共查询到19条相似文献,搜索用时 156 毫秒
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车用燃料油吸附法深度脱硫技术进展 总被引:25,自引:8,他引:17
综述了车用燃料油吸附法深度脱硫的技术及吸附机理,主要包括物理吸附脱硫、化学吸附脱硫、络合吸附脱硫和选择性吸附脱硫等。物理吸附是极性吸附,吸附剂对硫化物的选择性差,难以对燃料油进行深度脱硫;化学吸附能对燃料油进行深度脱硫,但吸附温度和吸附剂再生温度较高;络合吸附和选择性吸附脱硫技术操作条件温和、投资和操作费用低,能深度脱硫,可生产硫含量小于50μg/g的低硫车用燃料油,但目前吸附剂对含硫芳烃的选择性和容硫量还较低,不能满足工业应用的要求。 相似文献
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燃料油选择性吸附脱硫研究进展 总被引:1,自引:0,他引:1
依据燃料油中硫化物与吸附剂表面活性点相互作用的类型,综述了π络合吸附、S—M配位吸附、酸性位吸附和多活性位吸附等选择性吸附脱硫方式的研究进展。认为通过结合多种选择性吸附原理,制备具有多种活性位的吸附剂,达到深度脱硫过程中高选择性和高吸附容量的目的,是燃料油深度脱硫吸附剂研究和开发的主要方向。 相似文献
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以过氧化叔戊醇(TAHP)为氧化剂、MoO3/D 113为催化剂、N-甲基吡咯烷酮(NMP)为萃取剂,对焦化柴油进行氧化-萃取脱硫实验,考察了氧化温度、氧化时间、氧化剂用量、催化剂用量、萃取剂用量等工艺条件对脱硫率的影响.结果表明,最适宜的氧化-萃取脱硫工艺条件如下:氧化温度90 ℃,氧化时间2.5h,氧化剂/柴油(摩尔比)4,催化剂用量0.1g,萃取剂/柴油(体积比)1;在此条件下,柴油中硫化物的脱除率为96.8%,含硫量降至29.7 μg/g,柴油的回收率达98.6%. 相似文献
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以噻吩/石油醚模拟油为原料、Ag/γ-Al2O3为催化剂、氧气为氧化剂,研究了催化氧化深度脱硫技术,对催化剂进行了X射线衍射(XRD)和低温氮吸附表征,并考察了催化剂用量、反应温度、反应时间和萃取条件对脱硫效果的影响。在噻吩/石油醚模拟油20 mL、Ag/γ-Al2O3催化剂0.12 g、氧化温度70 ℃的反应条件下,氧化50 min后,将得到的产物采用甲醇为萃取剂,在20 ℃、剂油体积比1︰1的条件下萃取30 min,脱硫率达到98.1%。反应动力学研究结果表明,噻吩氧化过程可用一级反应动力学方程式来表示,其表达式为:k=0.049 45exp[-10 683.4/(RT)]。 相似文献
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A deep desulfurization process for FCC light gasoline has been investigated. The process is comprised of liquid-liquid extraction with acetonitrile, and photooxidation with ultraviolet light from a high-pressure mercury lamp. After the extraction the sulfur-containing compounds transfer from the oil to the solvent and then the solvent containing these sulfur compounds was photo-irradiated with ultraviolet light from a high pressure mercury lamp 300 W and with λ 200-300 nm, using strengthen electronic stirrer during the irradiation .The oil from the solvent was recovered with water. An azeotropic mixture (containing 86% acetonitrile and 14% water) was recovered successfully with one distillation column, and can reuse. The total sulfur content in this gasoline decreased from 309 to 68 ppm following 8 h of photo-irradiation .The total yield of the oil vary between 90-96%. The main sulfur compounds of this gasoline are alkyl substituted thiophenes. 相似文献
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《Petroleum Science and Technology》2013,31(9-10):1555-1573
Abstract A deep desulfurization process for FCC light gasoline has been investigated. The process is comprised of liquid-liquid extraction with acetonitrile, and photooxidation with ultraviolet light from a high-pressure mercury lamp. After the extraction the sulfur-containing compounds transfer from the oil to the solvent and then the solvent containing these sulfur compounds was photo-irradiated with ultraviolet light from a high pressure mercury lamp 300 W and with λ 200–300 nm, using strengthen electronic stirrer during the irradiation .The oil from the solvent was recovered with water. An azeotropic mixture (containing 86% acetonitrile and 14% water) was recovered successfully with one distillation column, and can reuse. The total sulfur content in this gasoline decreased from 309 to 68 ppm following 8 h of photo-irradiation .The total yield of the oil vary between 90–96%. The main sulfur compounds of this gasoline are alkyl substituted thiophenes. 相似文献
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The perchloroethylene coal refining process utilizes perchloroethylene (PCE) as its solvent in all phases of the precombustion desulfurization process, including wet grinding, organic sulfur removal, gravitational separation of pyrites and mineral matter, and recovery of elemental sulfur (S8). The Process is capable of producing compliance coal which emits less than 1.2 lb SOX/MBTU when burnt, starting from 5 mass percent sulfur Midwestern and Eastern U.S. coals. However, the process efficiency was found to be very strongly dependent upon the degree of weathering or the level of coal oxidation. In this paper, perchloroethylene extraction data of fresh, low-sulfate coals are summarized and critically assessed. The extraction efficiency of the organic sulfur removal ranged from 5 to 30 percent for fresh coals, while that for weathered coals ranged from 30 to 60 percent. This study provides a valuable insight into the chemical reaction mechanism of perchloroethylene desulfurization process. 相似文献
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The high shear agitation device was first adopted for gasoline desulfurization by ionic liquids. The effect of benzylimidazol fluoborate in desulfurization of gasoline and the influence of moisture on deuslfurization rate were investigated. The experimental results showed that the ionic liquid could effectively decrease the sulfur content of gasoline and the optimal conditions were as follows: The reaction could be carried out at room temperature, a volumetric ratio between oil and the liquid of 2∶1, a volumetric ratio between water and ionic liquid of 0.04∶1, a rotational speed of 5 krad/s, and a reaction time of 1 minute. The desulfurization rate of gasoline reached 53.6%, and the gasoline yield was up to 97.3%. The ionic liquid could be recycled for repeated use, and the use of high shear agitation for gasoline would have good prospects. 相似文献
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ABSTRACT The perchloroethylene coal refining process utilizes perchloroethylene (PCE) as its solvent in all phases of the precombustion desulfurization process, including wet grinding, organic sulfur removal, gravitational separation of pyrites and mineral matter, and recovery of elemental sulfur (S8). The Process is capable of producing compliance coal which emits less than 1.2?lb SOX/MBTU when burnt, starting from 5 mass percent sulfur Midwestern and Eastern U.S. coals. However, the process efficiency was found to be very strongly dependent upon the degree of weathering or the level of coal oxidation. In this paper, perchloroethylene extraction data of fresh, low-sulfate coals are summarized and critically assessed. The extraction efficiency of the organic sulfur removal ranged from 5 to 30 percent for fresh coals, while that for weathered coals ranged from 30 to 60 percent. This study provides a valuable insight into the chemical reaction mechanism of perchloroethylene desulfurization process. 相似文献
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新型离子液体对苯并噻吩、二苯并噻吩的萃取性能研究 总被引:3,自引:1,他引:2
离子液体是一种优良的绿色溶剂,可应用在石油油品脱硫工艺中,以降低燃油对环境的污染。本文合成了五种新型离子液体[bmim]AlCl4, [bmin]TBP, [bmim]BeS, [bmim]PF6, [bmim]BF4,并将他们用于油品脱硫的模拟体系。比较了五种离子液体萃取性能,结合分子间作用力的理论和价键理论阐述了离子液体萃取脱硫的机理。结果表明,离子液体的萃取性能与其阴离子结构有关,其中[bmim]TBP适宜作萃取脱硫溶剂。苯并噻吩(BT)、二苯并噻吩(DBT)在模拟油品中的初始浓度分别为1000μg/g时,用[bmim]TBP经四级错流萃取和5级逆流萃取,含硫量均能降至50μg/g以下。 相似文献
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以氧气作氧化剂,甲酸作催化剂,N-甲基吡咯烷酮(NMP)作萃取剂,采用催化氧化反应与溶剂萃取相结合的方法对催化裂化柴油进行了氧化萃取脱硫实验。通过单因素实验考察了催化剂用量,催化氧化温度、时间、氧气压力及萃取剂的用量等对催化裂化柴油硫含量的影响。通过实验得出最适宜的脱硫条件为:反应温度80℃;反应时间90min;充氧压力0.6MPa;催化剂体积分数为10%。经催化氧化,柴油硫质量分数可从1694.2μg/g降到190.8μg/g,脱硫率达到88.7%;在剂油比为1.0和室温条件下,用NMP三级萃取,柴油硫质量分数为37.5μg/g,小于50μg/g,达到欧Ⅳ排放标准的要求。 相似文献
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The Perchloroethylene coal cleaning process effectively removes both organic and inorganic forms of sulfur in coal. Complete recyclability of the solvent is the key to both economic and environmental issues concerning the use of perchloroethylene in this process. Recyclability of the solvent has been fully established by repeated batch operation as well as FTIR structural investigations of solvent molecules. In the current investigation, the solvent has been subjected to various analyses after each stage in the operation i.e., before extraction, after extraction and after distillation. The organic desulfurization is based on an extraction-reaction mechanism and is catalyzed by the mineral matter inherently and naturally present in coal. This paper also aims at studying the role played by the solvent (perchloroethylene) in the extraction process as well as in the catalytic reaction occurring in the system. This paper also presents data on the effect of re-using 'sulfur-rich mother liquor', rich in extracted sulfur, on the organosulfur extraction efficiency. These data are very important from the point of view of process engineering and economics. 相似文献