Effect of exhaust gas recirculation (EGR) temperature for various EGR rates on heavy duty DI diesel engine performance and emissions

DI diesel engines are well established today as the main powertrain solution for trucks and other relevant heavy duty vehicles. At the same time emission legislation (mainly for NO_x and particulate matter) becomes stricter, reducing their limit to extremely low values. One efficient method to control NO_x in order to achieve future emissions limits is the use of rather high exhaust gas recirculation (EGR) rates accompanied by increased boost pressure to avoid the negative impact on soot emissions. The method is based on the reduction of gas temperature level and O₂ availability inside the combustion chamber, but unfortunately it has usually an adverse effect on soot emissions and brake specific fuel consumption (bsfc). The use of high EGR rates creates the need for EGR gas cooling in order to minimize its negative impact on soot emissions especially at high engine load were the EGR flow rate and exhaust temperature are high. For this reason in the present paper it is examined, using a multi-zone combustion model, the effect of cooled EGR gas temperature level for various EGR percentages on performance and emissions of a turbocharged DI heavy duty diesel engine operating at full load. Results reveal that the decrease of EGR gas temperature has a positive effect on bsfc, soot (lower values) while it has only a small positive effect on NO. As revealed, the effect of low EGR temperature is stronger at high EGR rates.     

Experimental study of various effects of exhaust gas recirculation (EGR) on combustion and emissions of an automotive direct injection diesel engine

Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production and is used on most modern high-speed direct injection (HSDI) diesel engines. However EGR has different effects on combustion and emissions production that are difficult to distinguish (increase of intake temperature, delay of rate of heat release (ROHR), decrease of peak heat release, decrease in O₂ concentration (and thus of global air/fuel ratio (AFR)) and flame temperature, increase of lift-off length, etc.), and thus the influence of EGR on NO_x and particulate matter (PM) emissions is not perfectly understood, especially under high EGR rates. An experimental study has been conducted on a 2.0 l HSDI automotive diesel engine under low-load and part load conditions in order to distinguish and quantify some effects of EGR on combustion and NO_x/PM emissions. The increase of inlet temperature with EGR has contrary effects on combustion and emissions, thus sometimes giving opposite tendencies as traditionally observed, as, for example, the reduction of NO_x emissions with increased inlet temperature. For a purely diffusion combustion the ROHR is unchanged when the AFR is maintained when changing in-cylinder ambient gas properties (temperature or EGR rate). At low-load conditions, use of high EGR rates at constant boost pressure is a way to drastically reduce NO_x and PM emissions but with an increase of brake-specific fuel consumption (BSFC) and other emissions (CO and hydrocarbon), whereas EGR at constant AFR may drastically reduce NO_x emissions without important penalty on BSFC and soot emissions but is limited by the turbocharging system.     

Experimental investigation of control of NOx emissions in biodiesel-fueled compression ignition engine

Biodiesel is an alternative fuel consisting of the alkyl esters of fatty acids from vegetable oils or animal fats. Vegetable oils are produced from numerous oil seed crops (edible and non-edible), e.g., rapeseed oil, linseed oil, rice bran oil, soybean oil, etc. Research has shown that biodiesel-fueled engines produce less carbon monoxide (CO), unburned hydrocarbon (HC), and particulate emissions compared to mineral diesel fuel but higher NO_x emissions. Exhaust gas recirculation (EGR) is effective to reduce NO_x from diesel engines because it lowers the flame temperature and the oxygen concentration in the combustion chamber. However, EGR results in higher particulate matter (PM) emissions. Thus, the drawback of higher NO_x emissions while using biodiesel may be overcome by employing EGR. The objective of current research work is to investigate the usage of biodiesel and EGR simultaneously in order to reduce the emissions of all regulated pollutants from diesel engines. A two-cylinder, air-cooled, constant speed direct injection diesel engine was used for experiments. HCs, NO_x, CO, and opacity of the exhaust gas were measured to estimate the emissions. Various engine performance parameters such as thermal efficiency, brake specific fuel consumption (BSFC), and brake specific energy consumption (BSEC), etc. were calculated from the acquired data. Application of EGR with biodiesel blends resulted in reductions in NO_x emissions without any significant penalty in PM emissions or BSEC.     

Hydrogen rich exhaust gas recirculation (H2EGR) for performance improvement and emissions reduction of a compression ignition engine

Hydrogen (H₂), being carbon free energy carrier, is best suitable for compression ignition (CI) engines with better performance and lower carbon derived emissions. Novelty of present study is the employment of low-cost catalyst (alumina) for production of H₂ reformate (hydrogen rich exhaust gas recirculation: H2EGR) in an indigenous catalytic reactor. Experimental tests were carried out on a CI engine under three conditions; base diesel, exhaust gas recirculation (EGR), and H2EGR. Results indicated that brake thermal efficiency of the engine with H2EGR was higher than EGR and comparable with base diesel operation. All carbon-based emissions including smoke emission decreased significantly with H2EGR than diesel and EGR operations. In addition, oxides of nitrogen emission (NO_x) also decreased by about 46% with H2EGR than base diesel operation. It is concluded that H2EGR is a promising option for CI engines for simultaneous reduction of both NO_x and smoke emissions along with the additional benefit of higher efficiency.     

Homogeneous Charge Compression Ignition (HCCI) combustion: Implementation and effects on pollutants in direct injection diesel engines

Homogeneous Charge Compression Ignition (HCCI) combustion is a combustion concept which offers simultaneous reductions in both NO_x and soot emissions from internal combustion engines. In light of increasingly stringent diesel emissions limits, research efforts have been invested into HCCI combustion as an alternative to conventional diesel combustion. This paper reviews the implementation of HCCI combustion in direct injection diesel engines using early, multiple and late injection strategies. Governing factors in HCCI operations such as injector characteristics, injection pressure, piston bowl geometry, compression ratio, intake charge temperature, exhaust gas recirculation (EGR) and supercharging or turbocharging are discussed in this review. The effects of design and operating parameters on HCCI diesel emissions, particularly NO_x and soot, are also investigated. For each of these parameters, the theories are discussed in conjunction with comparative evaluation of studies reported in the specialised literature.     

Analysis of exhaust waste heat recovery from a dual fuel low temperature combustion engine using an Organic Rankine Cycle

This paper examines the exhaust waste heat recovery potential of a high-efficiency, low-emissions dual fuel low temperature combustion engine using an Organic Rankine Cycle (ORC). Potential improvements in fuel conversion efficiency (FCE) and specific emissions (NO_x and CO₂) with hot exhaust gas recirculation (EGR) and ORC turbocompounding were quantified over a range of injection timings and engine loads. With hot EGR and ORC turbocompounding, FCE improved by an average of 7 percentage points for all injection timings and loads while NO_x and CO₂ emissions recorded an 18 percent (average) decrease. From pinch-point analysis of the ORC evaporator, ORC heat exchanger effectiveness (?), percent EGR, and exhaust manifold pressure were identified as important design parameters. Higher pinch point temperature differences (PPTD) uniformly yielded greater exergy destruction in the ORC evaporator, irrespective of engine operating conditions. Increasing percent EGR yielded higher FCEs and stable engine operation but also increased exergy destruction in the ORC evaporator. It was observed that hot EGR can prevent water condensation in the ORC evaporator, thereby reducing corrosion potential in the exhaust piping. Higher ? values yielded lower PPTD and higher exergy efficiencies while lower ? values decreased post-evaporator exhaust temperatures below water condensation temperatures and reduced exergy efficiencies.     

Generating efficiency and NOx emissions of a gas engine generator fueled with a biogas–hydrogen blend and using an exhaust gas recirculation system

This paper investigates the generating efficiency and NO_x emissions of a gas engine generator with a low-pressure loop exhaust gas recirculation system, fueled by a model biogas. Experiments for improving the generating efficiency and reducing NO_x emissions were conducted, utilizing optimum spark timings based on the maximum generating efficiencies with varying exhaust gas recirculation (EGR) rates. The test results show that both the NO_x emissions and the generating efficiency generally decrease when the EGR rate is increased. Also, by utilizing optimum spark timings with varying EGR rates, the addition of hydrogen to the biogas increases the generating efficiency of the engine. In particular, the generating efficiency of the biogas–hydrogen test increased by about 1.5% in comparison with the model biogas test for the optimum spark timing at 15% EGR. Accordingly, comprehensive techniques, such as the use of a biogas–hydrogen fuel mixture and optimum spark timings with respect to EGR rates, should be employed to efficiently generate electricity with a biogas engine.     

Computational modeling, validation, and utilization for predicting the performance, combustion and emission characteristics of hydrogen IC engines

Hydrogen-fueled internal combustion engines are considered to be more efficient and cleaner alternatives to their fossil-fueled counterparts. Reasonably fast and accurate predictive computational tools are essential for practical design, control and optimization of hydrogen engines. To serve for this broader purpose, a computational model, which has been widely used for gasoline and diesel engines, is investigated for its capability to simulate hydrogen engines. Specifically, fuel-specific sub-models are first incorporated by properly accounting for hydrogen’s distinct properties such as flame speed and burn rate. The accuracy of the model is then assessed by validating it in comparison to independent experimental data. Finally, it is utilized to quantify the environmental impact of exhaust gas recirculation. With these improvements, the present predictive model is shown to capture the measured engine performance and emission data well under different operating conditions. In particular, the variations of peak in-cylinder pressure, heat release rate, brake power, brake thermal efficiency, exhaust temperature, and NO_x emissions are predicted close to the measured values. With the addition of a proportional-integral-derivative controller to the engine model, exhaust gas recirculation level is varied, resulting in nearly an order of magnitude reduction in NO_x emissions during the present simulations.     

Effect of exhaust gas recirculation on diesel engine nitrogen oxide reduction operating with jojoba methyl ester

Jojoba methyl ester (JME) has been used as a renewable fuel in numerous studies evaluating its potential use in diesel engines. These studies showed that this fuel is good gas oil substitute but an increase in the nitrogenous oxides emissions was observed at all operating conditions. The aim of this study mainly was to quantify the efficiency of exhaust gas recirculation (EGR) when using JME fuel in a fully instrumented, two-cylinder, naturally aspirated, four-stroke direct injection diesel engine. The tests were carried out in three sections. Firstly, the measured performance and exhaust emissions of the diesel engine operating with diesel fuel and JME at various speeds under full load are determined and compared. Secondly, tests were performed at constant speed with two loads to investigate the EGR effect on engine performance and exhaust emissions including nitrogenous oxides (NO_x), carbon monoxide (CO), unburned hydrocarbons (HC) and exhaust gas temperatures. Thirdly, the effect of cooled EGR with high ratio at full load on engine performance and emissions was examined. The results showed that EGR is an effective technique for reducing NO_x emissions with JME fuel especially in light-duty diesel engines. With the application of the EGR method, the CO and HC concentration in the engine-out emissions increased. For all operating conditions, a better trade-off between HC, CO and NO_x emissions can be attained within a limited EGR rate of 5–15% with very little economy penalty.     

Hydrogen-diesel fuel co-combustion strategies in light duty and heavy duty CI engines

The co-combustion of diesel fuel with H₂ presents a promising route to reduce the adverse effects of diesel engine exhaust pollutants on the environment and human health. This paper presents the results of H₂-diesel co-combustion experiments carried out on two different research facilities, a light duty and a heavy duty diesel engine. For both engines, H₂ was supplied to the engine intake manifold and aspirated with the intake air. H₂ concentrations of up to 20% vol/vol and 8% vol/vol were tested in the light duty and heavy duty engines respectively. Exhaust gas circulation (EGR) was also utilised for some of the tests to control exhaust NO_x emissions.The results showed NO_x emissions increase with increasing H₂ in the case of the light duty engine, however, in contrast, for the heavy duty engine NO_x emissions were stable/reduced slightly with H₂, attributable to lower in-cylinder gas temperatures during diffusion-controlled combustion. CO and particulate emissions were observed to reduce as the intake H₂ was increased. For the light duty, H₂ was observed to auto-ignite intermittently before diesel fuel injection had started, when the intake H₂ concentration was 20% vol/vol. A similar effect was observed in the heavy duty engine at just over 8% H₂ concentration.     

Natural-gas fueled spark-ignition (SI) and compression-ignition (CI) engine performance and emissions

Natural gas is a fossil fuel that has been used and investigated extensively for use in spark-ignition (SI) and compression-ignition (CI) engines. Compared with conventional gasoline engines, SI engines using natural gas can run at higher compression ratios, thus producing higher thermal efficiencies but also increased nitrogen oxide (NO_x) emissions, while producing lower emissions of carbon dioxide (CO₂), unburned hydrocarbons (HC) and carbon monoxide (CO). These engines also produce relatively less power than gasoline-fueled engines because of the convergence of one or more of three factors: a reduction in volumetric efficiency due to natural-gas injection in the intake manifold; the lower stoichiometric fuel/air ratio of natural gas compared to gasoline; and the lower equivalence ratio at which these engines may be run in order to reduce NO_x emissions. High NO_x emissions, especially at high loads, reduce with exhaust gas recirculation (EGR). However, EGR rates above a maximum value result in misfire and erratic engine operation. Hydrogen gas addition increases this EGR threshold significantly. In addition, hydrogen increases the flame speed of the natural gas-hydrogen mixture. Power levels can be increased with supercharging or turbocharging and intercooling. Natural gas is used to power CI engines via the dual-fuel mode, where a high-cetane fuel is injected along with the natural gas in order to provide a source of ignition for the charge. Thermal efficiency levels compared with normal diesel-fueled CI-engine operation are generally maintained with dual-fuel operation, and smoke levels are reduced significantly. At the same time, lower NO_x and CO₂ emissions, as well as higher HC and CO emissions compared with normal CI-engine operation at low and intermediate loads are recorded. These trends are caused by the low charge temperature and increased ignition delay, resulting in low combustion temperatures. Another factor is insufficient penetration and distribution of the pilot fuel in the charge, resulting in a lack of ignition centers. EGR admission at low and intermediate loads increases combustion temperatures, lowering unburned HC and CO emissions. Larger pilot fuel quantities at these load levels and hydrogen gas addition can also help increase combustion efficiency. Power output is lower at certain conditions than diesel-fueled engines, for reasons similar to those affecting power output of SI engines. In both cases the power output can be maintained with direct injection. Overall, natural gas can be used in both engine types; however further refinement and optimization of engines and fuel-injection systems is needed.     

Comparison of the effects of EGR and lean burn on an SI engine fueled by hydrogen-enriched low calorific gas

A naturally aspirated spark ignition (SI) engine fueled by hydrogen-blended low calorific gas (LCG) was tested in both exhaust gas recirculation (EGR) and lean burn modes. The “dilution ratio” was introduced to compare their effects on engine performance and emissions under identical levels of dilution. LCG composed of 40% natural gas and 60% nitrogen was used as a main fuel, and hydrogen was blended with the LCG in volumes ranging from 0 to 20%. The engine test results demonstrated that EGR operations at stoichiometry showed a narrower dilution range, inferior combustion characteristics, lower brake thermal efficiency, faster nitrogen oxides (NO_x) suppression, and higher total hydrocarbon (THC) emissions for all hydrogen blending rates compared to lean burn. These trends were mainly due to the increased oxygen deficiency as a result of using EGR in LCG/air mixtures. Hydrogen enrichment of the LCG improved combustion stability and reduced THC emissions while increasing NO_x. In terms of efficiency, hydrogen addition induced a competition between combustion enhancement and increases in the cooling loss, so that the peak thermal efficiency occurred at 10% H₂ with excess air ratio of 1.5. The engine test results also indicated that a close-to-linear NO_x-efficiency relationship occurred for all hydrogen blending rates in both operations as long as stable combustion was achieved. NO_x versus combustion duration analysis showed that adding H₂ reduced combustion duration while maintaining the same level of NO_x. The methane fraction contained in the THC emissions decreased slightly with an increase in hydrogen enrichment at low EGR or excess air dilution ratios, but this tendency was diminished at higher dilution ratios because of the combined dilution effects from the inert gas in the LCG and the diluents (EGR or excess air).     

Experimental study of the performances of a modified diesel engine operating in homogeneous charge compression ignition (HCCI) combustion mode versus the original diesel combustion mode

Homogeneous charge compression ignition (HCCI) combustion mode provides very low NO_x and soot emissions; however, it has some challenges associated with hydrocarbon (HC) emissions, fuel consumption, difficult control of start of ignition and bad behaviour to high loads. Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production in diesel and HCCI combustion mode. However EGR has different effects on combustion and emissions, which are difficult to distinguish. This work is intended to characterize an engine that has been modified from the base diesel engine (FL1 906 DEUTZ-DITER) to work in HCCI combustion mode. It shows the experimental results for the modified diesel engine in HCCI combustion mode fueled with commercial diesel fuel compared to the diesel engine mode. An experimental installation, in conjunction with systematic tests to determine the optimum crank angle of fuel injection, has been used to measure the evolution of the cylinder pressure and to get an estimate of the heat release rate from a single-zone numerical model. From these the angle of start of combustion has been obtained. The performances and emissions of HC, CO and the huge reduction of NO_x and smoke emissions of the engine are presented. These results have allowed a deeper analysis of the effects of external EGR on the HCCI operation mode, on some engine design parameters and also on NO_x emission reduction.     

Increasing the power output of hydrogen internal combustion engines by means of supercharging and exhaust gas recirculation

Spark ignition engines can be relatively easily converted to hydrogen using port fuel injection (PFI). However, because of the lower volumetric energy density of a hydrogen–air mixture and the occurrence of abnormal combustion phenomena such as backfire, hydrogen-fueled PFI engines suffer from a power deficit in comparison with gasoline engines. This paper reports measurements on a single-cylinder hydrogen engine equipped with a supercharger and an exhaust gas recirculation (EGR) system. Using EGR combined with supercharging and a three-way catalyst (TWC) is shown to significantly increase the power output while limiting tailpipe emissions of oxides of nitrogen (NO_x).     

Effect of induction on exhaust gas recirculation and hydrogen gas in compression ignition engine with simarouba oil in dual fuel mode

Biofuels extracted from non-edible oil is sustainable and can be used as an alternative fuel for internal combustion engines. This study presents the performance, emission and combustion characteristic analysis by using simarouba oil (obtained from Simarouba seed) as an alternative fuel along with hydrogen and exhaust gas recirculation (EGR) in a compression ignition (CI) engine operating on dual fuel mode. Simarouba biofuel blend (B20) was prepared on volumetric basis by mixing simarouba oil and diesel in the proportion of 20% and 80% (v/v), respectively. Hydrogen gas was introduced at the flow rate of 2.67 kg/min, and EGR concentration was maintained at 30% of total air introduction. Performance, combustion and emission characteristics analysis were examined with biodiesel (B20), biodiesel with hydrogen substitution and biodiesel, hydrogen with EGR and were compared with neat diesel operation. Results indicate that BTE of the engine operating with biodiesel B20 was decreased when compared to neat diesel operation. However, introducing hydrogen along with B20 blend into the combustion chamber shows a slight increase in the BTE by 1%. NO_x emission was increased to 18.13% with the introduction of hydrogen than that of base fuel (diesel) operation. With the introduction of EGR, there is a significant reduction in NO_x emission due to decrease in in-cylinder temperature by 19.07%. A significant reduction in CO, CO_2, and smoke emissions were also noted with the introduction of both hydrogen and EGR. The ignition delay and combustion duration were increased with the introduction of hydrogen, EGR with biodiesel than neat diesel operation. Hence, the proposed biodiesel B20 with H₂ and EGR combination can be applied as an alternative fuel in CI engines.     

A comparative study of lean burn and exhaust gas recirculation in an HCNG-fueled heavy-duty engine

Two dilution strategies, exhaust gas recirculation (EGR) with a stoichiometric mixture and excess air with a lean mixture, were investigated for an 11 L, 6-cylinder H₂-blended compressed natural gas (HCNG) engine. The engine was operated at 1260 rpm and 50% of maximum engine load (575 Nm) at maximum brake torque for each strategy. To evaluate the EGR approach, the stoichiometric combustion mode was varied, and to evaluate the lean combustion mode, the excess air ratio was varied. The maximum EGR rate and lean flammability limit were constrained by the combustion stability. The dilution rate was employed to compare the dilution effect on engine performance and emission levels under identical levels of the dilution for both combustion modes. The thermal efficiencies under stoichiometric combustion with EGR were lower than those under lean combustion, owing to a higher pumping loss and a lower combustion speed. The total hydrocarbon emissions under the lean combustion mode were lower than those under the stoichiometric combustion mode only when the combustion speed was relatively slow, due to the higher mixing rate caused by the active combustion. As the dilution rate was increased in the lean combustion mode, the rate of decrease in NO_x emissions slowed compared to the stoichiometric combustion mode. The lowest level of engine-out NO_x emissions was observed under lean combustion.     

Soot processes in compression ignition engines

While diesel engines are arguably superior to any other power-production device for the transportation sector in terms of efficiency, torque, and overall driveability, they suffer from inferior performance in terms of noise, NO_x and particulate emissions. The majority of particulate originates with soot particles which are formed in fuel-rich regions of burning diesel jets. Over the past two decades, our understanding of the formation process of soot in diesel combustion has transformed from inferences based on exhaust measurements and laboratory flames to direct in-cylinder observations that have led to a transformation in diesel engine combustion. In-cylinder measurements show the diesel spray to produce a jet which forms a lifted, partially premixed, turbulent diffusion flame. Soot formation has been found to be strongly dependent on air entrainment in the lifted portion of the jet as well as by oxygen in the fuel and to a lesser extent the composition and structure of hydrocarbons in the fuel. Soot surviving the combustion process and exiting in the exhaust is dominated by soot from fuel-rich pockets which do not have time to mix and burn prior to exhaust valve opening. Higher temperatures at the end of combustion enhance the burnout of soot, while high temperatures at the time of injection reduce air entrainment and increase soot formation. Using a conceptual model based on in-cylinder soot and combustion measurements, trends seen in exhaust particulate can be explained. The current trend in diesel engine emissions control involves multi-injection combustion strategies which are transforming the picture of diesel combustion rapidly into a series of low temperature, stratified charge, premixed combustion events where NO_x formation is avoided because of low temperature and soot formation is avoided by leaning the mixture or increasing air entrainment prior to ignition.     

Combustion performance and emission reduction characteristics of automotive DME engine system

This article is a condensed overview of a dimethyl ether (DME) fuel application for a compression ignition diesel engine. In this review article, the spray, atomization, combustion and exhaust emissions characteristics from a DME-fueled engine are described, as well as the fundamental fuel properties including the vapor pressure, kinematic viscosity, cetane number, and the bulk modulus. DME fuel exists as gas phase at atmospheric state and it must be pressurized to supply the liquid DME to fuel injection system. In addition, DME-fueled engine needs the modification of fuel supply and injection system because the low viscosity of DME caused the leakage. Different fuel properties such as low density, viscosity and higher vapor pressure compared to diesel fuel induced the shorter spray tip penetration, wider cone angle, and smaller droplet size than diesel fuel. The ignition of DME fuel in combustion chamber starts in advance compared to diesel or biodiesel fueled compression ignition engine due to higher cetane number than diesel and biodiesel fuels. In addition, DME combustion is soot-free since it has no carbon–carbon bonds, and has lower HC and CO emissions than that of diesel combustion. The NO_x emission from DME-fueled combustion can be reduced by the application of EGR (exhaust gas recirculation). This article also describes various technologies to reduce NO_x emission from DME-fueled engines, such as the multiple injection strategy and premixed combustion. Finally, the development trends of DME-fueled vehicle are described with various experimental results and discussion for fuel properties, spray atomization characteristics, combustion performance, and exhaust emissions characteristics of DME fuel.     

Analysis of reformed EGR on the performance of a diesel particulate filter

The use of a diesel particulate filter (DPF) in combination with an upstream diesel oxidation catalyst (DOC) has been successfully implemented and shown to reduce carbon monoxide (CO), hydrocarbon (HC) and Particulate Matter (PM) diesel exhaust gas emissions. However issues including cost, size and uncontrolled active regeneration under a low temperature window still require attention. This study therefore primarily focuses on the potential benefits of using a single catalytic coated DPF (cDPF) and a combined DOC-cDPF instead of the DOC-DPF aftertreatment system utilising a passive, low temperature regeneration method. Comparisons were made through monitoring exhaust gas compositions from an experimental single cylinder diesel engine as well as measuring the pressure drop across the filters to analyse the accumulation of soot particles. The influence of reformed EGR (REGR), enriched simulated hydrogen (H₂) and CO, on DPF and cDPF soot loading was of interest as H₂ promotes the NO to NO₂ oxidation. Similarly the addition of simulated reformate (added either directly into the engine intake or exhaust manifold) for optimal performance of the aftertreatment systems was examined.The effects of adding REGR resulted in a significant decrease in total engine-out NO_x emissions, as well as an increase in both NO₂ concentration and NO₂/NO_x ratio. This resulted in improved filter efficiency and overall loading, especially under a DOC-cDPF aftertreatment configuration system. As a whole, a simultaneous NO_x and PM reduction was achieved.     

Biofuels and thermal barrier: A review on compression ignition engine performance,combustion and exhaust gas emission

The performance of an internal combustion engine is affected when renewable biofuels are used instead of fossil fuels in an unmodified engine. Various engine modifications were experimented by the researchers to optimise the biofuels operated engine performance. Thermal barrier coating is one of the techniques used to improve the biofuels operated engine performance and combustion characteristics by reducing the heat loss from the combustion chamber. In this study, engine tests results on performance, combustion and exhaust emission characteristics of the biofuels operated thermal barrier coated engines were collated and reviewed. The results found in the literature were reviewed in three scenarios: (i) uncoated versus coated engine for fossil diesel fuel application, (ii) uncoated versus coated engine for biofuels (and blends) application, and (iii) fossil diesel use on uncoated engine versus biofuel (and blends) use on coated engine. Effects of injection timing, injection pressure and fuel properties on thermal barrier coatings were also discussed. The material type, thickness and properties of the coating materials used by the research community were presented. The effectiveness and durability of the coating layer depends on two key properties: low thermal conductivity and high thermal expansion coefficient. The current study showed that thermal barrier coatings could potentially offset the performance drop due to use of biofuels in the compression ignition engines. Improvements of up to 4.6% in torque, 7.8% in power output, 13.4% in brake specific fuel consumption, 15.4% in brake specific energy consumption and 10.7% in brake thermal efficiency were reported when biofuels or biofuel blends were used in the thermal barrier coated engines as compared to the uncoated engines. In coated engines, peak cylinder pressure and exhaust gas temperature were increased by up to 16.3 bar and 14% respectively as compared to uncoated condition. However, changes in the heat release rates were reported to be between ?27% and +13.8% as compared to uncoated standard engine. Reductions of CO, CO₂, HC and smoke emissions were reported by up to 3.8%, 11.1%, 90.9% and 63% respectively as compared to uncoated engines. Significant decreases in the PM emissions were also reported due to use of thermal barrier coatings in the combustion chamber. In contrast, at high speed and at high load operation, increase in the CO and CO₂ emissions were also reported in coated engines. Coated engines gave higher NO_x emissions by about 4–62.9% as compared to uncoated engines. Combined effects of thermal barrier coatings and optimisation of fuel properties and injection parameters produced further performance and emissions advantages compared to only thermal barrier coated engines. Overall, current review study showed that application of thermal barrier coatings in compression ignition engines could be beneficial when biofuels or biofuel blends are used instead of standard fossil diesel. However, more research is needed combining coatings, types of biofuels and other engine modifications to establish a concrete conclusion on the effectiveness of the thermal barrier when biofuels are used in the compression ignition engine. Reduction of NO_x emissions is another important R & D area.