed samples have been measured using both thermal-desorption-spectrometry (TDS) during baking at 1400 K and ion beam nuclear reaction analysis (NRA). The total deuterium inventory has been obtained from TDS while NRA measured the deuterium depth distribution. In the analysed fluence range at target temperature of 1070 K, no fluence dependence was observed. The measured released deuterium is . In the case of target exposure with beryllium-seeded plasma no change in the released amount of deuterium was found. The deuterium concentration inside the samples is almost constant until the probed depth of ?m, except in the first 1 μm surface layer, where it is 5 times higher than in the bulk. No C erosion/redeposition was observed in the Be-seeded plasma cases. The measured retention, applied to 50 m2 of ITER CFC surface, would imply a tritium saturated value of 0.3 gT, much lower than the ITER safety limit of 350 g. 相似文献
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10.
N. Bernier C. Brosset E. Tsitrone H. Khodja J.P. Gunn 《Journal of Nuclear Materials》2009,385(3):601-605
Carbon fiber composite (CFC) Sepcarb® N11 is used in the tokamak Tore Supra as plasma-facing components. To investigate the fuel retention capability of this material, a mobile sample holder was used to expose CFC N11 samples to direct irradiation by the scrape-off layer plasma of Tore Supra at fluences up to 1 × 1025 m−2. Deuterium (D) elemental mapping using nuclear reaction analysis for the most-exposed CFC sample showed that D retention occurs at depths greater than 8 μm due to the presence of deep (>3.5 μm) local retention sites. In this work, combining transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS), we describe at a high spatial resolution where and how D atoms are trapped in these sites. TEM experiments performed on thin cross-sections of the plasma-modified surface show evidence of the presence of a 3.5 μm-thick deuterated amorphous carbon layer deposited on the CFC surface. We show that specific localized retention sites correspond to the filling of relatively large (∼3 μm.) and deep (at least 3 μm below the initial CFC surface) cracks between fibres and matrix by the deuterated amorphous carbon layer. 相似文献
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12.
H. O. Menlove M. M. Fowler E. Garcia M. C. Miller M. A. Paciotti R. R. Ryan S. E. Jones 《Journal of Fusion Energy》1990,9(4):495-506
Experiments using high-efficiency neutron detectors have detected neutron emission from various forms of Pd and Ti metal in pressurized D2 gas cells and D2O electrolysis cells. Four independent neutron detectors based on3He gas tubes were used. Both random neutrons (0.05–0.2 n/s) and time-correlated neutron bursts (10–280 n) of 100-s duration were measured using time-correlation counting techniques. The majority of the neutron burst events occurred at –30°C as the samples were warming up from the liquid nitrogen temperature. 相似文献
13.
The prismatic VHTR neutronic simulation presents challenges due to thermalization of the neutrons in the graphite reflector which leads to a spectral change in the peripheral fuel blocks. Two calculation schemes were tested on a simple 2D core calculation: a single block path wherein a classical single block lattice calculation provides the homogenized cross-sections, and a supercell path where the homogenized cross-sections are generated using a lattice of a fuel block surrounded by some of its surroundings. In both paths, several group condensations were performed to assess the effect of increasing the number of groups in the core calculation from 2 to 295. Core and lattice calculations were validated with respect to MCNP. The study revealed that the supercells lead to improvement in the calculation of power shape over the single-block path. This improvement is rather pronounced with small numbers of energy groups. For larger numbers of energy groups, however, both solution methods appear to yield adequate accuracy and the improvement gained through supercells in these cases may not warrant the computational cost. Lattice depletion calculations also show that the presence of the reflector creates strong heterogeneities on isotopic densities after 1000 days of burning. 相似文献
14.
Andreas Mutzke Ivan Bizyukov Ralf SchneiderJames Davis 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2011,269(6):582-589
In this work, a Si pitch grating with typical lateral dimensions of 200-250 nm was exposed to 6 keV C+ ions at normal incidence and at an angle of 42° both parallel and perpendicular to the grating structure. In contrast to volatile and recycling ions (like Ar+ or H+), non-recycling ions are able to modify the surface not only due to sputtering, but also due to implantation of incident ions and the re-deposition of projectile atoms following sputtering or reflection. The target-projectile combination used in this work is an example of such a system forming a mixed Si-C surface. The interaction between the ion beam and the surface has been studied both experimentally and numerically with the focus on validation of the numerical model of the newly developed SDTrimSP-2D code. SDTrimSP-2D is capable of following the evolution of the Si-C system including ion-surface interactions with 2D micro- and nano-structured surfaces. The SDTrimSP-2D code takes the interdependency of surface morphology, sputtering and implantation into account. The simulated surface morphology has been compared to cross-sections of bombarded Si pitch grating obtained by SEM, revealing good agreement between experiment and simulation. The calculations also provide improved insight into the mechanisms of surface modification by sputtering, implantation and material transport by redeposition. 相似文献
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16.
G.V. Kornich G. BetzV.G. Kornich V.I. ShulgaO.A. Yermolenko 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2011,269(14):1600-1603
Molecular dynamics simulation of Cu cluster sputtering by 50-200 eV/atom Cu2 dimers and Cu single atoms has been performed. The clusters were located on a (0 0 0 1) graphite surface and consisted of 13-195 atoms. Synergy features were identified in the sputtering yield and energy distributions of sputtered particles calculated for the cases of cluster bombardment with Cu dimers and monomers at the same velocity. The reason for the nonlinear effects in surface cluster sputtering is the overlapping of collision cascades generated by each of the dimer atoms. 相似文献
17.
Yoshinori Kawamura Masabumi Nishikawa Tomofumi Shiraishi Kenji Okuno 《Journal of Nuclear Materials》1996,230(3):287-294
It has been proposed to make use of the isotope exchange reaction for enhancement of the tritium release rate from the blanket material by adding hydrogen isotopes to the purge gas. However, it is found by the present authors that formation of water in the lithium oxide bed occurs when hydrogen isotopes are introduced to the He sweep gas. The amount of water generated in various lithium ceramics beds at hydrogen addition to purge gas is discussed in this paper. The reaction rate of the water formation reaction is also discussed. The water formation reaction in each lithium ceramics bed is considered to be second order reaction which is affected by the concentration of active point as the oxygen supplier on the lithium ceramics and the concentration of hydrogen in the purge gas. 相似文献
18.
V.Kh. Alimov B. Tyburska-Püschel S. Lindig Y. Hatano M. Balden J. Roth K. Isobe M. Matsuyama T. Yamanishi 《Journal of Nuclear Materials》2012,420(1-3):519-524
Surface topography and deuterium retention in polycrystalline ITER-grade tungsten have been examined after exposure to a low-energy (38 eV/D), high-flux (1022 D/m2 s) deuterium plasma with ion fluences of 1026 and 1027 D/m2 at various temperatures. The methods used were scanning electron microscopy equipped with focused ion beam, thermal desorption spectroscopy, and the D(3He,p) 4He nuclear reaction at 3He energies varied from 0.69 to 4.0 MeV. During exposure to the D plasma at temperatures in the range from 320 to 815 K, small blisters of size in the range from 0.2 to 5 μm, depending on the exposure temperature and ion fluence, are formed on the W surface. At an ion fluence of 1027 D/m2, the deuterium retention increases with the exposure temperature, reaching its maximum value of about 1022 D/m2 at 500 K, and then decreases below 1019 D/m2 at 800 K. 相似文献
19.
B. Johannessen P. Kluth C.J. Glover S.M. Kluth G.J. Foran D.J. Cookson D.J. Llewellyn M.C. Ridgway 《Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms》2006,250(1-2):210-214
Cu nanocrystals (NCs) were synthesized in SiO2 by ion implantation and thermal annealing. Annealing at two different temperatures of 950 °C and 650 °C yielded two different nanocrystal size distributions with an average diameter of 8.1 and 2.5 nm, respectively. Subsequently the NCs were exposed to 5.0 MeV Sn3+ ion irradiation simultaneously with a thin Cu film as a bulk reference. The short-range atomic structure and average NC diameter was measured by means of extended X-ray absorption fine structure (EXAFS) spectroscopy and small angle X-ray scattering (SAXS), respectively. Consistent with the high regeneration rate of bulk elemental metals, no irradiation induced defects were observed for the reference, whereas the small NCs (2.5 nm) were dissolved as Cu monomers in the matrix. The latter was attributed to irradiation-induced mixing of Cu, Si and O based on dynamic binary collision simulations. For the large NCs (8.1 nm) only minor structural changes were observed upon irradiation, consistent with a more bulk-like pre-irradiation structure. 相似文献
20.
《Journal of Nuclear Science and Technology》2013,50(7):759-770
In the case of severe accidents, the radionuclides release from fuel could mostly occur at high temperature under elevated pressure. The effect of temperature on the release has been clarified in many previous studies while the pressure influence has been scarcely investigated so far due to difficulty in the experimental operation. To investigate the effect of pressure on the release, two tests under the same conditions except for the system pressure were performed in the VEGA program at JAERI by heating up the irradiated UO2fuels up to 2,773 K in inert helium. The test results uniquely showed that the release rate of cesium for the temperatures below 2,773 K at 1.0 MPa could be suppressed by about 30% compared with that at 0.1 MPa. This article describes the outlines of the two tests and the observed effects of system pressure on cesium release as well as the results of various post-irradiation examinations. Moreover, the mechanisms and models that explain the pressure effect are discussed. 相似文献