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1.
Titanium carbide (TiC) and carbon nanotubes (CNTs) were introduced into zirconium carbide (ZrC) ceramics to improve the fracture toughness. ZrC–TiC and ZrC–TiC–CNT composites containing 0–30 vol.% TiC and 0.25–1 mass% CNT were prepared by spark plasma sintering at temperatures of 1750–1850 °C for 300 s under a pressure of 40 MPa. Densification behavior, microstructure, and mechanical properties of the ZrC-based composites were investigated. Fully dense ZrC–TiC and ZrC–TiC–CNT composites with a relative density of more than 98 % were obtained. Vickers hardness of ZrC-based composites increased with increasing TiC content and the highest hardness was achieved with the addition of 20 vol.% TiC. Addition of CNTs up to 0.5 wt% significantly increased the fracture toughness of ZrC-based composites, whereas the addition of TiC did not have this effect. 相似文献
2.
AbstractThe aim of the present experimental study was to investigate improvement of the toughness and strength of grey cast iron by reinforcing with steel fibres. The carbon content of the steel fibres was chosen to be sufficiently low that graphite flakes behaving as cracks were removed by carbon diffusion from the cast iron to the steel fibres during the solidification and cooling stages. To produce a graphite free matrix, steel fibres with optimum carbon content were used and the reinforced composite structure was cast under controlled casting conditions and fibre orientation. Three point bend test specimens were manufactured from steel fibre reinforced and unreinforced flake graphite cast iron and then normalising heat treatments were applied to the specimens at temperatures of 800 and 850°C. The fracture toughness and strength properties of the steel fibre reinforced material were found to be much better than those of unreinforced cast iron. The microstructures of the composite at the fibre–matrix transition zone were examined. 相似文献
3.
Micro- or nano-fibrillar composites (MFCs or NFCs) are created by blending two homopolymers (virgin or recycled) with different
melting temperatures such as polyethylene (PE) and poly(ethylene terephthalate) (PET), and processing the blend under certain
thermo-mechanical conditions to create in situ fibrils of the polymer that has the higher-melting temperature. These resulting
fibrillar composites have been reported to possess excellent mechanical properties and can have wide ranging applications
with suitable processing under controlled conditions. However, the properties and applications very much depend on the morphology
of created polymer fibrils and their thermal stability. The present paper develops an understanding of the mechanism of micro-/nano-fibril
formation in PE/PET and polypropylene (PP)/PET blends by studying their morphology at various stages of extrusion and drawing.
It is revealed that this subsequent mechanical processing stretches the polymer chains and creates fibrils of very high aspect
ratios, thus resulting in superior mechanical performance of the composites compared to the raw blends. The study also identifies
the primary mechanical properties of the main types of MFCs, as well as quantifying their enhanced resistance to oxygen permeability.
Furthermore, the failure phenomena of these composites are studied via application of the modified Tsai–Hill criterion. In
addition to their usage as input materials in different manufacturing processes, possible applications of these fibrillar
composites in two different areas are also discussed, namely food packaging with controlled oxygen barrier properties and
biomedical tissue scaffolding. Results indicate a significant scope for using these materials in both areas. 相似文献
4.
The aim of this study is the fabrication of dental glass-ceramics able to elicit bioactive behaviour around the margins of fixed restorations and to provide a bioactive surface which can lead to periodontal tissue attachment, providing complete sealing of the marginal gap between tooth and fixed prosthesis. Sol–gel technique is applied for the fabrication of a new glass-ceramic in the system SiO 260%–P 2O 53%–Al 2O 314%–CaO6%–Na 2O7%–K 2O10% (wt.%) and a related composite material combining this phase with the bioactive glass 58S. This composite material aims to create a bioactive surface which could lead to periodontal tissue attachment, providing complete sealing of the marginal gap between tooth and fixed prosthesis. The microstructural and thermal properties and the bioactive behaviour of the new materials were determined and were observed to be similar in respect to a commercial leucite based fluorapatite dental glass-ceramic. The feasibility of the new composite material to be applied as coating on the base porcelain as well as the bioactive behaviour of the fabricated coated specimes were confirmed. 相似文献
5.
This article accesses the impact performance of ceramic-faced, metal–ceramic interpenetrating composites (IPCs) produced in
situ from infiltrating ceramic foams with a molten aluminium–magnesium alloy. The approach had two variations, viz., the production
of a metal bond between a ceramic front face and backing IPC and the creation of a ceramic bond. The impact performance of
metal-bonded IPCs was evaluated using both split Hopkinson’s pressure bar (SHPB) and depth of penetration (DoP) techniques.
With a 4-mm thick Al 2O 3 front face and an 8-mm thick IPC backing, the DoP was zero. In one case, a sample survived fundamentally intact with only
spall damage to the dense Al 2O 3 front face. The resulting damage was thoroughly assessed using a range of techniques, including polarized light microscopy,
scanning electron microscopy (SEM), 3D MicroCT and transmission electron microscopy (TEM). The metal phase deformed as a result
of the formation of large numbers of dislocations, whilst the ceramic phase accommodated the deformation via localised cracking.
Metal bridges across the cracks formed, increasing the damage tolerance of the IPCs. The metal bond between the ceramic front
face and the IPC was also observed to withstand the impact of the armour piercing rounds without any sign of debonding occurring. 相似文献
6.
The study was carried out to investigate the effects of silane coupling agent, γ-aminopropyl triethoxy silane (KH-550), on
the preparation and dielectric properties of Barium titanate (BaTiO 3)/Bisphenol-A dicyanate (2,2′-bis (4-cyanatophenyl) isopropylidene)(BADCy) composites for embedded passive implications. It
was found that KH-550 accelerated the polymerization of BADCy and was beneficial to improve the compatibility between BaTiO 3 particles and BADCy matrix. The dielectric constant (ε) and dielectric loss (tanδ) both increased at first and then decreased
with the increase of the KH-550 content. With the increase of the frequency, the variation ranges of the dielectric constant
and dielectric loss of these composites were not obvious since the dielectric properties of cyanate ester were stable at various
frequencies. 相似文献
7.
Al–Li–SiC p composites were fabricated by a modified version of the conventional stir casting technique. Composites containing 8, 12 and 18 vol% SiC particles (40 mm) were fabricated. Hardness, tensile and compressive strengths of the unreinforced alloy and composites were determined. Ageing kinetics and effect of ageing on properties were also investigated. Additions of SiC particles increase the hardness, 0.2% proof stress, ultimate tensile strength and elastic modulus of Al–Li–8%SiC and Al–Li–12%SiC composites. In case of the composite reinforced with 18% SiC particles, although the elastic modulus increases the 0.2% proof stress and compressive strength were only marginally higher than the unreinforced alloy and lower than those of Al–Li–8%SiC and Al–Li–12%SiC composites. Clustering of SiC particles appears to be responsible for reduced the strength of Al–Li–18%SiC composite. The fracture surface of unreinforced 8090 Al-Li alloy (8090Al) shows a dimpled structure, indicating ductile mode of failure. Fracture in composites occurs by a mixed mode, giving rise to a bimodal distribution of dimples in the fracture surface. Cleavage of SiC particles was also observed in the fracture surface of composites. Composites show higher peak hardness and lower peak ageing time compared with unreinforced 8090Al alloy. Macroand microhardness increase significantly after peak ageing. Ageing also results in considerable improvement in strength of the unreinforced 8090Al alloy and its composites. This is attributed to formation of δ' (Al 3Li) and S' (Al 2CuMg) precipitates during ageing. Per cent elongation, however, decreases due to age hardening. Al–Li–12%SiC, which shows marginally lower UTS and compressive strength than the Al–Li–8%SiC composite in extruded condition, exhibits higher strength than Al–Li–8%SiC in peak-aged condition. 相似文献
9.
Journal of Materials Science - The evolution of heterogeneous microstructure and mechanical properties of a 12Cr–10Ni–Mo–Ti maraging steel was investigated at different aging... 相似文献
10.
The inherently poor wear resistance of titanium alloys limits their application as femoral heads in femoral (hip) implants. Reinforcing the soft matrix of titanium alloys (including new generation β-Ti alloys) with hard ceramic precipitates such as borides offers the possibility of substantially enhancing the wear resistance of these composites. The present study discusses the microstructure and wear resistance of laser-deposited boride reinforced composites based on Ti–Nb–Zr–Ta alloys. These composites have been deposited using the LENS™ process from a blend of elemental Ti, Nb, Zr, Ta, and boron powders and consist of complex borides dispersed in a matrix of β-Ti. The wear resistance of these composites has been compared with that of Ti–6Al–4V ELI, the current material of choice for orthopedic femoral implants, against two types of counterfaces, hard Si 3N 4 and softer SS440C stainless steel. Results suggest a substantial improvement in the wear resistance of the boride reinforced Ti–Nb–Zr–Ta alloys as compared with Ti–6Al–4V ELI against the softer counterface of SS440. The presence of an oxide layer on the surface of these alloys and composites also appears to have a substantial effect in terms of enhanced wear resistance. 相似文献
11.
AbstractThe presence of carbide particles in metal matrix composites improves abrasive wear resistance properties. Abrasive wear characteristics of TiC reinforced cast iron composites have been investigated. The TiC particle size and distribution influence the wear properties of the composites. TiC reinforced cast iron composites possess better wear resistance properties than those of chromium cast irons with and without nitrogen. 相似文献
12.
This paper for the first time investigates combustion synthesis of 3Ni-Al–carbon nanotube (CNT) powder compacts simultaneously under two modes of ignition (electrically activated reaction synthesis (EARS) and electrically ignited self-propagating high-temperature synthesis (EISHS)), using a novel setup. The resulting phases, microstructure, porosity, and hardness were investigated and discussed. An increase in CNT (0–3 vol.%) content led to an increase in product porosity and microstructural inhomogeneity. This was seen most dramatically in the EISHS mode compared to the EARS. The increased pore content in EISHS regions resulted in lower hardness values. However, in regions of the compact that experienced EARS, an increase in CNT content led to an increase in microhardness, in spite of the higher porosity levels. The latter result highlights the important benefit of adding CNTs to nickel aluminides. 相似文献
13.
AbstractTiC/Ti–6Al–4V composites containing various volume fractions of TiC were produced by induction skull melting and common casting utilising in situ reaction between titanium and carbon powder. The microstructure and room tensile properties of as cast and heat treated TiC/Ti–6Al–4V composites were investigated. Bar-like or small globular eutectic TiC were found in 5 vol.-%TiC/Ti–6Al–4V composite, whereas the equiaxed or dendritic primary TiC particles were found to be the main reinforcements in 10 and 15 vol.-%TiC/Ti–6Al–4V composites. The as cast TiC/Ti–6Al–4V composites have shown higher strength but lower ductility than those of monolithic Ti–6Al–4V alloy. The shape and fracture of TiC particles can strongly influence the fracture and failure of the composites, and so the ultimate tensile strengths and elongations of as cast composites reduce with the increase in volume fraction of TiC. TiC particles appear to be spheroidised, and titanium precipitation can be found within large TiC particles after heat treatment at 1050°C for 8 h, which can promote the resistance to fracture of composites. Therefore, the elongations of the composites increase significantly, and the ultimate tensile strengths also have marginal increase especially for the 10 and 15 vol.-%TiC/Ti–6Al–4V composites after heat treatment. 相似文献
14.
In this paper, we discuss the optimization of chemical composition, processing (forging and rolling) and heat treatment parameters to obtain the best combination of mechanical properties in case of a Fe–15Cr–5Ni–4Cu precipitation hardenable stainless steel. The ε-copper precipitates that form during aging are spherical in shape and coherent with the matrix and principally provide strengthening in this alloy. The orientation relationship is found to be Kurdjumov–Sachs (K–S), which is common in fcc–bcc systems. Results obtained from metallurgical evaluation (mechanical property and metallography) on 15–5 PH alloy during type certification on 3 different melts were used for the optimization, attempted in this study. The mechanical properties following strain deformation has been carried out using optical microscope, scanning electron microscope (SEM) and transmission electron microscope (TEM). In the aged conditions, the 15–5 PH alloy exhibited brittle failure with extensive cleavage and/or quasicleavage fracture. This paper reports all results and also factually shows that indigenously developed and produced 15–5 PH stainless steel matches in its properties with the equivalent aeronautical grade precipitation hardening stainless steels globally produced by internationally renowned manufactures. 相似文献
15.
A new kind of V–Ti–N high strength microalloyed medium carbon steel has been developed, which is used for fracture splitting
connecting rod. In this article, the characteristics of this carbon steel and its production process were studied. The microstructure,
precipitated phases and their effects on mechanical properties were investigated by optical microscope, SEM, and TEM. The
results showed that the steel was constituted of ferrite and pearlite. By reducing the finish rolling temperature and accelerating
the cooling rate after rolling, microstructure with fine grain ferrite and narrow lamellar space pearlite could be obtained
in V–Ti–N microalloyed medium carbon, and a large number of precipitated phases distributed over ferrite. These led the tensile
strength to be more than 1000 MPa, yield strength (YS) more than 750 MPa. The impact fractograph showed typically brittle
fracture characteristic. 相似文献
16.
Using a new cast-sintering technique, iron-base surface composites reinforced by VC and TiC particles which were produced in situ and consisting of self-lubricant graphite and chromium-carbide, were sintered on the surface of cast steel during casting. The structure and composition of the surface composites were studied with the help of a SEM, an electron probe and XRD. From the outside in of the iron-based surface composites, the concentration of V and Ti was relatively stable and consistently retained a high level, while the concentration of Cr and Ni took on a gradient distribution and decreased gradually. The fine particles of VC and TiC measuring between 1 and 3 μm in diameter were uniformly dispersed in their matrices, and there was a perfect metallurgy-bond between the surface composite layer and the master-alloy. Under the condition of dry slipping with a heavy load, the Fe–VC and Fe–TiC surface composites offer virtually unique wear-resistance. 相似文献
18.
The work aimed to develop surfaces that could resist wear at high temperatures, thus achieving a prolonged component life. Surface modification of a low-alloy steel by incorporating TiC particles has been undertaken by melting the surface using a tungsten inert gas torch. The dry sliding wear behaviour at 600°C of the original and modified surfaces was compared. Microscopic examination of both surfaces showed glazed layers across the wear tracks, with differing amounts of oxide and homogeneity. Extensive wear occurred on the steel surface, which showed deformation of the wear scar tracks and a steadily increased friction coefficient. The TiC addition reduced the wear loss, coinciding with a glazed layer 33% thinner than that on the low-alloy steel sample. 相似文献
19.
Al 2O 3/steel metal–matrix composites (MMCs) were fabricated by activated pressureless infiltration at atmospheric pressure in different gas atmospheres; N 2, Ar and Ar–5%H 2. The infiltration quality was evaluated with examination of the microstructure, infiltrated area and remaining porosity. The atmosphere with the best infiltration quality was chosen for improvement of infiltration by varying infiltration parameters such as temperature, holding time and heating and cooling rates. Further improvement was achieved by addition of Si or SiO 2 powder to the preform in order to reduce the effect of the residual carbon. The results show that the activated melt infiltration can be successfully done at atmospheric pressure in inert gas. 相似文献
20.
The currently used composites produced by classical sintering methods are characterised by numerous limitations due to the difficulties in combining different materials with extreme properties. One of the ways to overcome these limitations is in the use of modern sintering methods, including the high pressure-high temperature process. This study describes the composite materials based on 316L austenitic steel reinforced with titanium diboride and examines the effect of sintering conditions on the mechanical properties and microstructure of sintered composites. It has been found that the key parameter in the manufacture of composites with optimal properties is the sintering time and temperature, while martensitic transformation taking place in the composite matrix can be controlled by the properly selected pressure applied during the sintering process. 相似文献
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