A new S-shaped MEMS PZT cantilever for energy harvesting from low frequency vibrations below 30 Hz

In this paper, a new S-shaped piezoelectric PZT cantilever is microfabricated for scavenging vibration energy at low frequencies (<30 Hz) and low accelerations (<0.4g). The maximum voltage and normalized power are 42 mV and 0.31 μW g ⁻², respectively, at input acceleration of 0.06g. For acceleration above 0.06g, the vibration of PZT cantilever changes from a linear oscillation to a nonlinear impact oscillation due to the displacement constraint introduced by a mechanical stopper. Based on theoretical modeling and experimental results, the frequency broadening effect of the PZT cantilever is studied with varying stop distances and input accelerations. The operation bandwidth of the piezoelectric PZT cantilever is able to extend from 3.4 to 11.1 Hz as the stop distance reduces from 1.7 to 0.7 mm for an acceleration of 0.3g, at the expense of the voltage and normalized power at resonance decreasing from 40 to 16 mV and from 17.8 to 2.8 nW g⁻², respectively.     

Molecular valve consisting of poly(acrylic acid) gel

A molecular valve, consisting of poly(acrylic acid) gel-coated Au mesh, was developed based on volume change of the gel in response to cation concentration. The valve closed when concentration of cations such as H⁺, Na⁺, K⁺, Ca²⁺, Cu²⁺, or Al³⁺ was low, whereas opened upon increase in its concentration. The valve re-closed when water was flowed. The concentration where the valve opens was found to increase in the order of Al³⁺, Ca²⁺, and Na⁺ (2 × 10⁻⁴, 5 × 10⁻⁴, and 6 × 10⁻³ M, respectively). The response to Cu²⁺ ion showed similar behaviour, but the opening concentration was ca. 2 × 10⁻⁴ M, which is lower than that of Ca²⁺ ion. The valve appeared to close over the pH range from 3 to 12, whereas to open below and above it. The fastest response time to open the valve (less than 1 min) was obtained for a solution of pH 1–2. The valve showed repeatability at least 25 cycles upon successive loading of a solution of pH 2 and water. Effects of anions and pressure were also studied.     

A novel microbial biosensor based on Circinella sp. modified carbon paste electrode and its voltammetric application

Microbial biosensors have been developed for voltammetric determination of various substances. This paper describes the development of a new biosorption based microbial biosensor for determination of Cu²⁺. The developed biosensor is based on carbon paste electrode consisting of whole cells of Circinella sp. Cu²⁺ was preconcentrated on the electrode surface at open circuit and then cathodically detected with the reduction of Cu²⁺. The voltammetric responses were evaluated with respect to percentage cell loading in the carbon paste, preconcentration time, pH of preconcentration solution, scan rate and interferences. The optimum response was realized by biosensor constructed using 5 mg of dry cell weight per 100 mg of carbon paste in pH 5.5 preconcentration solution. Under the optimum experimental conditions, the developed microbial biosensor exhibited an excellent current response to Cu²⁺ over a linear range from 5.0 × 10⁻⁷ to 1.0 × 10⁻⁵ M (r² = 0.9938) with a detection limit of 5.4 × 10⁻⁸ M (S/N = 3). The microbial biosensor had good sensitivity and reproducibility (R.S.D. 4.3%, n = 6). Finally, the applicability of the proposed microbial biosensor to voltammetric determination of Cu²⁺ in real sample was also demonstrated and validated with atomic absorption spectrophotometric (AAS) method.     

Automatic detection of Salmonella enterica in sprout irrigation water using a nucleic acid sensor

A nucleic acid sensor capable of automated sample and reagent loading, real-time PCR, automated detection, and sample line cleaning was tested. Real-time PCR reactions were performed with Salmonella enterica in autoclaved and spent alfalfa sprout irrigation water. S. enterica boiled cells were detected over a range of approximately 10⁴ to 10⁸ CFU/reaction (rxn). It was possible to generate enough PCR product to visualize a band on a gel at the expected size over approximately five orders of magnitude from 3.2 × 10³ to 10⁸ CFU/rxn. Automated detection experiments yielded correct identification of 9/9 positive control reactions over a range of 10⁴ to 10⁸ CFU/rxn, correctly identified a negative control reaction, and a sample of 3.2 × 10³ CFU/rxn was incorrectly identified as negative. Primer dimers were not seen in positive or negative control reactions with sprout irrigation water, suggesting that it may be possible to improve the detection limit simply by increasing the number of thermal cycles or by lowering the annealing temperature. The system required no interpretation of real-time PCR data by the operator. The entire process of loading, running the PCR, automated data interpretation, and sample line cleaning was completed in under 2 h and 20 min, significantly faster than it would take to ship a sample and have it tested by an independent laboratory.     

Electrochemical sensor for hydroperoxides determination based on Prussian blue film modified electrode

An electrochemical sensor for hydroperoxides determination was investigated. The sensor was based on the electrocatalytic reduction of hydroperoxides on Prussian blue (PB)-modified glassy carbon electrode. The modified electrode possesses a high electrocatalytic effect towards all studied peroxides with the highest effect obtained with H₂O₂ followed by tert-butyl hydroperoxide (TBH), cumene hydroperoxide (CH) and linoleic acid hydroperoxide (LAH). In addition, the modified electrode showed a good stability and a fast response time (<20 s). The lower detection limits of H₂O₂, TBH, CH and LAH were found to be 10⁻⁷ mol L⁻¹, 2 × 10⁻⁷ mol L⁻¹, 3.5 × 10⁻⁷ mol L⁻¹ and 4 × 10⁻⁷ mol L⁻¹, respectively. The electrochemical sensor was then applied for amperometric determination of peroxide value (PV) in edible oil at an applied potential of 50 mV (vs. Ag/AgCl (1 M KCl)). A good linearity has been found in the range 0.02–1.0 mequiv. O₂/kg, with a detection limit (S/N = 3) of 0.001 mequiv. O₂/kg. The precision of the method (R.S.D., n = 9) for within and between-days is better than 1.9% and 2.7%, respectively at 0.1 mequiv. O₂/kg. The method was successfully applied to the determination of PV in real edible oil samples with an excellent agreement with results obtained with the official standard procedure. The proposed method is accurate, simple, cheap and could be used to control edible oil rancidity with a high sample throughputs (more than 120 samples/h).     

Application of carbon ionic liquid electrode for the electrooxidative determination of catechol

A carbon ionic liquid electrode (CILE) was constructed using graphite powder mixed with N-butylpyridinium hexafluorophosphate (BPPF₆) in place of paraffin as the binder, which showed strong electrocatalytic activity to the direct oxidation of catechol. In pH 3.0 phosphate buffer solution (PBS) a pair of redox peaks appeared on the CILE with the anodic and the cathodic peak potential located at 387 and 330 mV (vs. SCE), respectively. The electrochemical behaviors of catechol on the CILE were carefully investigated, and the electrochemical parameters were calculated with the results of the electrode reaction standard rate constant k_s as 1.27 s⁻¹, the charge-transfer coefficient α as 0.58 and the electron transferred number n as 2. Under the selected conditions, the anodic peak current increased linearly with the catechol concentration over the range from 1.0 × 10⁻⁶ to 8.0 × 10⁻⁴ mol L⁻¹ by cyclic voltammetry at the scan rate of 100 mV s⁻¹. The detection limit was calculated as 6.0 × 10⁻⁷ mol L⁻¹ (3σ). The CILE showed good ability to separate the electrochemical responses of catechol and ascorbic acid (AA) with the anodic peak potential separation as 252 mV (vs. SCE). The proposed method was further applied to the synthetic samples determination with satisfactory results.     

Design and fabrication of a capacitive infrared detector with a floating electrode and thermally isolatable bimorph legs

A new capacitive infrared detector structure that incorporates one electrically floated top electrode that acts as an infrared absorber and two bottom electrodes is proposed and fabricated. The concept begins from an attempt to remove metal lines, the main heat transfer media in the thermal-type infrared detector, from the device's thermal insulation section. A thermal insulation section can be composed without metal lines and instead be solely comprised of an insulator having very low thermal conductivity compared to metals. Therefore, low thermal conductance can be easily achieved with small dimensions of thermal insulation section material. The floating electrode is electrically disconnected from the substrate. Instead, the capacitance change is read only using the two bottom electrodes, which are separated from the absorber and placed on the substrate. The position of the top electrode (infrared absorber) is changed through a bimorph actuation in accordance with the absorption of LWIR (8–12 μm) rays, with an absorptance of 70%. This approach provides an enlarged fill-factor (25%) compared with earlier devices, because the portion of the leg in the pixel area is reduced, whereas the portion of the absorber area is increased. With the small dimension of the thermal insulation section (0.2 × 2 × 10 μm³), thermal conductance of 1.27 × 10⁻⁷ W/K is achieved. In addition, the shortened leg lends the device a higher spring constant relative to the conventional devices, and therefore a higher signal reading voltage can be achieved, resulting in increased temperature responsivity. With the bimorph-type infrared detector's characteristics of low noise and high sensitivity, the proposed structure can achieve a low NETD value of 12.7 mK.     

An investigation of dielectric material selection of RF-MEMS switches using Ashby’s methodology for RF applications

This paper presents a dielectric material selection methodology for RF-MEMS switch used for radio frequency applications. Here Ashby’s material selection approach is used to optimize the performance indices of RF-MEMS switch such as dielectric charging, stability, hold down voltage and RF performance. In this work, dielectric constant (ɛ _r), electrical resistivity (ρ), thermal conductivity (λ), thermal expansion coefficient (α), Young’s Modulus (E) are chosen as material indices of dielectric layer in RF-MEMS switch to evaluate the various performance indices. The Ashby’s material selection charts shows that Al₂O₃ and SiN are the best suitable material for dielectric layer in RF-MEMS switches to exhibit improved performance for radio frequency applications.

     

Electrochemical DNA biosensor for the detection of interaction between di[azino-di(5,6-azafluorene)-κ-NN′]dichlormanganous and DNA

A new Mn(II) complex of MnL₂Cl₂ (L = azino-di(5,6-azafluorene)-κ²-NN′) was synthesized and utilized as an electrochemical indicator for the determination of hepatitis B virus (HBV) based on its interaction with MnL₂Cl₂. The electrochemical behavior of interaction of MnL₂Cl₂ with salmon sperm DNA was investigated on glassy carbon electrode (GCE). In the presence of salmon sperm DNA, the peak current of [MnL₂]²⁺ was decreased and the peak potential was shifted positively without appearance of new peaks. The binding ratio between [MnL₂]²⁺ and salmon sperm DNA was calculated to be 2:1 and the binding constant was 3.72 × 10⁸ mol² L⁻². The extent of hybridization was evaluated on the basis of the difference between signals of [MnL₂]²⁺ with probe DNA before and after hybridization with complementary sequence. Control experiments performed with non-complementary and mismatch sequence demonstrated the good selectivity of the biosensor. With this approach, a sequence of the HBV could be quantified over the range from 1.76 × 10⁻⁸ to 1.07 × 10⁻⁶ mol L⁻¹, with a linear correlation of r = 0.9904 and a detection limit of 6.80 × 10⁻⁹ mol L⁻¹. Additionally, the binding mechanism was preliminarily discussed. The mode of interaction between MnL₂Cl₂ and DNA was found to be primary intercalation binding.     

Detection of Escherichia coli using CMOS array photo sensor-based enzyme biochip detection system

This work presents optical enzyme detection system based on the CMOS array photo sensor and 1 × 3 polymeric enzyme biochip for detecting Escherichia coli in a one-step procedure. This assay, using 4-methylumbelliferyl-β-d-glucuronide (MUG) as a fluorogenic substrate, had a detection limit of 0.1 U/ml for β-glucuronidase (GUD), which was approximately equal to a cell concentration of 10⁶ CFU/ml of E. coli. MUG was incorporated into lauryl tryptose broth at a final concentration of 100 μg/ml for immediate verification of the presence of E. coli in 1 × 3 polymeric enzyme biochip. The 40 strains of E. coli studied all produced GUD. Of another 36 strains of bacteria tested, one strain (Salmonella choleraesuis subsp. choleraesuis) yielded very small amounts of GUD after 24 h incubation. The optical enzyme detection system was sensitive and rapid.     

Dynamic simulation of a contact-enhanced MEMS inertial switch in Simulink?

A novel contact-enhanced design of MEMS (micro-electro-mechanical system) inertial switch was proposed and modeled in Simulink^?. The contact effect is improved by an easily realized modification on the traditional design, i.e. introducing a movable contact point between the movable electrode (proof mass) and the stationary electrode, therefore forming a dual mass-spring system. The focus of this paper is limited to a vertically driven unidirectional one for the purposes of demonstration, but this design concept and Simulink^? model is universal for various kinds of inertial micro-switches. The dynamic simulation confirmed the contact-enhancing mechanism, showing that the switch-on time can be prolonged for the dynamic shock acceleration and the bouncing effect can be reduced for the quasi-static acceleration. The threshold acceleration of the inertial switch is determined by the proof mass-spring system’s natural frequency. Since the inertial switches were fabricated by the multilayer electroplating technology, the proof mass thickness were assigned two values, 100 and 50 μm, in order to get threshold levels of 56 and 133 g respectively for the dynamic acceleration of half-sine wave with 1 ms duration. Other factors that influence the dynamic response, such as the squeeze film damping and the contact point-spring system’s natural frequency were also discussed. The fabricated devices were characterized by the drop hammer experiment, and the results were in agreement with the simulation predictions. The switch-on time was prolonged to over 50 μs from the traditional design’s 10 μs, and could reach as long as 120 μs. Finally, alternative device configurations of the contact-enhancing mechanism were presented, including a laterally driven bidirectional inertial switch and a multidirectional one.     

Micromachined PZT cantilever based on SOI structure for low frequency vibration energy harvesting

A PZT piezoelectric cantilever with a micromachined Si proof mass is designed and fabricated for a low frequency vibration energy harvesting application. The SiO₂ layer in the SOI wafer promotes accurate control of the silicon thickness that is used as a supporting layer in the cantilever beam structure. The entire effective volume of the fabricated device is about 0.7690 mm³. When excited at 0.75g (g = 9.81 m/s²) acceleration amplitude at its resonant frequency of 183.8 Hz, the AC output measured across a resistive load of 16 kΩ connecting to the device in parallel has an amplitude of 101 mV. The average power and power density determined by the same measurement conditions are, respectively, 0.32 μW and 416 μW/cm³.     

RF-MEMS for 5G applications: a reconfigurable 8-bit power attenuator working up to 110 GHz. Part 1: design concept,technology and working principles

RF-MEMS technology is indicated as a key enabling solution to realise the high-performance and highly-reconfigurable passive components that future 5G communication standards will demand for. In this work, a novel design concept of an 8-bit reconfigurable power attenuator manufactured in the RF-MEMS technology available at the CMM-FBK, in Italy, is tested and discussed. In the current Part 1 of the contribution, the RF-MEMS power attenuator design concept is discussed. The device features electrostatically controlled MEMS ohmic switches, in order to select/deselect resistive loads (both in series and shunt configuration) that attenuate the RF signal, and comprises eight cascaded stages (i.e. 8-bit), thus implementing 256 different network configurations. In Part 2 of the article, fabricated samples are measured (S-parameters) from 10 MHz to 110 GHz in a wide range of different configurations, and modelled/simulated in with a Finite Element Method software tool. Despite the attenuator complexity, the simulation approach leads to accurate prediction of the experimental behaviour. The device exhibits attenuation levels (S21) in the range from − 10 to − 60 dB, up to 110 GHz. In particular, the S21 shows flatness from 15 dB down to 3–5 dB, from 10 MHz to 50 GHz, while less linear traces up to 110 GHz. A comprehensive discussion is developed around the voltage standing wave ratio, employed as quality indicator for the attenuation levels. Finally, margins of improvement at design level are also discussed, in order to overcome the limitations of the presented RF-MEMS device.

     

The reduction of driving voltage in organic light-emitting devices by inserting step barrier layer

The electron injection and transport in OLEDs have been improved by using a tris-[8-hydroxyquinoline] gallium (Gaq) layer as step barrier between tris-[8-hydroxyquinoline]aluminum (Alq₃) (or 4,7-diphyenyl-1,10-phenanthroline (Bphen)) and 2-t-butyl-9,10-di-(2-naphthyl)anthracene (TBADN). Since the LUMO (lowest unoccupied molecular orbital) of Gaq (2.9 eV) lies in between that of Alq₃ (3.1 eV) (or Bphen (3.0 eV)) and TBADN (2.8 eV), step barrier from Alq₃ (or BPhen) though Gaq to TBADN can be formed. The experimental results indicate that the J–V characteristics of both the electron-only and the complete devices show the increase of the current density in devices with step barrier compared with the devices without step barrier. For electron-only devices, the driving voltage at the current density of 20 mA/cm² is reduced from 7.9 V to 4.9 V for devices with Alq₃, and from 4.2 V to 3.1 V for devices with BPhen, respectively, owing to the introduction of step barrier. For the complete devices, when Gaq step barrier is introduced, at 20 mA/cm², the driving voltage is reduced from 7 V to 5.8 V for devices with Alq₃ and from 6.2 V to 5.1 V for devices with BPhen. It has also been observed that for devices with step barrier layer, the luminance at 200 mA/cm² is increased from 1992 cd/m² to 3281 cd/m² for device with Alq₃, and from 1745 cd/m² to 2876 cd/m² for devices with BPhen, respectively. The highest luminance reaches 3420 cd/m² in devices with Alq₃ as ETL and 3176 cd/m² in devices with BPhen as ETL after the introduction of step barrier. The phenomena are explained by using tunnel theory.     

Direct amperometric determination of l-ascorbic acid (Vitamin C) at octacyanomolybdate-doped-poly(4-vinylpyridine) modified electrode in fruit juice and pharmaceuticals

The glassy carbon electrode (GCE) modified with Mo(CN)₈⁴⁻-incorporated-poly(4-vinylpyridine) (PVP/Mo(CN)₈⁴⁻), which has been recently shown to possess several attractive attributes as an efficient electrocatalytic electrode for l-ascorbic acid oxidation and its estimation, is used for l-ascorbic acid estimation directly in orange fruit juice and Celin tablet in a 0.1 M H₂SO₄ acid solution without any special treatment. Constant potential amperometry at 570 mV (saturated calomel electrode, SCE) in stirred solutions is used for this purpose. A good correlation is attained with the official titrametric method. To understand the possible electrocatalytic reaction mechanism for the electro-oxidation of l-ascorbic acid, calibration graphs over the range 1 × 10⁻⁵ to 1 × 10⁻² mol dm⁻³ l-ascorbic acid are compared for the three electrodes, ca. PVP/Mo(CN)₈⁴⁻, undoped PVP, and GCE; the curvature at high ascorbic acid concentration for the PVP/Mo(CN)₈⁴⁻ electrode is explained in terms of Michaelis–Menten (MM) saturation kinetics. The apparent MM constant (K_M), the maximum catalytic current (i_M), the complex decomposition rate constant (k_c), and the heterogeneous modified electrode rate constant (k^′_ME) are calculated from three different approaches. A reasonably high value of ≈1 × 10⁻² cm s⁻¹ is obtained for k^′_ME, indicating efficient l-ascorbic acid mediation at the PVP/Mo(CN)₈⁴⁻ electrode, thus accounting for quite a high sensitivity of this modified film electrode compared to several other modified electrodes.     

Numerical simulation of cloud droplet formation in a tank

Using the computational fluid dynamics (CFD) code FLUENT 6 together with the fine particle model (FPM), numerical simulations of droplet dynamics in a 12.4 m³ cloud tank were conducted. The coupled fields of water vapor, temperature, flow velocity, particle number concentration, and particle mass concentration inside the cloud tank were computed.The system responses to changes of the wall's temperature and mass fraction of water vapor, respectively, were investigated. Typical times for mixing the cloud tank's contents are in the range of some tens of seconds. The maximum volume-averaged deviations from the mean of temperature and mass fraction of water vapor are around 5% of the respective parameter changes applied to the wall.Time-dependent simulations were performed in order to study the growth of ammonium-sulfate particles in humid air at around room temperature. Supersaturation up to (S_w–1)=8.2×10⁻³ was achieved by the expansion of the gas. The particles were activated and grew rapidly to a maximum diameter of 5.2×10⁻⁶ m after critical supersaturation was reached. After S_w fell again below the equilibrium value, the particles shrank quickly and deactivated roughly 60 s after activation.The spatial inhomogeneities of temperature and water-vapor concentration cause volume-averaged deviations of the particle number N and diameter d_g of up to 2.3% and 36%, respectively.     

A sensitive and selective sensor for dopamine determination based on a molecularly imprinted electropolymer of o-aminophenol

A simple and reliable method was proposed for preparing a selective dopamine (DA) sensor based on a molecularly imprinted electropolymer of o-aminophenol. The sensor is selective for the determination of DA in the presence of high concentrations of ascorbic acid (AA), with a maximum molar ratio of 1/1000. The molecular imprinted (MIP) sensor was tested by cyclic voltammetry (CV) as well as differential pulse voltammetry (DPV) to verify the changes in oxidative currents of ferricyanide. In optimized conditions, DA at concentrations of 2 × 10⁻⁸ to 0.25 × 10⁻⁶ mol/L could be determined with a detection limit of 1.98 × 10⁻⁹ mol/L (S/N = 3). The MIP sensor showed high selectivity, sensitivity, and reproducibility. Determination of DA in simulated samples of dopamine hydrochloride showed good recovery.     

Anodic stripping voltammetric determination of copper(II) using a functionalized carbon nanotubes paste electrode modified with crosslinked chitosan

The development and application of a functionalized carbon nanotubes paste electrode (CNPE) modified with crosslinked chitosan for determination of Cu(II) in industrial wastewater, natural water and human urine samples by linear scan anodic stripping voltammetry (LSASV) are described. Different electrodes were constructed using chitosan and chitosan crosslinked with glutaraldehyde (CTS-GA) and epichlorohydrin (CTS-ECH). The best voltammetric response for Cu(II) was obtained with a paste composition of 65% (m/m) of functionalized carbon nanotubes, 15% (m/m) of CTS-ECH, and 20% (m/m) of mineral oil using a solution of 0.05 mol L⁻¹ KNO₃ with pH adjusted to 2.25 with HNO₃, an accumulation potential of −0.3 V vs. Ag/AgCl (3.0 mol L⁻¹ KCl) for 300 s and a scan rate of 100 mV s⁻¹. Under these optimal experimental conditions, the voltammetric response was linearly dependent on the Cu(II) concentration in the range from 7.90 × 10⁻⁸ to 1.60 × 10⁻⁵ mol L⁻¹ with a detection limit of 1.00 × 10⁻⁸ mol L⁻¹. The samples analyses were evaluated using the proposed sensor and a good recovery of Cu(II) was obtained with results in the range from 98.0% to 104%. The analysis of industrial wastewater, natural water and human urine samples obtained using the proposed CNPE modified with CTS-ECH electrode and those obtained using a comparative method are in agreement at the 95% confidence level.     

Analysis of interface states of metal–insulator–semiconductor photodiode with n-type silicon by conductance technique

A metal–insulator–semiconductor photodiode (MIS-PD) as active layer with n-type silicon as interdigitated Schottky electrodes has been fabricated. The current–voltage characteristics, density of interface states and photovoltaic properties of the MIS-PD diode have been investigated. The diode has a metal–insulator–semiconductor configuration with ideality factor higher than unity. The electronic parameters (ideality factor, series resistance and barrier height) of the diode were found to be 1.94, 2.23 × 10⁴ Ω and 0.74, respectively. At voltages between 0.13 and 0.50 V, the charge transport mechanism of the diode is controlled by space charge-limited current mechanism. The interface state density of the diode was found to vary from 5.54 × 10¹² to 5.67 × 10¹² eV⁻¹ cm⁻² with bias voltage. The Au/SiO₂/n-Si/Al device shows a photovoltaic behavior with a maximum open circuit voltage V_oc of 97.7 mV and short-circuit current I_sc of 17.4 μA under lower illumination intensities. The obtained electronic parameters confirm that the Au/SiO₂/n-Si/Al diode is a MIS type photodiode.     

Research on Fractional Critical Covered Graphs

A graph G is called a fractional (g, f)-covered graph if for any e ∈ E(G), G admits a fractional (g, f)-factor covering e. A graph G is called a fractional (g, f, n)-critical covered graph if for any S ? V(G) with ∣S∣ = n, G ? S is a fractional (g, f)-covered graph. A fractional (g, f, n)-critical covered graph is said to be a fractional (a, b, n)-critical covered graph if g(x) = a and f(x) = b for every x ∈ V(G). A fractional (a, b, n)-critical covered graph was first defined and studied in [1]. In this article, we investigate fractional (g, f, n)-critical covered graphs and present a binding number condition for the existence of fractional (g, f, n)-critical covered graphs, which is an improvement and generalization of a previous result obtained in [2].