A Comparative NBTI Study of $hbox{HfO}_{2}$, $hbox{HfSiO}_{x}$, and SiON p-MOSFETs Using UF-OTF $I_{rm DLIN}$ Technique

The time, temperature, and oxide-field dependence of negative-bias temperature instability is studied in $hbox{HfO}_{2}/hbox{TiN}$, $ hbox{HfSiO}_{x}/hbox{TiN}$, and SiON/poly-Si p-MOSFETs using ultrafast on-the-fly $I_{rm DLIN}$ technique capable of providing measured degradation from very short (approximately microseconds) to long stress time. Similar to rapid thermal nitrided oxide (RTNO) SiON, $hbox{HfO}_{2}$ devices show very high temperature-independent degradation at short (submilliseconds) stress time, not observed for plasma nitrided oxide (PNO) SiON and $hbox{HfSiO}_{x}$ devices. $hbox{HfSiO}_{x}$ shows lower overall degradation, higher long-time power-law exponent, field acceleration, and temperature activation as compared to $hbox{HfO}_{2}$, which are similar to the differences between PNO and RTNO SiON devices, respectively. The difference between $ hbox{HfSiO}_{x}$ and $hbox{HfO}_{2}$ can be attributed to differences in N density in the $hbox{SiO}_{2}$ IL of these devices.      

Electrical Properties of $hbox{Bi}_{5}hbox{Nb}_{3} hbox{O}_{15}$ Thin Film Grown on $hbox{TiN}/hbox{SiO}_{2}/ hbox{Si}$ at Room Temperature for Metal–Insulator–Metal Capacitors

Buckling was observed in $hbox{Bi}_{5}hbox{Nb}_{3}hbox{O}_{15}$ (BiNbO) films grown on $hbox{TiN}/hbox{SiO}_{2}/hbox{Si}$ at 300 $^{circ}hbox{C}$ but not in films grown at room temperature and annealed at 350 $^{circ}hbox{C}$. The 45-nm-thick films showed a high capacitance density and a low dissipation factor of 8.81 $hbox{fF}/muhbox{m}^{2}$ and 0.97% at 100 kHz, respectively, with a low leakage current density of 3.46 $hbox{nA}/hbox{cm}^{2}$ at 2 V. The quadratic and linear voltage coefficients of capacitance of this film were 846 $hbox{ppm}/hbox{V}^{2}$ and 137 ppm/V, respectively, with a low temperature coefficient of capacitance of 226 $hbox{ppm}/^{circ}hbox{C}$ at 100 kHz. This suggests that a BiNbO film grown on a $hbox{TiN}/ hbox{SiO}_{2}/hbox{Si}$ substrate is a good candidate material for high-performance metal–insulator–metal capacitors.      

High-Density and Low-Leakage-Current MIM Capacitor Using Stacked $hbox{TiO}_{2}/hbox{ZrO}_{2}$ Insulators

We have fabricated high-$kappa hbox{Ni}/hbox{TiO}_{2}/hbox{ZrO}_{2}/ hbox{TiN}$ metal–insulator–metal (MIM) capacitors. A low leakage current of $hbox{8} times hbox{10}^{-8} hbox{A/cm}^{2}$ at 125 $^{circ}hbox{C}$ was obtained with a high 38- $hbox{fF}/muhbox{m}^{2}$ capacitance density and better than the $hbox{ZrO}_{2}$ MIM capacitors. The excellent device performance is due to the lower electric field in 9.5-nm-thick $hbox{TiO}_{2}/ hbox{ZrO}_{2}$ devices to decrease the leakage current and to a higher $kappa$ value of 58 for $ hbox{TiO}_{2}$ as compared with that of $hbox{ZrO}_{2}$ to preserve the high capacitance density.      

Nonvolatile-Memory Characteristics of $hbox{AlO}^{-}$ -Implanted $hbox{Al}_{2}hbox{O}_{3}$

The nonvolatile-memory (NVM) characteristics of $hbox{AlO}^{-}$ -implanted $hbox{Al}_{2}hbox{O}_{3}$ structures are reported and shown to exhibit promising behaviors, including fast program/erase speeds and high-temperature data retention. Photoconductivity spectra show the existence of two dominant trap levels, located at around 2 and 4 eV below the conduction band minimum of $hbox{Al}_{2}hbox{O}_{3}$, and our calculations show that these levels are likely attributed to the defects in the $hbox{Al}_{2}hbox{O}_{3}$, such as the Al–O divacancy. The relative concentrations of these defects vary with the implant fluence and are shown to explain the NVM characteristics of the samples irradiated to different fluences.      

High-Performance $hbox{In}_{0.7}hbox{Ga}_{0.3}hbox{As}$ -Channel MOSFETs With High-$kappa$ Gate Dielectrics and $alpha$-Si Passivation

Long and short buried-channel $hbox{In}_{0.7}hbox{Ga}_{0.3}hbox{As}$ MOSFETs with and without $alpha$-Si passivation are demonstrated. Devices with $alpha$-Si passivation show much higher transconductance and an effective peak mobility of 3810 $hbox{cm}^{2}/ hbox{V} cdot hbox{s}$. Short-channel MOSFETs with a gate length of 160 nm display a current of 825 $muhbox{A}/muhbox{m}$ at $V_{g} - V_{t} = hbox{1.6} hbox{V}$ and peak transconductance of 715 $muhbox{S}/muhbox{m}$. In addition, the virtual source velocity extracted from the short-channel devices is 1.4–1.7 times higher than that of Si MOSFETs. These results indicate that the high-performance $hbox{In}_{0.7}hbox{Ga}_{0.3} hbox{As}$-channel MOSFETs passivated by an $alpha$ -Si layer are promising candidates for advanced post-Si CMOS applications.      

Impacts of $hbox{N}_{2}$ and $hbox{NH}_{3}$ Plasma Surface Treatments on High-Performance LTPS-TFT With High-$kappa$ Gate Dielectric

Low-temperature polycrystalline-silicon thin-film transistors (LTPS-TFTs) with high- $kappa$ gate dielectrics and plasma surface treatments are demonstrated for the first time. Significant field-effect mobility $mu_{rm FE}$ improvements of $sim$86.0% and 112.5% are observed for LTPS-TFTs with $hbox{HfO}_{2}$ gate dielectric after $hbox{N}_{2}$ and $ hbox{NH}_{3}$ plasma surface treatments, respectively. In addition, the $hbox{N}_{2}$ and $ hbox{NH}_{3}$ plasma surface treatments can also reduce surface roughness scattering to enhance the field-effect mobility $mu_{rm FE}$ at high gate bias voltage $V_{G}$, resulting in 217.0% and 219.6% improvements in driving current, respectively. As a result, high-performance LTPS-TFT with low threshold voltage $V_{rm TH} sim hbox{0.33} hbox{V}$, excellent subthreshold swing S.S. $sim$0.156 V/decade, and high field-effect mobility $mu_{rm FE} sim hbox{62.02} hbox{cm}^{2}/hbox{V} cdot hbox{s}$ would be suitable for the application of system-on-panel.      

Resistive-Switching Characteristics of $hbox{Al}/ hbox{Pr}_{0.7}hbox{Ca}_{0.3}hbox{MnO}_{3}$ for Nonvolatile Memory Applications

A systematic study on the switching mechanism of an $hbox{Al}/ hbox{Pr}_{0.7}hbox{Ca}_{0.3}hbox{MnO}_{3}$ (PCMO) device was performed. A polycrystalline PCMO film was deposited using a conventional sputtering method. A thin Al layer was introduced to induce a reaction with the PCMO, forming aluminum oxide $(hbox{AlO}_{x})$. Transmission electron microscopy analysis of the interface between Al and PCMO showed that resistive switching was governed by the formation and dissolution of $hbox{AlO}_{x}$. Some basic memory characteristics, such as good cycle endurance and data retention of up to $hbox{10}^{4}$ s at 125 $^{circ}hbox{C}$, were also obtained. It also showed excellent switching uniformity and high device yield.      

Recessed 70-nm Gate-Length AlGaN/GaN HEMTs Fabricated Using an $hbox{Al}_{2}hbox{O}_{3}/hbox{SiN}_{x}$ Dielectric Layer

In this letter, a novel process for recessed-gate AlGaN/GaN high-electron-mobility transistors using an $hbox{Al}_{2}hbox{O}_{3}/ hbox{SiN}_{x}$ dielectric has been developed. The $hbox{Al}_{2}hbox{O}_{3}/hbox{SiN}_{x}$ dielectric bilayer was used as a recess etch-mask for short-gate-footprint definition. Recessed-gate devices with a gate length of 70 nm have been fabricated on a molecular-beam-epitaxy-grown layer structure using this process. After the removal of the dielectric layers, excellent dc and small-signal results, a high drain–current density of 1.5 A/mm, a unity gain cutoff frequency of 160 GHz, and a maximum frequency of oscillation of 200 GHz were obtained.      

Electrical Properties of $hbox{Ga}_{2}hbox{O}_{3}/ hbox{GaAs}$ Interfaces and GdGaO Dielectrics in GaAs-Based MOSFETs

Electrical properties of $hbox{Ga}_{2}hbox{O}_{3}/hbox{GaAs}$ interfaces with GdGaO cap dielectrics used in recent enhancement-mode GaAs-based NMOSFETs which perform in line with theoretical model predictions are presented. Capacitors with GdGaO thickness ranging from 3.0 to 18 nm ($hbox{0.9} leq hbox{EOT} leq hbox{3.9} hbox{nm}$) have been characterized by capacitance–voltage measurements. Midgap interface state density $D_{rm it}$, effective workfunction $phi_{m}$, fixed charge $Q_{f}$, dielectric constant $kappa$, and low field leakage current density are $hbox{2} times hbox{10}^{11} hbox{cm}^{-2} cdot hbox{eV}^{-1}$, 4.93 eV, $-hbox{8.9} times hbox{10}^{11} hbox{cm}^{-2}$, 19.5, and $hbox{10}^{-9}{-} hbox{10}^{-8} hbox{A/cm}^{2}$, respectively. The presence of interfacial Gd was confirmed to dramatically degrade electrical interface properties. The data illuminate the intimate interplay between heterostructure and interface engineering to achieve optimum MOSFET operation.      

Performance Improvement of N-Type $hbox{TiO}_{x}$ Active-Channel TFTs Grown by Low-Temperature Plasma-Enhanced ALD

We report on performance improvement of $n$-type oxide–semiconductor thin-film transistors (TFTs) based on $hbox{TiO}_{x}$ active channels grown at 250 $^{circ}hbox{C}$ by plasma-enhanced atomic layer deposition. TFTs with as-grown $hbox{TiO}_{x}$ films exhibited the saturation mobility $(mu_{rm sat})$ as high as 3.2 $hbox{cm}^{2}/hbox{V}cdothbox{s}$ but suffered from the low on–off ratio $(I_{rm ON}/I_{rm OFF})$ of $hbox{2.0} times hbox{10}^{2}$. $hbox{N}_{2}hbox{O}$ plasma treatment was then attempted to improve $I_{rm ON}/I_{rm OFF}$. Upon treatment, the $hbox{TiO}_{x}$ TFTs exhibited $I_{rm ON}/I_{rm OFF}$ of $hbox{4.7} times hbox{10}^{5}$ and $mu_{rm sat}$ of 1.64 $hbox{cm}^{2}/hbox{V}cdothbox{s}$, showing a much improved performance balance and, thus, demonstrating their potentials for a wide variety of applications such as backplane technology in active-matrix displays and radio-frequency identification tags.      

Improvement of On–Off-Current Ratio in $ hbox{TiO}_{rm x}$ Active-Channel TFTs Using $hbox{N}_{2} hbox{O}$ Plasma Treatment

Without sacrificing the on-current in the transfer characteristics, we have successfully reduced the off-current part by the optimal $hbox{N}_{2}hbox{O}$ plasma treatment to improve the on–off-current ratio in n-type titanium oxide $( hbox{TiO}_{rm x})$ active-channel thin-film transistors. While the high-power (275 W) $hbox{N}_{2}hbox{O}$ plasma treatment oxidizes the whole $hbox{TiO}_{rm x}$ channel and results in the reduction of both on- and off-current, the optimized low-power (150 W) process makes the selective oxidation of the top portion in the channel and reduces only the off-current significantly. Increase in on–off ratio by almost five orders of magnitude is achieved without change in on-current by using the presented method.      

Improvement of Resistive Switching in $hbox{Cu}_{x} hbox{O}$ Using New RESET Mode

Wide dispersions of memory switching parameters are observed in resistive random access memory based on $hbox{Al/Cu}_{x}hbox{O/Cu}$ structure. Moreover, the switching instability induced by these dispersions is studied. In this letter, a ramped-pulse series operation method is put forward, which can improve switching stability and cycling endurance remarkably. A method for minimizing the dispersion of $V_{rm reset}$ by optimizing the amplitude of pulse is proposed further. The write–read–erase–read operations can be over $hbox{8} times hbox{10}^{3}$ cycles without degradation by using the new operation mode. The role of Joule heating behind this behavior of $ hbox{Al/Cu}_{x}hbox{O/Cu}$ device is discussed.      

Resistive Switching in $hbox{CeO}_{x}$ Films for Nonvolatile Memory Application

$hbox{Al}/hbox{CeO}_{x}/hbox{Pt}$ devices with nonstoichiometric $hbox{CeO}_{x} (hbox{1.5} ≪ x ≪ hbox{2})$ films were fabricated. The unique resistive switching (RS) behaviors for resistive random access memory applications, including stable and sharp bipolar RS processes and a multilevel and self-stop set process without current compliance and without excessive requirement on a high-voltage electroforming process, were demonstrated. A multifilament switching model based on the distribution characteristics of oxygen vacancies in $hbox{CeO}_{x}$ films is proposed to explain the observed RS behaviors.      

Effective Modulation of Quadratic Voltage Coefficient of Capacitance in MIM Capacitors Using $hbox{Sm}_{2}hbox{O}_{3}/hbox{SiO}_{2}$ Dielectric Stack

We report the first demonstration of metal–insulator–metal (MIM) capacitors with $hbox{Sm}_{2}hbox{O}_{3}/hbox{SiO}_{2}$ stacked dielectrics for precision analog circuit applications. By using the “canceling effect” of the positive quadratic voltage coefficient of capacitance (VCC) of $hbox{Sm}_{2}hbox{O}_{3}$ and the negative quadratic VCC of $hbox{SiO}_{2}$, MIM capacitors with capacitance density exceeding 7.3 $hbox{fF}/muhbox{m}^{2}$ , quadratic VCC of around $-hbox{50} hbox{ppm/V}^{2}$ , and leakage current density of $hbox{1} times hbox{10}^{-7} hbox{A/cm}^{2}$ at $+$3.3 V are successfully demonstrated. The obtained capacitance density and quadratic VCC satisfy the technical requirements specified in the International Technology Roadmap for Semiconductors through the year 2013 for MIM capacitors to be used in precision analog circuit applications.      

High-Performance Poly-Silicon TFTs Using a High-$k$ $hbox{PrTiO}_{3}$ Gate Dielectric

In this letter, a polycrystalline-silicon thin-film transistor (poly-Si TFT) with a high- $k$ $hbox{PrTiO}_{3}$ gate dielectric is proposed for the first time. Compared to TFTs with a $hbox{Pr}_{2}hbox{O}_{3}$ gate dielectric, the electrical characteristics of poly-Si TFTs with a $hbox{PrTiO}_{3}$ gate dielectric can be significantly improved, such as lower threshold voltage, smaller subthreshold swing, higher $I_{rm on}/I_{rm off}$ current ratio, and larger field-effect mobility, even without any hydrogenation treatment. These improvements can be attributed to the high gate capacitance density and low grain-boundary trap state. All of these results suggest that the poly-Si TFT with a high- $k$ $hbox{PrTiO}_{3}$ gate dielectric is a good candidate for high-speed and low-power display driving circuit applications in flat-panel displays.      

Electrical Properties of Amorphous $hbox{Bi}_{5} hbox{Nb}_{3}hbox{O}_{15}$ Thin Film for RF MIM Capacitors

Amorphous $hbox{Bi}_{5}hbox{Nb}_{3}hbox{O}_{15}(hbox{B}_{5} hbox{N}_{3})$ film grown at 300 $^{circ}hbox{C}$ showed a high-$k$ value of 71 at 100 kHz, and similar $k$ value was observed at 0.5–5.0 GHz. The 80-nm-thick film exhibited a high capacitance density of 7.8 fF/$muhbox{m}^{2}$ and a low dissipation factor of 0.95% at 100 kHz with a low leakage-current density of 1.23 nA/ $hbox{cm}^{2}$ at 1 V. The quadratic and linear voltage coefficient of capacitances of the $hbox{B}_{5}hbox{N}_{3}$ film were 438 ppm/$hbox{V}^{2}$ and 456 ppm/V, respectively, with a low temperature coefficient of capacitance of 309 ppm/$^{circ}hbox{C}$ at 100 kHz. These results confirmed the potential of the amorphous $hbox{B}_{5}hbox{N}_{3}$ film as a good candidate material for a high-performance metal–insulator–metal capacitors.      

Low-Voltage Organic Field-Effect Transistor With PMMA/$ hbox{ZrO}_{2}$ Bilayer Dielectric

This paper reports on the application of a bilayer polymethylmethacrylate (PMMA)/ $hbox{ZrO}_{2}$ dielectric in copper phthalocyanine (CuPc) organic field-effect transistors (OFETs). By depositing a PMMA layer on $hbox{ZrO}_{2}$, the leakage of the dielectric is reduced by one order of magnitude compared to single-layer $hbox{ZrO}_{2}$. A high-quality interface is obtained between the organic semiconductor and the combined insulators. By integrating the advantages of polymer and high- $k$ dielectrics, the device achieves both high mobility and low threshold voltage. The typical field-effect mobility, threshold voltage, on/off current ratio, and subthreshold slope of OFETs with bilayer dielectric are $hbox{5.6}timeshbox{10}^{-2} hbox{cm}^{2}/hbox{V} cdot hbox{s}$, 0.8 V, $hbox{1.2} times hbox{10}^{3}$, and 2.1 V/dec, respectively. By using the bilayer dielectrics, the hysteresis observed in the devices with single-layer $hbox{ZrO}_{2}$ is no longer present.      

0.8-V Supply Voltage Deep-Submicrometer Inversion-Mode $hbox{In}_{0.75}hbox{Ga}_{0.25}hbox{As}$ MOSFET

We report the experimental demonstration of deep-submicrometer inversion-mode $hbox{In}_{0.75}hbox{Ga}_{0.25}hbox{As}$ MOSFETs with ALD high- $k$ $hbox{Al}_{2}hbox{O}_{3}$ as gate dielectric. In this letter, n-channel MOSFETs with 100–200-nm-long gates have been fabricated. At a supply voltage of 0.8 V, the fabricated devices with 200–130-nm-long gates exhibit drain currents of 232–440 $muhbox{A}/muhbox{m}$ and transconductances of 538–705 $muhbox{S}/muhbox{m}$. The 100-nm device has a drain current of 801 $muhbox{A}/muhbox{m}$ and a transconductance of 940 $muhbox{S}/muhbox{m}$. However, the device cannot be pinched off due to severe short-channel effect. Important scaling metrics, such as on/off current ratio, subthreshold swing, and drain-induced barrier lowering, are presented, and their relations to the short-channel effect are discussed.      

Gate-Recessed InAlN/GaN HEMTs on SiC Substrate With $ hbox{Al}_{2}hbox{O}_{3}$ Passivation

We studied submicrometer $(L_{G} = hbox{0.15} {-} hbox{0.25} mu hbox{m})$ gate-recessed InAlN/AlN/GaN high-electron mobility transistors (HEMTs) on SiC substrates with 25-nm $hbox{Al}_{2}hbox{O}_{3}$ passivation. The combination of a low-damage gate-recess technology and the low sheet resistance of the InAlN/AlN/GaN structure resulted in HEMTs with a maximum dc output current density of $I_{{rm DS}, max} = hbox{1.5} hbox{A/mm}$ and a record peak extrinsic transconductance of $g_{m, {rm ext}} = hbox{675} hbox{mS/mm}$. The thin $hbox{Al}_{2}hbox{O}_{3}$ passivation improved the sheet resistance and the transconductance of these devices by 15% and 25%, respectively, at the same time that it effectively suppressed current collapse.      

$hbox{TiN/ZrO}_{2}$/Ti/Al Metal–Insulator–Metal Capacitors With Subnanometer CET Using ALD-Deposited $hbox{ZrO}_{2}$ for DRAM Applications

We provide the first report of the structural and electrical properties of $hbox{TiN/ZrO}_{2}$/Ti/Al metal–insulator–metal capacitor structures, where the $hbox{ZrO}_{2}$ thin film (7–8 nm) is deposited by ALD using the new zirconium precursor ZrD-04, also known as Bis(methylcyclopentadienyl) methoxymethyl. Measured capacitance–voltage ($C$– $V$) and current–voltage ( $I$–$V$) characteristics are reported for premetallization rapid thermal annealing (RTP) in $hbox{N}_{2}$ for 60 s at 400 $^{circ}hbox{C}$, 500 $^{circ}hbox{C}$, or 600 $^{ circ}hbox{C}$. For the RTP at 400 $^{circ}hbox{C}$ , we find very low leakage current densities on the order of nanoamperes per square centimeter at a gate voltage of 1 V and low capacitance equivalent thickness values of $sim$ 0.9 nm at a gate voltage of 0 V. The dielectric constant of $ hbox{ZrO}_{2}$ is 31 $pm$ 2 after RTP treatment at 400 $^{circ}hbox{C}$.