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[目的]对化学镀镍废液中的含磷物质进行正确处理和有效回收是实现可持续发展的有效策略。[方法]采用化学沉淀法处理化学镀镍废液,使其中的磷以羟基磷灰石(HAP)沉淀形式得以回收。研究了反应温度、初始pH及Ca/P比(指硝酸钙与废液中磷的质量比)对磷去除率的影响,通过正交试验优化工艺参数。[结果]在温度为75℃、初始pH为12及Ca/P比为1.67的条件下处理后,化学镀镍废液的磷去除率达到了99.998%,并且所得沉淀为HAP。[结论]采用本工艺可有效去除化学镀镍废液中的磷,并且随之产生的HAP有望得以回收利用。 相似文献
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采用电解法回收化学镀镍废液中的重金属镍.研究了直流电解pH值,温度,搅拌,电流密度,电解时间等因素对Ni2+回收率的影响,比较了脉冲电源和直流电源作为电解废液电源对Ni2+回收率和电能消耗的影响.结果表明,废液pH值调为7,电流密度8.0 mA/cm2,电解温度为60 ℃,搅拌,直流电解2 h,Ni2+浓度从4.47 g/L降到0.048 g/L,Ni2+的回收率为98.93%,电流效率为40.40%,能耗为5.88 kW·h/kg Ni2+.采用脉冲电源电解可使能耗降低12.93%. 相似文献
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采用电渗析法研究了化学镀镍废液的再生工艺,研究分析了离子交换膜的选择方法,以及电流密度和处理时间对镀液中不同离子去除(损失)率的影响。结果表明,以日本的CMS离子交换膜和上海的异相阴离子交换膜组成的膜对作为离子交换膜,在65mA/cm2下对化学镀镍废液处理48h时的再生效果较好,23HPO的去除率达60.86%,22HPO和Ni2+的损失率分别为63.13%和1.20%。经本法处理并补加有效成分22HPO之后,可从再生化学镀镍液中制得性能良好的镍镀层,即化学镀镍废液得到回用。 相似文献
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采用碳酸钙过滤-离子交换法,去除化学镀镍废液中的有害成分亚磷酸根、硫酸根、钠离子,使化学镀镍废液得到净化再生.讨论了流速、静置时间、pH值、温度等因素对废液再生效果的影响,确定了本体系适宜的反应条件.在优化工艺条件下,亚磷酸根、硫酸根、钠离子去除率分别可达50%、30%、80%,并对其机理作了初步探讨. 相似文献
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以多孔结构的多元合金为填料,采用微电解法处理镀镍染色有机废水。以废水COD(化学需氧量)去除效率为指标,研究了废水初始pH、填充比、微电解时间等对废水处理效果的影响。多元微电解处理镀镍染色废水的最佳工艺为:初始pH3.0,填充比1∶1,时间120min,充氧曝气。在最优工艺下,COD的平均去除率为74.7%,出水COD、镍及总铬的平均质量浓度分别为74.8、0.066和0.067mg/L,总铁含量也小于0.5mg/L,满足GB21900–2008的排放要求。 相似文献
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通过采用强化微电解法处理橡胶厂拉开粉废水的实验并与传统的微电解法相比较,得出强化微电解法处理拉开粉废水优于传统微电解法,CODCr去除率由20%提高到50%,拉开粉去除率由25%提高到50%,克服了传统微电解工艺中存在的铁屑表面易钝化失效和铁屑结块等缺点。 相似文献
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化学镀镍废液处理的现状及展望 总被引:1,自引:0,他引:1
综述了近年来国内外化学镀镍废液的净化处理及资源回收利用技术最新进展.介绍了化学沉淀法、离子交换法、电渗析法、电解法等工艺原理,并对其优缺点进行了简要讨论.预计今后发展方向是将各种方法有机地结合.实现化学镀过程的无排放,达到环境效益和经济效益的统一. 相似文献
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壳聚糖对化学镀镍废液中Ni2+的吸附 总被引:2,自引:0,他引:2
研究了用壳聚糖吸附化学镀镍废液中Ni2 的最佳条件及其脱附和再生方法,以及镀液中络合剂等其他组分对吸附率的影响.结果表明,壳聚糖对化学镀镍废液中的Ni2 具有较好的吸附能力,pH是影响吸附的主要因素.在室温、pH=5.0时,Ni2 质量浓度为4.695 2 g/L的化学镀镍废液被0.939 0 g壳聚糖吸附2 h后,Ni2 的去除率达72.25%. 相似文献
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Wastewater treatment after electroless nickel plating runs has been known to be difficult and this has been a subject of worldwide
concern. Discarding wastewater of electroless nickel plating into sea was prohibited under the London Dumping Treaty since
1996. We have studied on recovering nickel from wastewater by reduction crystallization. In this study, the characteristics
of nickel ion removal and recovery were investigated in the process of reduction crystallization using a laboratory scale
batch crystallizer (500 ml), in order to propose a new process for wastewater treatment from nickel plating. In the reduction
crystallization, which can use hypophosphite ion as a reducing agent for nickel ion in the wastewater, nickel ion could be
recovered as a form of nickel metal by seeding nickel powder having large specific surface area. 相似文献
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以Ni~(2+)、总磷和氨氮为考察对象,采用Fenton氧化和沸石吸附联合处理化学镀镍废水。探讨了Fenton破络及协同氧化非正磷酸盐时,H_2O_2的质量浓度、m(Fe~(2+))∶m(H_2O_2)、初始pH值对Ni~(2+)和总磷去除率的影响。另外,研究了沸石吸附氨氮时,沸石量、吸附时间、吸附pH值对氨氮去除率的影响。结果表明:当H_2O_2的质量浓度为6.66g/L、m(Fe~(2+))∶m(H_2O_2)为0.06、初始pH值为3时,破络完全,非正磷酸盐转化率为99.45%;同时,Ni~(2+)和总磷的去除率分别达到99.72%和91.88%。当沸石量为8g/100mL、pH值为7、反应时间为60min时,氨氮的去除率为86.30%。 相似文献
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电渗析法再生化学镀镍老化液的实验研究 总被引:4,自引:0,他引:4
应用电渗析技术,再生化学镀镍老化液以降低镀液成本,减少环境污染。在采用非均相离子交换膜条件下,考察了4种工艺条件对电渗析的选择去除效果的影响,得出了优化工艺条件,在去除副产物的同时限制了有效物质的流失。 相似文献
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实验探讨了微电解法处理高浓度电镀废水的效果,考察了pH值、铁炭比、铁炭总投加量和反应时间对镍去除率的影响。实验得出的最佳反应条件为:pH为3、铁投加量60 g/L、炭投加量60 g/L,反应120 min时,镍的去除率可达64.09%,较好的降低了废水中Ni2+的含量,为后续处理奠定了基础。 相似文献
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Ganesh Skandan Nick Glumac Yi-Jia Chen Fredric Cosandey Eric Heims Bernard H. Kear 《Journal of the American Ceramic Society》1998,81(10):2753-2756
The influence of electroless nickel plating on lead-based relaxor ferroelectric multilayer ceramic capacitors (MLCs) was studied by a comparison experiment. It was found that the influence is related to reactions in the electroless plating. It is proposed that adsorbed hydrogen atoms generated in electroless plating can diffuse into the ceramic bodies of MLCs and undergo some reduction reaction with them, resulting in the failure of electroless nickel plating. The implications for the negative influence of electroplating on MLCs and for the degradation in MLCs are also included, in which much attention is paid to the reduction reaction of hydrogen atoms generated by electrolysis of water. 相似文献
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Wanping Chen Longtu Li Jianquan Qi Yu Wang Zhilun Gui 《Journal of the American Ceramic Society》1998,81(10):2751-2752
The influence of electroless nickel plating on lead-based relaxor ferroelectric multilayer ceramic capacitors (MLCs) was studied by a comparison experiment. It was found that the influence is related to reactions in the electroless plating. It is proposed that adsorbed hydrogen atoms generated in electroless plating can diffuse into the ceramic bodies of MLCs and undergo some reduction reaction with them, resulting in the failure of electroless nickel plating. The implications for the negative influence of electroplating on MLCs and for the degradation in MLCs are also included, in which much attention is paid to the reduction reaction of hydrogen atoms generated by electrolysis of water. 相似文献
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硫脲稳定化学镀镍的机理 总被引:3,自引:0,他引:3
测定了硫脲对镍的沉积速度和氢的析出量的影响。结果表明,一定量的硫脲(大于3mg/L)可同时抑制镍的沉积和氢的析出,用电化学方法研究了化学镀镍液的电化学行为。并借助XPS对化学镀镍层进行了分析。提出了硫脲稳定化学镀镍的机理。 相似文献