不同Al2O3-TiO2-Cr2O3-SiO2配比等离子喷涂层的耐磨粒磨损性能

为了探讨等离子喷涂制备Al2O3-TiO2-Cr2O3-SiO2层的可行性及其喷涂层的耐磨性,采用等离子喷涂在Q235钢表面分别制备了54%Al2O3-36%TiO2-10%Cr2O3-0.5%SiO2,42%Al2O3-28%TiO2-28.5%Cr2O3-1.5%SiO2和30%Al2O3-20%TiO2-47.5%Cr2O3-2.5%SiO23种陶瓷层,分析了陶瓷涂层的金相显微形貌、显微硬度及耐磨粒磨损性能,并分析了其耐磨粒磨损的机理。结果表明:3种涂层的显微硬度分布均具有梯度分布特性,Al2O3+Cr2O3硬质相含量越高,涂层硬度越大;30%Al2O3-20%TiO2-47.5%Cr2O3-2.5%SiO2喷涂粉制成的涂层的硬度最大,耐磨粒磨损性能最佳。     

自蔓延高温合成反应热喷涂Al2O3基复相陶瓷涂层的性能

为了改善AZ31B镁合金的耐磨性,以Al2O3-13%TiO2为陶瓷骨料,在其中加入Al/CuO铝热荆,采用普通氧乙炔火焰自蔓延高温合成反应热喷涂技术在镁合金表面制备Al2O3基复相陶瓷涂层.通过X射线衍射分析了陶瓷涂层的组成.结果表明,所得复相陶瓷涂层具有良好的抗热震性,涂层内有Cu4MgO5,CuAlO2等新的物相产生.磨粒磨损试验、黏着干磨损试验和黏着油磨损试验表明:自蔓延反应热喷涂陶瓷涂层的耐磨性是AZ31B基体的6.48,3.32,6.04倍,普通热喷涂层的耐磨性是AZ31B基体的3.60,1.76,1.67倍,自蔓延反应热喷涂陶瓷涂层的耐磨性比普通热喷涂层有较大提高.     

Al2O3陶瓷爆炸喷涂涂层性能分析

使用爆炸喷涂法制备了Al2O3陶瓷涂层,以自熔性NiAl合金粉末作为底层,基体为45钢。涂层的XRD图谱分析表明,爆炸喷涂的Al2O3陶瓷涂层结构以α-Al2O3及γ-Al2O3为主,说明在爆炸喷涂中存在相变过程;使用国标JB/T7509-94铁试剂方法进行测定,Al2O3陶瓷涂层孔隙率为0.019个/mm2,爆炸喷涂的Al2O3陶瓷涂层结构致密;滑动磨损试验说明,爆炸喷涂Al2O3陶瓷涂层提高了钢基体的耐磨损性能,适用于耐磨涂层。     

等离子喷涂纳米Al2O3-TiO2复合陶瓷涂层的研究现状

等离子喷涂纳米Al2O3-TiO2复合陶瓷涂层具有耐磨、耐腐蚀、抗热氧化等优良性能,因而成为目前纳米涂层领域的研究热点之一。归纳了纳米结构Al2O3-TiO2喂料的制备方法,介绍了纳米结构涂层的显微结构和力学性能(断裂韧性、显微硬度、结合强度等),分析了纳米结构涂层的抗热氧化性和摩擦学性能,综述了等离子喷涂纳米Al2O3-TiO2复合陶瓷涂层的研究现状,讨论并展望了其未来的发展方向和应用前景。     

反应等离子喷涂Fe-Al2O3-FeAl2O4复合涂层的反应机理研究

金属/陶瓷复合涂层具有金属的韧性和陶瓷的高强度、高硬度等优点,利用反应等离子喷涂技术将Fe2O3/Al复合粉制备成金属/陶瓷复合涂层,以X射线衍射(XRD)、扫描电镜(SEM)、能谱仪(EDS)等分析技术研究了该复合涂层的反应机理和涂层性能.结果表明:涂层具有以层状的FeAl2O4、Al2O3为骨架,球形的Fe及部分FeAl为弥散相的复合组织;复合粉体反应形成涂层的过程是分步进行的,而且在熔滴到达基体后部分反应仍继续进行;一定程度上,由于反应过程受到Al元素的扩散限制,同时等离子喷涂的冷却速度较高,使得涂层中主要含有FeAl2O4及少量的FeO.     

等离子喷涂Al2O3+13%TiO2陶瓷涂层的组织结构及其耐磨性

本文用X射线衍射、扫描电镜等研究了等离子喷涂Al2O3+13%TiO2(质量分数)陶瓷涂层的相结构、相组成及其组织特征.陶瓷涂层孔隙率低,致密程度较高,以亚稳相γ-Al2O3为主要相,同时存在α-Al2O3和金红石TiO2.富Al2O3区与富TiO2区呈明显相互交迭的层状结构,且存在相互成分扩散.另外,涂层设计对硬度有一定影响,TiO2的引入提高了涂层的耐磨性.     

纳米掺杂Al2O3/ZrO2等离子喷涂涂层组织结构研究

利用大气等离子喷涂技术,在N80钢基体上制备纳米掺杂Al2O3/ZrO2热障涂层。利用XRD、SEM等观察分析了纳米掺杂Al2O3/ZrO2粉末及等离子喷涂涂层组织形貌及结构,结果表明,Al2O3/ZrO2等离子喷涂粉末是由纳米包覆微米级粒子及少量的纳米团聚体球团粒子构成。纳米掺杂等离子喷涂Al2O3/ZrO2涂层的微观组织形貌复杂,存在着纳米柱状晶薄壳内包裹着微米级柱状晶、未熔化的ZrO2陶瓷粒子嵌镶在晶体内部的独特晶内结构。涂层主要由α-Al2O3及亚稳四方相t,-ZrO2相构成。     

AZ31B镁合金表面自蔓延反应火焰喷涂Al_2O_3基陶瓷层的组织结构及性能

为了提高火焰喷涂Al2O3基陶瓷涂层的致密度、结合强度和耐磨性,将铝热剂Al/CuO加入氧化铝钛粉(AT)陶瓷骨料中,采用自蔓延(SHS)反应火焰喷涂技术在AZ31B镁合金表面制备了Al2O3基复相陶瓷层,并对涂层的组织结构、致密度、抗热震性、结合强度和耐磨性进行了测试,分析了铝热剂对陶瓷层性能的影响。结果表明:与普通火焰喷涂制备的AT陶瓷层相比,SHS反应火焰喷涂制备的Al2O3基陶瓷层内部有Cu2+1O,Cu3TiO5,Al等新相生成,具有良好的致密度、结合强度和显微硬度,其耐磨性较普通火焰喷涂AT层提高较多。     

TiC-TiB2 复相陶瓷涂层的反应火焰喷涂制备

基于SHS 反应火焰喷涂技术, 采用Ti-B₄C-C 喷涂体系, 在钢基表面制备了TiC- TiB₂ 复相陶瓷涂层。通过对SHS 火焰喷涂陶瓷涂层的电子显微观察和X射线衍射及能谱分析, 探讨了SHS 反应火焰喷涂TiC- TiB₂复相陶瓷涂层的组织结构及成因。研究发现, 涂层是一种复相非均质、传统热喷涂层状涂层特征不明显的亚稳结构。涂层由占主体的TiC_0.7N_0.3 、TiC_0.2N_0.8 、TiB₂ 相和少量TiO₂ 、Ti₂O、Ti₃O₅ 相及气孔组成。涂层中有三类特征各异的组织, 即尺度在微2纳米级呈团簇状分布的组织, 尺寸在1～3μm 之间呈等轴状颗粒分布的组织和呈深黑色的不规则气孔。三类组织是由在喷涂粒子与基材接触之前, 喷涂团聚粉粒经飞行燃烧和反应合成形成的熔融陶瓷液滴(又分为实心和空心两类) 和不规则陶瓷颗粒(其形状与原喷涂团聚颗粒一样, 但组织结构已发生转变,基本成为陶瓷相) 与基材碰撞变形、冷却凝固、快速结晶形成的。      

Al-Fe2O3体系等离子反应合成金属颗粒增韧复合陶瓷涂层的研究

利用Al-Fe2O3体系放热反应,采用等离子反应合成技术,制备出了金属颗粒增韧的FeAl2O4-Al2O3-Fe复合陶瓷涂层,并研究分析了复合涂层的组织及其性能.结果表明:等离子反应合成得到了以层状基体相FeAl2O4与硬质相Al2O3为骨架,球状Fe相弥散分布于基体相上的复合涂层;所制得的金属/陶瓷复合涂层的韧性得到明显提高,其韧性优于在同样基材上等离子喷涂的陶瓷涂层;特别是复合涂层具有较高的耐磨性能.     

Superconductivity of barium-doped Bi2Sr2CaCu2Oy

Sintered ceramic samples of Bi₂Sr_2–x Ba _x CaCu₂O_y with nominal barium fraction 0x0.3 have been prepared by the solid-state reaction method. WDS studies verified that barium enters the superconducting phase. For slowly cooled samples, the midpointT _c of the superconducting transition is significantly increased by barium doping, whereas for quenched samplesT _c is little affected. The increase ofT _c with increasing barium fraction is consistent with a decrease in the hole concentration in the superconducting layers.     

Comparison of the Electronic Structures of La2CuO4, Sr2CuO2Cl2, and Sr2CuO2F2

First-principles cluster calculations are reported of the local electronic structure of the three compounds: La₂CuO₄, Sr₂CuO₂Cl₂, and Sr₂CuO₂F₂. The copper and the planar oxygen 2p atomic orbitals exhibit a similar degree of covalency. The out-of-plane orbitals, however, are quite different with the atomic orbital lowered significantly in energy for chlorine and fluorine apical positions.     

Selective solar-driven CO2 reduction mediated by 2D/2D Bi2O2SiO3/MXene nanosheets heterojunction

Photocatalytic CO₂ reduction reaction (CO₂RR) is an environment-friendly technique for clean fuel generation.Developing low-cost and efficient photocatalyst/cocatalyst systems for boosting CO₂ RR is still a challenge.Herein,a novel Bi₂O₂SiO₃/Ti₃C₂2D/2D heterojunction photocatalysts are successfully prepared by in situ growth of Bi₂O₂SiO₃ on the surface of ultrathin Ti₃     

Reactivity of the H2O2/TiO2 system

The reactivity of the H₂O₂/TiO₂ system for samples treated at atmospheric pressure is studied by means of Auger Electron Spectroscopy. The most significant changes on the TiO₂ ‘final’ state are: (i) The I(O)/I(Ti) peak-to-peak ratio is diminished by 15%. (ii) The LMV transition suffers an energy shift of +2 eV, whereas the peak-to-peak width diminishes 1.5 eV. (iii) Its structure changes with respect to that of the TiO₂ ‘initial’ state although it is not identified with any one of the known stoichiometric oxides. (iv) When the samples that represent the ‘final’ state are heated up to 650 K, the AES spectrum matches quite well that of the TiO₂ ‘initial’ state.     

Quasiparticle dispersion of Sr2CuO2Cl2

Recent angle resolved photoemission (ARPES) measurements for the insulating cuprate Sr₂CuO₂Cl₂ have provided the first experimental data which can be directly compared to the (theoretically) well-studied problem of a single hole propagating in an antiferromagnet. Some discrepancies withthe familiar 2D t— J model were observed. Here we discuss a comparison between the ARPES results and the quasiparticle dispersion of both (i) the extended t— t— J Hamiltonian and (ii) the three-band Hubbard model.     

MgO-Al2O3-SiO2-TiO2-Y2O3玻璃的弹性模量

根据硬盘基板用材料的要求，制备了MgO-Al2O3-SiO2-TiO2-Y2O3高弹性模量玻璃（120GPa)，玻璃的弹性模量随组成的变化服从Makishima-Mackenzie理论，MgO,Al2O3,TiO2,Y2O3等具有较高单位体积离解能的氧化物有利于提高玻璃的弹性模量，但玻璃弹性模量的理论计算值低于测试值，这是因为Makishima-Mackenzie理论没有考虑玻璃内阳离子的具体配位，对MgO,Y2O3堆积密度因子的堆导存在误差，因此利用Makishima-Mackenzie理论发展高弹性模量玻璃时应对MgO,Y2O3等氧化物的计算进行修正。     

Les phases SrLa2Al2O7 et SrGd2Al2O7

SrLa₂Al₂O₇ and SrGd₂Al₂O₇ belong to the structural type Sr₃Ti₂O₇. In SrGd₂Al₂O₇ strontium and gadolinium occupy respectively the 12 and 9 coordinated sites, whereas in SrLa₂Al₂O₇ the homologous cations are statistically distributed. The fluorescence spectra of both phases activated by Eu³⁺ ions show that the only possible position of Eu³⁺ is the 9 coordinated site.     

Ti/SnO2+Sb2O3+MnO2/PbO2阳极的性能研究

制备了一种非贵金属阳极－Ｔi/SnO2 Sb2O3 MnO2/PbO2,并用ＸＲＤ、ＳＥＭ进行了表征,计算出了电极的分形维数,测定了该电极在硫酸中的使用寿命和动力学参数,把该电极用于处理含酚废水和Ｐb电极进行对,结果表明,节电３３％,转化率达９５％,是一种优良的电化学催化剂。     

Na2O-B2O3-SiO2-SnO2系统的分相与析晶

对Na2O-B2O3-SiO2-SnO2四元系统的分相与析晶进行了探讨．通过对不同组成点在热处理、化学处理各阶段的试样进行能谱分析、XRD分析及SEM分析，确认了SnO2分布在分相结构中的富硼碱相中；在该系统中SnO2晶体的析出有赖于分相过程；分相结构尺度限制了SnO2的析晶尺寸．试验结果表明，通过控制分相结构得到了负载于多孔富硅载体的纳米尺寸的SnO2材料．该材料具有较高的CO氧化催化活性．     

Subsolidus phase equilibria in the Al2O3-CeO2-PbO and Al2O3-CeO2-RuO2 systems

The subsolidus phase equilibria in air for the Al₂O₃-CeO₂-PbO and Al₂O₃-CeO₂-RuO₂ systems were studied with the aim of obtaining information on possible interactions between a CeO₂-based solid electrolyte in solid-oxide fuel cells (SOFCs) and other oxides. No ternary compound was found in either of the systems. The tie line in the Al₂O₃-PbO-CeO₂ system is between Al₂Pb₂O₅ and the CeO₂.