高平整度GaN HEMT欧姆接触工艺

研究了不同金属体系对GaN HEMT欧姆接触表面形貌、击穿电压的影响。研究了不同合金温度以及不同金属体系对接触特性的影响,通过对金属体系结构的优化改善了欧姆接触特性及形貌。采用Ti/Al/Pd/Au(10/200/40/50nm)金属,在750℃合金温度时,得到较低的接触电阻,最小值达到0.18Ω·mm,欧姆接触电极表面粗糙度降低到0.4nm。良好的欧姆接触形貌使GaN HEMT击穿电压提高了10%。通过加速电迁移实验,证明Ti/Al/Pd/Au金属体系可靠性满足工程化需要。     

Ti/Al/Ni/Au金属体系在N-polar GaN上的欧姆接触特性

利用金属有机化合物化学气相淀积(MOCVD)在SiC衬底上外延生长了N-polar GaN材料,采用传输线模型(TLM)分析了Ti/Al/Ni/Au金属体系在N-polar GaN上的欧姆接触特性.结果表明,Ti/Al/Ni/Au (20/60/10/50 nm)在N-polar GaN上可形成比接触电阻率为2.2×10-3Ω·cm2的非合金欧姆接触,当退火温度升至200℃,比接触电阻率降为1.44×10-3 Ω·cm2,随着退火温度的进一步上升,Ga原子外逸导致欧姆接触退化为肖特基接触.     

Ti/Al/Ni/Au在GaN N面上的欧姆接触

以Ti/Al/Ni/Au作为欧姆接触金属体系,通过电感耦合等离子体(ICP)刻蚀的预处理,在氢化物气相外延法生长的单晶氮化镓(GaN)材料的N面实现了良好的欧姆接触,其比接触电阻率为3.7×10-4 Ω·cm2.通过扫描电子显微镜、原子力显微镜、阴极荧光和光致发光谱对GaN N面的表面、光学特性进行了对比表征.结果表明:未刻蚀GaN衬底的N面表面存在一定的损伤层,导致近表面处含有大量缺陷,不利于欧姆接触的形成;而ICP刻蚀处理有效地去除了损伤层.X射线光电子能谱(XPS)分析显示刻蚀后样品的Ga 3d结合能比未刻蚀样品向高能方向移动了约0.3 eV,其肖特基势垒则相应降低,有利于欧姆接触的形成.同时对Fe掺杂半绝缘GaN的N面也进行了刻蚀处理,同样实现了良好的Ti/Al/Ni/Au欧姆接触,其比接触电阻率为0.12 Ω·cm2.     

超薄势垒InAlN/GaN HFET器件高频特性分析

采用二次外延重掺杂n+ GaN实现非合金欧姆接触,并通过优化干法刻蚀和金属有机化学气相沉积(MOCVD)外延工艺,有效降低了欧姆接触电阻.将非合金欧姆接触工艺应用于InAlN/GaN异质结场效应晶体管(HFET)器件制备,器件的有效源漏间距缩小至600 nm.同时,结合40 nm T型栅工艺,制备了高电流截止频率(fT)和最大振荡频率(fmax)的InAlN/GaN HFET器件.结果显示减小欧姆接触电阻和栅长后,器件的电学特性,尤其是射频特性得到大幅提升.栅偏压为0V时,器件最大漏源饱和电流密度达到1.88 A/mm;直流峰值跨导达到681 mS/mm.根据射频小信号测试结果外推得到器件的fT和fmax同为217 GHz.     

GaN外延材料测试技术的研究

分别用金属In和Ti/Al/Ni/Au合金层制备GaN HEMT结构外延片的霍尔测试电极,并对样品进行霍尔测试.发现In金属与外延片形成非欧姆接触,Ti/Al/Ni/Au合金层与外延片形成良好的欧姆接触.用电化学C-V方法测试样品,得到的载流子浓度与合金电极制备的样品经霍尔测试得到的载流子浓度一致,从而验证了此种霍尔测试方法的准确性,为GaN外延材料的测试提出了准确可行的测试方法.     

fT为350 GHz的InAlN/GaN HFET高频器件研究

采用再生长n+ GaN非合金欧姆接触工艺研制了具有高电流增益截止频率(fT)的InAlN/GaN异质结场效应晶体管 (HFETs),器件尺寸得到有效缩小,源漏间距减小至600 nm.通过优化干法刻蚀和n+ GaN外延工艺,欧姆接触总电阻值达到0.16 Ω·mm,该值为目前金属有机化学气相沉积(MOCVD)方法制备的最低值.采用自对准电子束曝光工艺实现34 nm直栅.器件尺寸的缩小以及欧姆接触的改善,器件电学特性,尤其是射频特性得到大幅提升.器件的开态电阻(Ron)仅为0.41 Ω·mm,栅压1 V下,漏源饱和电流达到2.14 A/mm.此外,器件的电流增益截止频率(fT)达到350 GHz,该值为目前GaN基HFET器件国内报道最高值.     

f_T为350 GHz的InAlN/GaN HFET高频器件研究（英文）

采用再生长n~+GaN非合金欧姆接触工艺研制了具有高电流增益截止频率(f_T)的InAlN/GaN异质结场效应晶体管(HFETs),器件尺寸得到有效缩小,源漏间距减小至600 nm.通过优化干法刻蚀和n~+GaN外延工艺,欧姆接触总电阻值达到0.16Ω·mm,该值为目前金属有机化学气相沉积(MOCVD)方法制备的最低值.采用自对准电子束曝光工艺实现34 nm直栅.器件尺寸的缩小以及欧姆接触的改善,器件电学特性,尤其是射频特性得到大幅提升.器件的开态电阻(R_(on))仅为0.41Ω·mm,栅压1 V下,漏源饱和电流达到2.14 A/mm.此外,器件的电流增益截止频率(f_T)达到350 GHz,该值为目前GaN基HFET器件国内报道最高值.     

Ti/Al/Ti/Au与AlGaN欧姆接触特性

研究了溅射Ti/Al/Ti/Au四层复合金属与AlGaN/GaN的欧姆接触特性,并就环境温度对欧姆接触特性的影响进行了分析研究.试验证实:溅射的Ti/Al/Ti/Au与载流子浓度为2.24×1018cm-3的AlGaN之间在室温下无需退火即可形成欧姆接触.随快速退火温度的升高接触电阻降低.快速退火时间30s已可实现该温度下最佳欧姆接触.当工作温度不高于300℃时接触电阻几乎不受温度的影响.     

基于AlGaN/GaN HEMT的源漏整体刻蚀欧姆接触结构

研究了源漏整体刻蚀欧姆接触结构对AlGaN/GaN高电子迁移率晶体管(HEMT)的欧姆接触电阻和金属电极表面形貌的影响.利用传输线模型(TLM)对样品的电学性能进行测试,使用原子力显微镜(AFM)对样品的表面形貌进行表征,通过透射电子显微镜(TEM)和X射线能谱仪(EDS)对样品的剖面微结构和界面反应进行表征与分析.实验结果显示,采用Ti/Al/Ni/Au(20 nm/120 nm/45 nm/55 nm)金属和源漏整体刻蚀欧姆接触结构,在合金温度870 c℃,升温20 s,退火50 s条件下,欧姆接触电阻最低为0.13 Ω·mm,方块电阻为363.14 Ω/□,比接触电阻率为4.54×10-7Ω·cm2,形成了良好的欧姆接触,降低了器件的导通电阻.     

GaN基蓝光LED关键技术进展

以高亮度GaN基蓝光LED为核心的半导体照明技术对照明领域带来了很大的冲击,并成为目前全球半导体领域研究和投资的热点。本文首先综述了GaN基材料的基本特性,分析了GaN基蓝光LED制程的关键技术如金属有机物气相外延,P型掺杂,欧姆接触,刻蚀工艺,芯片切割技术,介绍了目前各项技术的工艺现状,最后指出了需要改进的问题,展望了末来的研究方向。     

GaN紫外探测器的Ti/Al接触的电学特性

在非故意掺杂的和掺Si的GaN薄膜上蒸镀Ti(24nm)/Al(nm)薄膜,氮气环境下400～800℃范围内进行退火。实验结果表明,在非故意掺杂的样品上,随退火温度的升高,肖特基势垒高度下降,理想因子升高,表面状况逐渐变差,600℃退火形成较低接触电阻的欧姆接触,比接触电阻率为3.03×10-4Ωcm2,而载流子浓度为5.88×1018cm-3的掺Si的样品未退火就形成欧姆接触,比接触电阻可达到4.03×10-4Ωcm2。     

Structural properties of alloyed Ti/Al/Ti/Au and Ti/Al/Mo/Au ohmic contacts to AlGaN/GaN

Two alloyed ohmic contact structures for AlGaN/GaN–Ti/Al/Ti/Au and Ti/Al/Mo/Au were studied. Both structures were optimized for minimum ohmic contact resistance. Structures grown on sapphire and SiC substrates were used to investigate structural properties of ohmic contacts to AlGaN/GaN. Ohmic contacts to AlGaN/GaN on SiC showed higher contact resistance values compared to contacts to AlGaN/GaN on sapphire. Ohmic contact metals were etched on samples after annealing. The alloyed interface was studied with backside illumination under an optical microscope. Alloyed inclusions associated with threading dislocations were observed on the surface. For the AlGaN/GaN on SiC sample the inclusion density was an order of magnitude lower than for the sample on sapphire. Conductive atomic force microscopy with carbon nanotube tip was used to investigate topography and conductivity profile of the surface after ohmic contact metal removal by etching.     

High temperature induced failure in Ti/Al/Ni/Au Ohmic contacts on AlGaN/GaN heterostructure

Ti/Al/Ni/Au (200/1200/500/2000 Å) Ohmic contact on AlGaN/GaN was prepared and it was subjected to thermal aging experiments. Thermal processing at 400 and 500 °C did not change the contact resistance significantly, while high temperature storage at 600 °C resulted in a surge in the contact resistance. The Al–Au alloy in the contact metal is believed to re-melt because its lowest melting temperature is 525 °C. The liquid of Al–Au alloy is observed to diffuse to the AlGaN surface and consume some AlGaN layer. In addition, voids are found to be produced during thermal process, which can reduce the effective contact area and thus lead to higher contact resistance. The TEM and EDX results of Ohmic contact’s cross sectional images provide evidence for this proposed mechanism.     

Compositional Study of Copper-Germanium Ohmic Contact to <Emphasis Type="Italic">n-</Emphasis>GaN

400°C alloying of Ge/Cu/Ge films on modestly doped n-GaN results in linear current-voltage (I-V) behavior over a wide range of relative Ge compositions. X-ray diffraction (XRD) and Auger depth profiling data suggest that the lowest contact resistivity is due to film compositions near 25 at.% Ge, where the amount of interfacial nonreacted Ge is low. Ohmic contact is likely established by a heavily doped GaN interfacial region influenced by premetallization reactive ion etching (RIE) and later low-temperature alloying, which assists in the formation of donorlike complexes possibly involving Ge_Ga or Si_Ga. This contact shows exceptionally smooth surface morphology, as revealed by atomic force microscopy (AFM). [rl](Received ...; accepted ...)     

Effect of AlN buffer thickness on GaN epilayer grown on Si(1 1 1)

We studied the influence of high temperature AlN buffer thickness on the property of GaN film on Si (1 1 1) substrate. Samples were grown by metal organic chemical vapor deposition. Optical microscopy, atomic force microscopy and X-ray diffraction were employed to characterize the samples. The results demonstrated that thickness of high temperature AlN buffer prominently influenced the morphology and the crystal quality of GaN epilayer. The optimized thickness of the AlN buffer is found to be about 150 nm. Under the optimized thickness, the largest crack-free range of GaN film is 10 mm×10 mm and the full width at half maximum of GaN (0 0 0 2) rocking curve peak is 621.7 arcsec. Using high temperature AlN/AlGaN multibuffer combined with AlN/GaN superlattices interlayer we have obtained 2 μm crack-free GaN epilayer on 2 in Si (1 1 1) substrates.     

Ohmic contacts to n-type GaN using Pd/Al metallization

Ohmic contacts to n-type GaN grown by metalorganic chemical vapor deposition were formed using a Pd/Al-based metallization. Ohmic contact resistances and specific contact resistances were investigated as a function of rapid thermal annealing temperature, Pd interlayer thickness, and annealing time. As-deposited Pd/AI was found to produce rectifying contacts while the metallization exhibited ohmic characteristics after annealing at temperatures as low as 400°C. A minimum contact resistance of 0.9 ohm-mm (specific contact resistance = 1.2 × 10⁻⁵ ohm-cm²) was obtained upon annealing at 650°C for 30 s. For comparison, Al and Ti/Al contacts were also investigated. Auger electron spectroscopy, secondary ion mass spectrometry, and x-ray diffraction were used to investigate metallurgical reactions.     

Study of contact resistivity, mechanical integrity, and thermal stability of Ti/Al and Ta/Al ohmic contacts to n-type GaN

The annealing conditions and contact resistivities of Ta/Al ohmic contacts to n-type GaN are reported for the first time. The high temperature stability and mechanical integrity of Ti/Al and Ta/Al contacts have been investigated. Ta/Al (35 nm/115 nm) contacts to n-type GaN became ohmic after annealing for 3 min at 500°C or for 15 s at 600°C. A minimum contact resistivity of 5×10⁻⁶Ω cm² was measured after contacts were repatterned with an Al layer to reduce the effect of a high metal sheet resistance. Ti/Al and Ta/Al contacts encapsulated under vacuum in quartz tubes showed a significant increase in contact resistivity after aging for five days at 600°C. Cross section transmission electron microscopy micrographs and electrical measurements of aged samples indicate that the increased contact resistivity is primarily the result of degradation of the metal layers. Minimal reactions at the metal/GaN interface of aged samples were observed.     

用于紫外探测器的AlGaN/GaN异质结构的Ti/Al/Ni/Au欧姆接触特性

采用Ti/Al/Ni/Au多层金属体系在Al0.27Ga0.73N/GaN异质结构上制备了欧姆接触.分别采用线性传输线方法(LTLM)和圆形传输线方法(CTLM)对其电阻率进行了测试.当Ti(10nm)/Al(100nm)/Ni(40nm)/Au(100nm)金属体系在650℃高纯N2气氛中退火30s时,测量得到的最小比接触电阻率为1.46×10-5Ω·cm2.并制备了Al0.27Ga0.73N/GaN光导型紫外探测器,通过测试发现探测器的暗电流.电压曲线呈线性分布.实验结果表明在Al0.27 Ga0.73N/GaN异质结构上获得了好的欧姆接触,能够满足制备高性能AlGaN/GaN紫外探测器的要求.     

Very low resistance ohmic contacts to n-GaN

Ohmic contacts with low resistance are fabricated on n-GaN films using Al/Ti bilayer metallization. GaN films used are 0.3 μm thick layers with carrier concentrations of 1 × 10¹⁹ cm⁻³ grown on the c-plane sapphire by ion-removed electron cyclotron resonance molecular beam epitaxy. The lowest value for the specific contact resistivity (ρ_c) of 1.2×10⁻⁸ Ω·cm² was obtained with furnace annealing at 500°C for 60 min. This result shows the effectiveness of high carrier concentration GaN layers and the low temperature annealing for the realization of low resistance ohmic contacts. Sputtering Auger electron spectroscopy analysis reveals that Al diffuses into Ti layer and comes into contact with the GaN surface.