影响水泥净浆流动度的几个因素浅析

水泥同外加剂的适应性对预拌混凝土的品质和性能产生较大影响,净浆流动度法基本能反映水泥同外加剂的适应性情况,目前被广泛使用。因此积极探讨影响水泥净浆流动度的相关因素对改善水泥性能、提高混凝土质量意义重大,同时可为预拌混凝土厂选择合适的水泥供应厂家提供必要的技术支持。本文主要针对HR公司P·O42.5级水泥及其熟料进行讨论。1水泥同外加剂适应性情况常规判断方法预拌混凝土厂判断水泥同外加剂适应情况,一般是按照GB50119—2003附录A《混凝土外加剂同水泥适应性的检测方法》要求测定水泥净浆流动度,水泥厂家为了同预拌混凝土…     

提高水泥净浆流动度的措施

大连金山水泥制造有限公司2500t/d生产线,其水泥粉磨系统配套4台Φ3m×11m闭路磨,主要生产P·O42.5及以上散装水泥,混合材掺加量基本在16%左右,其中矿渣8%,石灰石3%,矿渣粉5%。自2007年投产以来水泥各项指标和性能一直比较稳定,水泥3d抗压强度在28MPa以上,水泥净浆流动度平均在180mm左右。但据商品混凝土搅拌站反映,水泥净浆流动度偏低,而且每到夏季时水泥净浆流动度降低且波动较大,搅拌站只好通过增加外加剂掺加量的办法来改善混凝土性能,既增加了混凝土成本,又给施工带来不便。近年来,公司不断地采取技术措施,改善和提高水泥净浆流动度。     

水泥净浆流动度与混凝土流变性能相关性试验

在工程试配C100自流平混凝土的同时,进行了水泥净浆流动度与混凝土流变性能相关性试验。结果表明,水泥净浆流动度与混凝土流变性能之间没有明显的相关关系;水泥净浆流动度损失率与混凝土保塌性之间也没有明显的相关关系。至少在超高强自流平混凝土的条件下,按GB/T8077—2000测定的水泥净浆流动度与混凝土流变性能的关系值得商榷。     

出磨水泥与出厂水泥净浆流动度差距大的原因分析

我公司有两台Φ4.2m×11.5m的水泥磨,生产3个水泥品种,其中1号磨生产P·C32.5R、P·O42.5,2号磨生产P·O42.5、P·O52.5,有6个水泥库,每个库库容6000t,并配有3台倒库提升机（每个品种单独倒库）,7个散装库。2017年5月下旬开始,出现P·O42.5出磨水泥流动度较好（加外加剂的净浆流动度）而出厂水泥流动度波动时好时差的情况,本文介绍两者差别较大的原因分析及主要处理措施。     

水泥净浆流动度与混凝土流动性能相关性研究

正0前言聚羧酸高性能减水剂是继萘系、三聚氰胺系列高性能减水剂后发展起来的第三代高性能混凝土减水剂,由于聚羧酸高性能减水剂在使用中具备掺量低、减水性强、保坍性高等优点,在混凝土工程中迅速发展。但在实际工程实践中,聚羧酸高性能减水剂对不同产地、不同成分的水泥非常敏感。本文通过采用不同厂家生产的P·O42.5级普通硅酸盐水泥与某品牌ART-M1型聚羧酸高性能减水剂进行试验,分析研究掺减水剂的水泥净浆流动度与混凝土     

钛石膏作缓凝剂对水泥净浆流动度影响的研究

本文重点研究了钛石膏对M32.5、P·C42.5、P·O42.5及P·Ⅱ42.5水泥净浆流动度的影响。结果表明,钛石膏完全取代脱硫石膏作水泥缓凝剂时,对M32.5和P·C42.5水泥净浆流动度的影响不大。当混合材粉煤灰与硫铁渣的掺量比为3∶5时,钛石膏做缓凝剂使得P·O42.5水泥的净浆流动度降低约10 mm,而当掺量比为5∶3和1∶1时,混合材改善了钛石膏对P·O42.5水泥的净浆流动度的负面影响。对于P·Ⅱ42.5水泥,钛石膏替代脱硫石膏导致净浆流动度降低25 mm。     

混合水泥密度对标准稠度用水量的影响

水泥密度是一个非常重要的性能参数，它决定水泥在其净浆、砂浆以及混凝土中所占的体积，直接影响水泥标准稠度用水量的大小，从而对水泥混凝土性能产生重大影响。     

水泥净浆流动度影响因素分析及净浆自流淌平台研制

排除水泥和外加剂本身特性、状态因素,水泥净浆流动度还受到测定流动度的玻璃板是否水平、操作者上提截锥圆模速度、浆体和试验玻璃面的浸润性等因素的影响,其中测定流动度的玻璃板是否水平是最主要的客观因素。尤其在净浆中添加一定比例的外加剂,净浆流动性更好,玻璃板面不水平带来的偏差更大。为提高净浆流动性结果准确性、稳定性,我们开发制作了一种自流淌水泥净浆标准平台,设计原理简单,易于调整水平,方便携带。试验完毕可直接在玻璃平面上读数,不仅提高了试验检测结果的重复性、再现性,同时提高了试验效率。     

净浆流动度损失与混凝土坍损的相关性研究

对粉煤灰取代水泥量、粉煤灰质量,砂的含泥量和外加剂掺量等因素对净浆流动度经时变化及混凝土坍落度损失的影响进行了研究,探索了净浆保持性与混凝土坍损间的关系。结果表明:砂的含泥量对混凝土的工作性能影响明显,当实验所用砂含泥量达到I、II类时,同掺量外加剂的净浆流动度保持性能可以较为准确地反映出混凝土的工作性能;当实验所用砂为III类时,净浆流动度保持性能优异的外加剂掺量增加10%推荐为混凝土的试拌试验掺量。     

浅谈水泥标准稠度用水量对混凝土用水量的影响

1 水泥标准稠度用水量的含义 水泥净浆在某一用水量和特定测试方法下达到的稠度,称为水泥的标准稠度;这一用水量即称为水泥的标准稠度用水量,它是水泥净浆需水性的一种反应,用100克水泥需用水的毫升数(%)表示.     

Marsh筒法和净浆流动度法用于水泥与减水剂适应性测试的比较

通过Marsh筒法和净浆流动度法用于水泥与减水剂适应性测试比较发现,采用Marsh筒法无论在测定减水剂饱和掺量点、对经时损失的敏感性上,还是与水泥标准稠度用水量和胶砂流动度的相关性上都优于净浆流动度法。     

Effects of polycarboxylate-type superplasticizer on fluidity and hydration behavior of cement paste

Polycarboxylate (PC)-type superplasticizers were synthesized with different average molecular weight of polyethylene oxide (PEO) graft groups, the molar ratios of graft group to carboxylic group, and then the chemical structure, polymerization condition, and physical and chemical properties were analyzed. In order to evaluate the effects of PC-type superplasticizers in cement paste, the adsorption, the initial plasticity and slump retention characteristics and the degree of hydration reaction were investigated. As the average molecular weight of graft group decreased and molar ratio increased, the conversion rate to copolymers, the adsorption amount of PC-type superplasticizer on cement particles improved; on the other hand, the hydration reaction was delayed.     

水泥生产中影响水泥与外加剂适应性的因素探讨

结合水泥生产过程和实际工作中遇到的问题,探讨了水泥生产中影响水泥与外加剂适应性的主要因素,包括水泥的碱含量、熟料的fCaO含量、混合材种类及掺加量、水泥粉磨细度、水泥温度及新鲜度、外加剂的种类及性质、熟料的化学成分、石膏的种类及掺量、粉磨工艺、技术指标稳定性等多种因素,并对有效解决适应性问题的途径作了探讨。     

掺入纳米SiO_2对水泥净浆流动性和力学性能的影响

掺入纳米SiO2,采用2种掺入方法和不同掺量,讨论了对水泥净浆的流动度和强度等性能的影响,得出最佳掺量和掺入方法。进一步探究掺入不同粒径的纳米SiO2对水泥净浆性能的影响规律。实验得出,采用将纳米SiO2与水泥先干混再拌合方法更利于拌合分散均匀,掺量越大流动度降低程度越大,而粒径越小流动度明显降低;纳米SiO2掺量的强度影响临界值为1.5%;各个粒径对早、中期强度均有明显增强,30nm的效果最明显。     

The influence of aminosilanes on macroscopic properties of cement paste

In this work the authors present the results obtained by studying the influence of γ-aminopropyltriethoxysilane or (CH₃CH₂O)₃Si(CH₂)₃NH₂, (APTES), and N-β-aminoethyl-γ-aminopropyltrimethoxylsilane or (CH₃O)₃Si(CH₂)₃NH(CH₂)₂NH₂, (AEAPTES), on macroscopic properties of fresh and hardened cement pastes and mortars prepared from ordinary Portland cement. The mixing ability of aminosilane substances with water is an advantage in comparison to other types of organofunctional silanes when used as an admixture to the cement system. This enables direct blending with water and cement and homogeneous distribution of aminosilane molecules through the bulk of the cement material. The highly polar amine and alkoxide groups of aminosilane molecules exhibit strong chemical interactions with cement matrix which are reflected in modified macroscopic properties of the cement system. The effect of APTES and AEAPTES on (a) properties of fresh cement paste and mortar as workability, setting time, water/cement ratio, air content and density, and on (b) properties of hardened cement paste and mortar as compressive and flexural strength, was studied.     

Effect of admixture on hydration of cement, adsorptive behavior of admixture and fluidity and setting of fresh cement paste

The adsorptive behavior of admixtures and the hydration of cement in the presence of admixtures were examined and the relationships of them with the physical properties of fresh cement paste including fluidity, variation of fluidity with time and setting time were discussed with the quantitative determination of organic admixture adsorbed on the cement, and with the observation and determination of the surface microstructure and composition of polished clinker dipped in aqueous solution containing a specified quantity of admixture by advanced method of surface analysis.

In order to prepare the same fluidity of fresh cement paste, mortar and concrete, the required amount of an easily adsorbed admixture is larger than that of a hard adsorbed one. An admixture having a functional group producing a complex salt with Ca²⁺ decreases the concentration of Ca²⁺ in liquid phase at early age and delays the saturation of Ca²⁺, which influences the morphology of hydrate produced, causes fluidity loss with time and delays the setting time of cement. The microstructural and compositional estimations of the adsorption layer of admixture on the surface of clinker minerals by in-lens FESEM, ESCA-imaging, AES and AFM indicates that the admixture is partially adsorbed to the interstitial phase in a thick layer, forming characteristic three dimensional surface structure.     

不同几何尺寸纤维对水泥浆体性能的影响

选用碳纤维、微细钢纤维和普通钢纤维三种不同几何尺寸纤维,通过抗压抗折实验以及抗弯荷载曲线等方法,研究了它们对水泥基最基本层次水泥浆体的作用效果.研究结果表明,在相同体积掺量时,水泥净浆抗折与抗压以及抗弯强度均按普通钢纤维、微细钢纤维、碳纤维的次序递增,增韧作用则按此次序递减;不同掺量的同种纤维,其抗折强度与抗压强度则随纤维掺量的递增而提高;采用声发射试验,能较好地反映不同几何尺寸的纤维对净浆的增强与增韧作用.