Intensity of critical opalescence of helium-4

We present measurements of the critical opalescence of helium-4. The results are analyzed by the Einstein and Ornstein-Zernike theory and the power laws. We obtain ==1.17±0.02, ==0.62±0.1,/=4.5±0.3,P _c =1706.008 mm Hg, andT _c =5,189.863 mK (T ₅₈ ). The critical behavior of helium-4 is almost the same as that of classical fluids and the influence of the quantum nature of helium-4 is not as evident as has been claimed.     

Inertia of measurements with “auxiliary-wall” type heat meters

The article examines the problem of thermal inertia on the basis of an auxiliary-wall type heat meter, it demonstrates the boundaries of applicability of the approximate relationship for calculating non-steady-state heat fluxes.Notation q() non-steady-state heat flux through the heat meter - _i,a _i thermal conductivity, thermal diffusivity, and thickness of the heat meter, respectively - ₂,a ₂ thermal conductivity and thermal diffusivity, respectively, of the base of the heat meter - t() temperature gradient over the thickness of the heat meter - index of thermal inertia - time - s parameter of Laplace transform - t₁ (x, ) temperature of the heat meter at point x - t₂(x, ) temperature of the base - t_c ambient temperature - Y_q(s) transfer function from the heat flux q() to the temperature gradient t() Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 2, pp. 298–305, August, 1980.     

Transport property and battery discharge characteristic studies on 1−x(0.75Agl∶0.25AgCl)∶ xAl2O3 composite electrolyte system

Various experimental studies on a new fast Ag⁺ ion-conducting composite electrolyte system: (1–x) (0.75Agl0.25AgCl)xAl₂O₃ are reported. Undried Al₂O₃ particles of size <10 m were used. The conventional matrix material Agl has been replaced by a new mixed 0.75Agl0.25AgCl quenched and/or annealed host compound. Conductivity enhancements 10 from the annealed host and 3 times from the quenched host obtained for the composition 0.7(0.75Agl0.25AgCl)0.3Al₂O₃, can be explained on the basis of the space charge interface mechanism. Direct measurements of ionic mobility as function of temperature together with the conductivity were carried out for the best composition. Subsequently, the mobile ion concentration n values were calculated from and a data. The value of heat of ion transport q* obtained from the plot of thermoelectric power versus 1/T supports Rice and Roth's free ion theory for superionic conductors. Using the best composition as an electrolyte various solid state batteries were fabricated and studied at room temperature with different cathode preparations and load conditions.     

The Interplay of Electronic and Nuclear Magnetism in PtFe x at Milli-, Micro-, and Nanokelvin Temperatures

We have measured ac susceptibility, nuclear magnetic resonance, and nuclear heat capacity of two PtFe _x samples with concentrations of magnetic impurities x = 11 ppm and 41 ppm at magnetic fields (0 ± 0.05) mTB248 mT. The susceptibility data have been measured at temperatures of 0.3 KT100 mK, no hint for nuclear magnetic ordering could be detected to a temperature of 0.3 K. The nuclear heat capacity data taken at 1.4 KT10 mK show enhanced values which scale with x at low polarization. This effect is described by a model assuming an internal magnetic field caused by the impurities. No indication for nuclear magnetic ordering could be detected to 1.4 K. The nuclear magnetic resonance experiments have been performed on these samples at 0.8 KT0.5 mK and 2.5 mTB22.8 mT as well as on three other samples with x = 5, 10, 31 ppm in a different setup at 40 KT0.5 mK and at 5.4 mTB200 mT. Spin-lattice and effective spin-spin relaxation times ₁and ₂ ^* of ¹⁹⁵ Pt strongly depend on x and on the external magnetic field. No temperature dependence of ₁and ₂ ^* could be detected and the NMR data, too, give no hint for nuclear magnetic ordering to 0.8 K.     

Deformation of a carbon-epoxy composite under hydrostatic pressure

This paper describes the behaviour of a carbon-fibre reinforced epoxy composite when deformed in compression under high hydrostatic confining pressures. The composite consisted of 36% by volume of continuous fibres of Modmur Type II embedded in Epikote 828 epoxy resin. When deformed under pressures of less than 100 MPa the composite failed by longitudinal splitting, but splitting was suppressed at higher pressures (up to 500 MPa) and failure was by kinking. The failure strength of the composite increased rapidly with increasing confining pressure, though the elastic modulus remained constant. This suggests that the pressure effects were introduced by fracture processes. Microscopical examination of the kinked structures showed that the carbon fibres in the kink bands were broken into many fairly uniform short lengths. A model for kinking in the composite is suggested which involves the buckling and fracture of the carbon fibres.List of symbols d diameter of fibre - E _f elastic modulus of fibre - E _m elastic modulus of epoxy - G _m shear modulus of epoxy - k radius of gyration of fibre section - l length of buckle in fibre - P confining pressure (= ₂ = ₃) - R radius of bent fibre - V _f volume fraction of fibres in composite - _t, _c bending strains in fibres - angle between the plane of fracture and ₁ - ₁ principal stress - ₃ confining pressure - _c strength of composite - _f strength of fibre in buckling mode - _n normal stress on a fracture plane - _m strength of epoxy matrix - shear stress - tangent slope of Mohr envelope - slope of pressure versus strength curves in Figs. 3 and 4.     

Breakup of an anomolously viscous liquid film in a centrifugal force field

An equation is obtained for the breakup radius with consideration of tipping moments and Laplacian pressure forces acting on the liquid ridge at the critical point.Notation K, n rhenological constants - density - surface tension - r current cup radius - R maximum cup radius - r_c critical radius for film breakup - ¯r=¯r=r/R dimensionless current radius - ¯r_c=r_c/R dimensionless critical radius - ₀, _c actual and critical film thicknesses - current thickness - R_r ridge radius - h₀ ridge height - h current ridge height - ₀ limiting wetting angle - current angle of tangent to ridge surface - angle between axis of rotation and tangent to cup surface - angular velocity of rotation - q volume liquid flow rate - v₁ and v meridional and tangential velocities - =4vv _lm/r,=4v_m/r dimensionless velocities - M moments of surface and centrifugal forces - M_v moment from velocity head - p_r pressure within ridge - P_vm pressure from velocity head - p_m, p_pm pressures from centrifugal force components tangent and normal to cup surface - deviation range of breakup radius from calculated value - ¯r_max, ¯r_min limiting deviations of breakup radius - _c angle of tangent to curve _c/°₀=f(¯r) at critical point - t random oscillation of ratio _c/_c Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 51–56, July, 1980.     

Thermodynamics of the quasiequilibrial growth of crazes

By comparing the morphology and physical properties (averaged over the scale of 1 to 10m) of a crazed and uncrazed polymer, it can be concluded that crazing is a new phase development in the initially homogeneous material. The present study is based on recent work on the general thermodynamic explanation of the development of a damaged layer of material. The treatment generalizes the model of a crack-cut in mechanics. The complete system of equations for the quasiequilibrial craze growth follows from the conditions of local and global phase equilibrium, mechanical equilibrium and a kinematic condition. Constitutive equations of craze growth-equations are proposed that are between the geometric characteristics of a craze and generalized forces. It is shown that these forces, conjugated with the geometric characteristics of a craze, can be expressed through the known path independent integrals (J, L, M,). The criterion of craze growth is developed from the condition of global phase equilibrium. F Helmholtz's free energy - G Gibb's free energy (thermodynamic potential) - f density ofF - g density ofG - T absolute temperature - S density of entropy - strain tensor - components of - stress tensor - components of - _y stress along the boundary of an active zone (yield stress) - _b stress along the boundary of an inert zone - applied stress - value of at the moment of craze initiation - K stress intensity factor - C tensor of elastic moduli - C ^–1 tensor of compliance - internal tensorial product - V volume occupied by sample - V ₁ volume occupied by original material - V ₂ volume occupied by crazed material - V boundary ofV - (V) vector-function localized on V - (x) characteristic function of an area - (x) variation of(x) - (x) a finite function - tensor of alternation - components of the boundary displacement vector - l components of the vector of translation - n components of the normal to a boundary - _k components of the vector of rotation - e symmetric tensor of deviatoric deformation of an active zone - expansion of an active zone - J ⁽ⁱ⁾ ,L _k ⁽ⁱ⁾ ,M ⁽ⁱ⁾,N ⁽ⁱ⁾ partial derivatives ofG ⁽ⁱ⁾ with respect tol , _k, ande , respectively - [ ] jump of the parameter inside the brackets - thickness of a craze - 2l length of a craze - 2b length of an active zone - l _c distance between the geometrical centres of the active zone and the craze - ^* craze thickness on the boundary of an active and the inert zone - l ^* craze parameter (length dimension) - A craze parameter (dimensionless) - ^* extension of craze material     

The physics and mechanics of fibre-reinforced brittle matrix composites

This review compiles knowledge about the mechanical and structural performance of brittle matrix composites. The overall philosophy recognizes the need for models that allow efficient interpolation between experimental results, as the constituents and the fibre architecture are varied. This approach is necessary because empirical methods are prohibitively expensive. Moreover, the field is not yet mature, though evolving rapidly. Consequently, an attempt is made to provide a framework into which models could be inserted, and then validated by means of an efficient experimental matrix. The most comprehensive available models and the status of experimental assessments are reviewed. The phenomena given emphasis include: the stress/strain behaviour in tension and shear, the ultimate tensile strength and notch sensitivity, fatigue, stress corrosion and creep.Nomenclature a _i Parameters found in the paper by Hutchinson and Jensen [33], Table IV - a _o Length of unbridged matrix crack - a _m Fracture mirror radius - a _N Notch size - a _t Transition flaw size - b Plate dimension - b _i Parameters found in the paper by Hutchinson and Jensen [33], Table IV - c _i Parameters found in the paper by Hutchinson and Jensen [33], Table IV - d Matrix crack spacing - d _s Saturation crack spacing - f Fibre volume fraction - f _l Fibre volume fraction in the loading direction - g Function related to cracking of 90 ° plies - h Fibre pull-out length - l Sliding length - l _i Debond length - l _s Shear band length - m Shape parameter for fibre strength distribution - m _m Shape parameter for matrix flaw-size distribution - n Creep exponent - n _m Creep exponent for matrix - n _f Creep exponent for fibre - q Residual stress in matrix in axial orientation - s _ij Deviatoric stress - t Time - t _p Ply thickness - t _b Beam thickness - u Crack opening displacement (COD) - u _a COD due to applied stress - u _b COD due to bridging - v Sliding displacement - w Beam width - B Creep rheology parameter _o/ _o ⁿ - C _v Specific heat at constant strain - E Young's modulus for composite - E _o Plane strain Young's modulus for composites - Unloading modulus - E _* Young's modulus of material with matrix cracks - E _f Young's modulus of fibre - E _m Young's modulus of matrix - E _L Ply modulus in longitudinal orientation - E _T Ply modulus in transverse orientation - E _t Tangent modulus - E _s Secant modulus - G Shear modulus - G Energy release rate (ERR) - G _tip Tip ERR - G _tip ^o Tip ERR at lower bound - K Stress intensity factor (SIF) - K _b SIF caused by bridging - K _m Critical SIF for matrix - K _R Crack growth resistance - K _tip SIF at crack tip - I _o Moment of inertia - L Crack spacing in 90 ° plies - L _f Fragment length - L _g Gauge length - L _o Reference length for fibres - N Number of fatigue cycles - N _s Number of cycles at which sliding stress reaches steady-state - R Fibre radius - R R-ratio for fatigue (_max/_min) - R _c Radius of curvature - S Tensile strength of fibre - S _b Dry bundle strength of fibres - S _c Characteristic fibre strength - S _g UTS subject to global load sharing - S _o Scale factor for fibre strength - S _p Pull-out strength - S _th Threshold stress for fatigue - S _u Ultimate tensile strength (UTS) - S _* UTS in the presence of a flaw - T Temperature - T Change in temperature - t Traction function for thermomechanical fatigue (TMF) - t _b Bridging function for TMF - Linear thermal coefficient of expansion (TCE) - _f TCE of fibre - _m TCE of matrix - Shear strain - _c Shear ductility - _c Characteristic length - Hysteresis loop width - Strain - _* Strain caused by relief of residual stress upon matrix cracking - _e Elastic strain - _o Permanent strain - _o Reference strain rate for creep - Transient creep strain - _s Sliding strain - Pull-out parameter - Friction coefficient - Fatigue exponent (of order 0.1) - Beam curvature - Poisson's ratio - Orientation of interlaminar cracks - Density - Stress - _b Bridging stress - ¯_b Peak, reference stress - _e Effective stress = [(3/2)s _ijs_ij]^1/2 - _f Stress in fibre - _i Debond stress - _m Stress in matrix - _mc Matrix cracking stress - ^o Stress on 0 ° plies - _o Creep reference stress - _rr Radial stress - ^R Residual stress - _s Saturation stress - _s ^* Peak stress for traction law - Lower bound stress for tunnel cracking - ^T Misfit stress - Interface sliding stress - _f Value of sliding stress after fatigue - _o Constant component of interface sliding stress - _s In-plane shear strength - ¯_c Critical stress for interlaminar crack growth - _ss Steady-state value of after fatigue - ^R Displacement caused by matrix removal - _p Unloading strain differential - _o Reloading strain differential - Fracture energy - _i Interface debond energy - _f Fibre fracture energy - _m Matrix fracture energy - _R Fracture resistance - _s Steady-state fracture resistance - _T Transverse fracture energy - Misfit strain - _o Misfit strain at ambient temperature     

The engulfment of foreign particles by a freezing interface

The interactions of second-phase particles, liquid droplets or gas bubbles with a solidification front form the basis of various materials synthesis and purification processes and the design of microstructures in cast metal-matrix composites, as well as frost heaving and biological cell interactions. The physical mechanisms of this interaction phenomenon are based upon surface thermodynamic factors, solidification parameters, and fluid dynamic effects such as fluid drag and buoyancy. An overview is presented of the role of various factors which determine the nature as well as the kinetics of foreign particle-solidification front interactions, and the current status and limitations of the various theoretical models of the phenomenon.Nomenclature V Critical velocity for particle engulfment - L Latent heat of fusion - a ₀ Atomic radius - Atomic volume - D ₁ Diffusion coefficient in the liquid - T Temperature - R Particle radius - S Entropy of fusion - _s Density of the solid - ₁ Density of the liquid - _p Density of the particle - k Boltzmann's constant - v Difference in the specific volumes of solid and liquid - G Temperature gradient - h ₀ Critical gap thickness - R _b Radius of surface bump on particle - _sl Surface energy of solid-liquid interface - _pl Surface energy of particle-liquid interface - _sp Surface energy of solid-particle interface - Viscosity of the melt - g Acceleration due to gravity - Density difference between particle and liquid - A Hamaker constant - B A/6 - K _p Thermal conductivity of the particle - K _l Thermal conductivity of the liquid - C Bulk concentration of the liquid - m _l Slope of liquidus line - K _c Partition coefficient - C _p Specific heat of the particle - C ₁ Specific heat of the liquid     

An instability mechanism for the sliding motion of finite depth of bulk granular materials

Summary Field observations and experimental records indicate that the primary mode of motion of many large landslides is that ofsliding rather thanflowing. Most of shear during sliding is concentrated at the base of slides, with little or no mixing taking place away from the base. This sliding motion may generate strong pressure waves at the interface between the quasi-static deforming granular mass and the grain-inertia dominated rapid granular flow, thus inducing a Kelvin-Helmholtz type instability mechanism for large landslides. The existence of a transitional zone in granular flow is essential for the generation of this type of instability waves. A model using a finite depth of elastic sliding bulk granular materials riding on a basal granular shear flow layer is estabilished to represent the sliding motion of these large volume of bulk granular materials. The balance and the stability of this sliding system are investigated under the perturbation of internal pressure waves. The generated instability waves will force favorable phase shifts between the overburden pressure and the sliding velocity, leading to a net reduction in the total power loss due to friction. The depth of sliding mass will affect the generation of this type of instability waves. Both analytical and numerical results show that smaller depth slides can induce stronger instability waves than larger depth slides do.Notation a perturbation wave amplitude - C nondimensional instability wave speed - C _i growth rate, the imaginary part ofC - C _r wave phase speed, the real part ofC - c _p compressional wave speed in elastic medium - c _s shear wave speed in elastic medium - D nondimensional depth of sliding mass - d depth of sliding mass - G shear modulus of elastic medium - H nondimensional basal depth - h depth of basal shear zone - i - K Coulomb friction coefficient - P _xx, P_yy lateral and normal pressures in granular material, respectively - P _xy shear stress in granular material - p ₀ amplitude of perturbation pressure - p _yy perturbation pressure - r nondimensional complex wave number of instability wave - S nondimensional wave number of shear wave - t time scale - U uniform sliding velocity of a landslide inx direction - u, v velocities inx direction andy direction, respectively - u ₀ granular flow velocity in the basal shear zone - V, V _c nondimensional sliding velocity and its critical velocity, respectively - W power loss to friction - internal friction angle - , Lame's potentials, and are time-independent amplitudes of and , respectively - perturbation wave surface profile - wave number of perturbation wave, _r and _i are the real and imaginary parts of - Poisson's ratio of elastic medium - wave frequency of perturbation wave - , _g density of granular material - stress component in elastic medium - Rankine's earth pressure coefficient - -K ² - Re{}, Im{} the real and imaginary parts of complex quantity inside {}, respectively - , the divergence and the curl of perturbation wave velocities, respectively - Laplacian operator - _ij Kronecker delta; _ij =1 fori=j, _ij =0 forij - ()i, ()j, ()ij tensor - ()1, ()e in sliding mass - ()2, ()b in ground     

Residual thermal stresses in the pull-out specimen: A finite element calculation

The residual thermal stress field in the pull-out specimen is calculated in the case of a high properties thermoset system (carbon-bismaleimide). The calculation is performed within the framework of the linear theory of elasticity by means of a finite element method. The specimen is modelled as a three-phase composite (holder-fibre-matrix). The meniscus which forms at the fibre entry is taken into account in order to provide a realistic stress concentration. The latter is far higher than the matrix strength. Evidence that fibre debonding propagates from the fibre end during cooling is then produced.Nomenclature T thermal load - L _e embedded length - r _f fibre radius - _c curvature radius of the meniscus (fibre entry) - r _c radial dimension of the finite element mesh - E _m,E _h matrix and holder moduli - E _A,E _T fibre axial and transverse moduli - _m, _h matrix and holder thermal expansion coefficients - _A, _T fibre axial and transverse thermal expansion coefficients - _rr, , _zz, _rz non-zero components of the residual stress field - _rr ⁱ , ^im , _zz ^im , _rz ⁱ stresses at the interface in the matrix (r=r _f + ) - _rr ⁱ , ^if , _zz ^if , _rz ⁱ stresses at the interface in the fibre (r=r _f–) - _p1 maximum principal stress - _zz ^f mean axial stress over the fibre section - _rupt ^m matrix strength - u _r ,u _z non-zero components of the displacement field     

Thermal conductivity of hydrocarbons in the naphthene group under high pressures

The thermal conductivity of hydrocarbons in the naphthene group has been experimentally determined. An equation is now proposed for calculating the thermal conductivity over the given temperature and pressure ranges.Notation thermal conductivity - ₂₀ and ₃₀ values of the thermal conductivity at 20 and 30°C, respectively - t₀,P₀ thermal conductivity at t₀, p₀ - _t p thermal conductivity at temperature t and under pressure P - change in thermal conductivity - P pressure - P_melt melting pressure - P₀ atmospheric pressure - t₀ 20°C temperature - T, t temperature - T_cr critical temperature - temperature coefficient of thermal conductivity - ₂₀ temperature coefficient of density - density - ₂₀ density at 20°C - _cr critical density - M molar mass - =T/T_cr referred temperature - v specific volume - v₀ specific volume at 20°C - v change in specific volume - _{3 0} a coefficient - B (t) a function of the temperature - S a quadratic functional - W_i, weight of the i-th experimental point - _i error of the i-th experimental value of thermal conductivity - B _{y, =0.6} value of B (t) at T = 0.6T_cr - B = B (t)/B_{, =0.6} referred value of coefficient B (t) Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 41, No. 3, pp. 491–499, September, 1981.     

Relationship between the energy supply parameters and the physicochemical l characteristics of polymer compositions during drying and thermal processing

The effect of the type of energy supply on the formation of temperature and concentration fields in the thermal processing of polymer compositions is considered.Notation T₀, T initial and current temperature of the coating - T_m temperature of the air - =(T-T_o)/(T_m-T₀) dimensionless temperature of the coating - a thermal diffusivity - A absorption power of the coating - D diffusion coefficient - thermal conductivity - c thermal capacity - density - _k convective heat transfer coefficient - i number of moles of reacting groups per unit volume of polymer - K₀ factor in front of the exponential - R gas constant - u concentration - Q thermal effect of the reaction - q_n density of the incident radiant flux - =x/ dimensionless coordinate over the thickness of the coating - Ki=Aq_n /(T_m-T₀) Kirpichev criterion characterizing the thermal effect of the reaction - Ki_p=Qi/c (T_m-T₀) analog of the Predvoditelev criterion, characterizing the rate of occurrence of a chemical excess in the system - Bu= Bouguer criterion - Lu=D/a Lykov number - Fo=a/² Fourier number - Bi= _k Biot number Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 1, pp. 26–33, July, 1980.     

A gradient method of defining smooth solutions to inverse boundary-value problems in thermal conduction

An iterative algorithm is described for solving boundary-value inverse problems in thermal conduction by steepest descent, which utilizes information on the smoothness of the solution.Notation A, B linear operators - u element of solution space U - f exact reference data - f reference data uncertainty - value of reference data uncertainty - A^–1 inverse operator - u^(k)() k-th derivative of function u - _m length of observation interval - _i(t) polynomials of degree i–1 - A^*, B^*, L^* operators conjugate to the operators A, B, L - Jg discrepancy functional gradient - _n descent step along the discrepancy antigradient for the n-th iteration - K( –) kernel of integral equation - q() heat flux - T() measured temperature inside body Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 39, No. 2, pp. 259–263, August, 1980.     

Bounding-surface plasticity: Stress space versus strain space

Summary A bounding-surface plasticity model is formulated in stress space in a general enough manner to accommodate a considerable range of hardening mechanisms. Conditions are then established under which this formulation can be made equivalent to its strain-space analogue. Special cases of the hardening law are discussed next, followed by a new criterion to ensure nesting. Finally, correlations with experimental data are investigated.Notation (a) centre of the stress-space (strain-space) loading surface; i.e., backstress (backstrain) - ^* (a ^*) centre of the stress-space (strain-space) bounding surface - (a ) target toward which the centre of the stress-space (strain-space) loading surface moves under purely image-point hardening - (b) parameter to describe how close the loading surface is to nesting with the bounding surface in stress (strain) space; see (H10) - (c) elastic compliance (stiffness) tensor - (d) parameter to describe how close the stress (strain) lies to its image point on the bounding surface; see (H10) - (D) generalised plastic modulus (plastic compliance); see (1) - function expressing the dependence of the generalised plastic modulus on (plastic complianceD ond) - ^* (D ^*) analogue to (D) for the bounding surface - function expressing the dependence of ^* on (D ^* ond) - () strain (stress) - ' (') deviatoric strain (stress) - ^P ( ^R ) plastic strain (stress relaxation); see Fig. 1 - () image point on the bounding surface corresponding to the current strain (stress) - _iso (f _iso) at the point of invoking consistency, the fraction of local loading-surface motion arising from a change of radius; i.e., fraction of isotropic hardening in the stress-space theory - _kin (f _kin) at the point of invoking consistency, the fraction of local loading-surface motion arising from a change in the backstress (backstrain); i.e., fraction of kinematic hardening in the stress-space theory - _nor (f _nor) at the point of invoking consistency, the fraction of backstress (backstrain) motion directed toward the image stress (strain); i.e., the image-point fraction of the kinematic hardening in the stress-space theory - _ima (f _ima) at the point of invoking consistency, the fraction of backstress (backstrain) motion directed toward the image stress (strain); i.e., the image-point fraction of the kinematic hardening in the stress-space theory - function relating _iso to , , and (f _iso tob,d, andl) - function relating _kin to , , and (f _kin onb,d, andl) - function relating _nor to , , and (f _nor onb,d, andl) - function relating _ima to , , and (f _ima onb,d, andl) - the fraction of outwardly normal bounding-surface motion at the Mróz image point which arises from a change of radius - the fraction of outwardly normal bounding-surface motion at the Mróz image point which arises from a change in the centre - function relating _iso ^* to (f _iso ^* tod) - function relating _kin ^* to (f _kin ^* tod) - (l) parameter to describe the full extent of plastic loading up to the present, giving the arc length of plastic strain (stress relaxation) trajectory; see (H10) - function relating the direction for image-point translation of the loading surface to various other tensorial directions associated with the current state; see (H5). With 6 Figures     

Low endurance fatigue in metals and polymers

The fatigue behaviour of commercially pure aluminium and of nylon under sequentially varying strain amplitudes is compared with a damage law of the type suggested by Miner. Aluminium obeys such a law for both cyclic and uniaxial prestrains but the behaviour of nylon is significantly affected by microcracking, which produces a marked effect of loading sequence.Appendix N Number of strain cycles at a given time - N _f Value of N at failure - True tensile stress - True stress range for a strain cycled specimen - _h Value of at half the life of the specimen - True tensile strain - Total true strain range - _p True plastic strain range (= the breadth of the hysteresis loop at = 0) - _d True diametral strain range - E Young's modulus - Linear strain hardening rate when tested at a particular value of _p - D Damage due to cycling - D _p Damage due to prestrain - _p Prestrain. C, K, K₁, , are constants     

Synthesis of silicon nitride powder through nitrogen gas atomization

The feasibility of synthesizing silicon nitride powder utilizing reactive atomization processing was analysed. The range of times required for the flight time of particles, the cooling rate of the silicon melt, the reaction time of silicon and nitrogen, and the diffusion of nitrogen through silicon nitride layers were obtained and compared. The results of this study indicated that the production of silicon nitride powder through the reactive atomization process would be limited by diffusion of nitrogen through the nitride (ash) layer, assuming the nitride layer was coherent and the unreacted core model was a valid representation of the liquid silicon-silicon nitride system.Nomenclature k(T) reaction rate constant at temperature, T(s^–1) - k ₀ Arrhenius coefficient - E activation energy (kJ mol^–1) - R gas constant - T temperature (K) - fraction of normalized conversion of -phase in time t - fraction of normalized conversion of -phase in time t - k reaction rate constant for -phase (s^–1) - k reaction rate constant for -phase (s^–1) - k ⁱ intrinsic first-order rate constant for -phase (s^–1) - x conversion fraction of -phase in time t - x conversion fraction of -phase in time t - n reaction order for -phase = 1 - n reaction order for -phase = 0.5 - J diffusion flux (mol m^–2 s^–1) - D diffusivity, or diffusion coefficient (m² s^–1 or cm² s^–1) - dC change in concentration (mol m^–3) - dl change in distance, l (m) - A(_g) gaseous reactant A - B reactant B (may be solid or liquid) - P solid product P - b stoichiometric coefficient of reactant B - p stoichiometric coefficient of product P - t time of reaction passed (s) - time for complete reaction of a particle (s) - X _B conversion fraction - r _c core radius (m) - R _p particle radius (m) - _B molar density of reactant B (mol m^–3) - k _g mass transfer coefficient between fluid and particle (m s^–1) - C _Ag concentration of gaseous reactant A (mol m^–3) - D _e effective diffusion coefficient of gaseous reactant in ash layer (m² s^–1)     

Mössbauer studies of α″-Fe16N2 and α′-Fe8N films

Conversion-electron Mössbauer spectra of epitaxial -Fe₁₆N₂ and -Fe₈N films have been studied and their differences are discussed in detail. The Mössbauer spectrum of -Fe₁₆N₂ can be decomposed into three subspectra, which correspond to the 4d, 8h and 4c sites. The Mössbauer spectrum of -Fe₈N can be fitted using four spectra based on a nitrogen-atom-random-distribution model. The average hyperfine field is larger (3%) for -Fe₁₆N₂ than for -Fe₈N, which is approximately consistent with a 4.1% enhancement of the magnetic moments for -Fe₁₆N₂. The iron moments tend to locate in the film plane for -Fe₁₆N₂ and to arrange perpendicularly to the film plane for -Fe₈N.     

Nucleate boiling

The study deals with the effect of the surface conditions on the nucleate boiling curve. A relation is proposed which describes the complete nucleate boiling curve.Notation q thermal flux - q* thermal flux at which the liquid boils after one-phase convection - q_c thermal flux during one-phase convection - q_cr1, q_cr2 first and the second critical thermal flux - T saturation temperature - T superheat of the heating surface relative to the saturation temperature - T* superheat prior to boiling of the liquid after one-phase convection - T_cr1 superheat during the first boiling crisis - T_cr3min minimum superheat at which the third boiling crisis can occur - P pressure - P_cr critical pressure - heat transfer coefficient during nucleate boiling - R_cr radius of a critical vapor forming nucleus - coefficient of surface tension - r latent heat of evaporation - thermal conductivity of the liquid - kinematic viscosity of the liquid - , densities of the liquid and the vapor - g gravitational constant - k Boltzmann constant - N Avogadro number - h Planck's constant Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 40, No. 3, pp. 394–401, March, 1981.     

The Infrared Hall Effect in YBCO: Temperature and Frequency Dependence of Hall Scattering

We measure the Hall angle, _H , in YBCO films in the far- and mid-infrared to determine the temperature and frequency dependence of the Hall scattering. Using novel modulation techniques we measure both the Faraday rotation and ellipticity induced by these films in high magnetic fields to deduce the complex conductivity tensor. We observe a strong temperature dependence of the mid-infrared Hall conductivity in sharp contrast to the weak dependence of the longitudinal conductivity. By fitting the frequency dependent normal state Hall angle to a Lorentzian _H () = _H /( _H – i) we find the Hall frequency, _H , is nearly independent of temperature. The Hall scattering rate, _H , is consistent with _H T ² up to 200 K and is remarkably independent of IR frequency suggesting non-Fermi liquid behavior.