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自蔓延高温合成(self-propagating high-temperature synthesis,SHS)是一种在数秒~几十秒内即可完成的合成技术,但是直接产物是多孔状的.在SHS产物还处于高温软化状态时立即快速加压(quick pressing,QP),可以一步实现合成和致密化获得致密材料,这一技术被称为SHS/QP技术.传统的高温烧结的致密化过程主要靠原子扩散实现,SHS/QP过程如此之快,其致密化机理尚不明确.为此,探讨了SHS/OP技术制备金属陶瓷和复相陶瓷的致密化机理.研究了SHS/OP技术制备金属陶瓷、复相陶瓷和叠层复合材料的结构和工艺过程,并制备了密实材料.结果表明:基于塑性变形机理,SHS/QP技术能制备出密实、晶粒基本不长大的纳米陶瓷. 相似文献
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俄罗斯专家与我国山东科技大学合作利用镍、铝、钛等金属之间的自蔓延高温合成反应制备金属 间化合物多孔材料,它既具有金属的强韧性又有陶瓷的高硬度和耐热性,将其做成多孔状用于汽车尾 相似文献
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碳热还原、镁热还原、铝热还原合成技术广泛应用于无机材料的合成中,应用它们可以制备碳化物、硼化物、氮化物、金属单质及复合材料等多种新型材料。自蔓延高温还原合成技术(SHS Reduction)是一种工艺简单、节能、高效的制备高技术材料的先进方法,主要有镁热还原SHS技术和铝热还原SHS技术。本文阐述了传统还原合成工艺及自蔓延高温还原合成技术在无机材料合成中的应用及进展。 相似文献
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金属间化合物/陶瓷复合材料由于具有很多优秀的性能而被广泛应用在工程领域中,本文主要介绍金属间化合物/陶瓷复合材料的制备方法是粉末冶金法和金属熔渗法,主要包括粉末冶金法,自蔓延高温合成法,金属熔体熔融渗透法,原位合成法。其中粉末冶金法又包括热压烧结工艺,常压烧结工艺,放电等离子烧结工艺,热等静压烧结工艺,热压反应烧结工艺等。并对这些制备技术的原理和发展现状进行评述,并对这些制备方法在研究和生产中的应用进行介绍,并对金属间化合物/陶瓷复合材料的研究现状和发展趋势进行评述。并对金属间化合物/陶瓷复合材料制备技术的研究发展方向进行了展望。 相似文献
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M. S. J. Simmonds W. M. Blaney F. Delle Monache M. Marquina Mac-Quhae G. B. Marini Bettolo 《Journal of chemical ecology》1985,11(12):1593-1599
Vismiones and ferruginins, representatives of a new class of lypophilic anthranoids from the genusVismia were found to inhibit feeding in larvae of species ofSpodoptera, Heliothis, and inLocusta migratoria. 相似文献
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Halyomorpha halys (Stål) (Pentatomidae), called the brown marmorated stink bug (BMSB), is a newly invasive species in the eastern USA that is rapidly spreading from the original point of establishment in Allentown, PA. In its native range, the BMSB is reportedly attracted to methyl (E,E,Z)-2,4,6-decatrienoate, the male-produced pheromone of another pentatomid common in eastern Asia, Plautia stali Scott. In North America, Thyanta spp. are the only pentatomids known to produce methyl 2,4,6-decatrienoate [the (E,Z,Z)-isomer] as part of their pheromones. Methyl 2,4,6-decatrienoates were field-tested in Maryland to monitor the spread of the BMSB and to explore the possibility that Thyanta spp. are an alternate host for parasitic tachinid flies that use stink bug pheromones as host-finding kairomones. Here we report the first captures of adult and nymph BMSBs in traps baited with methyl (E,E,Z)-2,4,6-decatrienoate in central Maryland and present data verifying that the tachinid, Euclytia flava (Townsend), exploits methyl (E,Z,Z)-2,4,6-decatrienoate as a kairomone. We also report the unexpected finding that various isomers of methyl 2,4,6-decatrienoate attract Acrosternum hilare (Say), although this bug apparently does not produce methyl decatrienoates. Other stink bugs and tachinids native to North America were also attracted to methyl 2,4,6-decatrienoates. These data indicate there are Heteroptera in North America in addition to Thyanta spp. that probably use methyl 2,4,6-decatrienoates as pheromones. The evidence that some pentatomids exploit the pheromones of other true bugs as kairomones to find food or to congregate as a passive defense against tachinid parasitism is discussed. 相似文献
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中蓝晨光化工研究院《塑料工业》编辑部 《塑料工业》2007,35(3):1-25,67
收集了2005年7月~2006年6月国外塑料工业的相关资料,介绍了2005—2006年国外塑料工业的发展情况。提供了世界塑料产量、消费量及全球各类树脂生产量以及各国塑料制品的进出口情况。作为对比,介绍了中国塑料的生产情况。按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(聚酰胺、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、通用热固性树脂(酚醛、聚氨酯、不饱和树脂、环氧树脂)、特种工程塑料(聚苯硫醚、液晶聚合物、聚醚醚酮)的品种顺序,对树脂的产量、消费量、供需状况及合成工艺、产品开发、树脂品种的延伸及应用的扩展作了详细的介绍。 相似文献
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中蓝晨光化工研究院有限公司《塑料工业》编辑部 《塑料工业》2009,37(3)
收集了2007年7月~2008年6月世界塑料工业的相关资料,介绍了2007~2008年国外塑料工业的发展情况,提供了世界塑料产量、消费量及全球各类树脂的需求量及产能情况.按通用热塑性树脂(聚乙烯、聚丙烯、聚苯乙烯、聚氯乙烯、ABS树脂)、工程塑料(尼龙、聚碳酸酯、聚甲醛、热塑性聚酯、聚苯醚)、特种工程塑料(聚苯·硫醚、液晶聚合物、聚醚醚酮)、通用热固性树脂(酚醛、聚氨酯、不饱和聚酯树脂、环氧树脂)不同品种的顺序,对树脂的产量、消费量、供需状况及合成工艺、产品应用开发、树脂品种的延伸及应用的进一步扩展等技术作了详细介绍. 相似文献
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Inorganic/organic hybrid materials have considerable promise and are beginning to become a major area of research for many
coating usages, including abrasion and corrosion resistance. Our primary approach is to prepare the inorganic phase in situ
within the film formation process of the organic phase. The inorganic phase is introduced via sol-gel chemistry into a thermosetting
organic phase. By this method, the size, periodicity, spatial positioning, and density of the inorganic phase can be controlled.
An important aspect of the inorganic/organic hybrid materials is the coupling agent. The initial task of the coupling agent
is to provide uniform mixing of the oligomeric organic phase with the sol-gel precursors, which are otherwise immiscible.
UV-curable inorganic/organic hybrid systems have the advantages of a rapid cure and the ability to be used on heat sensitive
substrates such as molded plastics. Also, it is possible to have better control of the growth of the inorganic phase using
UV curing. It is our ultimate goal to completely separate the curing of inorganic and organic phases to gain complete control
over the morphology, and hence optimization of “all” the coating properties. Thus far, it has been found that concomitant
UV curing of the inorganic and organic phases using titanium sol-gel precursors afforded nanocomposite coatings which completely
block the substrate from UV light while maintaining a transparent to visible light. Also, it has been found that the morphology
of the inorganic phase is highly dependent on the concentration and reactivity of the coupling agent.
Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004, in Chicago,
IL. 相似文献
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Miller DR 《Journal of chemical ecology》2006,32(4):779-794
Ethanol and α-pinene were tested as attractants for large wood-boring pine beetles in Alabama, Florida, Georgia, North Carolina, and South Carolina in 2002–2004. Multiple-funnel traps baited with (−)-α-pinene (released at about 2 g/d at 25–28°C) were attractive to the following Cerambycidae: Acanthocinus nodosus, A. obsoletus, Arhopalus rusticus nubilus, Asemum striatum, Monochamus titillator, Prionus pocularis, Xylotrechus integer, and X. sagittatus sagittatus. Buprestis lineata (Buprestidae), Alaus myops (Elateridae), and Hylobius pales and Pachylobius picivorus (Curculionidae) were also attracted to traps baited with (−)-α-pinene. In many locations, ethanol synergized attraction of the cerambycids Acanthocinus nodosus, A. obsoletus, Arhopalus r. nubilus, Monochamus titillator, and Xylotrechus s. sagittatus (but not Asemum striatum, Prionus pocularis, or Xylotrechus integer) to traps baited with (−)-α-pinene. Similarly, attraction of Alaus myops, Hylobius pales, and Pachylobius picivorus (but not Buprestis lineata) to traps baited with (−)-α-pinene was synergized by ethanol. These results provide support for the use of traps baited with ethanol and (−)-α-pinene to detect and monitor common large wood-boring beetles from the southeastern region of the USA at ports-of-entry in other countries, as well as forested areas in the USA. 相似文献