钛合金与铬青铜电子束自熔钎焊接头组织与力学性能

采用铜侧偏束工艺实现了TA15钛合金与QCr0.8铬青铜的电子束自熔钎焊,采用光学显微镜、扫描电子显微镜和X射线衍射分析仪对焊缝组织进行了分析,通过接头抗拉强度对接头力学性能进行了评价。结果表明,电子束偏向铜合金1mm时,钛合金母材只有上部少量熔化,实现与铜合金的连接,而接头中部和下部的连接则通过液态金属对钛合金母材的钎接而实现连接。钎缝界面由较薄的Ti-Cu化合物层组成,主要包括TiCu、Ti2Cu3、TiCu2和TiCu4。而在铜侧焊缝内,细小的Ti-Cu化合物弥散分布于铜基固溶体上,使焊缝得到强化。接头强度达到300MPa,拉伸时断裂发生在铜合金上,呈韧窝状塑性断裂模式。     

Interfacial microstructure and strength of steel/aluminum alloy joints welded by resistance spot welding with cover plate

We joined aluminum alloy A5052 to cold-rolled steel SPCC (Steel Plate Cold Commercial) and austenitic stainless steel SUS304 using resistance spot welding with a cover plate. The interfacial microstructure was observed using transmission electron microscopy. A thick two-layered reaction layer contains Fe₂Al₅ and FeAl₃ and a thin serration reaction layer contains Fe₂Al₅ and FeAl₃ were observed at the A5052/SPCC and A5052/SUS304 interface, respectively. Mechanical property analysis suggested that the reaction layer has no effect on the tensile shear strength of the A5052/SUS304 joint and that the tensile shear strength of the A5052/SPCC joint is influenced by the reaction layer formed at its interface.     

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with copper interlayer sheet

Electron beam welding of Ti-15-3 titanium alloy to 304 stainless steel with a copper sheet as interlayer was carried out.Microstructures of the joint were studied by optical microscopy(OM),scanning electron microscopy(SEM) and X-ray diffractometry(XRD).In addition,the mechanical properties of the joint were evaluated by tensile test and the microhardness was measured.These two alloys were successfully welded by adding copper transition layer into the weld.Solid solution with a certain thickness was located at the interfaces between weld and base metal in both sides.Regions inside the weld and near the stainless steel were characterized by solid solution of copper with TiFe2 intermetallics dispersedly distributed in it.While weld near titanium alloy contained Ti-Cu and Ti-Fe-Cu intermetallics layer,in which the hardness of weld came to the highest value.Brittle fracture occurred in the intermetallics layer when the joint was stretched.     

Dissimilar Joining of Zircaloy-4 to Type 304L Stainless Steel by Friction Welding Process

Zirconium- and titanium-based dissolver vessels containing highly radioactive and concentrated corrosive nitric acid solution needs to be joined to the rest of fuel reprocessing plant made of AISI type 304L stainless steel (SS), which demands high integrity and corrosion resistant dissimilar joints. Solid-state joining process of friction welding was proposed in the present work to join zircaloy-4 and type 304L SS since fusion welding processes produce brittle intermetallic precipitates at the interface which reduce the mechanical strength as well as the corrosion resistance of the joint. The present study attempts to optimize joining parameters, without and with thin Ta and Ni interlayers that can prevent brittle intermetallic formation. Tensile test, three-point bend test, and microhardness measurements were performed on the joints. Characterization techniques such as optical microscopy, scanning electron microscopy (SEM), and x-ray diffraction (XRD) were employed. A good friction weld joint of zircaloy-4 to 304L SS was achieved with the joint strength (~540 MPa) greater than that of the base of zircaloy-4, without using any interlayer. A bend ductility of 5° was only obtained without using any interlayer. However, XRD patterns indicated the presence of intermetallics in the friction-welded joints without interlayers. Corrosion test carried out on zircaloy-4 to 304L SS friction joint in boiling 11.5 M nitric acid exhibited corrosion rate of 225 μm/year after 240 h. SEM examination of the corroded joint indicated severe intergranular corrosion attack over stainless steel and preferential dissolution at the interface.     

TA15钛合金与304不锈钢的电子束焊接

对TA15钛合金和304不锈钢的电子束焊接进行了研究,对接头显微组织、相组成和显微硬度进行了分析.结果表明,TA15与304不锈钢电子束焊接性较差,在较小的热应力下即在焊缝内产生大量裂纹.焊缝内生成连续分布的化合相,主要包括TiFe2,TiFe,Cr2Ti等,脆性化合物的产生是裂纹形成的根本原因.焊缝区内显微硬度明显高于母材,且TiFe2的硬度高于TiFe相,贯穿裂纹在TiFe2相富集的区域产生.二者的直接电子束焊接难以实现,需要添加中间层以改善焊缝的冶金条件,改变化合物的种类和分布,从而实现可靠连接.     

采用不同结构Cu/V填充层的钛合金/不锈钢电子束焊接试验

对采用不同结构Cu/V填充层的钛合金与不锈钢电子束焊接头横截面形貌、微观组织及力学性能进行了分析.结果表明,采用片层结构的Cu/V填充层进行焊接时,焊缝组织由钒基固溶体、铜基固溶体及铁基固溶体组成,但由于焊缝底部有钢层未熔,形成未熔合缺陷,接头强度为288 MPa.采用楔形结构的Cu/V填充层,在保持接头固溶体过渡组织结构特征的同时,消除了未熔合缺陷,接头抗拉强度达到385 MPa.未熔钒层为接头力学性能薄弱区域,不同结构填充层的焊接接头断裂均发生于未熔钒层处.     

Wettability,microstructure and properties of 6061 aluminum alloy/304 stainless steel butt joint achieved by laser-metal inert-gas hybrid welding-brazing

Laser-metal inert-gas (MIG) hybrid welding-brazing was applied to the butt joint of 6061-T6 aluminum alloy and 304 stainless steel. The microstructure and mechanical properties of the joint were studied. An excellent joint-section shape was achieved from good wettability on both sides of the stainless steel. Scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffractometry indicated an intermetallic compound (IMC) layer at the 6061-T6/304 interface. The IMC thickness was controlled to be ～2 μm, which was attributed to the advantage of the laser-MIG hybrid method. Fe₃Al dominated in the IMC layer at the interface between the stainless steel and the back reinforcement. The IMC layer in the remaining regions consisted mainly of Fe₄Al₁₃. A thinner IMC layer and better wettability on both sides of the stainless steel were obtained, because of the optimized energy distribution from a combination of a laser beam with a MIG arc. The average tensile strength of the joint with reinforcement using laser-MIG hybrid process was improved to be 174 MPa (60% of the 6061-T6 tensile strength), which was significantly higher than that of the joint by traditional MIG process.     

Microstructures and Mechanical Properties of Electron Beam-Welded Titanium-Steel Joints with Vanadium,Nickel, Copper and Silver Filler Metals

Electron beam welding experiments of titanium alloy to stainless steel with V, Ni, Cu and Ag filler metals were carried out. The interfacial microstructures of the joints were examined by optical microscopy, scanning electron microscopy, and x-ray diffraction analysis. Mechanical properties of the joints were evaluated according to tensile strength and microhardness. The results showed that all the filler metals were helpful to restrain the Ti-Fe intermetallics formed in the Ti/Fe joint. The welds with different filler metals were all characterized by solid solution and interfacial intermetallics. And the type of solid solution and interfacial intermetallics were depended on the metallurgical reactions between the filler metals and base metals. The interfacial intermetallics were Fe₂Ti + Ni₃Ti + NiTi₂, TiFe, Ti₂Ag, and Cu₂Ti + CuTi + CuTi₂ in the joints welded with Ni, V, Ag, and Cu filler metals, respectively. The tensile strengths of the joints were primarily determined by the hardness of the interfacial intermetallics. The highest tensile strength was obtained in the joint welded with silver filler metal, which is about 310 MPa.     

Impulse pressuring diffusion bonding of titanium to 304 stainless steel using pure Ni interlayer

In the present study,impulse pressuring diffusion bonding technology(IPDB)was utilized between commercially pure titanium and 304 stainless steel(SS)using pure nickel(Ni)as interlayer metal.The interfacial microstructures of the bonded joints were investigated by scanning electron microscopy(SEM)and energy dispersive spectroscope(EDS)analyses.It is found that with the aid of the Ni interlayer,the interdiffusion and reaction between Ti and SS can be effectively restricted and robust joints can be obtained.Intermetallic compounds(IMCs)including Ti_2Ni,Ti Ni,and TiNi_3 are detected at the Ti/Ni interface;however,only Ni–Fe solid solution is found at the Ni/SS interface.The maximum tensile strength of 358 MPa is obtained by IPDB for 90 s and the fracture takes place along the Ti_2Ni and Ti Ni phase upon tensile loading.The existence of cleavage pattern on the fracture surface indicates the brittle nature of the joints.     

TiNi形状记忆合金与不锈钢激光焊接头裂纹分析及防止措施

采用激光焊对TiNi形状记忆合金与不锈钢异种材料进行焊接,用扫描电镜和激光共聚焦显微镜研究了TiNi合金/不锈钢接头裂纹及断口特征,分析了焊缝裂纹的形成机理,并提出了防止裂纹的措施.结果表明,裂纹多以微裂纹的形式出现于焊缝中心和TiNi合金侧熔合区.焊缝中存在大量的脆性化合物是产生裂纹的内在原因,接头受到拉伸应力是产生裂纹的必要条件,焊缝裂纹是二者共同作用的结果.通过焊接区加镍和钴中间层材料、改变激光光斑位置、焊接区施加轴向力及优化激光焊接参数的方法均能在一定程度上改善焊缝金属的裂纹敏感性,其中加金属中间层效果更为明显,加镍和钴中间层后,接头抗拉强度分别达到372和347 MPa,比未加中间层的接头的抗拉强度分别提高98.9%和85.6%.     

焊丝对工业纯铜和304不锈钢钨极氩弧焊接的影响(英文)

采用不同焊丝对工业纯铜和304不锈钢进行钨极氩弧焊接。结果表明,采用铜做焊丝时,焊缝无任何缺陷生成,而采用304不锈钢和Ni-Cu-Fe合金为焊丝材料时,焊缝中有凝固裂纹和未熔化区存在。在最优条件下,焊缝的抗拉强度能达到铜材的96%。焊缝在弯曲到180°下也没有分离、撕裂和断裂等现象发生。这表明铜是一种较好的工业纯铜与304不锈钢GTA焊的焊丝材料。     

铟对低银Ag-Cu-Zn钎料显微组织和性能的影响

研究了低银Ag-Cu-Zn钎料(ωAg≤20%)的熔化特性、铺展性能、钎料显微组织。以黄铜/304不锈钢作为母材,采用火焰钎焊方法,进行了搭接钎焊试验。结果表明,低银Ag-Cu-Zn钎料显微组织主要由铜基固溶体、银基固溶体、Cu Zn化合物相构成。In的添加降低了Ag-Cu-Zn钎料的固、液相线温度,改善了钎料润湿性能;添加In的低银Ag-Cu-Zn钎料在凝固过程中析出富In的银基固溶体,起到了固溶强化的效果,改善了钎焊接头的显微组织,从而提高了钎缝接头的力学性能。使用17Ag Cu Zn-1In火焰钎焊黄铜/304不锈钢,钎焊接头成形美观、组织致密、无缺陷存在,综合性能与含银量为25%的BAg25Cu Zn Sn银钎料的性能相当,节银效果显著。     

Influence of Vanadium Element on Microstructure of Electron Beam Welded Titanium Alloy to Stainless Steel Joint

Electron beam welding experiments of titanium alloys with different vanadium content to stainless steel,as well as alpha titanium to stainless steel using vanadium sheets as filler metal and transition portion were carried out.Microstructures of the joints were examined by scanning electron microscope.The properties were evaluated by microhardness and tensile strength.It was shown that electron beam welding is not feasible due to the brittle Ti-Fe intermetallics with high hardness.Increase of vanadium content in base metal can restrain but can’t avoid the formation of cracks.When vanadium content was too large,the joint was embrittled by FeTi compound with supersaturated V and also cracked after welding.Crack free joint was achieved by using vanadium transition portion which can prevent the contact of Ti and Fe elements.However,the formation of brittle σ intermetallics reduced the tensile strength of the joint,only up to 134MPa.     

不锈钢与耐候钢MIG电弧钎焊工艺

采用手工MIG电弧钎焊工艺对SUS304不锈钢与Q355GNHD耐候钢薄板对接接头进行工艺试验,按照相关技术标准进行焊接工艺评定。结果表明,MIG电弧钎焊工艺能够成功用于SUS304不锈钢和Q355GNHD耐候钢薄板对接接头的钎焊,焊缝成形质量良好,经X射线探伤无缺陷;接头的抗拉强度平均值为339.58 MPa,接头强度系数为78.97%。采用光学显微镜观察SUS304不锈钢与铜基钎料间产生的渗透裂纹,讨论渗透裂纹的产生机理。     

镀锌钢一6016铝合金异种金属加入中间夹层铅的激光焊接

对1．2mm厚镀锌钢板和1．15mm厚6016铝合金平板试件进行了加入中间夹层铅的激光搭接焊试验,通过调整焊接工艺参数获得最佳焊接成形,利用卧式金相显微镜、扫描电镜、x射线衍射、微机控制电子万能试验机等手段研究了焊接接头各区域的金相组织、断口形貌、主要物相与接头力学性能．结果表明,在钢／铝激光焊中添加中间夹层铅,焊接接...     

添加QCr0.8阻隔层的钛/钢电子束焊接接头组织与性能

采用1.5 mm厚QCr0.8铬青铜作为阻隔层进行了TA15钛合金与304不锈钢的电子束焊接,重点分析了焊接接头的横截面形貌、微观组织和力学性能。结果表明,焊缝中存在约0.5 mm宽的未熔QCr0.8阻隔层,实现了Ti元素与Fe元素的物理隔离,避免了Ti-Fe化合物的形成。铜/钢侧焊缝由铜基固溶体与铁基固溶体组成。而钛/铜侧焊缝中V元素的加入很好地抑制了Ti-Cu界面化合物的大量生成,焊缝组织由铜基固溶体、(Ti,V)基固溶体及少量Ti-Cu化合物组成,提高了该区域的强度和塑性。未熔铜阻隔层在热作用下发生软化,接头拉伸断裂发生在未熔的QCr0.8上,接头抗拉强度为293 MPa,为塑性断裂模式。     

Inconel 718镍基合金与304不锈钢电子束焊接

对Inconel 718镍基合金与304不锈钢进行了电子束焊接试验,分析了接头显微组织及力学性能. 结果表明,焊缝区中部由枝晶及细小的等轴晶组成,在近镍侧及近钢的熔合线,都由向焊缝中心方向生长的树枝晶组成. 各特征区域显微硬度值各不相同,焊缝区高于镍基合金侧,高于不锈钢侧. 当焊接束流为8 mA,焊接速度为700 mm/min时,接头的抗拉强度最高为722 MPa. 拉伸试样断裂发生于焊缝区内部,呈典型的延性断裂,断口可观察到明显等轴状韧窝.     

304不锈钢与QCr0.8铬青铜填加铜焊丝的电子束焊接

采用填铜焊丝对304不锈钢与QCr0.8铬青铜进行电子束焊接。采用正交试验法研究不同工艺参数对焊接接头抗拉强度的影响,并对焊接工艺参数进行优化。优化工艺参数如下：束流30 mA,焊接速度100 mm/min,送丝速度1 m/min,束偏移量-0.3 mm。对优化后接头组织的分析结果表明,焊缝主要由树枝状α相与少量球形ε相组成;仅在焊缝区的上部出现铜的混合不均匀;而在铜侧熔合线附近存在一个铜的熔化但未混合区,该区域晶粒长大严重,是接头的最薄弱区。显微硬度测试结果显示,焊缝硬度随固溶体中铜含量的增加而减小。接头的最高抗拉强度为276 MPa。     

添加铜填充层的Ti-15-3钛合金与304不锈钢电子束焊接过程中的温度与应力场(英文)

采用铜填充金属对Ti-15-3钛合金与304不锈钢进行电子束焊接,对Ti/Fe和Ti/Cu/Fe接头在焊接过程中的温度场和应力场进行数值模拟和试验测量。结果表明,高斯旋转体热源适用于电子束焊接过程的模拟。温度场对于焊缝中心呈非对称分布,钛侧的温度高于不锈钢侧的。热应力同样呈非对称分布,残余拉应力主要存在于不锈钢侧。铜填充金属的加入,降低了焊接过程中的峰值温度、温度梯度以及残余应力,纵向和横向残余拉应力分别降低了66MPa和31MPa。从温度场和应力场的角度可以看出,铜合金是一种较好的Ti-15-3钛合金与304不锈钢电子束焊接的填充金属材料。     

镍作中间层脉冲加压扩散连接钛合金与不锈钢

采用纳米Ni粉、纳米Ni镀层、Ni箔作中间过渡层,对TA17近。型钛合金与0Cr18Ni9Ti不锈钢进行了脉冲加压扩散连接,接头抗拉强度分别达到了175,212,334MPa。在金相显微镜下,对拉伸断口形貌进行了观察和分析;利用扫描电镜（SEM）、能谱仪（EDS）、X射线衍射分析（XRD）测定了连接接头各区域内的微区成分和物相。结果表明,纳米Ni粉致密度不够高,纳米Ni镀层质量不够高,在很大程度上限制了接头强度的提高;Ni箔中间层的存在成功地阻止了Fe与Ti之间的互扩散,避免了形成脆而硬的Fe—Ti系金属间化合物。