A new ferritic stainless steel with improved thermo-mechanical fatigue resistance for exhaust parts

Abstract

Over the past few years, car manufacturers have been considering ever higher service temperatures for the engine in order to comply with the constraints of depollution standards. The requirements in terms of exhaust gas temperature could easily reach and overtake the limits of common stainless steel grades used for such applications in the coming years.

A new ferritic stainless steel – named K44X – with increased high temperature resistance has therefore been developed to withstand service temperature up to 1000 °C. K44X belongs to EN 1.4521 and AISI 444 classifications and is composed of approximately 19% Cr, 2%Mo and 0.6% Nb. This specific composition leads to better mechanical properties, higher creep and fatigue resistance than EN 1.4509, while keeping comparable weldability and formability. Its coefficient of thermal expansion is lower in comparison to austenitic stainless steel grades and its resistance to cyclic oxidation is improved significantly.

High-temperature properties (mechanical properties, creep, cyclic oxidation resistance, and high cycle fatigue) of K44X are presented in this paper and compared with common ferritic and austenitic stainless steels used in the hot end of exhaust lines. A thermal fatigue test – designed to reproduce exhaust manifold service conditions – has also been carried out with the highest temperatures of the cycle in the range of 850–1000 °C. The results of these thermal fatigue tests were compared with the above-mentioned stainless steels. A thermal fatigue damage criterion was then identified based on these experimental results and using a cyclic behaviour law obtained from isothermal low cycle fatigue tests.     

An energy‐based damage parameter for the life prediction of AISI 304 stainless steel subjected to mean strain

Abstract

This study extends the plastic strain energy approach to predict the fatigue life of AISI 304 stainless steel. A modified energy parameter based on the stable plastic strain energy density under tension conditions is proposed to account for the mean strain and stress effects in a low cycle fatigue regime. The fatigue life curve based on the proposed energy parameter can be obtained directly by modifying the parameters in the fatigue life curve based on the stable plastic strain energy pertaining to fully reversed cyclic loading. Hence, the proposed damage parameter provides a convenient means of evaluating fatigue life on the mean strain or stress effect. The modified energy parameter can also be used to explain the combined effect of alternating and mean strain/stress on the fatigue life. In this study, the mean strain effects on the fatigue life of AISI 304 stainless steel are examined by performing fatigue tests at different mean strain levels. The experimental results indicate that the combination of an alternating strain and a mean strain strongly influences the fatigue life. Meanwhile, it is found that the change in fatigue life is sensitive to changes in the proposed damage parameter under the condition of a constant strain amplitude at various mean strain levels. A good agreement is observed between the experimental fatigue life and the fatigue life predicted by the proposed damage parameter. The damage parameter proposed by Smith et al. (1970) is also employed to quantify the mean strain effect. The results indicate that this parameter also provides a reasonable estimate of the fatigue life of AISI 304 stainless steel. However, a simple statistical analysis confirms that the proposed damage parameter provides a better prediction of the fatigue life of AISI 304 stainless steel than the SWT parameter.     

Influence of martensite formation and grain size on room temperature low cycle fatigue behaviour of AISI 304LN austenitic stainless steel

Abstract

The effects of strain induced martensite formation and grain size on the room temperature low cycle fatigue behaviour of AISI 304LN austenitic stainless steel were considered. Two grain sizes, namely, 60 and 350 μm, were developed via suitable solution annealing treatments. Microstructural changes before and after low cycle fatigue testing were identified. The martensitic transformation was studied using aferritescope, X-ray diffractometry, and optical microscopy. The mechanical response was correlated with the microstructural changes. Secondary hardening as well as a crossover in the strain–life plots for the two grain sizes resulted from martensite formation. Dislocation configurations depended on the strains imposed.

MST/1902     

Mechanical behaviour of high-nitrogen stainless steels

Abstract

The application of previously published equations describing the dependence of proof stress on the nitrogen content of austenitic stainless steels has been validated and also extended to higher nitrogen contents in an experimental study of the mechanical property–structure relationships in Rex 734 steel. The proof stress is increased by nitrogen alloying through a combination of solid-solution hardening and a grain-size effect. The effective grain size of these steels is influenced by the nitrogen content through changes in stacking-fault energy, which Increases the density of twinning. In the analysis of tensile test data this effect appears as an increase in the grain-size coefficient of the Hall–Petch equation with increasing nitrogen concentration. Compression–tension low-cycle fatigue properties are similarly enhanced by a combination of nitrogen in solid solution and the influence of nitrogen on stacking-fault energy. An increase in the extent of planar slip is observed with increasing nitrogen content, and is most pronounced at low levels of fatigue strain. The increase in fatigue life observed at the strain levels examined reaches a limit at about 0·12 wt-%N both in AISI 316 grade steels and in Rex 734.

MST/453     

Effect of grain size on austenite stability and room temperature low cycle fatigue behaviour of solution annealed AISI 316LN austenitic stainless steel

Abstract

The present paper investigates completely reversed room temperature low cycle fatigue (LCF) behaviour of solution annealed austenitic stainless steel AISI 316L with two different grain sizes of 90 and 139 μm developed by solution annealing treatment at 1050 and 1150°C respectively and at six strain amplitudes ranging between ± 0·375 and ± 1·00%. Complete cyclic hardening has been observed for both the grain sizes. While fine grained steel shows an improvement in cyclic life compared with that of coarse grained steel for strain amplitudes ± 0·375 and ± 0·50%, and perfectly follows the Coffin–Manson (C–M) behaviour within the experimental domain, higher cyclic life with bilinear C–M behaviour is observed in the case of coarse grained steel at ± 0·625% strain amplitude and above. Optical microscopy of fatigue fracture surfaces reveals the formation of martensite on cyclic straining predominantly at higher strain amplitudes.     

Life prediction of stainless steels by cyclic and stable hysteresis curves

Abstract

This study develops an analytical expression to describe the cyclic stress‐strain curve obtained from a series of fully‐reversed fatigue tests. A set of stress‐strain relationships is proposed to simulate the tensile branch of the stable hysteresis loop. The complete shape of the stable hysteresis loop is then constructed and the associated theoretical plastic work calculated by integrating the area within the enclosed curve. The theoretical plastic work is employed to predict the fatigue lives of the investigated materials on the basis of their respective stable plastic work per cyclelife curves. In this paper, the current mathematical derivations are based upon the endochronic theory of plasticity. The accuracy of the proposed set of stress‐strain relationships is verified by conducting fully‐reversed constant strain amplitude fatigue tests on AISI 316 and AISI 304 stainless steels. The experimental and simulation results are found to be in good agreement, hence confirming the accuracy of the proposed analytical stress‐strain relationships. Again, comparing the obverted and predicted fatigue lives, a good agreement is found between the two sets of results.     

Deformation and microstructure evolution of a duplex stainless steel under out-of-phase thermo-mechanical fatigue

Abstract

Thermo-mechanical fatigue (TMF) of the duplex stainless steel SAF2205 (X2CrNiMoN22-5-3) was studied in the temperature range of 100–350°C. The tests were carried out on the duplex steel and on single-phase ferritic (X6Cr17, AISI 430) and austenitic steels (X2CrNiMo18-14-3, AISI 316L) similar to the two phases of the duplex steel for comparison. The mechanical behaviour of the three steels is analysed and discussed together with microstructural investigations by scanning electron microscopy, including electron backscatter diffraction and electron channelling contrast imaging.     

On the high cycle fatigue behavior of a type 304L stainless steel at room temperature

An extensive study of the uniaxial cyclic material behavior of an AISI 304L austenitic stainless steel is proposed in the high cycle regime and in constant amplitude loadings. More particularly, the effect on the material behavior and lifetime of a mean axial stress is evaluated imposing either a stress or a strain amplitude. Almost no effect is observed on the stress fatigue curve while a reduction of about 30% is obtained on the strain fatigue curve in the endurance regime. It appears that a stress amplitude fatigue parameter or a Smith–Watson–Topper parameter predict accurately such differences based on the material behavior at maximum cyclic softening.     

Identification of processing parameters for Fe–15Cr–2.2Mo–15Ni–0.3Ti austenitic stainless steel using processing maps

Abstract

The processing parameters for hot working of Fe–15Cr–2.2Mo–15Ni–0.3Ti austenitic stainless steel (alloy D9) are identified using processing maps developed on the basis of the dynamic materials model and hot compression data in the temperature range 850–1250°C and strain rate range 0.001–100 s^-1. The efficiency of power dissipation increased with increase in temperature and decrease in strain rate. Dynamically recrystallised microstructures resulted when the efficiency of power dissipation was in the range 27–37%, i.e. in the temperature range 1050–1250°C and strain rate range 0.001–0.5 s^-1. Flow localisation occurred in the regions of instability at temperatures lower than 1000°C and at higher strain rates. The dynamic recrystallisation regime observed in this alloy is compared with other austenitic stainless steels, namely, AISI type 304L and 316L.     

Modification of Olson–Cohen model for predicting stress-state dependency of martensitic transformation

The well-known Olson–Cohen model is modified by incorporating the effect of stress state on the transformation kinetics in metastable austenitic stainless steels. By assuming isothermal condition, the relationships between the parameters of Olson–Cohen model, stress triaxiality and absolute value of Lode angle parameter have been established. The proposed model predicts that the saturation level and slope of transformation curve increase with increasing the stress triaxiality in addition to the absolute value of Lode angle parameter. Uniaxial and plane strain tension tests have been conducted on the two types of austenitic stainless steels AISI 304 and AISI 201 to evaluate the validity of the model. The results show that the predicted transformation curves are in good agreement with the experimental data.     

Cyclic deformation behavior of austenitic Cr–Ni-steels in the VHCF regime: Part II – Microstructure-sensitive simulation

In Part I – Experimental study, the cyclic deformation behavior of two austenitic stainless steel grades (AISI 304, AISI 316 L) were experimentally investigated at low stress amplitudes in the very high cycle fatigue (VHCF) regime. The observations indicate that during VHCF the metastable austenitic stainless steel (304 grade) performs a pronounced localization of plastic deformation in shear bands followed by a deformation-induced martensitic phase transformation. The 316 grade undergoes only a very limited local plastic deformation in shear bands with almost no phase transformation. Consequently, both materials exhibit distinctly different cyclic softening and hardening characteristics during VHCF. In order to provide a more detailed knowledge about the individual deformation mechanisms and their effect on the cyclic softening and hardening behavior the experimental study is extended by microstructure-sensitive modeling and simulation. Two-dimensional (2-D) microstructures consisting of several grains are represented using the boundary element method and plastic deformation within the microstructure is considered by a mechanism-based approach. Specific mechanisms of cyclic plastic deformation in shear bands and deformation-induced martensitic phase transformation – as documented by experimental results and based on well-known model approaches – are defined and implemented into the simulation. The fatigue behavior at low stress amplitudes observed in experiments can be well represented in simulations so that the underlying model helps to understand the cyclic deformation behavior of austenitic stainless steels at low stress amplitudes in the regime of VHCF strength. In a comparative study based on the resonant behavior the effect of certain deformation mechanisms on the global cyclic softening and hardening characteristics is pointed out for both materials.     

Stress corrosion cracking and hydrogen embrittlement of cold worked AISI type 304 austenitic stainless steel in mode I and mode III

Abstract

Comparative testing of cold worked AISI type 304 austenitic stainless steel in mode I and mode III under conditions of cathodic charging and chloride stress corrosion cracking (SCC) has been used to assess the role of hydrogen in SCC. The experimental results of these tests and those previously published have been used to deduce the mechanism and rate controlling step for SCC. The mechanism for chloride SCC in mode I is anodic dissolution of active slip planes containing hydrogen with the rate controlling step being the transport of hydrogen to these slip planes. The mechanism of SCC in mode III is tunnelling corrosion followed by overload again occurring on a plane of maximum hydrogen concentration.

MST/348     

Deformation twinning in AISI 316L austenitic stainless steel: role of strain and strain path

Abstract

AISI 316L austenitic stainless steel was deformed at different strain and strain paths. The twin boundaries in the deformed microstructure had two possible origins: decay of original annealing twins and generation of deformation twins. Assuming that rotations of grains, specifically grains on both sides of a twin boundary, are responsible for the twin decay, a simple model was proposed to bring out the domain of relative twin generation. A biaxial strain path, in general, was associated with strong twin generation – an association or dependency linked to the texture estimated values of Taylor factor. Formation of strain induced martensite was also observed to be strain and strain path dependent and was more in biaxial strain path.     

Assessment of low cycle fatigue improvement of machined AISI 316 stainless steel by brush hammering

The effects of wire brush hammering on low cycle fatigue behaviour of AISI 316 austenitic stainless steel has been investigated on turned samples through an experimental study combining strain controlled fatigue tests, scanning electron microscope examination and X‐ray diffraction analysis. An increase in fatigue life by 266% was reported at an imposed strain amplitude of Δε_t/2 = 0.2%. This improvement is limited to Δε_t/2 ≤ 0.5%. It is found that wire brush hammering produces a surface texture that favours, under cyclic loading, nucleation of randomly dispersed short cracks of the order of 50 µm in length stabilized by a compressive residual stress field. In contrast, turned surface showed much longer unstable cracks of the order of 200 µm in length nucleated in the machining groves and propagated under the effect of a tensile residual stress field. It has also been established that wire brush hammering can be used as intermittent treatment to improve the residual fatigue life of components subjected to cyclic loading. The treatment is very efficient if it is performed at a fraction of service lifetime n_i/N_r lower than 0.5.     

Cyclic deformation behaviour,microstructural evolution and fatigue life of duplex steel AISI 329 LN

This paper summarises fatigue results obtained on the duplex steel AISI 329 LN (German designation 1.4462). For the characterisation of the fatigue behaviour, the mechanical stress–strain hysteresis loops, the temperature change and the evolution of the electrical resistance were monitored. Transmission electron microscopy was performed to investigate the microstructural changes caused by the fatigue loading. The data were used to apply the fatigue life calculation method “PHYBAL_LIT”. This procedure requires only one load increase test and two constant amplitude tests for a timesaving and material-efficient assessment of S–N (Woehler) curves. The method has already been successfully applied to different carbon and austenitic steels as well as lightweight materials. The results show an excellent agreement between the conventionally determined and the calculated fatigue lifetimes. This agreement is rationalized on a microstructural basis.     

Some factors exerting an influence on the coaxing effect of austenitic stainless steels

The present paper describes some factors exerting an influence on the coaxing effect of austenitic stainless steels. Particularly, the influence of prestrain was investigated in detail. The materials used were austenitic stainless steels, type 304 and 316. Type 304N2 was also used to examine the properties of the stabilized austenitic phase in type 304. Two types of rotating bending fatigue tests, i.e. the conventional constant amplitude tests and stress‐incremental tests, were performed using the specimens subjected to the several tensile‐prestrain levels. Under the constant amplitude tests, the fatigue strengths of type 304 and 316 increased with increasing prestrain. Under the stress‐incremental tests, type 304 showed a remarkable coaxing effect, where the fatigue failure stress significantly increased regardless of the prestrain level. The coaxing effect in the unprestrained specimens was larger than those of the prestrained ones. Type 304N2 showed lower coaxing effect than type 304. In addition, the strain‐induced martensitic transformation did not occur because of the higher stability of austenitic phase in type 304N2. In type 316, the coaxing effect was dependent on the prestrain level, i.e. below 15% prestrain the coaxing effect became smaller with increasing prestrain, whereas above 25% prestrain the coaxing effect reappeared. Based on the tests results, it was considered that the coaxing effect in austenitic stainless steel was due to the mechanisms such as work hardening, strain ageing and strain‐induced martensitic transformation. The contribution of these mechanisms to the coaxing effect was different among type 304, 304N2 and 316.     

THE INFLUENCE OF NITROGEN ON HIGH TEMPERATURE LOW CYCLE FATIGUE BEHAVIOUR OF AUSTENITIC STAINLESS STEELS

Abstract— High strain fatigue properties of AISI 316 , AISI 316N and Sandvik 253MA have been investigated at 600°C. The two latter alloys, which contain significant amounts of N, exhibit a higher resistance to fatigue than 316. This effect is accompanied by a planar dislocation slip mode in 316N and 253MA as opposed to a wavy slip mode in 316. The results provide strong evidence that N improves fatigue strength in austenitic stainless steels, by inhibiting cross-slip of screw dislocations.     

Effect of variation of strain rate on thermal and acoustic emission during tensile deformation of nuclear grade AISI type 316 stainless steel

Abstract

A systematic study has been undertaken to correlate the changes in thermal and acoustic emissions during tensile deformation of AISI type 316 nuclear grade stainless steel (SS) due to variations in the strain rate. Strain rates were varied in the range 3.3 × 10^-4s^-1 to 1.7 × 10^-2s^-1. Thermal emissions were monitored using a focal plane array based thermal imaging system. For a given strain rate, the rate of increase in temperature was observed to be gradual and uniform in the work hardening zone, and to increases drastically during necking. With increasing strain rate, the temperature also increased. Based on the experimental results a constitutive equation can be modelled relating the rise in temperature to strain rate. In the case of acoustic emission (AE), the root mean square (RMS) voltage of the AE signal and cumulative counts increase with strain rate due to the increase in source activation. The peak amplitude distribution of AE hits has shown that hits with similar peak amplitude are generated for all strain rates.     

Creep fatigue behaviour of Type 321 stainless steel at 650°C

Abstract

Type 321 austenitic stainless steel has been used in the UK’s advanced gas cooled reactors for a wide variety of thin section components which are within the concrete pressure vessel. These components operate at typically 650°C and experience very low primary stresses. However, temperature cycling can give rise to a creep fatigue loading and the life assessment of these cycles is calculated using the R5 procedure. In order to provide materials property models and to validate creep fatigue damage predictions, the available uniaxial creep, fatigue and creep fatigue data for Type 321 have been collated and analysed. The analyses of these data have provided evolutionary models for the cyclic stress strain and the stress relaxation behaviour of Type 321 at 650°C. In addition, different methods for predicting creep fatigue damage have been compared and it has been found that the stress modified ductility exhaustion approach for calculating creep damage gave the most reliable predictions of failure in the uniaxial creep fatigue tests. Following this, validation of the new R5 methods for calculating creep and fatigue damage in weldments has been provided using the results of reversed bend fatigue and creep fatigue tests on Type 321 welded plates at 650°C in conjunction with the materials properties that were determined from the uniaxial test data.     

Effects of aging at 700°C on ductile fracture of AISI 316 stainless steel

Abstract

The micromechanisms of ductile fracture have been studied in a commercial AISI 316 austenitic stainless steel. Tensile, Charpy impact, and ductile fracture toughness testing have been performed on unaged material and samples aged at 700°C for times up to 4380 h. Examination of the specimens after testing has shown that the microstructural changes occurring at grain boundaries are responsible for the observed losses of ductility and crack growth resistance. The relative magnitude of the observed changes in mechanical properties has been explained using a simple model to describe the ductile fracture process.

MST/1001