Experimental investigation of mass recovery adsorption refrigeration cycle

The study investigates the performance of silica gel–water adsorption refrigeration cycle with mass recovery process by experimental prototype machine. In an adsorption refrigeration cycle, the pressures in adsorber and desorber are different. The mass recovery cycle utilizes the pressure difference to enhance the refrigerant mass circulation. Moreover, novel cycle was proposed for improvement of cooling output. In our previous study, simulation analysis shows that mass recovery cycle has the advantage over conventional single-stage. Experiments with prototype machine were conducted to investigate the performance improvement of mass recovery cycle in the present paper. Specific cooling power (SCP) and coefficient of performance (COP) were calculated with experimental data to analyze the influences of operating conditions. The proposed cycle was compared with the single-stage cycle in terms of SCP and COP. The results show that SCP of mass recovery cycle is superior to that of conventional cycle and mass recovery cycle is effective with low temperature heat source.     

Experimental investigation on R134a vapour ejector refrigeration system

The experimental investigation of the performance of a vapour ejector refrigeration system is described. The system uses R134a as working fluid and has a rated cooling capacity of 0.5 kW. The influence of generator, evaporator and condenser temperatures on the system performance is studied. This kind of system can be operated with low grade thermal energy such as solar energy, waste heat, etc. The operating conditions are chosen accordingly as, generator temperature between 338 K and 363 K, condenser temperature between 299 K and 310.5 K, and evaporator temperature between 275 K and 285.5 K. Six configurations of ejectors of different geometrical dimensions are selected for the parametric study. The performance of the refrigeration system at different operating temperatures is presented.     

Thermodynamic limits to thermal regeneration in adsorption cooling cycles

Energy and exergy models for ideal adsorption cycles with isothermal beds and no mass recovery are developed to predict the limits to COP enhancement using thermal regeneration. The models are applied to compare the performance of zeolite–water and silica gel–water adsorbent–refrigerant pairs over a range of maximum bed temperatures. The thermodynamic consistencies of several alternate adsorption property assumptions are quantified. Differences in adsorption characteristics between zeolite–water and silica gel–water result in a significantly larger potential to enhance COP by implementing thermal regeneration for zeolite–water. Based on COP, the zeolite–water pair is preferred when both thermal regeneration and a high temperature thermal energy source (>150 °C) are used, while the silica gel–water pair is preferred when thermal regeneration is not used and/or a low temperature thermal energy source (<100 °C) is used.     

Study of a novel silica gel–water adsorption chiller. Part I. Design and performance prediction

A novel silica gel–water adsorption chiller is designed and its performance is predicted in this work. This adsorption chiller includes three vacuum chambers: two adsorption/desorption (or evaporation/condensation) vacuum chambers and one heat pipe working vacuum chamber as the evaporator. One adsorber, one condenser and one evaporator are housed in the same chamber to constitute an adsorption/desorption unit. The evaporators of two adsorption/desorption units are combined together by a heat-pipe heat exchanger to make continuous refrigerating capacity. In this chiller, a vacuum valve is installed between the two adsorption/desorption vacuum chambers to increase its performance especially when the chiller is driven by a low temperature heat source. The operating reliability of the chiller rises greatly because of using fewer valves. Furthermore, the performance of the chiller is predicted. The simulated results show that the refrigerating capacity is more than 10 kW under a typical working condition with hot water temperature of 85 °C, the cooling water temperature of 31 °C and the chilled water inlet temperature of 15 °C. The COP exceeds 0.5 even under a heat source temperature of 65 °C.     

Performance evaluation of a two-stage adsorption refrigeration cycle with different mass ratio

The performance of a two-stage adsorption chiller with different mass allocation between upper and bottom beds has been investigated numerically. It is found that the chiller can be driven effectively by the waste heat of temperature 55 °C with the heat sink at environment temperature. Results show that cooling capacity can be improved with the optimum allocation of adsorbent mass to the bottom beds than that to the upper beds. The improvement in Coefficient of Performance (COP) values, however, is less significant. It is also seen that the improvement in cooling capacity is more significant for the relatively higher heat source temperature. It is shown that the cooling capacity can be improved up to 20% if the heat source temperature is 80 °C and the average outlet temperature is fixed at 7 °C.     

Numerical study of a novel cascading adsorption cycle

A novel cascading adsorption cooling cycle for refrigeration purposes is proposed in this paper. This cycle consists of two zeolite adsorbent beds and a silica gel adsorbent bed. The working refrigerant for the three adsorbers is water. The zeolite adsorbent bed is configured as the high temperature stage while the silica gel adsorbent bed acts as the low temperature stage. Both heat and mass recovery are carried out between the two zeolite adsorbent beds. In addition, heat is also exchanged between the zeolite adsorbent and the silica gel adsorbent beds. A lumped model is assumed for this cascading cycle. The COP for the base case is found to be 1.35, which is much higher than the COP of an intermittent cycle (about 0.5) and a two-bed combined heat and mass recovery cycle (about 0.8). However, its specific cooling power (SCP) of 42.7 W/kg is much lower than that of the intermittent cycle. The numerical results indicate that an optimal middle temperature exists for a prescribed driven temperature. The optimal COP increases with an increase in the driven temperature. However, when the driven temperature increases beyond 503 K, there is negligible change in the COP.     

Study on adsorption refrigeration cycle utilizing activated carbon fibers. Part 1. Adsorption characteristics

Thermal heat driven adsorption systems using natural refrigerants have been focused on the recent energy utilization trend. However, the drawbacks of these adsorption systems are their poor performance in terms of system cooling capacity and coefficient of performance (COP). The objective of this paper is to improve the performance of thermally powered adsorption cooling system by selecting new adsorbent–refrigerant pair. Adsorption capacity of adsorbent–refrigerant pair depends on the thermophysical properties (pore size, pore volume and pore diameter) of adsorbent and isothermal characteristics of the pair. In this paper, the thermophysical properties of two PAN types of activated carbon fibers (FX-400 and KF-1000) are determined from the nitrogen adsorption isotherms. The standard nitrogen gas adsorption/desorption measurements on various adsorbents at liquid nitrogen of temperature 77.3 K were performed. Surface area of each adsorbent was determined by the Brunauer, Emmett and Teller (BET) plot of nitrogen adsorption data. Pore size distribution was measured by the Horvath and Kawazoe (HK) method. As of the adsorption/desorption isotherms, FX-400 shows very small hysteresis when the value of P/P_o exceeds 0.4, while KF-1000 has no hysteresis in the whole range of P/P_o. The adsorption capacity of FX-400 is about 30% higher than that of KF-1000. The adsorption equilibrium data of activated carbon fiber (ACF)-methanol are presented and correlated with simple equations. The adsorption equilibrium data of ACF (KF-1000)-water also presented in order to facilitate comparison with those of ACFs-methanol pair. The results will contribute significantly in designing the adsorber/desorber heat exchanger for thermally driven adsorption cooling system.     

Performance of diffusion absorption refrigeration cycle with organic working fluids

A diffusion absorption refrigeration (DAR) cycle is driven by heat and utilizes a binary solution of refrigerant and absorbent as working fluid, together with an auxiliary inert gas. Commercial DAR systems operate with ammonia–water solution and hydrogen or helium as the inert gas. In this work, the performance of a simplified DAR system working with an organic absorbent (DMAC – dimethylacetamide) and five different refrigerants and helium as inert gas was examined numerically, with the aim of lowering the generator temperature and system pressure along with a non-toxic refrigerant The refrigerants were: chlorodifluoromethane (R22), difluoromethane (R32), 2-chloro-1,1,1,2-tetrafluoroethane (R124), pentafluoroethane (R125) and 1,1,1,2-tetrafluoroethane (R134a). The results were compared with the performance of the same system working with ammonia–water and helium. Similar behavior was found for all systems, regarding the coefficient of performance (COP) and rich and poor solution concentrations as functions of generator temperature. It was found that typical generator temperature with the new substances was 150 °C, yet lower COPs, higher evaporator temperatures and lower condensation temperature of about 40 °C governed these systems.     

Thermoeconomic evaluation and optimization of a double-effect H2O/LiBr vapour-absorption refrigeration system

In this paper, the thermoeconomic concept is applied to the optimization of a double-effect H₂O/LiBr VAR system, aimed at minimizing its overall product cost. A simplified cost minimization methodology based on the thermoeconomic concept is applied to calculate the economic costs of all the internal flows and products of the system by formulating thermoeconomic cost balances. Once these costs are determined, the system is thermoeconomically evaluated to identify the effects of the design variables on cost of the flows and products. This enables to suggest changes of the design variables that would make the overall system cost-effective. Finally, an approximate optimum design configuration is obtained by means of an iterative procedure. The result shows significant improvement in the system performance. The sensitivity analysis shows that the changes in optimal values of the decision variables are negligible with changes in the fuel cost.     

Study on adsorption refrigeration cycle utilizing activated carbon fibers. Part 2. Cycle performance evaluation

Thermal heat driven adsorption systems have been gained considerable attention on the recent energy utilization trend. However, the drawbacks of these adsorption systems are their poor performance. It is urgently necessary to improve the system performance of the adsorption cycles. There are two major ways for the system performance improvement. One is to develop new adsorbent material well suited to low temperature heat regeneration. The other is to enhance heat and mass transfer in the adsorber/desorber heat exchanger. The objective of the paper is to investigate the system performance of an adsorption cycle. The cycle utilizes activated carbon fiber (ACF)/methanol as adsorbent/refrigerant pair. In this paper, specific cooling effect SCE and COP of the system are numerically evaluated from the adsorption equilibrium theory with different hot, cooling and chilled fluid inlet temperatures. It is confirmed that the influences of hot, cooling and chilled fluid inlet temperatures on the system performance are qualitatively similar to those of silica gel/water pair. Even though, the driving temperature levels of ACF/methanol and silica gel/water are different. There is an optimum condition for COP to reach at maximum for ACF/methanol pair. Particularly, the ACF/methanol system shows better performance with lower chilled fluid inlet temperature between −20 and 20 °C.     

A generalized analysis for cascading single fluid vapor compression refrigeration cycles using an entropy generation minimization method

This paper focuses on cascading an ideal vapor compression cycle and determining the optimal intermediate temperatures based on the entropy generation minimization method. Only superheating and throttle losses of the cycle are considered since they are inherent to the ideal vapor compression refrigeration cycle. The second law equations have been developed in terms of specific heats and temperature ratios with the intent of reducing involved property modeling. Also the entropy generation was expressed in terms of a single independent variable and minimized to develop an advanced rule for selecting optimum intermediate temperatures. Results for a cascade system operating between reduced temperatures of 0.684 and 0.981 with R-134a as the working fluid are presented. The approximate method presented here predicted the optimum intermediate reduced temperature for a two-stage system to be 0.88, a difference of 2% from the optimum. The method presented was a much better predictor of the optimum temperature than the geometric mean method which was 0.82, a difference of 5% from the optimum. The entropy generation distribution of the optimum solution was investigated. For a two-stage system, the lower stage and higher stage entropy generation was 44% and 56%, respectively. In comparison to the single stage, the two-stage reduced losses by 78%.     

Extended temperature–entropy (T–s) diagrams for aqueous lithium bromide absorption refrigeration cycles

Temperature–entropy (T–s) diagrams have the unique capability of being able to quantify processes in terms of both the first and second laws of thermodynamics. Although use of generalised T–s diagrams has been made to indicate or represent generalised absorption cycles, with the exception for NH₃/water systems, these diagrams have not been specifically tailored to scale to quantify LiBr/water systems. The main barrier for this is that the diagram needs to represent the necessary properties of both the refrigerant (water) and of the solution (LiBr/water). This paper describes the use of the T–s diagram of water extended with additional curves to represent real and ideal LiBr/water absorption cycles. An explanation is provided on several methods available, including details of the thermodynamic justification of the method that was used, to construct the extended diagrams. Finally, the extended T–s diagram is provided with the representation of a real single-effect LiBr/water absorption refrigeration cycle. This should prove to be a valuable tool for design and research engineers to study and optimise LiBr/water chillers.     

Study of a novel silica gel–water adsorption chiller. Part II. Experimental study

The prototype of a novel silica gel–water adsorption chiller is built and its performance is tested in detail. The experimental results show that the refrigerating capacity (RC) and COP of the chiller are 7.15 and 0.38 kW, respectively, when the hot water temperature is 84.8 °C, the cooling water temperature is 30.6 °C, and the chilled water outlet temperature is 11.7 °C. The RC will reach 6 kW under the condition of 65 °C hot water temperature, 30.5 °C cooling water temperature and 17.6 °C chilled water temperature. The results confirm that this kind of adsorption chiller is an effective refrigerating machine though its performance is not as fine as the prediction results. Also it is well effectively driven by a low-grade heat source. Therefore, its applications to the low-grade heat source are much attractive.     

Thermodynamic analysis of an R744–R717 cascade refrigeration system

A thermodynamic analysis of carbon dioxide–ammonia (R744–R717) cascade refrigeration system is presented in this paper to optimize the design and operating parameters of the system. The design and operating parameters considered in this study include (1) condensing, subcooling, evaporating and superheating temperatures in the ammonia (R717) high-temperature circuit, (2) temperature difference in the cascade heat exchanger, and (3) evaporating, superheating, condensing and subcooling in the carbon dioxide (R744) low-temperature circuit. A multilinear regression analysis was employed in terms of subcooling, superheating, evaporating, condensing, and cascade heat exchanger temperature difference in order to develop mathematical expressions for maximum COP, an optimum evaporating temperature of R717 and an optimum mass flow ratio of R717 to that of R744 in the cascade system.     

Experimental investigation of silica gel–water adsorption chillers with and without a passive heat recovery scheme

We experimentally show that for the same heat exchanger inventory allocation, a four-bed adsorption chiller delivers a 12% higher ultimate cooling capacity than its two-bed counterpart. In addition it delivers a significantly improved quality of instantaneous cooling than a two-bed chiller at the same cooling capacity. The COP-enhancing feature of a passive heat recovery scheme that does not involve additional pumping action or valves is experimentally proven. It improves the COPs of a two-bed chiller and a four-bed chiller by as much as 38 and 25%, respectively, without any effect on their cooling capacities. The highest COPs achieved with a two-bed and four-bed chillers are 0.46±0.02 and 0.45±0.02, respectively. These are measured at a hot-water inlet temperature of 85 °C, cooling-water inlet temperature of 29.4 °C and chilled-water inlet temperature of 12.2 °C.     

Thermodynamic analysis of optimal condensing temperature of cascade-condenser in CO2/NH3 cascade refrigeration systems

This study thermodynamically analyzed a cascade refrigeration system that uses carbon dioxide and ammonia as refrigerants, to determine the optimal condensing temperature of the cascade-condenser given various design parameters, to maximize the COP and minimize the exergy destruction of the system. The design parameters include: the evaporating temperature, the condensing temperature and the temperature difference in the cascade-condenser. The results agreed closely with the reported experimental data. The optimal condensing temperature of the cascade-condenser increases with T_C, T_E and ΔT. The maximum COP increases with T_E, but decreases as T_C or ΔT increases. Two useful correlations that yield the optimal condensing temperature of the cascade-condenser and the corresponding maximum COP are presented.     

Fault diagnosis and refrigerant leak detection in vapour compression refrigeration systems

The environmental impact of refrigeration systems can be reduced by operation at higher efficiency and reduction of refrigerant leakage. Refrigerant loss contributes both directly and indirectly to global warming through inefficient system operation, increased power consumption and greenhouse gas emissions and higher maintenance costs. Existing sensor-based leak detection methods are limited by the inability to detect gradual leakage and the need for careful sensor location. There is a requirement for a real-time performance monitoring approach to leak detection and fault diagnosis which overcomes these disadvantages.This paper reports on the development of a fault diagnosis and refrigerant leak detection system based on artificial intelligence and real-time performance monitoring. The system has been used successfully to distinguish between faulty and fault free operation, steady-state and transient operation, leakage and over charge conditions. Work currently underway is aimed at testing additional fault conditions and establishing further rules to distinguish between these patterns.     

Modelling of reciprocating and scroll compressors

This paper presents simple and thermodynamically realistic models of two types of compressors widely used in domestic heat pumps (reciprocating and scroll compressors). These models calculate the mass flow rate of refrigerant and the power consumption from the knowledge of operating conditions and parameters. Some of these parameters may be found in the technical datasheets of compressors whereas others are determined in such a way that the calculated mass flow rate and electrical power match those given in these datasheets.The two models have been tested on five reciprocating compressors and five scroll compressors. This study has been limited to compressors with a maximum electrical power of 10 kW and for the following operating conditions: evaporating temperatures ranging from −20 to 15 °C and condensing temperatures ranging from 15 to 60 °C.The average discrepancies on mass flow rate and power for reciprocating compressors are 1.10 and 1.69% (for different refrigerants: R134a, R404A, R22, R12 and R407C). For scroll compressors, the average discrepancies on mass flow rate and power are 2.42 and 1.04% (for different refrigerants: R134a, R404A, R407C and R22).     

Carbon–ammonia pairs for adsorption refrigeration applications: ice making, air conditioning and heat pumping

A thermodynamic cycle model is used to select an optimum adsorbent-refrigerant pair in respect of a chosen figure of merit that could be the cooling production (MJ m⁻³), the heating production (MJ m⁻³) or the coefficient of performance (COP). This model is based mainly on the adsorption equilibrium equations of the adsorbent–refrigerant pair and heat flows. The simulation results of 26 various activated carbon–ammonia pairs for three cycles (single bed, two-bed and infinite number of beds) are presented at typical conditions for ice making, air conditioning and heat pumping applications. The driving temperature varies from 80 °C to 200 °C. The carbon absorbents investigated are mainly coconut shell and coal based types in multiple forms: monolithic, granular, compacted granular, fibre, compacted fibre, cloth, compacted cloth and powder. Considering a two-bed cycle, the best thermal performances based on power density are obtained with the monolithic carbon KOH-AC, with a driving temperature of 100 °C; the cooling production is about 66 MJ m⁻³ (COP = 0.45) and 151 MJ m⁻³ (COP = 0.61) for ice making and air conditioning respectively; the heating production is about 236 MJ m⁻³ (COP = 1.50).     

Methodology for thermal design of novel combined refrigeration/power binary fluid systems

Refrigeration cogeneration systems which generate power alongside with cooling improve energy utilization significantly, because such systems offer a more reasonable arrangement of energy and exergy “flows” within the system, which results in lower fuel consumption as compared to the separate generation of power and cooling or heating. This paper proposes several novel systems of that type, based on ammonia–water working fluid. Importantly, general principles for integration of refrigeration and power systems to produce better energy and exergy efficiencies are summarized, based primarily on the reduction of exergy destruction. The proposed plants analyzed here operate in a fully-integrated combined cycle mode with ammonia–water Rankine cycle(s) and an ammonia refrigeration cycle, interconnected by absorption, separation and heat transfer processes. It was found that the cogeneration systems have good performance, with energy and exergy efficiencies of 28% and 55–60%, respectively, for the base-case studied (at maximum heat input temperature of 450 °C). That efficiency is, by itself, excellent for cogeneration cycles using heat sources at these temperatures, with the exergy efficiency comparable to that of nuclear power plants. When using exhaust heat from topping gas turbine power plants, the total plant energy efficiency can rise to the remarkable value of about 57%. The hardware proposed for use is conventional and commercially available; no hardware additional to that needed in conventional power and absorption cycles is needed.