高氮奥氏体中温转变过程的研究

研究含氮量在(2．6—2．7)％wt范围的过饱和高氮奥氏体225℃中温转变过程中发现，Fe—N中温转变与Fe-C系中温贝氏体转变有明显不同。高氮奥氏体在225℃等温时首先析出γ‘‘-Fe4N，γ-Fe（N）与γ‘‘-Fe4N的亚稳定组织，等温1-2h后在含氮量降低的奥氏体中形成α-Fe,8-10h后分解成α-Fe,8-10h后分解成（α-Fe γ‘‘-Fe4N）的两相稳定组织，显微硬度最高可达l100HV0．025。分解后的两相组织品粒细小，使衍射蜂宽化，扫描电镜观察以及X-ray衍射分析表明：分解产物随等温时间延长粗化不明显。     

中温处理对FeCrAl合金力学性能的影响

含１５％～２５％Ｃｒ,４％～５％Ａｌ的ＦｅＣｒＡｌ合金在４００～５００℃时效后发生了４７５℃脆化,处理温度高于９００℃时发生高温脆化,但在中温（５４０～９００℃）处理后能获得较高的塑性和较低的硬度,σ相脆化的发展不明显,中温处理还能部分消除合金中已经产生了４７５℃的脆性和高温脆性,含０．２％～０．４％Ｙ的ＦｅＣｒＡｌ合金有很宽的高塑性区（５００～１３００℃）高温脆化几乎不发生,４７５℃脆化的发展缓     

高氮奥氏体特殊中温转变现象的初步观察

介绍了在含氮量接近质量分数２．８％的高氮奥氏体中出现的一种特殊的中温转变现象。在奥氏休晶界和晶内萌生细小的分解核心连成一片,在核心内可以看更细小的析出物,随后分解核心长大十分缓慢而核心的数量不断增加,最终各个细小的核心连成一片,形成高度弥散的分解产物,在共上分布着大量细小析出物,明显不同于马氏体或下体或下贝氏体的针片状组织。分解产物的硬度高达９００Ｖ左右,明显高于回火马氏体的硬度。这种高氮奥氏体的     

中温处理对FeCrAl合金力学性能的影响

含１５％～２５％Ｃｒ,４％～５％Ａｌ的ＦｅＣｒＡｌ合金在４００～５００℃时效后发生４７５℃脆化,处理温度高于９００℃时发生高温脆化,但在中温（５４０～９００℃）处理后能获得较高的塑性和较低的硬度,σ相脆化的发展不明显。中温处理还能部分消除合金中已经产生４７５℃的脆性和高温脆性。含０２％～０４％Ｙ的ＦｅＣｒＡｌＹ合金有很宽的高塑性区（５００～１３００℃）,高温脆化几乎不发生,４７５℃脆化的发展缓慢。已经产生的４７５℃脆性在５００～５６０℃处理后完全消除。钇的这些作用与合金中碳原子被ＹＦｅ相质点俘获、不发生碳化物析出过程有关。     

典型冷作模具钢经强化奥氏体化后的过冷奥氏体中温转变研究

研究了典型冷作模具钢65Cr4W3Mo2VNb、Cr7Mo3V2Si和Cr12MoV经强韧化奧氏体化后的过冷奥氏体中温转变。测定了其中温转变TTT曲线,求出了强韧化奥氏体化后钢中基体含碳量,得出了奥氏体化温度和中温转变等温温度对下贝氏体组织的影响以及中温转变等温时间对下贝氏体量的影响规律,还得出了部分低温转变对随后中温转变下贝氏体形成孕育期和下贝氏体组织的影响特点,包括连续冷却和等温马氏体转变的影响规律。     

ZA27合金等温转变动力学研究

利用所设计的热效应装置研究了ＺＡ２７合金等温转变动力学,结果发现：合金等温动力学转变曲线呈Ｃ曲线;淬火时效早期发生了ｓｐｉｎｏｄａｌ分解。     

新型中温金基钎料研究

研究了一种微电子器件高温封装用Au-In共晶型中温金基钎料合金,钎料由77%~75%Au和23%~25%In(质量分数)构成,规格为0.03~0.10?,钎料箔带材是采用多层叠加轧制方法制造的。实验结果表明,在保护气氛下,500~520℃无钎剂钎焊,钎料对镀金可伐合金和无氧铜、纯镍、纯银等多种母材具有优良的漫流性和间隙填充性,钎焊接头牢固、钎料箔带材塑性高,应用工艺性能良好。     

配位剂对黄铜中温化学镀 Ni-P 合金镀层的影响

为解决传统高温化学镀镍所存在的诸多问题,在中温(70℃)酸性条件下,以硫酸镍为主盐,次磷酸钠为还原剂,乙酸钠为缓冲剂,就乳酸、冰乙酸及二者复合的配位剂对黄铜中温化学镀Ni-P合金镀层性能的影响进行了研究.结果表明:复合配位剂中的乳酸主要起配位剂的作用,冰乙酸主要起缓冲剂的作用;采用复合配位剂的镀液的沉积速率与采用单一配...     

高氮奥氏体中温转变高硬度的显微组织及其表征

通过对0．1mm厚的纯铁片在640~650℃气体渗氮的方法制备含氮量均匀的单一高氮奥氏体，其含氮量约为2．7wt．％。利用光学显微镜、X射线衍射和透射电子显微镜研究了高氮奥氏体中温转变后的显微组织，初步确定了高氮奥氏体中温转变产生高硬度的原因是由于晶内纳米级7＇-Fe4N相的析出后，在晶内形成（α-Fe＋γ/γ＇-Fe4N）微纳级的晶粒，由这些微纳米颗粒引起的显微晶界强化是高氮奥氏体中温转变组织具超过常规时效强化的高硬度。     

INVESTIGATION ON LATER STAGE OF INTERMEDIATE TRANSFORMATION IN Fe-C-Mo ALLOYS

The transformation process and the products of long term isothermal transformation aroundthe kinetic B_s temperature(the bay temperature in TTT diagram)in Fe-C-Mo alloys havebeen investigated.It was found that,at the final stage of intermediate transformation,a kindof granular structure formed accompanying the growth of bainitic ferrite.In comparison withthe carbide Mo_2C in the bainitic ferrite plates or blocks,the carbide m granular eutectoid hasbeen determined to be cementite containing a tiny bit of molvbdenum,(Fe,Mo)_3C.     

金属间化合物对高温合金强化机理的研究

研究了金属间化合物对高温合金材料的强化作用,在CrWMoV合金中添加Al和Ni可以形成Ni-Al,Fe-Al和W－Al系等金属间化合物,在合金中起到弥散强化作用和抗氧化作用,能提高合金的高温强度和冲击韧性,实验发现以2％Al的添加为最佳。     

Fe—Mn—C合金奥氏体强化对马氏体相变的影响

测定了5种Fe-Mn-C合金的M_s温度及奥氏体在M_s温度时的屈服强度,结果表明两者成线性关系。还研究了奥氏体固溶强化对马氏体形态的影响,提出存在一个奥氏体强化特征温度T_c,当M_s>T_c时,马氏体形态主要为位错型条状马氏体,当M_s相似文献   

INFLUENCE OF AUSTENITE STRENGTHENING ON MARTENSITIC TRANSFORMATION IN Fe-Mn-C ALLOYS

The M_s temperature and the yield strength of austenite at M_s temperature have been meas-ured for five Fe-Mn-C alloys.The experimental results show that there is a linear relation-ship between them.The effect of the solution strengthening of austenite on martensitemorphology is also studied.It is pointed out that there is a characteristic temperature T_c inaustenite strengthening.Martensite morphology is mainly of dislocated laths when M_s>T_c,and is mainly of twinned plates when M_s相似文献   

NiTi合金中马氏体相变失稳与局部化的原位多场研究

采用数字图像相关(DIC)方法原位测定了NiTi形状记忆合金薄带在单轴拉伸下变形时的应变场,采用红外热成像法(IR)原位测定其温度场,并定量获得了单轴拉伸加载-卸载条件下马氏体带局部化的全场应变与温度信息.同时研究了相变带的形核、扩展、合并、缩减、分裂及消失等过程中相变带内和带外应变场、温度场、厚度场及折曲角场的变化规律.结果表明,相变应变主要集中在相变带内部,而带外应变量很小,温度场和厚度场变化主要集中在相界面移动的前端,折曲角场变化集中在相变前端且带内分布不均匀.     

EFFECT OF Zr ON PHASE TRANSFORMATION IN Cu-Zn-Al SHAPE MEMORY ALLOYS

An investigation was made of the influence of Zr additive on the high temperature phase trans-formations,martensitic forward/reverse transformations,and shape memory effect ofCu-Zn-Al base alloys by means of differential scanning calorimetry(DSC),X-raydiffraction and TEM.It was found that an addition of 0.35 wt-% Zn could effectively inhibitthe precipitation of α and γ phases and hence promote the order-martensitic transformationsβ_2→DO_3→18RM,thus resulting in a minimum activation energy of the martensitic trans-formation and narrow temperature ranges(M_s-M_f)and(A_s-A_f);the alloy so obtained pos-sessed smooth and mobile martensite intervariant interfaces,therefore showing the best shapememory effect.     

Fe—C—Si—Mn系合金贝氏体相变动力学计算

采用规则溶液模型与超组元模型计算了7种Fe—C—Si—Mn系合金的等温相变驱动力在此基础上估算了合金等温转变的相对形核率与相对孕育期。计算结果表明,不含碳的二元与三元合金,孕育期主要由相变驱动力决定;而含碳合金,相变驱动力不是相变动力学的主要控制因素,从一个侧面支持了溶质类拖曳(SDLE)理论。     

EFFECTS OF INTERSTITIAL IMPURITIES ON PHASE TRANSFORMATION OF Ti-Al ALLOYS

１ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅｔｉｔａｎｉｕｍａｌｕｍｉｎｉｄｅｃｏｍｐｏｕｎｄｓｈａｖｅｒｅｃｅｉｖｅｄｃｏｎｓｉｄｅｒａｂｌｅａｔｅｎｔｉｏｎｒｅｃｅｎｔｌｙａｓｃａｎｄｉｄａｔｅｍａｔｅｒｉａｌｓｆｏｒｒｅｌａｔｉｖｅｌｙｈｉｇｈｔｅｍ...     

THERMODYNAMICS OF MARTENSITIC TRANSFORMATION IN Fe-Mn-C AND Fe-Ni-C ALLOYS

A Central Atom Model is introduced and the LFG and Hsu models are modified in order toevaluate the driving force for the martensitic transformation in Fe-Mn-C and Fe-Ni-C al-loys.The results show that the relationship between the driving force and the yield strength ofaustenite at Ms temperature,σ_(0.2)~γ/M_s,fits Hsu's formula;ΔG~=2.1σ_(0.2)~γ/M_s+907J/mol.The M_s temperatures of Fe-Mn-C and Fe-Ni-C alloys are also calculated.Thecalculated results are in good agreement with experimental values.     

THERMODYNAMICS OF MARTENSITIC TRANSFORMATION IN β-Cu BASE ALLOYS

An approach for the thermodynamics of the thermoelastic martensitic transformation in β-Cu base alloys is suggested.Driving forces for martensitic transformation,T_0 and M_s tempera- tures in Cu-Zn,Cu-Al and Cu-Zn-Al alloys were calculated and the calculated M_s are in good agreement with the experimental ones.Ordering of the parent phase lowers M_s(T_0)in Cu-Zn and Cu-Zn-Al alloys,but raises M_s(T_0)in Cu-Al alloys.Two methods for the es- timation of the critical driving force for the thermoelastic martensitic transformation are also introduced.