a—Si TFT中钼与非晶硅之间的互作用

本文报导当在室温下向非晶硅（ａ－Ｓｉ）表面溅射钼（Ｍｏ）的过程中Ｍｏ与非晶硅发生互作用的现象。该互作用要求一定的临界溅射功率与钼层厚度。其作用速率在ａ－Ｓｉ界面为反应速率限制,而在与Ｍｏ交界面则为扩建速率限制。互作用生成非晶态钼硅Ｍｏ：ａ－Ｓｉ合金。它可阻止铝（Ａｌ）向ａ－Ｓｉ中扩散,同时可改善ａ－Ｓｉ ＴＦＴ的接触特性。当用Ａｌ／Ｍｏ作ａ－Ｓｉ薄膜晶体管（ａ－Ｓｉ ＴＦＴ）的源和漏电极时,可提高     

Preparation and measurement of highly efficient a‐Si:H single junction solar cells and the advantages of μc‐SiOx:H n‐layers

Reducing the optical losses and increasing the reflection while maintaining the function of doped layers at the back contact in solar cells are important issues for many photovoltaic applications. One approach is to use doped microcrystalline silicon oxide (μc‐SiO_x:H) with lower optical absorption in the spectral range of interest (300 nm to 1100 nm). To investigate the advantages, we applied the μc‐SiO_x:H n‐layers to a‐Si:H single junction solar cells. We report on the comparison between amorphous silicon (a‐Si:H) single junction solar cells with either μc‐SiO_x:H n‐layers or non‐alloyed silicon n‐layers. The origin of the improved performance of a‐Si:H single junction solar cells with the μc‐SiO_x:H n‐layer is identified by distinguishing the contributions because of the increased transparency and the reduced refractive index of the μc‐SiO_x:H material. The solar cell parameters of a‐Si:H solar cells with both types of n‐layers were compared in the initial state and after 1000 h of light soaking in a series of solar cells with various absorber layer thicknesses. The measurement procedure for the determination of the solar cell performance is described in detail, and the measurement accuracy is evaluated and discussed. For an a‐Si:H single junction solar cell with a μc‐SiO_x:H n‐layer, a stabilized efficiency of 10.3% after 1000 h light soaking is demonstrated. Copyright © 2015 John Wiley & Sons, Ltd.     

Laser-induced degradation of the photoluminescence intensity of porous silicon

Transmission Fourier-transform infrared (FTIR) spectroscopy has been used to monitor laser-induced degradation of the photoluminescence (PL) intensity of porous Si. It is observed that the release of hydrogen from silicon hydride surface species coincides with a decrease in the PL intensity and oxidation of the porous Si. The as-anodized PL characteristics can be recovered, with a slight blue shift, by a brief immersion in hydrofluoric acid.     

Study of thermal cycling and temperature aging on PbSnAg die attach solder joints for high power modules

High power modules are still facing the challenges to increase their power output, increase the junction temperature, and increase their reliability in harsh conditions. Therefore this study is doing a detail analysis of the soldering joint between a direct copper bonded substrate and a high power IGBT made with the high lead solder alloy Pb_92.5Sn_5.0Ag_2.5. The intermetallic phases and the microstructure of standard chip to substrate solder joint will be analysed and compared to deteriorated joints coming from modules which have undergone an active thermal cycling. As expected, the as soldered joint was clearly different than solder joints made for ball grid array or small components on PCBs. The as soldered joint shows no sign of Cu₆Sn₅ intermetallic layer, but instead shows the presence of Ag₃Sn particles at the solder–chip interface. Furthermore, the failure mechanisms under active thermal cycling also seem to be different. There is no growth of intermetallic phases and no strong delamination of the device. Instead a large network of intermetallic particles (Ag₃Sn) is produced during aging and seems to degrade the solder thermal properties.     

High potential of thin (<1 µm) a‐Si: H/µc‐Si:H tandem solar cells

Silicon based thin tandem solar cells were fabricated by plasma enhanced chemical vapor deposition (PECVD) in a 30 × 30 cm² reactor. The layer thicknesses of the amorphous top cells and the microcrystalline bottom cells were significantly reduced compared to standard tandem cells that are optimized for high efficiency (typically with a total absorber layer thickness from 1.5 to 3 µm). The individual absorber layer thicknesses of the top and bottom cells were chosen so that the generated current densities are similar to each other. With such thin cells, having a total absorber layer thickness varying from 0.5 to 1.5 µm, initial efficiencies of 8.6–10.7% were achieved. The effects of thickness variations of both absorber layers on the device properties have been separately investigated. With the help of quantum efficiency (QE) measurements, we could demonstrate that by reducing the bottom cell thickness the top cell current density increased which is addressed to back‐reflected light. Due to a very thin a‐Si:H top cell, the thin tandem cells show a much lower degradation rate under continuous illumination at open circuit conditions compared to standard tandem and a‐Si:H single junction cells. We demonstrate that thin tandem cells of around 550 nm show better stabilized efficiencies than a‐Si:H and µc‐Si:H single junction cells of comparable thickness. The results show the high potential of thin a‐Si/µc‐Si tandem cells for cost‐effective photovoltaics. Copyright © 2010 John Wiley & Sons, Ltd.