BEHAVIOUR OF FLUORINE IN BLAST-FURNACE SMELTING Ⅱ.SMELTING PAO-TOU IRON ORE IN AN EXPERIMENTAL BLAST-FURNACE

为了研究包头铁矿的冶炼特性及由于矿石含氟所引起的一系列问题起见,我所于1955年11月筹建了有效容积约为1米~3的实验高炉一座及全部附属设备。1955年11月30日至12月8日及12月20日至12月24日进行了二次试炉。经过设备上的改进后,于1956年1月20日至2月11日及4月23日至5月29日进行了二次冶炼试验,获得设计上所要求的的主要数据后停炉。在实验高炉冶炼试验期间并进行了4次物质平衡的试验。结果发现绝大部分的氟进入炉渣中,进入炉尘中的氟石多,而高炉煤气中的氟极低.     

BEHAVIOUR OF FLUORINE IN BLAST-FURNACE SMELTING Ⅳ. MECHANISM OF VOLATILIZATION OF FLUORINE AND ITS MOVEMENT IN A 11M~3 BLAST-FURNACE SMELTING PAO-TOU IRON ORE

本次对高炉内氟的变化的研究,系在石景山钢铁厂内11M~3高炉上进行,试验结果证实了前一文中关于1M~3实验高炉内氟变化情况的结论,即煤气中氟与石灰或石灰石间接近平衡,而与温度的分布有很大关系。本次度验取得炉料样品较多,因此对氟从矿石中和熔渣中的挥发机理有所阐明,而对氟在高炉内的变化获得了较为完整的概念。     

BEHAVIOUR OF FLUORINE IN BLAST-FURNACE SMELTING Ⅴ. AN INVESTIGATION OF THE SLAG-FORMING PROCESSES IN A 11M~3 BLASTFURNACE SMELTING PAO-TOU IRON ORE

在本文中,我们报告了11M~3高炉冶炼包头铁矿时炉料样品包括矿石、初渣、终渣的岩相分析及初渣的化学分析结果,并结合温度测定数据,画出了高炉中等温线及各区域的分市情况,以及各区域炉料中的矿物组成。根据以上实验结果,讨论了冶炼包头铁矿时的初渣形成机理,并指出初渣的性质与一般酸性铁矿不同,此点对高炉的顺行有利。     

BEHAVIOUR OF FLUORINE IN BLAST-FURNACE SMELTING Ⅰ.EFFECTS OF FLUORINE ON THE VISCOSITY,MELTING POINT AND DESULFURIZING POWER OF LIQUID BLASTFURNACE-TYPE SLAGS

在本文中,我们报告了含氟高炉型熔渣的的粘度、熔化性和脱疏力的研究结果。所用熔渣包括坩埚冶炼渣与合成渣,含氟化钙最高达40.7%。试验数据指出氟能显著地降低熔渣的粘度与熔化温度,但对硫在渣、铁间的平衡分配影响较小。因此作为初步估计,在计算硷度时可以将氟化钙视为中性。根据本文试验结果,我们从熔渣的离子结构观点讨论了氟影响熔渣性质的机理。     

THE ALLOYING BEHAVIOR OF BORON AND CARBON INNi_3Al

ＴＨＥＡＬＬＯＹＩＮＧＢＥＨＡＶＩＯＲＯＦＢＯＲＯＮＡＮＤＣＡＲＢＯＮＩＮＮｉ３Ａｌ①ＺｈａｎｇＹｕｎ，ＨｕａｎｇＪｉｎ，ＬｉｎＤｏｎｇｌｉａｎｇＳｈａｎｇｈａｉＪｉａｏｔｏｎｇＵｎｉｖｅｒｓｉｔｙ，Ｓｈａｎｇｈａｉ２０００３０ＡＢＳＴＲＡＣＴＴｏｆ...     

SIMULATION OF SOLIDIFICATION BEHAVIOR IN SPRAY DEPOSITED PREFORMⅠ. Theoretical Analysis

本文采用“虚拟”凝固层的概念,通过对沉积坯件内凝固过程的理论分析。建立了相应的理论模型,为进一步分析沉积坯件中的凝固行为提供了理论依据。     

THEORETICAL CALCULATION OF POINT DEFECTS IN Ni_3Al

Equilibrium equation of point defects in Ll_2 type intermetallic compounds was established tocalculate the relations of the concentration of antisite defects and vacancies and bulk composi-tion in Ni_3Al.The examination of temperature effects on the point defects cleared up the mis.understanding of the properties of the“constitutional point defects”in Ni_3Al.     

BEHAVIOR OF Mg AND ITS EFFECT ON MECHANICAL PROPERTIES OF CAST Fe_3Al ALLOYS

Proper addition of 0.002 wt-% Mg to cast Fe_3Al alloy may obviously improve the room andhigh temperature tensile properties.Auger spectra show that Mg segregates near grainboundaries as very thin layers.Observation under TEM reveals that a suitable amount of Mgenhances ability of cooperative internal deformation so that the dislocations will ease the con-tinuous slip deformation through grain boundaries.The fracture feature of Fe_3Al alloy is oftransgranular cleavage at room temperature and cracks initiate at grain boundaries.     

AN IN-SITU STUDY ON DISLOCATION BEHAVIOR OF CRACK-TIP IN Ti_3Al-Nb ALLOY

ＡＮＩＮＳＩＴＵＳＴＵＤＹＯＮＤＩＳＬＯＣＡＴＩＯＮＢＥＨＡＶＩＯＲＯＦＣＲＡＣＫＴＩＰＩＮＴｉ３ＡｌＮｂＡＬＬＯＹ①ＷｕＹｉｎｇ，ＺｈｅｎＬｉａｎｇ，ＹａｎｇＤｅｚｈｕａｎｇＳｃｈｏｏｌｏｆＭａｔｅｒｉａｌｓＳｃｉｅｎｃｅａｎｄＥｎｇｉｎｅｒ...     

PRECIPITATION BEHAVIOR OF Co PHASES IN B2-ORDERED(Ni,Co)Al COMPOUND

且．工口止OOdllCt1OllThe BZ－ordered NIAI has received considerable attention because oflts pete尬lal forhightemperature applicatlonsll,2]．Its ad皿ntages are high melting temperature,rel幼Ivelylow density ofs．959/cm’and good皿idatlon resistance at high     

INFLUENCE OF Al ON DUCTILITY IMPROVEMENT BY B IN Ni_3Al ALLOYS

The “order-disorder” model was adopted to calculate the lattice vacancies related to the com- position change in Ni_3Al alloys.A great deal of vacancies,i.e.,the non-stoichiometric vacan- cies,may exist in the Ni_3Al alloys containing Al over stoichiometry,i.e.25 at.-%.This was confirmed by the positron annihilation technique.Therefore,the influence of Al content on the enhancing behaviour of B towards the ductility of Ni_3Al alloys can be understood by the interaction of non-stoiehiometric vacancies and B atoms.     

SIMULATION OF SOLIDIFICAFION BEHAVIOR IN SPRAY DEPOSITED PREFORM Ⅱ.Calculation Results For Al-Cu Alloy

根据本文作者提出的喷射沉积成型沉积体内的凝固模型,对典型的Ａｌ－Ｃｕ合金进行了计算分析。结果表明,工艺参数和材料的热物性对沉积体内的凝固过程有明显影响。     

THERMODYNAMICS OF BAINITIC TRANSFORMATION IN Cu-24 at.-% Al ALLOY

Two driving forces △G~((β_1)+α')and △G~(β_1→β_2+α)for the bainitic transformation have been calcu-lated for Cu-24 at.-% Al alloy.Results reveal △G~(β_1→α')>0 within the transformation tem-perature range 600—750 K.Therefore,the bainitic transformation cannot be initiated by theβ_1→α' shearing mechanism.On the other hand,the driving force △G~(β_1→β_2+α)to produce 5% ofthe α becomes negative only when the composition of the α satisfiesx_(Al)~α≤0.204 at 700 K or x_(Al)~α=0.209 at 750 K.So the bainitic transformation can only proceedby β_1→β_2+α diffusional reaction with different diffusion amount at different temperatures.     

EVOLUTION OF MICROSTRUCTURE IN OXIDATIVE GROWTH OF Al_2O_3／Al ALLOY COMPOSITES

ＥＶＯＬＵＴＩＯＮＯＦＭＩＣＲＯＳＴＲＵＣＴＵＲＥＩＮＯＸＩＤＡＴＩＶＥＧＲＯＷＴＨＯＦＡｌ_２Ｏ_３／ＡｌＡＬＬＯＹＣＯＭＰＯＳＩＴＥＳ￥ＸｉａＣｈａｎｇｑｉｎｇ；ＪｉｎＺｈａｎｐｅｎｇ（ＤｅｐａｒｔｍｅｎｔｏｆＭａｔｅｒｉａｌｓＳｃｉｅｎｃｅａｎｄ...     

STUDY ON THE THERMODYNAMICS OF CuO／Al IN SITU Al2O3 REINFORCED Al MATRIX COMPOSITES

Based on the experiment and the thermodynamics analysis for CuO/Al system, it is founded that the compounding reaction of CuO/Al under low temperature is available. The general equation of adiabatic temperature of the system is set up, and the influence of resultant concentration and temperature on adiabatic temperature is theoretically analyzed. The values of heat effect of CuO/Al system under different temperature are also caculated.     

THE INFLUENCE OF Mo DIFFUSION ON THE THERMAL BEHAVIOR OF TBCs ON Ni_3Al BASED ALLOY IC-6

Conventional two-layered structure thermal barrier coatings (TBCs) were prepared onto γ'-Ni3Al based alloy IC-6 by electron beam physical vapor deposition (EB-PVD). Isothermal oxidation and thermal cycling tests were carried out to investigate the effect of Mo content at the interface between bond coat and ceramic top coat caused by diffusion. It has been found that the alloy coated with TBCs presented the lowest oxidation weight gain value for the reason that the ceramic top coat in TBC system can effectively stop Mo oxides evaporating. The life time of TBCs has close relation with Mo content at the interface between the bond coat and top coat. Spaliation of ceramic top coat occurred during thermal cyclic testing when Mo atoms accumulated at the interface up to certain amount to decline the combination between the bond coat and top coat.     

LOCAL CHEMISTRY AND THE COHESIVE STRENGTH OF GRAIN BOUNDARIES IN Ni_3Al

ＬＯＣＡＬＣＨＥＭＩＳＴＲＹＡＮＤＴＨＥＣＯＨＥＳＩＶＥＳＴＲＥＮＧＴＨＯＦＧＲＡＩＮＢＯＵＮＤＡＲＩＥＳＩＮＮｉ_３ＡｌＳｈａｎｔｈｉＳｕｂｒａｍａｎｉａｎ；ＤａｖｉｄＭｕｌｌｅｒ；ＪｏｈｎＳｉｌｃｏｘａｎｄＳｔｅｐｈｅｎＬ．Ｓａｓｓ（Ｄｅｐａｒｔ?..     

MOLECULAR STATIC SIMULATION OF ENERGY FEATURESOF INTERACTION BETWEEN GRAIN BOUNDARYAND DISLOCATIONS IN Ni＿3Al ALLOY

ＭＯＬＥＣＵＬＡＲＳＴＡＴＩＣＳＩＭＵＬＡＴＩＯＮＯＦＥＮＥＲＧＹＦＥＡＴＵＲＥＳＯＦＩＮＴＥＲＡＣＴＩＯＮＢＥＴＷＥＥＮＧＲＡＩＮＢＯＵＮＤＡＲＹＡＮＤＤＩＳＬＯＣＡＴＩＯＮＳＩＮＮｉ＿３ＡｌＡＬＬＯＹＣｈｅｎ，Ｄａ；Ｌｕ，Ｍｉｎ；Ｌｉｎ，Ｄｏｎｇ...     

PREPARATION AND SOLIDIFICATION CHARACTERISTIC OF IN SITU DIRECTIONALLY SOLIDIFIED EUTECTIC Al_(11)La_3/Al COMPOSITE

In situ eutectic Al_(11)La_3/Al composite material with regular arrangement was prepared byzone melt liquid metal cooling directionally solidification under conditions of high temperaturegradient G=700K/cm and growth rate R=6.0-20.0μm/s.Superpose diffraction pat-tern of Al_(11)La_3/Al composite shows that the preferred growth direction is[100]Al//[33]Al_(11)La_3,and the habit plane is(002)Al//(116)Al_(11)La_3.A low density(103)twin is ob-served in Al_(11)La_3 and the growth of(103)twin induces to branching to change theinterlamellar spacing.     

CRYSTALLOGRAPHY OF MARTENSITIC TRANSFORMATION IN A Cu-26Zn-4Al SHAPE MEMORY ALLOY Ⅱ. Application of Group Theory

本文试图用群论的理论分析,探讨Cu-Zn-Al合金马氏体相变的晶体学性质:由群的表示理论找得诱导该合金B_2结构母相β→非规则9R马氏体的不可约表示;由群论讨论该合金马氏体相变具有24个变态的可能性,找出由组态组成的自协调组织的对称性群D_2h,揭示了变态间的对称联系和分布规律。