共查询到20条相似文献,搜索用时 62 毫秒
1.
2.
3.
用萃淋树脂CL-P204作为萃取色层的固定相研究了淋洗液HCl酸度(1.5~1.9N),流速(0.65~1.05ml/cm~2·min),负载量(占饱和吸附量的0.65%、1.3%与1.95%)与柱长径比L/φ(17、37)对相邻稀土元素铽与镝分离的影响。用log D对log[H~+]作图得一组直线,其斜率~3。说明萃淋树脂上的P204萃取稀土时一个稀土离子置换三个氢离子。饱和吸附量法测得树脂上的P204与稀土形成的络合物的克分子比是3:1。其反应式可能是:Ln_(+3)+1.5(H_2A_2)=LnA_3+3H~+。 相似文献
4.
采用离子交换色层法用氨基膦酸螯合树脂对重稀土铥、镱、镥富集物进行动态吸附和淋洗分离研究,考察了淋洗剂浓度、酸度、淋洗液流速、温度等因素对分离的影响。结果表明,在吸附柱中,以0.1mL/(cm2.min)的流速进料时能得到较大的吸附率;在淋洗液流速为0.3mL/(cm2.min)、温度30℃的条件下,用pH=8.0、浓度0.02mol/L的EDTA淋洗重稀土富集物,可实现铥、镱、镥三者的完全分离。 相似文献
5.
采用P507萃淋树脂萃取色层法以Tb、Dy富集物作原料,研究了淋洗液酸度、柱径比、淋洗速度、稀土负载量以及原料中Tb、Dy含量对Tb、Dy分离的影响。并根据研究结果,选出较佳的分离工艺条件进行了多次综合条件试验,试验结果表明:一次分离可分别获得纯度>99.9 5%的髙纯Tb4O7和Dy2O3, 平均实收率分别为89.62%和87.63%。 相似文献
6.
萃取色层法分离铽镝研究 总被引:2,自引:0,他引:2
采用P507萃淋树脂萃取色层法以Tb、Dy富集物作原料,研究了淋洗液酸度、柱径比、淋洗速度、稀土负载量以及原料中Tb、Dy含量对Tb、Dy分离的影响。并根据研究结果,选出较佳的分离工艺条件进行了多次综合条件试验,试验结果表明:一次分离可分别获得纯度〉99.95%的高纯Tb4O7和Dy2O3平均实收率分别为89.62%和87.63%。 相似文献
7.
8.
9.
探究LN树脂对Sm(Ⅲ)和Gd(Ⅲ)的吸附效果,考察了时间、酸度和温度对树脂吸附量的影响,对吸附过程的吸附动力学和吸附热力学进行了研究,并测定了相关热力学参数?H、?S以及?G。结果表明,LN树脂在298 K下对Sm(Ⅲ)和Gd(Ⅲ)的吸附可在2 min后达到平衡,酸度越小平衡吸附量越大,且随温度升高平衡吸附量也逐渐升高。使用LN树脂色层柱进行了钐和钆的分离试验,Sm(Ⅲ)在0.75 mol/L HNO3酸度下洗脱,Gd(Ⅲ)在1.0 mol/L HNO3酸度下洗脱,不同洗脱液流速对柱分离效果的影响结果表明,流速为0.53 mL/min时分离效果最好。 相似文献
10.
P507萃淋树脂色层法制备高纯Tb4O7的研究 总被引:1,自引:0,他引:1
研究了P507-HCL体系萃取色层法分离Gd、Tb、Dy的影响因素,在温度为50℃,流速为0.75L/min和负载量3.8 kg条件下,用0.45、0.55、0.8 mol/L的HCl溶液梯度淋洗,可分别将Gd、Tb、Dy彻底分离,且可制得4N以上高纯Tb4O7. 相似文献
11.
12.
13.
<正>Minmetals Resources acquired the world’s largest copper mine under construction for USD5.85 billion.One after another,listed companies Jien Nickle,China Molybdenum and Chihong Zinc and Germanium raised money to get involved in overseas mining projects…SOEs and private enterprises are engaged in a frenzy of overseas mine purchasing.A reporter with Economic 相似文献
14.
正Judging from China’s copper consumption field,the biggest consumption unit is electric power,which accounts for 47%of total consumption;it is followed by light industry sector,including household electrical appliance,machinery,durable goods and hardware etc,which accounts for 22%of total consumption;followed by transportation field, 相似文献
15.
《China Nonferrous Metals Monthly》2014,(10)
正In 2013,the Central Geological Prospecting Fund(CGPF)Project newly discovered 15 ore fields,including 3 large above ore fields,and 5medium sized ore fields.The reporter learned from the recently published"Annual Report of Central Geological Prospecting Fund Project(2013)"that,from 2006 to 2013 the CGPF 相似文献
16.
《China Nonferrous Metals Monthly》2014,(10)
正This year,the investment growth rate of real estate industry continued to slow down,sold area of commercial housing also dropped significantly,which brought huge pressure to the domestic air conditioning manufactures.In the first half of the year,by relying on high growth in national financial expenditure,along with investment in public infrastructure 相似文献
17.
《China Nonferrous Metals Monthly》2014,(10)
正Kang Yi,Honorary Chairman of China Nonferrous Metals Industry Association,said recently at the Forum on Development of the Non-ferrous Metals Industry in Central and Western China held in Zhengzhou that,as more and more electrolytic aluminum factories in Xinjiang came into operation,the electrolytic aluminum output of Xinjiang had reached2,275,000 tons in the first 7 months this year, 相似文献
18.
《China Nonferrous Metals Monthly》2014,(12)
正"Xinjiang project has been completed according to schedule,but total completion and total start of production are two different concepts,after completion it still needs a gradual process of reaching production target."On the morning of November 3,Shenhuo Coal Industry and Electricity Power told investors the above statement on the investor interaction platform. 相似文献
19.
正The reporter learned from Guangdong Province Precious Metal Transaction Center that in 2013the Center maintained healthy development momentum,and had become the second largest precious metal transaction platform in China in terms of market size;currently Guangdong is quickening steps of financial innovation for the Center,aiming to build a transaction center with international core competitiveness. 相似文献
20.
正On May 22,Baotou Rare Earth Industry Cooperation Consultation MeetingProject Agreement-signing Ceremony was held in Ningbo,nearly 40 enterprises from Ningbo,Guangdong,Hunan,and Shanxi participated in project consultation.After multi-lateral communication,agreements were signed for a total of 7 rare earth projects successfully. 相似文献