Experimental study of the performances of a modified diesel engine operating in homogeneous charge compression ignition (HCCI) combustion mode versus the original diesel combustion mode

Homogeneous charge compression ignition (HCCI) combustion mode provides very low NO_x and soot emissions; however, it has some challenges associated with hydrocarbon (HC) emissions, fuel consumption, difficult control of start of ignition and bad behaviour to high loads. Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production in diesel and HCCI combustion mode. However EGR has different effects on combustion and emissions, which are difficult to distinguish. This work is intended to characterize an engine that has been modified from the base diesel engine (FL1 906 DEUTZ-DITER) to work in HCCI combustion mode. It shows the experimental results for the modified diesel engine in HCCI combustion mode fueled with commercial diesel fuel compared to the diesel engine mode. An experimental installation, in conjunction with systematic tests to determine the optimum crank angle of fuel injection, has been used to measure the evolution of the cylinder pressure and to get an estimate of the heat release rate from a single-zone numerical model. From these the angle of start of combustion has been obtained. The performances and emissions of HC, CO and the huge reduction of NO_x and smoke emissions of the engine are presented. These results have allowed a deeper analysis of the effects of external EGR on the HCCI operation mode, on some engine design parameters and also on NO_x emission reduction.     

Modeling of NOx formation in diesel engines using finite-rate chemical kinetics

A fast, physics-based model to predict the temporal evolution of NO_x in diesel engines is investigated using finite-rate chemical kinetics. The temporal variation of temperature required for the computation of the reaction rate constants is obtained from the solution of the energy equation. NO_x formation is modeled by using a six step mechanism with eight species instead of the traditional equilibrium calculations based on the Zeldovich mechanism. Fuel combustion chemistry is modeled by a single-step global reaction. Effects of various stages of combustion on NO_x formation is included using a phenomenological burning rate model. The effects of composition and temperature on the thermophysical properties of the working fluid are included in the computations. Comparison with measured single-cylinder engine-out NO shows good agreement with experimental data. The validated model is then used to demonstrate the impact of various operating parameters such as injection timing and EGR on engine-out NO_x. This fast, robust model has potential applications in model-based real-time control strategies seeking to reduce feed gas NO_x emissions from diesel engines.     

The influence of hydrogen-enriched gas on the performance of lean NOx trap catalyst for a light-duty diesel engine

Modern diesel engines have improved engine fuel economy and significantly reduced nitrogen oxides (NO_x) and particulate matter (PM) emissions achieved by advances in both combustion and exhaust aftertreatment technologies. Recently, it has been shown that the vehicle emissions can be further improved by several catalytic systems including fuel reformers and aftertreatment systems, such as the Lean NO_x Trap (LNT). This NO_x removal system, called LNT, absorbs NO_x under lean exhaust gas conditions and releases NO_x under rich conditions. This technology can provide high NO_x conversion efficiency, but the right amount of reducing agent should be supplied into the catalytic converter under appropriate conditions.     

Investigation of the effects of hydrogen on cylinder pressure in a split-injection diesel engine at heavy EGR

The distinctive properties of hydrogen have initiated considerable applied research related to the internal combustion engine. Recently, it has been reported that NO_x emissions were reduced by using hydrogen in a diesel engine at low temperature and heavy EGR conditions. As the continuing study, cylinder pressure was also investigated to determine the combustion characteristics and their relationship to NO_x emissions. The test engine was operated at constant speed and fixed diesel fuel injection rate (1500 rpm, 2.5 kg/h). Diesel fuel was injected in a split pattern into a 2-L diesel engine. The cylinder pressure was measured for different hydrogen flow rates and EGR ratios. The intake manifold temperature was controlled to be the same to avoid the gas intake temperature variations under the widely differing levels (2%-31%) of EGR. The measured cylinder pressure was analyzed for characteristic combustion values, such as mass burn fraction and combustion duration.The rising crank angle of the heat release rate was unaffected by the presence of hydrogen. However, supplying hydrogen extended the main combustion duration. This longer main combustion duration was particularly noticeable at the heavy EGR condition. It correlated well with the reduced NO_x emissions.     

A new heat release rate (HRR) law for homogeneous charge compression ignition (HCCI) combustion mode

Homogeneous charge compression ignition (HCCI) engines are drawing attracting attention as the next-generation’s internal combustion engine, mainly because of its very low NO_x and soot emissions and also for improvement in engine efficiency. Much research has been carried out in order to go deeper in this combustion process using multizone models or CFD codes. These simulation tools, although they can give a detailed view of the combustion process, are very time consuming and the results depend a lot on the initial conditions. A previous step to be considered in the simulation of the HCCI process is a heat release law evaluated from results of the experiment and a zero-dimensional model. This paper focuses on the development of a new heat release rate (HRR) law that models the HCCI process when the combustion chamber is considered as a homogeneous volume. The parameters of this law have been adjusted through an optimization process that has allowed to fit the combustion chamber pressure. All the engine operative conditions from low to full load have been successfully simulated with this HRR law, with the maximum error in the estimation of combustion chamber pressure less than 2%.     

Soot processes in compression ignition engines

While diesel engines are arguably superior to any other power-production device for the transportation sector in terms of efficiency, torque, and overall driveability, they suffer from inferior performance in terms of noise, NO_x and particulate emissions. The majority of particulate originates with soot particles which are formed in fuel-rich regions of burning diesel jets. Over the past two decades, our understanding of the formation process of soot in diesel combustion has transformed from inferences based on exhaust measurements and laboratory flames to direct in-cylinder observations that have led to a transformation in diesel engine combustion. In-cylinder measurements show the diesel spray to produce a jet which forms a lifted, partially premixed, turbulent diffusion flame. Soot formation has been found to be strongly dependent on air entrainment in the lifted portion of the jet as well as by oxygen in the fuel and to a lesser extent the composition and structure of hydrocarbons in the fuel. Soot surviving the combustion process and exiting in the exhaust is dominated by soot from fuel-rich pockets which do not have time to mix and burn prior to exhaust valve opening. Higher temperatures at the end of combustion enhance the burnout of soot, while high temperatures at the time of injection reduce air entrainment and increase soot formation. Using a conceptual model based on in-cylinder soot and combustion measurements, trends seen in exhaust particulate can be explained. The current trend in diesel engine emissions control involves multi-injection combustion strategies which are transforming the picture of diesel combustion rapidly into a series of low temperature, stratified charge, premixed combustion events where NO_x formation is avoided because of low temperature and soot formation is avoided by leaning the mixture or increasing air entrainment prior to ignition.     

Hydrogen assisted diesel combustion

Hydrogen assisted diesel combustion was investigated on a DDC/VM Motori 2.5L, 4-cylinder, turbocharged, common rail, direct injection light-duty diesel engine, with a focus on exhaust emissions. Hydrogen was substituted for diesel fuel on an energy basis of 0%, 2.5%, 5%, 7.5%, 10% and 15% by aspiration of hydrogen into the engine's intake air. Four speed and load conditions were investigated (1800 rpm at 25% and 75% of maximum output and 3600 rpm at 25% and 75% of maximum output). A significant retarding of injection timing by the engine's electronic control unit (ECU) was observed during the increased aspiration of hydrogen. The retarding of injection timing resulted in significant NO_X emission reductions, however, the same emission reductions were achieved without aspirated hydrogen by manually retarding the injection timing. Subsequently, hydrogen assisted diesel combustion was examined, with the pilot and main injection timings locked, to study the effects caused directly by hydrogen addition. Hydrogen assisted diesel combustion resulted in a modest increase of NO_X emissions and a shift in NO/NO₂ ratio in which NO emissions decreased and NO₂ emissions increased, with NO₂ becoming the dominant NO_X component in some combustion modes. Computational fluid dynamics analysis (CFD) of the hydrogen assisted diesel combustion process captured this trend and reproduced the experimentally observed trends of hydrogen's effect on the composition of NO_X for some operating conditions. A model that explicitly accounts for turbulence–chemistry interactions using a transported probability density function (PDF) method was better able to reproduce the experimental trends, compared to a model that ignores the influence of turbulent fluctuations on mean chemical production rates, although the importance of the fluctuations is not as strong as has been reported in some other recent modeling studies. The CFD results confirm that temperature changes alone are not sufficient to explain the observed reduction in NO and increase in NO₂ with increasing H₂. The CFD results are consistent with the hypothesis that in-cylinder HO₂ levels increase with increasing hydrogen, and that the increase in HO₂ enhances the conversion of NO to NO₂. Increased aspiration of hydrogen resulted in PM, and HC emissions which were combustion mode dependent. Predominantly, CO and CO₂ decreased with the increase of hydrogen. The aspiration of hydrogen into the engine modestly decreased fuel economy due to reduced volumetric efficiency from the displacement of air in the cylinder by hydrogen.     

Experimental study of various effects of exhaust gas recirculation (EGR) on combustion and emissions of an automotive direct injection diesel engine

Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production and is used on most modern high-speed direct injection (HSDI) diesel engines. However EGR has different effects on combustion and emissions production that are difficult to distinguish (increase of intake temperature, delay of rate of heat release (ROHR), decrease of peak heat release, decrease in O₂ concentration (and thus of global air/fuel ratio (AFR)) and flame temperature, increase of lift-off length, etc.), and thus the influence of EGR on NO_x and particulate matter (PM) emissions is not perfectly understood, especially under high EGR rates. An experimental study has been conducted on a 2.0 l HSDI automotive diesel engine under low-load and part load conditions in order to distinguish and quantify some effects of EGR on combustion and NO_x/PM emissions. The increase of inlet temperature with EGR has contrary effects on combustion and emissions, thus sometimes giving opposite tendencies as traditionally observed, as, for example, the reduction of NO_x emissions with increased inlet temperature. For a purely diffusion combustion the ROHR is unchanged when the AFR is maintained when changing in-cylinder ambient gas properties (temperature or EGR rate). At low-load conditions, use of high EGR rates at constant boost pressure is a way to drastically reduce NO_x and PM emissions but with an increase of brake-specific fuel consumption (BSFC) and other emissions (CO and hydrocarbon), whereas EGR at constant AFR may drastically reduce NO_x emissions without important penalty on BSFC and soot emissions but is limited by the turbocharging system.     

Effect of Exhaust Gas Recirculation (EGR) on performance,emissions, deposits and durability of a constant speed compression ignition engine

To meet stringent vehicular exhaust emission norms worldwide, several exhaust pre-treatment and post-treatment techniques have been employed in modern engines. Exhaust Gas Recirculation (EGR) is a pre-treatment technique, which is being used widely to reduce and control the oxides of nitrogen (NO_x) emission from diesel engines. EGR controls the NO_x because it lowers oxygen concentration and flame temperature of the working fluid in the combustion chamber. However, the use of EGR leads to a trade-off in terms of soot emissions. Higher soot generated by EGR leads to long-term usage problems inside the engines such as higher carbon deposits, lubricating oil degradation and enhanced engine wear. Present experimental study has been carried out to investigate the effect of EGR on soot deposits, and wear of vital engine parts, especially piston rings, apart from performance and emissions in a two cylinder, air cooled, constant speed direct injection diesel engine, which is typically used in agricultural farm machinery and decentralized captive power generation. Such engines are normally not operated with EGR. The experiments were carried out to experimentally evaluate the performance and emissions for different EGR rates of the engine. Emissions of hydrocarbons (HC), NO_x, carbon monoxide (CO), exhaust gas temperature, and smoke opacity of the exhaust gas etc. were measured. Performance parameters such as thermal efficiency, brake specific fuel consumption (BSFC) were calculated. Reduction in NO_x and exhaust gas temperature were observed but emissions of particulate matter (PM), HC, and CO were found to have increased with usage of EGR. The engine was operated for 96 h in normal running conditions and the deposits on vital engine parts were assessed. The engine was again operated for 96 h with EGR and similar observations were recorded. Higher carbon deposits were observed on the engine parts operating with EGR. Higher wear of piston rings was also observed for engine operated with EGR.     

Influence of biodiesel on engine combustion and emission characteristics

This paper discusses the influence of biodiesel on the engine combustion characteristics. The considered fuel is neat biodiesel from rapeseed oil. The considered engine is a bus diesel engine with injection M system. The engine characteristics are obtained by experiments and numerical simulation. The results obtained with biodiesel are compared to those obtained with mineral diesel under various operating regimes. In this way, the influences of biodiesel usage on the injection pressure, injection timing, ignition delay, in-cylinder gas pressure and temperature, heat release rate, exhaust gas temperatures, harmful emissions, specific fuel consumption, and on engine power are analyzed. Furthermore, the relationships among fuel properties, injection and combustion characteristics, harmful emissions, and other engine performance are determined. Special attention is given to possible explanations of higher NO_x emission in spite of lower in-cylinder gas temperature.     

Experimental study of combustion and emission characteristics of ethanol fuelled port injected homogeneous charge compression ignition (HCCI) combustion engine

The homogeneous charge compression ignition (HCCI) is an alternative combustion concept for in reciprocating engines. The HCCI combustion engine offers significant benefits in terms of its high efficiency and ultra low emissions. In this investigation, port injection technique is used for preparing homogeneous charge. The combustion and emission characteristics of a HCCI engine fuelled with ethanol were investigated on a modified two-cylinder, four-stroke engine. The experiment is conducted with varying intake air temperature (120–150 °C) and at different air–fuel ratios, for which stable HCCI combustion is achieved. In-cylinder pressure, heat release analysis and exhaust emission measurements were employed for combustion diagnostics. In this study, effect of intake air temperature on combustion parameters, thermal efficiency, combustion efficiency and emissions in HCCI combustion engine is analyzed and discussed in detail. The experimental results indicate that the air–fuel ratio and intake air temperature have significant effect on the maximum in-cylinder pressure and its position, gas exchange efficiency, thermal efficiency, combustion efficiency, maximum rate of pressure rise and the heat release rate. Results show that for all stable operation points, NO_x emissions are lower than 10 ppm however HC and CO emissions are higher.     

Analysis of reformed EGR on the performance of a diesel particulate filter

The use of a diesel particulate filter (DPF) in combination with an upstream diesel oxidation catalyst (DOC) has been successfully implemented and shown to reduce carbon monoxide (CO), hydrocarbon (HC) and Particulate Matter (PM) diesel exhaust gas emissions. However issues including cost, size and uncontrolled active regeneration under a low temperature window still require attention. This study therefore primarily focuses on the potential benefits of using a single catalytic coated DPF (cDPF) and a combined DOC-cDPF instead of the DOC-DPF aftertreatment system utilising a passive, low temperature regeneration method. Comparisons were made through monitoring exhaust gas compositions from an experimental single cylinder diesel engine as well as measuring the pressure drop across the filters to analyse the accumulation of soot particles. The influence of reformed EGR (REGR), enriched simulated hydrogen (H₂) and CO, on DPF and cDPF soot loading was of interest as H₂ promotes the NO to NO₂ oxidation. Similarly the addition of simulated reformate (added either directly into the engine intake or exhaust manifold) for optimal performance of the aftertreatment systems was examined.The effects of adding REGR resulted in a significant decrease in total engine-out NO_x emissions, as well as an increase in both NO₂ concentration and NO₂/NO_x ratio. This resulted in improved filter efficiency and overall loading, especially under a DOC-cDPF aftertreatment configuration system. As a whole, a simultaneous NO_x and PM reduction was achieved.     

Application of exhaust gas fuel reforming in diesel and homogeneous charge compression ignition (HCCI) engines fuelled with biofuels

This paper documents the application of exhaust gas fuel reforming of two alternative fuels, biodiesel and bioethanol, in internal combustion engines. The exhaust gas fuel reforming process is a method of on-board production of hydrogen-rich gas by catalytic reaction of fuel and engine exhaust gas. The benefits of exhaust gas fuel reforming have been demonstrated by adding simulated reformed gas to a diesel engine fuelled by a mixture of 50% ultra low sulphur diesel (ULSD) and 50% rapeseed methyl ester (RME) as well as to a homogeneous charge compression ignition (HCCI) engine fuelled by bioethanol. In the case of the biodiesel fuelled engine, a reduction of NO_x emissions was achieved without considerable smoke increase. In the case of the bioethanol fuelled HCCI engine, the engine tolerance to exhaust gas recirculation (EGR) was extended and hence the typically high pressure rise rates of HCCI engines, associated with intense combustion noise, were reduced.     

Effect of exhaust gas recirculation (EGR) temperature for various EGR rates on heavy duty DI diesel engine performance and emissions

DI diesel engines are well established today as the main powertrain solution for trucks and other relevant heavy duty vehicles. At the same time emission legislation (mainly for NO_x and particulate matter) becomes stricter, reducing their limit to extremely low values. One efficient method to control NO_x in order to achieve future emissions limits is the use of rather high exhaust gas recirculation (EGR) rates accompanied by increased boost pressure to avoid the negative impact on soot emissions. The method is based on the reduction of gas temperature level and O₂ availability inside the combustion chamber, but unfortunately it has usually an adverse effect on soot emissions and brake specific fuel consumption (bsfc). The use of high EGR rates creates the need for EGR gas cooling in order to minimize its negative impact on soot emissions especially at high engine load were the EGR flow rate and exhaust temperature are high. For this reason in the present paper it is examined, using a multi-zone combustion model, the effect of cooled EGR gas temperature level for various EGR percentages on performance and emissions of a turbocharged DI heavy duty diesel engine operating at full load. Results reveal that the decrease of EGR gas temperature has a positive effect on bsfc, soot (lower values) while it has only a small positive effect on NO. As revealed, the effect of low EGR temperature is stronger at high EGR rates.     

Oxides of nitrogen emissions from biodiesel-fuelled diesel engines

Biodiesel has received, and continues to receive, considerable attention for its potential use as an augmenting fuel to petroleum diesel. Its advantages include decreased net carbon dioxide, hydrocarbon, carbon monoxide, and particulate matter emissions, and fuel properties similar to petroleum diesel for ease of use in diesel engines. Its disadvantages include poorer cold flow characteristics, lower heating values, and mostly reported higher emissions of oxides of nitrogen (NO_x = NO + NO₂, where NO is nitric oxide and NO₂ is nitrogen dioxide). This latter disadvantage (i.e., higher emissions of oxides of nitrogen) is the focus of this review article. NO_x formation mechanisms are complex and affected by several different features (e.g., size, operating points, combustion chamber design, fuel system design, and air system design) of internal combustion engines. The slight differences in properties between biodiesel and petroleum diesel fuels are enough to create several changes to system and combustion behaviors of diesel engines. Combined, these effects lead to several complex and interacting mechanisms that make it difficult to fundamentally identify how biodiesel affects NO_x emissions. Instead, it is perhaps better to say that several parameters seem to most strongly influence observed differences in NO_x emissions with biodiesel, thus introducing several possibilities for inconsistency in the trends. These parameters are injection timing, adiabatic flame temperature, radiation heat transfer, and ignition delay. This article provides a review of the rich literature describing these parameters, and provides additional insight into the system responses that are manifested by the use of biodiesel.     

Numerical study of effects of reformed exhaust gas recirculation (REGR) on dimethyl ether HCCI combustion

The effects of reformed exhaust gas recirculation (REGR) on combustion and emissions of dimethyl ether (DME) homogeneous charge compression ignition (HCCI) engines are studied by multi-dimensional CFD coupled with chemical kinetic model. The results show that REGR combing EGR and DME reformed gases (DRG) improves combustion and emissions. REGR can delay ignition time by both EGR and DRG, and makes main combustion closer to top dead center (TDC), which is beneficial to reducing compression negative work and broadening load range of HCCI engines. The interaction of DRG and EGR helps avoid too high pressure rise rate or low power performance when being applied independent of each other. HC, CO and NO_x emissions can be controlled simultaneously by REGR. Both advantages of DRG and EGR are used to decrease the emissions of HCCI engines by REGR, while the disadvantages of high emissions are alleviated when one of them is applied.     

Fundamental phenomena affecting low temperature combustion and HCCI engines,high load limits and strategies for extending these limits

Low temperature combustion (LTC) engines are an emerging engine technology that offers an alternative to spark-ignited and diesel engines. One type of LTC engine, the homogeneous charge compression ignition (HCCI) engine, uses a well-mixed fuel–air charge like spark-ignited engines and relies on compression ignition like diesel engines. Similar to diesel engines, the use of high compression ratios and removal of the throttling valve in HCCI allow for high efficiency operation, thereby allowing lower CO₂ emissions per unit of work delivered by the engine. The use of a highly diluted well-mixed fuel–air charge allows for low emissions of nitrogen oxides, soot and particulate matters, and the use of oxidation catalysts can allow low emissions of unburned hydrocarbons and carbon monoxide. As a result, HCCI offers the ability to achieve high efficiencies comparable with diesel while also allowing clean emissions while using relatively inexpensive aftertreatment technologies.     

Modeling fuel NOx formation from combustion of biomass-derived producer gas in a large-scale burner

This study investigates the characteristics of fuel NO_x formation resulting from the combustion of producer gas derived from biomass gasification using different feedstocks. Common industrial burners are optimized for using natural gas or coal-derived syngas. With the increasing demand in using biomass for power generation, it is important to develop burners that can mitigate fuel NO_x emissions due to the combustion of ammonia, which is the major nitrogen-containing species in biomass-derived gas. In this study, the combustion process inside the burner is modeled using computational fluid dynamics (CFD) with detailed chemistry. A reduced mechanism (36 species and 198 reactions) is developed from GRI 3.0 in order to reduce the computation time. Combustion simulations are performed for producer gas arising from different feedstocks such as wood gas, wood + 13% DDGS (dried distiller grain soluble) gas and wood + 40% DDGS gas and also at different air equivalence ratios ranging from 1.2 to 2.5. The predicted NO_x emissions are compared with the experimental data and good levels of agreement are obtained. It is found out that NO_x is very sensitive to the ammonia content in the producer gas. Results show that although NO–NO₂ interchanges are the most prominent reactions involving NO, the major NO producing reactions are the oxidation of NH and N at slightly fuel rich conditions and high temperature. Further analysis of results is conducted to determine the conditions favorable for NO_x reduction. The results indicate that NO_x can be reduced by designing combustion conditions which have fuel rich zones in most of the regions. The results of this study can be used to design low NO_x burners for combustion of gas mixtures derived from gasification of biomass. One suggestion to reduce NO_x is to produce a diverging flame using a bluff body in the flame region such that NO generated upstream will pass through the fuel rich flame and be reduced.     

Effects of ammonia substitution on combustion stability limits and NOx emissions of premixed hydrogen–air flames

The combustion stability limits and nitrogen oxide (NO_x) emissions of burner-stabilized premixed flames of ammonia (NH₃)-substituted hydrogen (H₂)–air mixtures at normal temperature and pressure are studied to evaluate the potential of partial NH₃ substitution to improve the safety of H₂ use. The effects of NH₃ substitution, nitrogen (N₂) coflow and mixture injection velocity on the stability limits and NO_x emissions of NH₃–H₂–air flames are experimentally determined. Results show a reduction of stability limits with NH₃ substitution and coflow, supporting the potential of NH₃ as a carbon-free, green additive in H₂–air flames and indicating a different tendency from that for no coflow condition. The NO_x emission index is almost constant even with enhanced NH₃ substitution, though the absolute value of NO_x emissions increases in general. At fuel-rich conditions, the NO_x emission index decreases with increasing mixture injection velocity and the existence of coflow. The thermal deNO_x process in the post-flame region is involved in reducing NO_x emissions for the fuel-rich flames.     

Hydrogen applications in selective catalytic reduction of NOx emissions from diesel engines

Diesel engines have been considered as a major source in nitrogen oxide (NO_x) formation worldwide. The widespread use of diesel engines in consequence of their low fuel consumption, high durability and efficiency increases NO_x emissions day by day. NO_x emissions from diesel engines cause unavoidable damage on environment and people health. Although so many technologies such as exhaust gas recirculation (EGR), lean burn combustion, electronic controlling fuel injection systems, etc. have been developed to control NO_x emissions from diesel engines, they couldn't meet the desired reduction in NO_x emissions. In any case, Selective Catalytic Reduction (SCR) as one of the most promising aftertreatment-emission control technologies is an effective solution in restriction of NO_x emissions. The use of SCR systems especially in heavy-duty diesel powered vehicles has been increasing nowadays. In these systems, to use of hydrogen (H₂) as a reductant or promoter have been improved the conversion efficiency especially at low exhaust temperatures. Many researchers have been focused on the use of H₂ in SCR systems for controlling NO_x emissions.In this study, the applications of H₂ in SCR of NO_x have been discussed. The studies on use of H₂ in SCR of NO_x emissions were examined and the effects on NO_x conversions were determined. Consequently, it is confirmed that H₂ is a promising and alternative reductant in SCR of NO_x and it has been kept as an attracting subject for many researchers.