Stacking-fault formation and propagation in 4H-SiC PiN diodes

Stacking-fault growth in SiC PiN diodes has been examined using light-emission imaging and stressing at 80 A/cm² and 160 A/cm². Dark areas in the emission develop because of stacking faults and the current capability of the diode drops. More detailed images are produced by reducing the current by a factor of 1000. The low-current images are bright lines at dislocations bounding the stacking faults and at or near the stacking-fault intersection with the surface. Stacking faults nucleate 1–2 μm below the surface. Most, but not all, continue growing until they span the diode. Growth dynamics and their dependence on the current density are discussed. An erratum to this article is available at .     

Planar defects in 4H-SiC PiN diodes

Using plan-view transmission electron microscopy (PVTEM), we have identified stacking faults (SFs) and planar defects in 4H-SiC PiN diodes subjected to electrical bias. Our observations suggest that not all planar defects seen in the PiN diodes are SFs. By performing diffraction-contrast imaging experiments using TEM, we can distinguish SFs from other planar defects. In addition, high-resolution TEM (HRTEM) imaging and analytical TEM have revealed that some planar defects consist of a 3-nm-wide SiC amorphous layer. Many of these planar defects are orientated parallel to {1 00} planes, whereas others are roughly parallel to the (0001) plane. The appearance of these planar defects suggests that they are grain boundaries.     

Partial dislocations and stacking faults in 4H-SiC PiN diodes

Using plan-view transmission electron microscopy (TEM), we have identified stacking faults (SFs) in 4H-SiC PiN diodes subjected to both light and heavy electrical bias. Our observations suggest that the widely expanded SFs seen after heavy bias are faulted dislocation loops that have expanded in response to strain of the 4H-SiC film, while faulted screw or 60° threading dislocations do not give rise to widely expanded SFs. Theoretical calculations show that the expansion of SFs depends on the Peach-Koehler (PK) forces on the partial dislocations bounding the SFs, indicating that strain plays a critical role in SF expansion.     

Drift-free 10-kV, 20-A 4H-SiC PiN diodes

As impressive as the advancement in 4H-SiC material quality has been, 4H-SiC PiN diodes continue to suffer from irreversible, forward-voltage instabilities. In this work, we describe PiN diodes designed to block 10 kV and conduct 20 A at less than 4.5 V, which were fabricated on 4H-SiC PiN epitaxial layers that were grown with an innovative epitaxial process that has been developed specifically to suppress V_F drift. The diodes fabricated on epitaxial layers that implemented this new epitaxy process showed excellent V_F stability, with 86% of the diodes drifting less than 0.1 V during forward current stressing at 10 A (50 A/cm²) for 30 min. However, these improvements in V_F drift come with a cost in blocking yield, as the surface morphology and other crystal defects imparted by the epitaxial process resulted in only 1 of 50 diodes reaching the 10-kV blocking specification. Nevertheless, the remarkable progress in V_F drift yield brings us closer to commercialization of high-power 4H-SiC PiN diodes.     

High-voltage 4H-SiC PiN diodes with the etched implant junction termination extension

This paper presents the design and fabrication of an etched implant junction termination extension(JTE) for high-voltage 4H-SiC PiN diodes. Unlike the conventional JTE structure, the proposed structure utilizes multiple etching steps to achieve the optimum JTE concentration range. The simulation results show that the etched implant JTE method can improve the blocking voltage of SiC PiN diodes and also provides broad process latitude for parameter variations, such as implantation dose and activation annealing condition. The fabricated SiC PiN diodes with the etched implant JTE exhibit a highest blocking voltage of 4.5 kV and the forward on-state voltage of 4.6 V at room temperature. These results are of interest for understanding the etched implant method in the fabrication of high-voltage power devices.     

漂移层经碳处理后的4H-SiC PiN 二极管的特性与分析

The characteristics of 4H-SiC PiN diodes with a carbon-implanted drift layer was investigated and the reason of characteristics improvement was analyzed. The forward voltage drops of the diodes with carbonimplanted drift layer were around 3.3 V, which is lower than that of devices without carbon implantation, the specific-on resistance was decreased from 9.35 to 4.38 mΩcm² at 100 A/cm², and the reverse leakage current was also decreased. The influence of carbon incorporation in the Si C crystalline grids was studied by using deep-level transient spectroscopy（DLTS）. The DLTS spectra revealed that the Z_1/2 traps, which were regarded as the main lifetime limiting defects, were dramatically reduced. It is proposed that the reduction of Z_1/2 traps can achieve longer carrier lifetime in the drift layer, which is beneficial to the performance of bipolar devices.     

Analysis of bulk and surface components of leakage current in 4H-SiC PiN MESA diodes

The leakage current in circular- and ring-shaped epitaxial 4H-SiC PiN mesa diodes with different size and periphery to area ratios was evaluated under the influence of the UV irradiation and temperature in the range from room temperature (RT) to 250 °C. The surface leakage current component was found to dominate the reverse current characteristics and was found to be dependent on time and temperature both after reactive ion etching (RIE) of the diodes in the SF₆/Ar gas mixture and after the UV irradiation. Charging of the surface states is believed to be responsible for the observed behavior. The UV irradiation is believed to charge the surface positively. The drift of the I(V) characteristics is due to the trapping of the electrons neutralizing the positive donor states.     

Characterization of hard- and soft-switching performance of high-voltage Si and 4H-SiC PiN diodes

This paper presents a study of the performance of high-voltage Si and 4H-SiC diodes in a DC-DC buck converter. Device operation in both hard- and zero-voltage switching conditions is presented with the help of measurements and two-dimensional (2-D) mixed device-circuit simulations. Experimental results show that SiC PiN diodes have a strong potential for use in high-speed high-voltage power electronics applications operating at high temperature. A combination of low excess carrier concentration and low carrier lifetime results in superior switching performance of the 4H-SiC diode over ultrafast Si diodes. Soft switching is shown to minimize the switching loss and allow operation at higher switching frequencies using Si diodes. The power loss of 4H-SiC diodes is dominated by conduction loss. Consequently, soft-switching techniques result in a marginal reduction in power loss. However, the low overall power loss implies that SiC diodes can be used at very high switching frequencies even in hard-switching configurations.     

Development of 17 kV 4H-SiC PiN diode

The design, fabrication, and electrical characteristics of a 4H-SiC PiN diode with breakdown voltage higher than 17 kV are presented. The three-zone JTE has been used in the fabrication. Numerical simulations have been performed to optimize the parameters of the edge termination technique. The epilayer properties of the N-type are 175 μm with a doping of 2×10¹⁴cm^-3. With the three-zone JTE, a typical breakdown voltage of 17 kV has been achieved.     

一种带P型埋层的4H-SiC PiN二极管

碳化硅(SiC)PiN二极管是应用在高压大功率整流领域中的一种重要的功率二极管。受SiC外延材料的载流子寿命限制以及常规SiC PiN二极管较低的阳极注入效率的影响,SiC PiN二极管的正向导通性能较差,这极大限制了其在高压大电流领域的应用。文章提出了一种带P型埋层的4H-SiC PiN二极管,较常规SiC PiN二极管增强了阳极区的少子注入效率,降低了器件的导通电阻,增大了正向电流。仿真结果表明,当正向偏压为5 V时,引入P型埋层的SiC PiN二极管的正向电流密度比常规SiC PiN二极管提升了52.8%。     

High-Voltage 4H-SiC PiN Diodes With Etched Junction Termination Extension

Implantation-free mesa-etched 4H-SiC PiN diodes with a near-ideal breakdown voltage of 4.3 kV (about 80% of the theoretical value) were fabricated, measured, and analyzed by device simulation and optical imaging measurements at breakdown. The key step in achieving a high breakdown voltage is a controlled etching into the epitaxially grown p-doped anode layer to reach an optimum dopant dose of $sim!! hbox{1.2}times hbox{10}^{13} hbox{cm}^{-2}$ in the junction termination extension (JTE). Electroluminescence revealed a localized avalanche breakdown that is in good agreement with device simulation. A comparison of diodes with single- and double-zone etched JTEs shows a higher breakdown voltage and a less sensitivity to varying processing conditions for diodes with a two-zone JTE.      

SiC power Schottky and PiN diodes

The present state of SiC power Schottky and PiN diodes are presented in this paper. The design, fabrication, and characterization of a 130 A Schottky diode, 4.9 kV Schottky diode, and an 8.6 kV 4H-SiC PiN diode, which are considered to be significant milestones in the development of high power SiC diodes, are described in detail. Design guidelines and practical issues for the realization of high-power SiC Schottky and PiN diodes are also presented. Experimental results on edge termination techniques applied to newly developed, extremely thick (e.g., 85 and 100 μm) 4H-SiC epitaxial layers show promising results. Switching and high-temperature measurements prove that SiC power diodes offer extremely low loss alternatives to conventional technologies and show the promise of demonstrating efficient power circuits. At sufficiently high on-state current densities, the on-state voltage drop of Schottky and PiN diodes have been shown to be comparable to those offered by conventional technologies     

14kV-1 A SiC超高压PiN二极管

设计了一种耐压超过14kV的4H-SiC超高压PiN二极管。外延材料N-层掺杂浓度3.0×10~(14) cm~(-3),厚度140μm。通过模拟仿真,采用台面结合双JTE结终端保护结构,器件实现了14kV以上耐压,正向导通电流1A。     

Thermal Annealing and Propagation of Shockley Stacking Faults in 4H-SiC PiN Diodes

Stacking faults within 4H-SiC PiN diodes are known to be detrimental to device operation. Here, we present electroluminescence (EL) images of 4H-SiC PiN diodes providing evidence that electrically and optically stimulated Shockley stacking fault (SSF) propagation is a reversible process at temperatures as low as 210°C. Optical beam induced current (OBIC) images taken following complete optical stressing of a PiN diode and that lead to a small number of completely propagated SSFs provide evidence that such defects propagate across the n–/p+ interface and continue to grow throughout the p+ layer. These observations bring about questions regarding the validity of the currently accepted driving force mechanism for SSF propagation.     

High voltage 4H-SiC Schottky barrier diodes

Characteristics of 4H-SiC Schottky barrier diodes with breakdown voltages up to 1000 V are reported for the first time. The diodes showed excellent forward I-V characteristics, with a forward voltage drop of 1.06 V at an on-state current density of 100 A/cm². The specific on-resistance for these diodes was found to be low (2×10 ^-3 Ω-cm² at room temperature) and showed a T ^1.6 variation with temperature. Titanium Schottky barrier height was determined to be 0.99 eV independent of the temperature. The breakdown voltage of the diodes was found to decrease with temperature     

Microwave p-i-n diodes and switches based on 4H-SiC

The 4H-SiC p-i-n diodes were designed, fabricated, and characterized for use in microwave applications. The diodes with mesa structure diameters between 80 and 150 /spl mu/m, exhibited a blocking voltage of 1100 V, a 100-mA differential resistance of 1-2 /spl Omega/, a capacitance below 0.5 pF at a punchthrough voltage of 100 V and a carrier effective lifetime between 15-27 ns. X-band microwave switches based on 4H-SiC p-i-n diodes are demonstrated for the first time. The switches exhibited insertion loss as low as 0.7 dB, isolation up to 25 dB and were able to handle microwave power up to 2.2 kW in isolation mode and up to 0.4 kW in insertion mode.     

基于一种可靠非均匀场限环终端结构的1.4kV 4H型碳化硅PiN二极管

This paper presents the design and fabrication of an effective, robust and process-tolerant floating guard ring termination on high voltage 4H-SiC PiN diodes. Different design factors were studied by numerical simulations and evaluated by device fabrication and measurement. The device fabrication was based on a 12 μm thick drift layer with an N-type doping concentration of 8 × 10^15 cm^-3. P^＋ regions in the termination structure and anode layer were formed by multiple aluminum implantations. The fabricated devices present a highest breakdown voltage of 1.4 kV, which is higher than the simulated value. For the fabricated 15 diodes in one chip, all of them exceeded the breakdown voltage of 1 kV and six of them reached the desired breakdown value of 1.2 kV.     

A review of the etched terminal structure of a 4H-SiC PiN diode

The comparison of domestic and foreign studies has been utilized to extensively employ junction termination extension (JTE) structures for power devices. However, achieving a gradual doping concentration change in the lateral direction is difficult for SiC devices since the diffusion constants of the implanted aluminum ions in SiC are much less than silicon. Many previously reported studies adopted many new structures to solve this problem. Additionally, the JTE structure is strongly sensitive to the ion implantation dose. Thus, GA-JTE, double-zone etched JTE structures, and SM-JTE with modulation spacing were reported to overcome the above shortcomings of the JTE structure and effectively increase the breakdown voltage. They provided a theoretical basis for fabricating terminal structures of 4H-SiC PiN diodes. This paper summarized the effects of different terminal structures on the electrical properties of SiC devices at home and abroad. Presently, the continuous development and breakthrough of terminal technology have significantly improved the breakdown voltage and terminal efficiency of 4H-SiC PiN power diodes.     

P-type 4H and 6H-SiC high-voltage Schottky barrier diodes

High-voltage Schottky barrier diodes have been successfully fabricated for the first time on p-type 4H- and 6H-SiC using Ti as the barrier metal. Good rectification was confirmed at temperatures as high as 250°C. The barrier heights were estimated to be 1.8-2.0 eV for 6H-SiC and 1.1-1.5 eV for 4H-SiC at room temperature using both I-V and C-V measurements. The specific on resistance (R_on,sp) for 4H- and 6H-SiC were found to be 25 mΩ cm^-2 and 70 mΩ cm^-2 at room temperature. A monotonic decrease in resistance occurs with increasing temperature for both polytypes due to increased ionization of dopants. An analytical model is presented to explain the decrease of R_on,sp with temperature for both 4H and 6H-SiC which fits the experimental data. Critical electric field strength for breakdown was extracted for the first time in both p-type 4H and 6H-SiC using the breakdown voltage and was found to be 2.9×10⁶ V/cm and 3.3×10⁶ V/cm, respectively. The breakdown voltage remained fairly constant with temperature for 4H-SiC while it was found to decrease with temperature for 6H-SiC     

Simulation and Experimental Study on the Junction Termination Structure for High-Voltage 4H-SiC PiN Diodes

Designing and fabrication of 10-kV 4H-SiC PiN diodes with an improved junction termination structure have been investigated. An improved bevel mesa structure and a single-zonejunction termination extension (JTE) have been employed to achieve a high breakdown voltage $(geq!hbox{10} hbox{kV})$ . The improved bevel mesa structure, nearly a vertical sidewall at the edge of the p-n junction and a gradual slope at the mesa bottom, has been fabricated by reactive ion etching. The effectiveness of the improved bevel mesa structure has been experimentally demonstrated. The JTE region has been optimized by device simulation, and the JTE dose dependence of the breakdown voltage has been compared with experimental results. A 4H-SiC PiN diode with a JTE dose of $hbox{1.1} times hbox{10}^{13} hbox{cm}^{-2}$ has exhibited a high blocking voltage of 10.2 kV. The locations of electric field crowding and breakdown are also discussed.