Surface fluctuation spectroscopy by surface-light-scattering spectroscopy

In recent years surface-light-scattering spectroscopy has been transformed from a complex optical experiment requiring substantial effort to operate effectively to a simpler instrument for which an accurate theory of operation has been developed. The accuracy and precision are sufficiently enhanced that refinement of the theory of spectral band shapes is justified to include more subtle effects such as bending moduli and thin-film forces associated with the van der Waals and the Casimir effects. We show how to develop extensions of the theory of interfacial fluctuations through the mass and the momentum balances of interfacial transport. We also show that free-energy functionals can be used to express curvature effects crisply. The results are detailed formulas that can be used to fit experimental spectra.     

A new acoustic spectroscopy: Resonance spectroscopy by the MIIR

Recent and remarkable advances in the experimental study of acoustic scattering from targets immersed in water are leading to a new spectroscopy: resonance acoustic spectroscopy. The discovery and improvement of an intriguing method, the Method of Isolation and Identification of Resonances (MIIR), has made possible experimental determination of the eigenfrequency spectra of aluminum-elastic cylinders and cylindrical shells. This method gives a quasilinear resonance spectra. In addition, it shows the importance of circumferential waves which generate standing waves. They allow us to explain the reradiation of targets after the end of insonification. The MIIR has numerous applications, especially in underwater acoustics and nondestructive testing.     

OH absorption spectroscopy in a flame using spatial heterodyne spectroscopy

We demonstrate measurements of OH absorption spectra in the post-flame zone of a McKenna burner using spatial heterodyne spectroscopy (SHS). SHS permits high-resolution, high-throughput measurements. In this case the spectra span approximately 308-310 nm with a resolution of 0.03 nm, even though an extended source (extent of approximately 2x10(-7) m(2) rad(2)) was used. The high spectral resolution is important for interpreting spectra when multiple absorbers are present for inferring accurate gas temperatures from measured spectra and for monitoring weak absorbers. The present measurement paves the way for absorption spectroscopy by SHS in practical combustion devices, such as reciprocating and gas-turbine engines.     

Tip-enhanced optical spectroscopy

Spectroscopic methods with high spatial resolution are essential for understanding the physical and chemical properties of nanoscale materials including biological proteins, quantum structures and nanocomposite materials. In this paper, we describe microscopic techniques which rely on the enhanced electric field near a sharp, laser-irradiated metal tip. This confined light-source can be used for the excitation of various optical interactions such as two-photon excited fluorescence or Raman scattering. We study the properties of the enhanced fields and demonstrate fluorescence and Raman imaging with sub-20 nm resolution.     

Total current spectroscopy

A review of the technique of total current spectroscopy (TCS) and of its application to the study of the electronic structures of surfaces is presented. An attempt is made to include all the TCS results reported since 1978 and to discuss in some detail those results that have contributed to the characterization of this technique.The theoretical model most often used to interpret the energy features of TCS spectra is also discussed and a procedure is described to extract valence and conduction band density of states from the experimental spectra using this model.