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Zhichao Yu Chonghe Xu Kangkang Yuan Xinzhu Gan Haifeng Zhou Xinqiang Wang Luyi Zhu Guanghui Zhang Dong Xu 《Ceramics International》2018,44(8):9454-9462
MgO mesoporous nanofibers were obtained by a template-free electrospinning method. The unique bumpy-structure was obtained on the surface of nanofibers that could enhance the surface area and provide more active sites for adsorption. The formation mechanism of the bumpy-structure has been investigated. The as-prepared MgO nanofibers with a high surface area of 194.17?m2 g?1 exhibited excellent adsorption capacities for fluoride of 237.49?mg?g?1. Furthermore, the MgO nanofibers showed selective adsorption for different organic dyes and have superior adsorption capacity for Congo red (4802.27?mg?g?1). The adsorption processes for both fluoride and Congo red were systematically investigated, which were found to follow the pseudo-second-order kinetic model. By comparison with the reported fabrication routes and adsorption capacities of mesoporous MgO, the synthesis process is simple, controllable and template-free, and the superior adsorption performance provided a potential adsorbent for the removal of fluoride and Congo red in wastewater treatment. The high surface area of the MgO mesoporous nanofibers might also promote its application in basic catalysis and other fields. 相似文献
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Mesoporous MgO architectures were successfully synthesized by the direct thermal transformation of the sacrificial oxalate template. The as-prepared mesoporous architectures were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM), transmission electron microscopy (TEM), X-ray energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FTIR), and nitrogen adsorption-desorption techniques. The MgO architectures showed extraordinary adsorption capacity and rapid adsorption rate for removal of Congo red (CR) from water. The maximum adsorption capacity of the MgO architectures toward CR reached 689.7 mg g(-1), much higher than most of the previously reported hierarchical adsorbents. The CR removal process was found to obey the Langmuir adsorption model and its kinetics followed pseudo-second-order rate equation. The superior adsorption performance of the mesoporous MgO architectures could be attributed to the unique mesoporous structure, high specific surface area as well as strong electrostatic interaction. 相似文献
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Functionalized mesoporous silica nanocomposites were synthesized via in situ radical polymerization of vinyl monomers (vinylcarbazole, vinyl imidazole and vinyl sulphonic acid) and characterized for adsorption of dyes from aqueous solution. Physicochemical characterization (PXRD, SEM, adsorption studies etc.) of the functionalized nanocomposites showed the presence of mesoporous nature of the nanocomposites. Different adsorption parameters such as adsorption weight, adsorption time, temperature, pH etc., were optimized for adsorption of dyes under environmental friendly conditions. The adsorption studies showed 96.8 and 80.49 % removal for cationic and anionic dyes respectively. Adsorption kinetics of the dyes on the functionalized nanocomposites can be well depicted theoretically by using pseudo-second-order kinetic model. 相似文献
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Kechan Xia Guoxu Wang Hongliang Zhang Lei Liu Yifeng Yu Lingli Wang Aibing Chen 《Journal of Porous Materials》2017,24(6):1605-1612
Mesoporous materials with bimodal mesopores show advantages in adsorption, energy storage, and catalysis because such unique structures are beneficial to the mass transfer. Here, we describe the synthesis of bimodal mesoporous carbon nanospheres (BMCSs) by using phenolic resin as carbon precursor, triblock copolymer Pluronic F127 as the soft template, and mesoporous silica spheres as hard templates. The BMCSs with uniform spherical morphology, high specific surface area (1489 m2 g??1), large pore volume (0.92 cm3 g??1), and bimodal mesoporous structure (3.8 and 6.8 nm) exhibit promising properties for adsorption of methyl orange (MO). The maximum adsorption capacity of the BMCSs is 5.5?×?102 ± 0.2?×?102 mg g??1, which is higher than that of many adsorbents reported. The kinetics studies show a better fit of pseudo-second-order model. Meanwhile, fitting equilibrium data show that the Langmuir model is more suitable to describe the MO adsorption than Freundlich model. 相似文献
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《Carbon》2015
A 3D cubic structure of mesoporous graphitic carbon nitride (3D-g-CN) was fabricated by nano casting using the mesoporous silica hard template KIT-6. The abundant intrinsic amine functionalities of 3D-g-CN were applied as a selective adsorbent for silver ions using the unique affinity of silver and amine functionalities. The large surface area of 3D-g-CN resulted in increased amine functionalities at the surface and enabled it to form complexes with silver ions. As a result, almost 400 mg/g of silver ion could be removed from 100 mM of initial solution at 293.15 K. The isotherm of silver ion adsorption onto 3D-g-CN was described by the Freundlich and Sips models and indicated heterogeneity of the adsorbent surface. Thermodynamic parameters determined from temperature dependent isotherms were verified by the endothermic silver ion adsorption process of 3D-g-CN. The adsorption capacity of silver ion on 3D-g-CN was maintained during several reuses without a significant decrease in capacity. Overall, the results indicate that 3D-g-CN has intrinsic amine functional groups with a large surface area and could therefore be utilized as an efficient selective adsorbent of silver ions for water purification. 相似文献
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Yuchun Jiao Li Xu Huiling Sun Yijie Deng Tao Zhang Guoji Liu 《Journal of Porous Materials》2017,24(6):1565-1574
In this work, nitrogen-doped mesoporous carbon spheres (NMCS) were synthesized through a hard template method by using benzoxazine resin as precursor and ordered mesoporous silica spheres as template. The obtained N-doped mesoporous carbons were amorphous spherical nanoparticles with worm-like mesoporous channels and possessed high surface area of 789 m2/g, large pore volume of 0.49 cm3/g and high nitrogen content of 3.50 wt.%. The adsorption capacity of methyl orange (MO) by NMCS could attain 352.1 mg/g at an optimal condition, while the adsorption capacity of MO by non-doped mesoporous carbon spheres (MCS) was 251.9 mg/g at the same condition. The adsorption process fitted the pseudo-second-order kinetic model and the Langmuir isotherm well. Thermodynamic analysis indicated that the removal of MO by NMCS was spontaneous, endothermic and feasible process. In addition, the adsorption capacity of regenerated adsorbent was 89.04% of the initial level after four regeneration cycles. 相似文献
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Nuran Böke Ziboneni G. Godongwana Leslie F. Petrik 《Journal of Porous Materials》2013,20(5):1153-1161
An ordered mesoporous carbon (OMC) was prepared by a chemical vapor deposition technique using liquid petroleum gas (LPG) as the carbon source. During synthesis, LPG was effectively adsorbed in the ordered mesopores of SBA-15 silica and converted to a graphitic carbon at 800 °C. X-ray diffraction and nitrogen adsorption/desorption data and high-resolution transmission electron microscopy (HRTEM) of the OMC confirmed its ordered mesoporous structure. The OMC was utilized as an adsorbent in the removal of dyes from aqueous solution. A commercial powder activated carbon (AC) was also investigated to obtain comparative data. The efficiency of the OMC for dye adsorption was tested using acidic dye acid orange 8 (AO8) and basic dyes methylene blue (MB) and rhodamine B (RB). The results show that adsorption was affected by the molecular size of the dye, the textural properties of carbon adsorbent and surface-dye interactions. The adsorption capacities of the OMC for acid orange 8 (AO8), methylene blue (MB) and rhodamine B (RB) were determined to be 222, 833, and 233 mg/g, respectively. The adsorption capacities of the AC for AO8, MB, and RB were determined to be 141, 313, and 185 mg/g, respectively. The OMC demonstrated to be an excellent adsorbent for the removal of MB from wastewater. 相似文献
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Journal of Porous Materials - Metal–organic frameworks (MOFs) exhibit the prominent advantages in the efficient removal of organic dyes owing to their diverse topology structure, adjustable... 相似文献
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D.P. Xu S.-H. Yoon I. Mochida W.M. Qiao Y.G. Wang L.C. Ling 《Microporous and mesoporous materials》2008,115(3):461-468
Mesoporous carbon (MC) with high surface area and large pore volume was synthesized using mesophase pitch as a carbon precursor and nanosized MgO as an additive. The maximum surface area, largest pore volume and highest mesoporous ratio of as-prepared MC were up to 1400 m2/g, 2.8 cm3/g and 89%, respectively. The mesoporous structures (3–40 nm) of MC were directly observed under SEM and TEM. The adsorption capacity and adsorption rate of MC to vitamin B12 (VB), chicken egg white albumin (CEWA) and bovine serum albumin (BSA) were proportional to the mesopore volume and average pore size. MC (PM4-OC) exhibited the maximum adsorption capacity to the typical biomolecules, 486, 140 and 176 mg/g for VB, CEWA and BSA, respectively. In contrast, Maxsorbs (commercial activated carbons) with a surprising surface area gave a very low adsorption to such biomolecules. The research indicates that MC may be potential in the selective adsorption and separation of biomolecules, based on a molecule sieve effect. 相似文献
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Ling Zhu Xiaoya Li Xiangzhao Feng Xinyue Li Xiuyan Xu 《Journal of Porous Materials》2016,23(4):957-965
In this paper, graphite carbon with a mesoporous structure was synthesized using the template–catalysis procedure with hydrated metal oxide nanoparticle as template and catalyst, phenol and formaldehyde as carbon source. XRD, Raman, BET and TEM analyses were performed to study the effluence of synthetic conditions on the structure of samples. The adsorption performances for benzene vapor were evaluated. The results show that CCo and CFe samples have mesoporous graphitized carbon structures. The molar amount of template to carbon source significantly affects the specific surface area, pore structure and adsorption–desorption performance. The specific surface area of CCo-1, with the best graphite structure, was 287.638 m2/g, the pore size was 19.075 nm, and the adsorption capacity for benzene vapor was 19.615 mmol/g. The synergistic effect between the cobalt element and graphite carbons affects the adsorption capacity of CCo-3, which was 34.643 mmol/g. However, the desorption efficiency was only 89 %, and the adsorption performance of CCo-3 material was degraded greatly after three times run. 相似文献
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Deng Xu Feng Xiaohua Li Risheng Li Rongrong Zhou Ping Li Hua 《Journal of Porous Materials》2021,28(4):1129-1136
Journal of Porous Materials - This paper investigates the influence of the structure, composition, pore size distribution and morphology of three carbon materials obtained from the explosion of... 相似文献
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《Chemical Engineering and Processing: Process Intensification》1987,22(3):145-156
Adsorption isotherms have been determined experimentally for the single-component adsorption of three dyes, namely, Basic Red 22, Basic Yellow 21, and Basic Blue 69 onto carbon. In addition, the three possible bisolute isotherms and the one trisolute isotherm for these three dyes were determined. In each case the Langmuir, Freundlich and Jossens isotherm constants were determined and the Langmuir data were then used to correlate and predict the multicomponent isotherm data from single-component data in a simplified manner. 相似文献
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《Carbon》2013
A soft-templated ordered mesoporous carbon was synthesized, impregnated with urea and pyrolyzed at 500 and 800 °C. The samples obtained were tested as NO2 adsorbents. Their structural properties and surface chemistry, before and after NO2 exposure, were investigated using nitrogen adsorption, TEM, potentiometric titration and thermal analysis. Results showed that the ordered mesoporous structure remains stable throughout the treatment applied and exposure to NO2. Even though the initial carbon exhibited a high NO2 adsorption capacity, the incorporation of nitrogen groups to the carbon surface, resulted in the further improvement of the performance after heat treatment. The mechanism of reactive adsorption was found to be significantly affected by surface chemistry of mesoporous carbons. 相似文献