共查询到20条相似文献,搜索用时 46 毫秒
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利用X射线衍射、透射电子显微镜和差示扫描量热计分析表征了La55Al25Cu10Ni5Co5合金及其添加W颗粒后高能球磨产物的结构与相转变.由数个金属间化合物构成的La55Al25Cu10Ni5Co5合金经过机械研磨可转变为与熔体过冷形成的金属玻璃相类似的玻璃态合金,过冷液态温度区间的宽度△Tx可达到76 K.合金与W颗粒(体积分数10%-30%)的混和物机械研磨后,形成W纳米颗粒弥散分布于La基玻璃态合金基体上的复合材料.随着W含量的增加,基体合金的玻璃转变温度Tg和晶化起始温度Tx1均提高,同时△Tx增大,含30%W的复合材料,基体玻璃态合金的△Tx可达到92 K. 相似文献
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Mg-15%Al-5%Si-0.5%Sb合金制备及其组织研究 总被引:2,自引:1,他引:2
采用普通金属型重力铸造法制备了Mg-2.19%Si和Al-17.8%Si中间合金以及Mg-15%Al-5%Si-0.5%Sb自生复合材料。研究表明,采用粒径为4 mm的结晶硅,通过气体保护、添加覆盖剂等保护措施,在810℃下保温5 h可制得Mg-2.19%Si中间合金,Al-Si中间合金可采用低温加硅法制备。Mg-15%Al-5%Si-0.5%Sb自生复合材料中的Sb对Mg2Si相有一定的细化作用,并使树枝状的Mg2Si转变为粒状,但细化尺寸有限,应采取其它方式进一步细化。 相似文献
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Effects of calcium addition on as-cast microstructure and mechanical properties of Mg-5Zn-5Sn alloy 总被引:1,自引:0,他引:1
The effects of Ca addition on the as-cast microstructure and mechanical properties of the Mg-5Zn-5Sn (mass fraction,%) alloy were investigated.The results indicate that an addition of 0.5%-1.5% (mass fraction) Ca to the Mg-5Zn-5Sn alloy not only refines the as-cast microstructure of the alloy but also causes the formation of the primary and/or eutectic CaMgSn phases with high thermal stability;an increase in Ca amount from 0.5% to 1.5% (mass fraction) increases the amount and size of the CaMgSn phase.In addition,Ca addition to the Mg-5Zn-5Sn alloy improves not only the tensile properties at room temperature and 150 ℃ but also the creep properties.Among the Ca-containing Mg-5Zn-5Sn alloys,the one added 0.5% (mass fraction) Ca obtains the optimum ultimate tensile strength and elongation at room temperature and 150 ℃,however,the alloy added 1.5% (mass fraction) Ca exhibits the optimum yield strength and creep properties. 相似文献
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X-ray diffraction and DSC were used to investigate the crystallization behavior of amorphous Al90Ni5Ce5 alloys at different quenching temperatures.All the amorphous Al90Ni5Ce5 alloys quenched at different temperatures crystallize by two stages.The first stage corresponds to FCC Al phase precipitating from the amorphous matrix.The crystallization onset temperature increases with increasing quenching temperature.The quenching temperature also influences the isothermal behaviors.At low quenching temperatures,the FCC Al precipitation is only through grain growth.At high quenching temperatures,the FCC Al precipitation is through growth of quenched-in Al unclei and nucleation and growth of new crystallites.The reason that the crystallization onset temperature varies with quenching temperature is likely as that the quenched-in Al nuclei decreases with increasing temperature. 相似文献
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Dongming Liu Xiaofeng Liu Yunfeng Zhu Liquan Li 《Journal of Alloys and Compounds》2008,458(1-2):394-397
The composites of Mg–x wt.% CaNi5 (x = 20, 30 and 50) were prepared by hydriding combustion synthesis (HCS) and the phase evolution during HCS as well as the hydriding properties of the products were investigated. It was found that Mg reacted with CaNi5 forming Mg2Ni and Ca during the heating period of HCS. Afterwards, the resultant Mg2Ni and Ca as well as the remnant Mg reacted with hydrogen during the cooling period. The lower platform in the P–C isotherms corresponds to the hydriding of Mg, and the higher one corresponds to Mg2Ni. With the increase of the content of CaNi5 from 20 to 50 wt.%, the hydrogen content of the HCS products increases at first and then decreases. The Mg–30 wt.% CaNi5 composite has the maximum hydrogen capacity of 4.74 wt.%, and it can absorb 3.51 wt.% of hydrogen in the first hydriding process without activation. 相似文献
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The creep behaviors of as-cast Mg-5Zn-2.5Er alloy(mass fraction,%) ,under various applied stresses(50-70 MPa) and creep temperatures(150-200℃) for 100 h,were investigated.The stress exponent n is in the range of 1.5-5.8,and the activation energy Qc is in the range of 28.3-77.1 kJ/mol.With respect to the calculated n and Qc as well as the microstructures after creep,it is suggested that there is a transition region between grain boundary sliding(GBS) dominated creep to dislocation creep mechanism(from n3 to n3) ,arising in the steady-stage creep rate value of 2.89×10-9 s-1. 相似文献
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采用高能超声波搅拌法的方法对Al-5%Cu合金进行处理,制备半固态Al-5%Cu合金,重点研究了高能超声波处理熔体的温度、处理时间以及超声波的输出功率等重要参数对半固态Al-5%Cu合金组织形貌的演变过程的影响。实验结果表明:当铝合金熔体温度在610℃~660℃之间时,随着开始导入超声波时熔体温度的升高,铝合金的初生晶粒形貌逐渐演变成细小的球状颗粒;当控制熔体为660℃的时,随着导入超声波输出功率的增大和搅拌时间的延长,Al-5%Cu合金初生相形貌由粗大的枝晶状逐渐转变为细小的球状晶粒。 相似文献
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利用熔态旋淬法制备了系列铝含量的Fe-B-C-Si-Al系非晶合金薄带试样,采用X射线衍射仪(XRD)、差示扫描量热仪(DSC)和振动样品磁强计(VSM)研究了合金元素Al对Fe-B-C-Si系合金的非晶形成能力以及磁性能的影响。结果表明,Al元素明显提高Fe-B-C-Si合金的非晶形成能力,非晶合金薄带的临界厚度由无Al合金的小于35μm增加到含铝合金的70μm以上,并具有良好的塑性,可进行180o弯折而不断裂。饱和磁感应强度(Bs)也由无Al合金的1.52T增加到含铝合金的1.72T。 相似文献
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研究了悬浮铸造工艺对Al-5%Fe合金中的初生Al3Fe相形貌的影响。实验表明,采用Al-10%Fe混合粉末、Al-20%Fe混合粉末作为悬浮剂可以在一定程度上细化合金的铸态组织:未加悬浮剂时,合金中的组织为粗大的针状和花朵状;加入悬浮剂后,组织演变为较短小的针状、短杆状和颗粒状。 相似文献
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研究了不同处理状态下V-5Cr-5Ti合金的内耗特征,并结合微观缺陷的作用机制对内耗峰进行分析。利用倒扭摆仪和多功能内耗测试仪进行内耗测试,采用X射线衍射(XRD)分析相结构,扫描电镜(SEM)观察微观组织。研究结果表明,V-5Cr-5Ti合金制备过程中无法完全消除C、O、N等杂质元素,这些元素会以间隙原子或沉淀相颗粒形式存在,进而影响合金的微观组织缺陷。在不同的处理状态下,杂质元素的不同存在形式会使合金的内耗会产生不同的变化特征。根据内耗机制,所有的内耗峰均可以由应力作用下微观缺陷的运动来揭示,比如点缺陷、位错、晶界等。 相似文献
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采用铜模铸造法制备新型块体非晶合金Mg70Ni15Gd10Ag5(at%),其临界制备尺寸不低于5 mm,是目前Mg-Ni基非晶合金制备尺寸的最大值。采用差示扫描量热(DSC)法研究非晶合金的晶化行为,发现合金的晶化为多级晶化。随着升温速度的提高,玻璃转变温度Tg、晶化开始温度Tx、熔化前4个放热峰温度(Tp1、Tp2、Tp3、Tp4)、熔化开始温度(Tm)和液相线温度(Tl)均向高温区移动,晶化行为具有显著的动力学特征。利用Kissinger法计算特征温度对应的激活能,其值分别为Eg=188.05 kJ/mol、Ex=144.79 kJ/mol、Ep1=138 kJ/mol、Ep2=142.40 kJ/mol、Ep3=119.10 kJ/mol、Ep4=72.86 kJ/mol。 相似文献
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采用XRD、OM、SEM和TEM对V-5Cr-5Ti合金铸态组织进行分析,研究第二相的行为。结果表明:采用真空电子束熔炼制备的V-5Cr-5Ti合金铸态组织具有粗大的晶粒,晶粒内部存在以层状第二相堆垛成树枝状为特征的成分偏析区;金属钒和铸态V-5Cr-5Ti合金的晶格常数分别为0.30316和0.30375 nm,V的单胞体积膨胀约0.58%;存在2种类型的第二相:(1)短条状第二相,具有fcc结构,晶格常数为0.4182~0.4228 nm;(2)椭圆状第二相,具有fcc结构,晶格常数为0.4186~0.4242 nm。V-5Cr-5Ti合金凝固过程中,首先Ti元素与C元素反应析出具有立方结构的亚稳间隙相(Ti_2C)或V元素与C元素反应析出具有hcp结构的亚稳间隙相(V_2C),随后原子发生相互取代,最终形成以Ti元素为主,V、Cr元素为辅,具有fcc结构的碳-氧-氮化物,化学式记为(Ti_2-CON)。 相似文献
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AnomalousBehaviorofMagneticHysteresisLoopforSmCo_5AlloyPanShuming(潘树明)(GeneralResearchInstituteforNonforrousMetals,Beijing100... 相似文献
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研究了热处理对Fe17Mn5Si8Cr5Ni0.5NbC形状记忆合金回复应力的影响。结果表明:(1)随着淬火温度的升高,合金的回复应力增加,在750℃左右时,合金的回复应力(加热时的最大回复应力"h和冷却到室温的回复应力"r)最大;(2)合金经1100℃×30min固溶后再进行时效处理,时效温度在450~600℃(时效时间为1h)时,合金的回复应力达到最大;时效时间(时效温度为600℃)对"h影响不大,对"r有显著的影响,当时效时间为360min时,"r达到最大,然后又降低。 相似文献