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通过SEM和EDAX等,研究了La添加量对Sn3.5Ag0.5Cu钎料与Cu基体焊合界面IMC微观组织及性能的影响。结果表明:添加不同量的La均对Sn3.5Ag0.5Cu与Cu基体焊合后的组织有细化作用并增强其力学性能。其中以w(La)达到0.05%时最优,剪切强度可提高10.7%。材料热力学理论计算结果表明,La具有"亲Sn"倾向,添加少量La到Sn3.5Ag0.5Cu钎料中,可减小Cu6Sn5/Cu界面Sn的活度,降低IMC的长大驱动力。 相似文献
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运用莱卡显微镜、扫描电镜和能谱分析等手段,研究了稀土元素La的添加量对Sn3.5Ag0.5Cu钎料及其与Cu基体焊接后微观组织及性能的影响。结果表明:添加不同含量的稀土La均能使钎料及其与Cu基体焊接后组织与性能得到改善,其中以w(La)达到0.05%时为最优,显微硬度及剪切强度分别提高14%和10.7%。键参数函数计算结果表明La具有"亲Sn"倾向,可细化钎料组织,降低IMC(界面金属间化合物)的长大驱动力。 相似文献
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Ag对Sn-Pb电子钎料合金性能的影响 总被引:2,自引:0,他引:2
研究了Ag的合金化对Sn-Pb钎料合金材料性能的影响。并从钎料的润湿性能,机械性能及抗腐蚀性能等方面讨论了Ag的有利作用,研究表明,在一些特定条件下的电子元件的焊接,Sn-Pb-Ag钎料可部分地或全部地替代昂贵的遗金属钎料合金。 相似文献
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以Sn2.5Ag0.7Cu为基础,添加微量的稀土(RE)r(Ce︰La)为4︰1,研究了钎焊接头的显微组织与力学性能。结果表明:添加微量的RE后,钎料与Cu试样间的界面层厚度明显减小,且界面处的组织更加平滑,相应地其剪切强度随微量RE的添加而增大,并在RE含量(质量分数)为0.1%时达到最大值36MPa。 相似文献
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Sn-Ag系电子无铅软钎料的超电势研究 总被引:3,自引:0,他引:3
随着微电子表面组装技术(SMT)的迅速发展和公众环境意识的增强,无铅软钎料成为近年来研究的焦点。主要研究了Sn-Ag系合金钎料的超电势电化学性能,并且与传统的Sn-Pb近共晶合金进行了对比。试验证明在酸、碱两种不同的溶液环境中,无铅软钎料在Sn-Pb合金的超电势有明显的差异。并指出含铋的钎料的超电势随着铋的含量的增加而降低,从而提出了在无铅软钎料研究中应当考虑因超电势变化而引起的问题。 相似文献
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《电子元件与材料》2017,(3):59-62
向Zn20Sn高温无铅钎料中添加微量铈镧混合稀土(RE),研究了RE的添加量对该钎料合金显微组织及性能的影响。结果表明,添加微量RE的合金显微组织中出现含RE的金属间化合物(IMC)。随着RE的添加,形状各异的IMC的数量显著增加。RE质量分数为0.5%~1.0%的合金的固相线温度不变,而液相线温度略有降低。当RE质量分数为0.5%时,钎料在Cu基板上的铺展面积最大,比Zn20Sn钎料提高了57.6%。但随着RE的继续添加,钎料的润湿性降低。当RE质量分数超过0.1%时,钎料的显微硬度和电阻率随着RE含量的增加而增大。综合考虑,合适的RE添加量为质量分数0.5%。 相似文献
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研制开发熔点在260 ℃以上的高温无铅钎料来代替传统的高铅钎料运用于电子封装一直是钎焊领域的一大难题。熔点约为272 ℃的Bi-2.6 Ag-5 Sb钎料合金因润湿性和焊接可靠性不良在运用上受到限制。文中通过在Bi-2.6 Ag-5 Sb钎料合金中添加微量元素Cu来改善B-i2.6 Ag-5 Sb合金的润湿性及焊接可靠性。研究结果表明,Cu含量对BiAgSbCu系钎料合金熔点影响较小,当Cu含量为2 %时,润湿性及焊接可靠性最佳。 相似文献
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Solder joints used in electronic applications undergo reflow operations. Such operations can affect the solderability, interface
intermetallic layer formation and the resultant solder joint microstructure. These in turn can affect the overall mechanical
behavior of such joints. In this study the effects of reflow on solderability and mechanical properties were studied. Nanoindentation
testing (NIT) was used to obtain mechanical properties from the non-reflow (as-melted) and multiple reflowed solder materials.
These studies were carried out with eutectic Sn-3.5Ag solders, with or without mechanically added Cu or Ag reinforcements,
using Cu substrates. Microstructural analysis was carried out on solder joints made with the same solders using copper substrate. 相似文献
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Lili Gao Liang Zhang Feng Ji Sheng-lin Yu Guang Zeng 《Microelectronic Engineering》2010,87(11):2025-7059
Recent years, the SnAgCu family of alloys has been found a widely application as a replacement for the conventional SnPb solders in electronic industry. In order to further enhance the properties of SnAgCu solder alloys, alloying elements such as rare earth, Bi, Sb, Fe, Co, Mn, Ti, In, Ni, Ge and nano-particles were selected by lots of researchers as alloys addition into these alloys. Rare earth (RE) elements have been called the ‘‘vitamin” of metals, which means that a small amount of RE elements can greatly enhance the properties of metals, such as microstructure refinement, alloying and purification of materials and metamorphosis of inclusions. In addition, a small amount of Zn addition has the ability to reduce undercooling efficiently and suppress the formation of massive primary Ag3Sn plates, and Bi/Ga has the ability to enhance the wettability of SnAgCu alloys as well as Ni. Moreover, adding Co/Fe/Ge can effectively refine microstructure, modify interfacial Cu-Sn compounds and increase the shear strength of joints with Cu. This paper summarizes the effects of alloying elements on the wettability, mechanical properties, creep behavior and microstructures of SnAgCu lead-free solder alloys. 相似文献
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Paul Lauro Sung K. Kang Won Kyoung Choi Da-Yuan Shih 《Journal of Electronic Materials》2003,32(12):1432-1440
The microstructure property relations of several Pb-free solders are investigated to understand the microstructural changes
during thermal and mechanical processes of Pb-free solders. The Pb-free solder alloys investigated include pure Sn, Sn-0.7%
Cu, Sn-3.5% Ag, and Sn-3.8% Ag-0.7% Cu (in weight percent). To reproduce a typical microstructure observed in solder joints,
the cooling rate, ingot size, and reflow conditions of cast alloys were carefully controlled. The cast-alloy pellets are subjected
to compressive deformation up to 50% and annealing at 150°C for 48 h. The microstructure of Pb-free solders is evaluated as
a function of alloy composition, plastic deformation, and annealing. The changes in mechanical property are measured by a
microhardness test. The work hardening in Sn-based alloys is found to increase as the amount of alloying elements and/or deformation
increases. The changes in microhardness upon deformation and annealing are correlated with the microstructural changes, such
as recrystallization or grain growth, in Pb-free solder alloys. 相似文献
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The interfacial intermetallics between Cu and solder were studied for four Sn-Pb compositions at the annealing temperatures
of 125°C, 150°C, and 175°C for up to 30 days. The η-phase (Cu6Sn5) layer formed during reflow continues to grow during annealing. An additional layer of ɛ-phase (Cu3Sn) forms at the η/Cu interface after an incubation annealing time. The thickness results fit a power-law relationship against
time with average exponents 0.69 and 0.44 for the η phase and the ɛ phase, respectively. On prolonged annealing, the proportions
of the individual phases in the total layer reach a steady state. 相似文献
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Microstructure and mechanical properties were investigated for ten systems of lead-free solders compared with the eutectic
Sn-Pb solder. Mechanical properties including elastic, plastic, and creep deformations were predicted by indentation testing.
This method was established based on the elastic-plastic-creep finite-element method (FEM). The predicted mechanical properties
were obtained for the temperatures ranging between −20°C and 160°C. 相似文献
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颗粒增强Sn-Ag基无铅复合钎料显微组织与性能 总被引:2,自引:0,他引:2
通过外加法向Sn-3.5Ag焊料中加入体积分数为10%的微米级Cu、Ni颗粒制备了无铅复合钎料,对钎料的显微组织、拉剪及润湿性能进行了研究。结果表明,颗粒周围以及基板界面处的显微组织中生成了金属间化合物,其形态及大小因加入颗粒而不同。颗粒的加入提高了钎料钎焊接头的剪切强度,其中Cu颗粒增强的接头的剪切强度提高了33%,Ni颗粒的提高了20%。两种复合钎料的铺展面积均下降了约15%,其中Cu颗粒增强复合钎料润湿角由11°增加到18°。 相似文献
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The solidification microstructures and corresponding mechanical properties of Sn-20Bi and Sn-20Bi-0.4Cu alloys were studied with and without rotating magnetic field (RMF). Without RMF, the microstructures of both solders exhibit great numbers of undesirable columnar structure of dendrite primary β-Sn phase and large Cu6Sn5 phase. The RMF-driven flow has induced columnar-to-equiaxed transition (CET) of dendrite primary β-Sn phase, which simultaneously results in dendrite fragmentation, and provokes distinct grain and intermetallic compound (IMC) refinement effects due to Lorentz force acting on the melt. The individual contributions of RMF on the lattice strain, crystallite size, stress and energy density were evaluated from X-ray peak broadening using various Williamson-Hall models. RMF can also reduce effectively the lattice strain and crystallite size of both solders, which are likely vital prerequisite for property control on metallic materials. Tensile tests showed that the tensile strength of Sn-20Bi solder was enhanced and ductility of Sn-20Bi-0.4Cu alloy was improved. These effects could increase the elastic compliance and develop the drop impact reliability of bulk solders. 相似文献