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在1023~1373K的初始温度范围和0.05~268.91K/s的冷速范围内,用俄歇剖层分析确定了含硼Ni3Al合金中硼的非平衡晶界偏聚行为。基于由空位在晶界湮灭所产生的体系自由能下降驱动可动的溶质-空位复合体向晶界迁移。从而产生溶质非平衡晶界偏聚的模型,导出了定量描述非平衡偏聚行为的解析表达式,理论计算结果与硼非平衡偏聚的试验数据相符,通过模拟实测确定Ni3Al-B合金中硼及硼-空位复合体的扩 相似文献
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在1023~1373K的初始温度范围和0.05~268.91K/s的冷速范围内,用俄歇剖层分析确定了含硼Ni_3Al合金中硼的非平衡晶界偏聚行为。基于由空位在晶界湮灭所产生的体系自由能下降驱动可动的溶质-空位复合体向晶界迁移、从而产生溶质非平衡晶界偏聚的模型,导出了定量描述非平衡偏聚行为的解析表达式。理论计算结果与硼非平衡偏聚的试验数据相符。通过模拟实测确定Ni_3Al-B合金中硼及硼-空位复合体的扩散系数分别为:D=1×10 ̄(-6)exp[-1.96(eV)/kT]和D_(P(B))=1×10 ̄(-)4exp[-1.96(eV)/kT](m ̄2/s);硼-空位复合体的结合能为E_(b(B)=0.5eV。 相似文献
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置换溶质原产可以以溶质原子-空位复合体形式扩散,这一扩散机制可以圆满的说明非平衡偏聚现象发生的规律,密排晶体中溶质原子的异常快速扩散现象,B在γ-Fe中快速扩散和晶界非平衡偏聚,溶质原子在Al表面空位坑中的聚集以及Si在Al晶界处析出等问题. 相似文献
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固体中一种新发现的扩散机制──复合体扩散机制SCIEI 总被引:3,自引:0,他引:3
置换溶质原产可以以溶质原子-空位复合体形式扩散,这一扩散机制可以圆满的说明非平衡偏聚现象发生的规律,密排晶体中溶质原子的异常快速扩散现象,B在γ-Fe中快速扩散和晶界非平衡偏聚,溶质原子在Al表面空位坑中的聚集以及Si在Al晶界处析出等问题. 相似文献
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置换溶质原子可以以溶质原子-空位复合体形式扩散,这一扩散机制可以圆满的说明非平衡偏聚现象发生的规律,密排晶体中溶质原子的异常快速扩散现象,B在γ-Fe中快速扩散和晶界非平衡偏聚,溶质原子在Al表面空位坑中的聚集以及Si在Al晶界处析出等问题。 相似文献
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金相、X射线电子能谱和显微硬度等实验表明,Si在Al-0.35wt-%Si合金氧化膜下的过饱和空位造成的空位坑中有Si的偏聚.这种偏聚只能用空位-Si原子复合体扩散导致的非平衡偏聚理论来解释。 相似文献
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MECHANISM FOR DIFFUSION OF BORON IN γ-Fe 总被引:1,自引:0,他引:1
YU Zongsen CHEN Ning University of Science Technology Beijing Beijing China 《金属学报(英文版)》1992,5(5):318-323
Mechanism for diffusion of B in γ-Fe is believed to be mainly by means of boron-vacancycomplexes other than as interstitial atoms previously.This was made of calculation on the ba-sis of theoretical model proposed by the authors.The calculated diffusion coefficient of B inγ-Fe after this mechanism is consistent with the experimental values.In addition,this is alsosupported by the non-equilibrium segregation phenomenon of B at grain boundaries of γ-Feand the lattice constant measurement of Fe-B alloy. 相似文献
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业已证实,淬火硼钢中硼向奥氏体晶界的偏聚,是在冷却过程中发生的一种非平衡的晶界偏聚。本文通过解变温扩散方程,导出了非平衡晶界偏聚的理论公式,建立了晶界贫硼区宽度与淬火加热温度、冷却速度以及非平衡晶界偏聚扩散激活能与扩散常数之间的关系,理论预言与实验结果较好地吻合。 根据实验结果和理论分析,提出这种非平衡晶界偏聚的机制,是在冷却过程中,过饱和空位或双空位带着硼原子向晶界(空位阱)迁移的结果。 基于这种非平衡晶界偏聚的新概念,可以较完满地说明影响硼钢淬透性的众多复杂因素。 相似文献
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CHU Youyi ZHANG Sanhong HE Xinlai KE Jun 《金属学报(英文版)》1990,3(1):40-45
In consideration of the local equilibrium among vacancies,solute atoms and vacancy-soluteatom complexes and the influence of equilibrium grain boundary segregation,theoretical dy-namic formulas for non-equilibrium grain boundary segregation of solute have been derivedon the basis of the vacancy-dragging mechanism.Theoretical calculation by computer hasbeen carried out for the non-equilibrium segregation of boron to austenitic grain boundariesduring isothermal holding and continuous cooling after heating at high temperatures.The re-suits agree well with those obtained from experiments. 相似文献
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《Acta Materialia》1999,47(7):2047-2057
The superplastic behavior of a fine-grained AZ91 alloy, processed by equal channel angular extrusion, has been investigated in a low temperature range of 423–523 K. The experimental results showed a stress exponent of 2 and the activation energy for superplastic flow was in agreement with that for grain boundary diffusion of magnesium. The alloy with non-equilibrium grain boundary structures exhibited lower superplastic elongation than the alloy with equilibrium grain boundaries. Furthermore, the strain rate for superplastic flow of the former was lower than that of the latter. These differences probably arise because the accommodation process for grain boundary sliding is hampered by the long-range stresses associated with the non-equilibrium grain boundaries. 相似文献
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采用高分辨率的径迹显微照相技术,研究了淬火硼钢中硼向奥氏体晶界偏聚的规律,定量地测定出跨过奥氏体晶界的硼的成分剖面图以及非平衡晶界偏聚的特征参量(晶界贫硼区宽度、晶界富集程度和富集带宽度)。试验表明,这种偏聚具有如下特征: 在偏聚晶界的两侧存在有一定宽度的贫硼区,晶界偏聚的硼是在冷却过程中由该区富集而来;这种偏聚对冷却速度很敏感,急速冷却可以抑制这种偏聚。冷却速度降低,晶界偏聚由连续的偏聚带,逐步发展为不连续的聚集直至明显地析出硼相,贫硼区宽度与冷却速度的平方根成反比;它的温度关系与晶界平衡偏聚预言相反,随淬火温度升高,晶界偏聚程度与贫硼区宽度增加。 通过试验,论证了淬火钢中硼向奥氏体晶界的偏聚,是在冷却过程中发生的一种非平衡的晶界偏聚现象。 相似文献
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The segregation and diffusion of boron during heat treatments were studied.The influence of boron contents, aging time and applied stress on FeMo2B2 formation was also studied.Finally, the effects of boron contents and FeMo2B2 formation on the high temperature strength were studied.Boron atoms were segregated to prior austenite grain boundary during normalizing treatment.And these boron atoms were slowly diffused into the grain interior during tempering and aging at 700 ℃.The FeMo2B2 phase was only formed after 1,000 h aging at 700 ℃ in alloy containing 196 ppm boron.The formation of FeMo2B2 phase is accelerated by the applied stress.It was expected that the formation of FeMo2B2 is closely related to the redistribution of boron atoms.The tensile strengths at 700 ℃ are increased with the increase of boron contents.However, the formation of FeMo2B2 phase results in lower tensile strength. 相似文献
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《Intermetallics》2000,8(5-6):589-593
The discrete-variational method within the framework of density functional theory is used to study the effects of both boron and hydrogen on the embrittlement of polycrystalline Ni3Al. The calculated results show that there are strong repulsive interaction between the boron and the hydrogen atoms, if they occupy the nearest interstitial sites, respectively, in the Ni3Al grain boundaries. It indicates that the boron atoms inhibit the diffusion of hydrogen atoms along the grain boundary. It may be the main reason why boron can suppress the moisture induced hydrogen embrittlement. Our results also show that the attractive interactions between boron and some substrate atoms are weakened, but the attractive interactions between boron and other substrate atoms are enhanced, when hydrogen atoms are forced into the grain boundary and occupy the nearest interstitial sites to boron atoms. As a result, the bonding states are polarized in the local region of the grain boundary. It may suppress the movement of slips across the grain boundary. Furthermore, the weakening effects of hydrogen to the grain boundary are hardly affected by the boron atoms, even though they are very near to each other. It can be concluded that hydrogen embrittlement takes place when the boron-doped polycrystalline Ni3Al are charged with hydrogen. 相似文献
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对Fe-30%Ni合金和超低碳贝氏体钢在高温进行不同方式变形和保温,通过变形、回复、与再结晶,获得秒同的晶体缺陷数量与构型(主要是位错分布形态)。用硼径迹显微照相技术研究了 空冷过程中硼向晶界的非平衡偏聚及与不同形态晶体缺陷的关系。结果表明,在再结晶新晶粒冷却时晶界偏聚明显。晶界附近会出现较显著的贫硼现象,而变形并回复后的原始晶粒中此现象不明显,高温回复阶段形成的多边形化亚晶界(位错墙)对冷却时硼 相似文献