低对称晶体GdCa_4O(BO_3)_3电光系数的测量

用干涉法测量了低对称晶体 Gd Ca4 O(BO3) 3的全部电光系数。为了分离测量交叉电光系数 γ51 ,γ53,γ4 2和γ6 2 ,采用了新的样品趋向。测量结果为 :γ1 1 =0 .4 pm / V ,γ2 1 =0 .5 pm/ V,γ31 =0 .6 pm / V,γ1 3=0 .1pm/ V,γ2 3=0 .4 pm / V,γ33=2 .0 pm/ V,γ51 =0 .7pm / V ,γ53=1.5 pm / V,γ4 2 =0 .5 pm/ V,γ6 2 =0 .8pm / V .     

ZnCd(SCN)4晶体的电学性能和电光性能

测量了 Zn Cd(SCN) 4晶体的介电常数和直流电导率 ,结果为 :介电常数 εa=6 .9,εc=7.4。直流电导率ρa=4 .6× 10 1 0 Ω· cm,ρc=1.4× 10 1 1 Ω· cm。并用干涉法测量了该晶体的全部压电应变常数和电光系数 ,其结果为 :压电应变常数 d31 =1.5 p C/N,d36 =9.5 p C/N ,d1 4=1.6 p C/N,d1 5=15 .3p C/N;电光系数γ1 3=0 .0 4 pm /V ,γ6 3=9.4 pm /V,γ4 1 =1.3pm /V ,γ51 =1.7pm/V。     

低对称晶体YCa_4O(BO_3)_3电光系数的测量

用于涉法测量了低对称晶体YCa4O(BO3)3的全部电光系数,为了分离测量交叉电光系数γ51, γ53, γ42,和 γ62,采用了新的样品趋向,测量结果为:γ11=0.6, γ21=0.4, γ31=0.3, γ13=0.3, γ23=0.2, γ33=2.26, γ51=0.9, γ11=0.6, γ11=0.6, γ53=4.1, γ42=0.8, γ62=0.4×10-12m/V。     

基于M-Z光纤干涉仪测量极化聚合物的电光系数

提出了采用Mach Zehnder(M Z)光纤干涉仪的电光聚合物电光系数测量方法,对其测量原理进行了分析,研究了光纤干涉仪的臂长差、样品的插入损耗对系统可见度的影响,讨论了通过合理设置耦合器的耦合系数提高系统测量性能的方法。系统具有较好的稳定性和较高的灵敏度,既适合于聚合物薄膜也适合于聚合物波导的测量,系统干涉可见度为0.86,可分辨的最小相位变化约为6×10-6 rad。该系统可以同时测量2个独立的电光系数γ13和γ33,使用该系统测得一种有机/无机杂化材料ASD/SiO2 TiO2 极化后的电光系数为γ13=0.72±0.01 pm/V和γ33=2.8±0.01 pm/V。     

β—BBO晶体的电光性能

用干涉法测量了β－ＢＢＯ晶体的电光系数：γ２２＝２．６，γ３３＝０．２３，γ３１＝０．２５，γ５１＝－３．５×１０－１２ｍ／Ｖ。结果表明如果在Ｙ方向加电场，Ｚ方向通光，β—ＢＢＯ晶体可能制作成有应用价值的光开关。     

光谱法求解极化聚合物薄膜的电光系数

提出了利用透过光谱法和吸收光谱法相结合测定聚合物电光系数的一种新方法,并求得了合成的聚氨酯聚合物薄膜在632．8 nm处的电光系数为r33=34.4pm/V,r13=5.4pm/V     

光谱法求解析化聚合物薄膜的电子系数

提出了利用透过光谱法和吸收光地相结合测定聚合物电光系数的一种新方法,并求得了合成的聚氨酸薄膜在６３２．８ｎｍ处的电光系数为γ３３＝３４ｐｍ／Ｖ,γ１３＝５．４ｐｍ／Ｖ。     

RbTiOAsO4(RTA)晶体的电光性能

测量了ＲｂＴｉＯＡｓＯ４（ＲＴＡ）晶体的电光系数、介电常数和交流电导率,结果为：电光系数γ１３＝１０．８,γ２３＝１７．３,γ３３＝４０．０,γ５１＝１２．３,γ４２＝１４．６ｐｍ／Ｖ;介电常数ε１１＝ε２２＝１２,ε３３＝２１;交流电导率σｃ＝３．６×１０－８ｓ／ｃｍ。结果表明ＲＴＡ晶体波导调制器的品质因子ｎ７γ２／ε比ＫＴＰ晶体高１５％,但是其交流电导率比ＫＴＰ晶体小了两个数量级。这些性能使ＲＴＡ晶体有希望应用于波导调制器和其它电光器件。     

KNbO_3:Fe在632.8nm处的自泵相位共轭

本文报道在He-Ne激光的632.8nm实现KNbO_3:Fe自泵相位共轭。虽然光折变材料的耦合系数随工作波长的增加而减少,但通过晶体材料的特殊切割,充分利用了最大电光系数:r_42=380pm/V和内表面的全反射,获得的自泵相位共轭反射率可达40％。     

聚合物共面波导行波电极电光调制器

用聚合物材料BPAN-NT设计并初步成功制作了共面波导(CPW)行波电极电光调制器。用反应离子刻蚀(RIE)的方法制作脊波导,通过电晕极化使芯层有电光效应,利用电镀方法制作厚行波电极。对调制器的各项特性参数进行了测试,测得调制器的微波损耗系数0α=0.9 dB/cm.(GHz)1/2、在1.317μm波长上Vπ=250 V,由此算得芯层材料的电光系数3γ3=3.7 pm/V,同时测得消光比为13.49dB、插入损耗为18.6 dB,在8 GHz的微波频率上观察到了调制光信号,理论计算3 dB光调制带宽为43.77 GHz。     

碳酸锰和纳米钛酸钡的添加对钛酸钡陶瓷的影响

以钛酸丁酯和乙酸钡为起始原料,采用液相法制备了纳米钛酸钡。研究了纳米钛酸钡和碳酸锰的掺杂对普通亚微米级钛酸钡的形貌及介电性能的影响。结果表明,在普通钛酸钡中加入一定量的纳米钛酸钡可以促进晶粒的生长,同时提高陶瓷的介电常数。而在普通钛酸钡中加入一定量的碳酸锰则可以抑制晶粒的生长。但同时添加碳酸锰和纳米钛酸钡,碳酸锰对晶粒生长的抑制作用将居于主导地位,并且此时钛酸钡陶瓷的介电常数温度特性曲线与单独添加锰离子时的走势基本相同,室温附近的介电常数峰将由于钛酸钡陶瓷的细晶效应而弥散。     

Magnetic properties of Co- and Mn-implanted BaTiO3, SrTiO3 and KTaO3

Implantation of Co or Mn into single-crystal BaTiO₃(K), SrTiO₃ or KTaO₃(Ca), followed by annealing at 700 °C, produced ferromagnetic behavior over a broad range of transition metal concentrations. For BaTiO₃, both Co and Mn implantation produced magnetic ordering temperatures near 300 K with coercivities 70 Oe. The M–T plots showed either a near-linear decrease of magnetization with increasing temperature for Co and a non-Brillouin shaped curve for Mn. No secondary phases were detected by high-resolution X-ray diffraction. The same basic trends were observed for both SrTiO₃ and KTaO₃, with the exception that at high Mn concentrations (5 at.%) the SrTiO₃ was no longer ferromagnetic. Our results are consistent with recent reports of room temperature ferromagnetism in other perovskite systems (e.g. LaBaMnO₃) and theoretical predictions for transition metal doping of BaTiO₃ [Nakayama et al., Jap. J. Appl. Phys. 40 (2001) L1355].     

Dielectric properties of single crystals of Al2O3, LaAlO3, NdGaO3, SrTiO3, and MgOat cryogenic temperatures

A dielectric resonator technique has been used for measurements of the permittivity and dielectric loss tangent of single-crystal dielectric substrates in the temperature range 20-300 K at microwave frequencies. Application of superconducting films made it possible to determine dielectric loss tangents of about 5×10^-7 at 20 K. Two permittivity tensor components for uniaxially anisotropic samples were measured. Generally, single-crystal samples made of the same material by different manufacturers or by different processes save significantly different losses, although they have essentially the same permittivities. The permittivity of one crystalline ferroelectric substrate, SrTiO₃, strongly depends on temperature. This temperature dependence can affect the performance of ferroelectric thin-film microwave devices, such as electronically tunable phase shifters, mixers, delay lines and filters     

Characterization of the annealing impact on La2O3/HfO2 and HfO2/La2O3 stacks for MOS applications

The impact of various rapid thermal annealing used during the integration on the La₂O₃/HfO₂ and HfO₂/La₂O₃ stacks deposited by Atomic Layer deposition was analyzed. The consequences of lanthanum localization in such stacks on the evolution of the films during the rapid thermal annealing are investigated in term of morphology, crystalline structure, silicate formation and film homogeneity as a function of the depth. It appeared that the La₂O₃ location has an impact on the temperature of the quadratic phase formation which could be linked to the formation of SiOHfLa silicate and the resistance of the films to dissolution in HF 0.05 wt%.     

First-principle study of ferroelectricity in PbTiO3/SrTiO3 superlattices

We performed the first-principles calculation to investigate the electronic structure and polarization behaviors in PbTiO₃/SrTiO₃ (PST) superlattices. The DOS (density of state) profiles show that there are strong hybridizations of atom Ti–O and Pb–O which play very important roles on ferroelectricity of the PbTiO₃/SrTiO₃ superlattices. Comparing to the corresponding paraelectric phase, we find the electrons of the PT (PbTiO₃) layers occupy lower energy states and electrons of the ST (SrTiO₃) layer occupy higher energy states. It is shown that the polarizations of the superlattices decrease with proportion of SrTiO₃ increasing. The constant polarization of local layer indicates that PST superlattices with small modulation lengthen can be approximately considered as a single ferroelectric material. Furthermore, according to electrostatic model, we find that directions of internal electric fields in PT and ST layers are opposite. In PST superlattices, internal electric field in PT layer leads to the loss of polarization of this layer, but the polarization of ST layer is induced by internal electric field of this layer. Compared to the value of the polarization in bulk PbTiO₃, polarization of PST is smaller.     

使用Na_2CO_3/NaHCO_3体系进行单晶硅制绒

通过单晶硅表面制绒可以降低太阳能电池面板对光的反射率进而提高电池的转化效率。利用Na2CO3、NaHCO3和Na2CO3/NaHCO3溶液进行了单晶硅表面制绒,并利用扫描电子显微镜和紫外/可见光光度计对所得绒面的形貌及反色率分别进行了分析。研究了溶液浓度、溶液组成及反应时间等因素对所制单晶硅绒面反射率的影响。结果表明:在Na2CO3:NaHCO3质量比为10:1,反应温度为85℃,反应时间为10 min时,可获得反射率为15.22%的绒面。     

Electrooptic coefficient measurements in LiTaO3 andLiNbO3 waveguides

The magnitudes of linear electrooptic coefficients r₁₃ and r₃₃ in Zn:LiTaO₃ repoled channel waveguides are reported. The measurements were made at 0.633-μm wavelength using a Fabry-Perot interferometer. The waveguides were produced by diffusion from the vapor phase at a temperature above the Curie temperature. For full recovery of the Pockels effect, an electric field of 200 V/cm is needed during repoling. The measured values of r₁₃ and r₃₃ at 32-MHz modulation frequency are 7.2 and 30.3 pm/V, respectively. The difference between unclamped and clamped coefficients is comparable to that from bulk crystals. Measurements were also made on Ti:LiNbO₃ waveguides that did not require repoling, and good agreement with bulk crystal values was obtained     

Sensor effect in YBa2 Cu3 Oy

The high-T_c superconducting material YBa₂ Cu₃ O_y, well known as a 1–2–3 compound, shows other very interesting properties. One of them is very strong conductivity-oxygen content dependence. On the basis of our previous measurements, an investigation of dilatation synthesis, X-ray diffraction (XRD) analysis and conductivity measurements were performed. The results on quenched and slowly cooled samples show a phase transition region and an obvious interdependence between conductivity, unit cell volume and oxygen content.     

Piezoelectric Study of 0.65Pb(Mg1/3,Nb2/3)O3-0.35PTO3 Nanopoder Ceramics

The piezoelectric properties of relaxor ferroelectric 0.65Pb(Mg1/3Nb2/3)O3-0.35PbTiO3 ceramic prepared by a sol-gel combustion method have been investigated as function of sintering temperature. The results show that its phase structure is near the morphoteropic phase boundary (MPB), and outstanding electrical properties are obtained with this composition. The highest piezoelectric coefficients were observed for the samples sintered at temperature of 1200oC. In comparison with pure PMN ((1-x)Pb(Mg1/3Nb2/3)O3(x)PbTiO3), the substitution of 35% PT results in the decrease of sintered temperature and improved the relaxation behavior.     

Ga2O3(Gd2O3)/InGaAsenhancement-mode n-channel MOSFETs

We have demonstrated the first Ga₂O₃(Gd₂O₃) insulated gate n-channel enhancement-mode In_0.53Ga_0.47As MOSFET's on InP semi-insulating substrate. Ga₂O₃(Gd₂ O₃) was electron beam deposited from a high purity single crystal Ga₅Gd₃O₁₂ source. The source and drain regions of the device were selectively implanted with Si to produce low resistance ohmic contacts. A 0.75-μm gate length device exhibits an extrinsic transconductance of 190 mS/mm, which is an order of magnitude improvement over previously reported enhancement-mode InGaAs MISFETs. The current gain cutoff frequency, f_t, and the maximum frequency of oscillation, f_max, of 7 and 10 GHz were obtained, respectively, for a 0.75×100 μm² gate dimension device at a gate voltage of 3 V and drain voltage of 2 V