用数值模拟方法研究反向凝固主要工艺参数对母带厚度的影响

根据连续统一模型建立了描述反向凝固结晶器中的流动与传热的数学模型，计算出了反向凝固结晶器中母带厚度的变化规律，并进一步研究了反向凝固主要工艺参数对母带厚度变化的影响情况。计算结果表明采用数值模拟求解结果与实验数据是吻合的。     

反向凝固母带拉速对结晶器流场影响的数值模拟

在连续统一模型的基础上建立了描述反向凝固结晶器中的流动与传热的数学模型。利用有限差分方法，计算出了反向凝固结晶器中母带厚度的变化规律，随着母带在钢液中停留时间的增加，母带厚度初期迅速增长，中期平衡相持，后期快速回熔；并进一步研究了反向凝固母带拉速对结晶器中流场的影响情况，拉速较小时，紧贴母带的钢液随母带-同运动，对整个流场的影响不大，当拉速较大或拉速变化较大时，部分甚至整个流场都发生了变化。计算结果表明采用数值模拟求解结果与试验数据是吻合的，证明假设合理，模型正确。     

数值模拟研究钢液入口速度对结晶器流场的影响

在连续统一模型的基础上，建立描述反向凝固结晶器中的流动与传热的数学模型，利用有限差分方法，计算出反向凝固结晶器中母带厚度的变化规律，与实验数据基本吻合，在此基础上，研究入口钢液速度对结晶器中流场的影响。     

反向凝固高温轧制带坯及冷轧带的界面结合与力学性能

高温轧制带坯的研究了反向凝固高温轧制带坯的界面结合强度及横断面的硬度分布情况，并对反向凝固冷轧带的力学性能进行了检验。结果表明：界面结合强度约在380-490MPa之间；靠近界面处的凝固层的硬度远高于远离界面处的凝固层的硬度，靠近界面处的母带的硬度低于远离界面处的母带的硬度；反向凝固带坯冷轧后的屈服强度和抗拉强度均高于母带和凝固层金属，延伸率在两者之间。复合带的弯曲次数达到8.5次，其界面结合非常牢固。     

反向凝固法生产薄带母带与凝固层间焊合及复合机理的研究

研究了反向凝固法生产的钢带母带与凝固层间的焊合，分析了影响焊合的因素，并对复合机理进行了探讨。     

反向凝固与高温轧制过程中元素互扩散对复合界面的作用

在反向凝固与高温轧制过程中 ,母带与凝固层间一直进行着互扩散 ,C元素靠反应扩散由母带扩散到凝固层 ,Cr由凝固层扩散到母带 ,母带与凝固层之间存在明显的扩散层。Cr在母带中的扩散厚度约为 13μ。扩散到母带中的Cr和母带中的Fe形成固溶体 ,并析出Cr的碳化物。母带与凝固层界面实现了冶金结合     

铸造模拟关键热参数的反求优化及应用研究

铸造过程数值模拟技术已经得到广泛应用,想要获得准确的模拟结果,就需要输入准确的条件参数。然而,通过实验直接测量条件参数却比较困难,部分条件参数甚至无法直接测量获得。应用DOE设计方法进行重力砂铸凝固模型热物性参数敏感性实验,以实验实测温度曲线作为反算优化的初始输入条件,按热物性参数敏感性由高到低依次用ProCAST铸造模拟软件对数值模型的材料热属性、边界散热参数、界面传热系数等热物性关键参数进行反算优化,并将优化获得的热参数进行凝固模拟验证。结果表明,反算优化后的热参数可以准确匹配实测结果,达到无需直接测量而优化条件参数的目的。     

钢锭凝固过程温度场数值模拟

本研究采用大型商业软件MSC.Marc建立了38t钢锭凝固传热数学模型,模型中的钢热物性参数是通过钢凝固过程微观偏析模型预测钢锭凝固过程相的变化规律,并根据钢锭凝固过程钢热物性参数与相组成之间的关系式来确定.随后采用红外测温试验验证了钢锭凝固传热数学模型,并模拟了钢锭凝固过程温度场变化规律以及不同浇注温度和冒口保温条件对钢锭凝固过程的影响.结果表明:钢锭凝固过程由钢锭底部向冒口逐渐凝固,随着钢锭冒口发热剂的加入,钢锭凝固末期,最后凝固区域逐渐从无发热剂情况时位于钢锭本体向冒口区域移动.38t钢锭4125V2钢可采用向浇注后冒口加入200 mm厚发热剂增强钢锭凝固末期钢液补缩能力,脱模时间为浇注后12.5 h.     

反向凝固薄带的凝固层生长规律与焊合状况的研究

研究了母带厚度、钢液过热度、浸渍时间等工艺参数对薄带凝固层厚度的影响规律。认为母带与凝固层之间良好焊合的前提是母带表面产生部分熔化,并获得了焊合的最佳工艺条件。     

板坯连铸结晶器内钢凝固过程热行为研究Ⅰ.数学模型

建立了伴随δ/γ相变的钢凝固过程两相区溶质微观偏析模型,以其所确立的钢凝固过程各相分数与温度之间的关系获得钢的高温物性参数,并根据连铸坯在结晶器内凝固收缩量与结晶器内表面的位移关系、保护渣的液/固状态及厚度分布、铸坯表面和铜板热面的温度分布以及气隙的动态变化等建立了描述坯壳-铜板界面热流的数学模型.在此基础上,运用率相...     

金属板材成型性参数的预测方法

在材料织构定量分析的基础上，由织构级数展开系数计算金属板材的成型性参数，如塑性应变比Ｒ值与泰勒因子Ｍ等。通过物理数学模型的选择，提出了改进的简化数模。采用Ｂｕｎｇｅ符号系统与晶体学处理方法，建立了测算织构金属材料的成型性参数的新方法。理论预测与力学性能测试的结果相一致，证实了该法的准确性和可靠性     

高温金属间化合物的定向凝固特性

高温金属间化合物是一类重要的高温结构材料，其中Ti-Al及Ni-Al等许多合金系在凝固时都存在连续的包晶反应。本文就包晶合金凝固的特性从多方面加以总结和分析。凝固过程中的包晶相变对组成相的生长与取向有不同的影响。除此之外，定向凝固包晶反应过程中，相的竞争与选择及界面形态的演化也将同时对金属间化合物的凝固组织产生重要的影响。在考虑了界面温度对生长速率的响应后，可以发现生长速度超过某一值后亚稳相将析出，而根据凝固条件不同可以以不同的凝固方式进行长大，形成如带状、浅胞状和枝／胞双相共生等形式的组织，其中共生组织更有利于提高材料的单向力学性能。虽然定性的分析已获得某些规律，但作为工程应用的具有包晶反应特点的高温金属间化合物的定向凝固研究还极不充分，需进行大量的、基础的理论与实验研究。     

灰铁凝固过程中缩孔缩松的预测

通过热分析实验及对灰铁试件的浇注实验,分析了碳当量及孕育对灰铁凝固过程的影响.在动态膨胀叠加法的基础上,综合考虑了初始温度、碳当量、孕育、初晶和共晶体积的收缩与膨胀,建立了灰铁缩孔预测模型.开发了灰铁凝固过程数值模拟分析系统,并对实际的灰铁浇注件进行验证分析,预测结果与实验结果吻合较好.     

Sn60Pb40 solder powders produced by the planar flow casting atomization process

Conventional planar flow casting (PFC) is one of rapid solidification processes for the fabrication of microcrystalline or amorphous ribbons. Based on the conventional PFC process, the planar flow casting atomization (PFCA) process has been developed, which is a new rapid solidification process for the production of metal powder directly from alloy melts. A prototype experimental apparatus was designed and manufactured.With the apparatus, Sn60Pb40 alloy solder powders were prepared, and the effects of the main technological parameters on the powder size distribution and morphology were experimentally studied. The experimental investigations indicate that the metal powders produced by the PFCA process can be classified by velocity; and fine spherical tin-lead alloy solder powders can be fabricated by adjusting the technical parameters. The new PFCA process has such features as high productivity and efficiency, low energy consumption, simple operation,short technological process, and large gross yield.     

工艺参数对藕状多孔Mg合金结构影响的模拟仿真

在金属/气体共晶定向凝固工艺(Gasar)中,气体压力、过热度以及凝固速率是影响藕状多孔金属结构的最重要参数。建立了一个描述Gasar工艺过程的传热、传质、气孔形核、生长、合并及气孔与固相的协同生长的三维非稳态理论模型。并且采用有限差分的方式,实现了定向凝固铸造法Gasar工艺过程中藕状多孔结构形成及演变的计算机仿真,揭示了气体压力和凝固速率对藕状多孔金属最终结构参数的影响。基于Mg-H系的模拟与相应试验结果吻合较好,验证了所建仿真模型的合理性。     

A FINITE ELEMENT ANALYSIS OF ELECTROMAGNETIC SHEET METAL EXPANSION PROCESS

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A phase field model for isothermal solidification of multicomponent alloys

With the ability to model the kinetics and the pattern formation for solidification, a phase field model has been studied by many scientists. Currently available models, however, are restricted not only to binary alloys but also to those with substitutional solute elements. In this work, a new phase field model is developed to study solidification of a multicomponent alloy containing substitutional as well as interstitial solute elements. By employing the number of moles per unit volume as the concentration variable, the evolution equations of both the phase field and the concentration fields are derived from the free energy functional in the thermodynamically consistent way. In the model, the interfacial region is assumed to be a mixture of solid and liquid with the same composition, but with different chemical potentials. Based on this assumption, the phase field parameters are matched to the alloy properties and an interface thickness limitation is also deduced. Using the chemical rate theory, the phase field mobility is determined at a thin-interface limit condition under the assumption of negligible diffusivity in the solid phase. Another advantage of the model is that any thermodynamic database available in the literature can be directly ported to the model such that quantitative results for solidification of the real alloy systems could be made. As an example, a dendritic growth in an Fe-Mn-C ternary alloy is examined with the thermodynamic data from the commercial software Thermo-Calc code.     

液态结构对Al-Cu熔体过剩自由能的影响

通过分析Miediema模型和亚规则溶液模型在描述Al-Cu合金过剩自由能上的差异，提出了一个新的二元合金热力学模型。该模型考虑了液态结构因素对二元合金热力学性质的影响。与实验测定的溶液过剩自由能进行的比较表明，该模型具有良好的实用性。使用该模型可以计算熔体中不同成分的有序原子团对Al-Cu二元合金热力学性质的影响。     

Research on Transient Liquid Phase Diffusion Bonding of Steel Sandwich Panels Under Small Plastic Deformation

Plastic deformation was newly introduced in transient liquid phase (TLP) diffusion bonding of steel sandwich panels. The effect of plastic deformation on bonding strength was investigated through lab experiments. It was assumed that three factors, including newly generated metal surface area, deformation heat, and lattice distortion, contribute to the acceleration of interface atoms diffusion and increase of diffusion coefficients. A numerical model of isothermal solidification time was developed for TLP bonding process under plastic deformation and applied to carbon steel sandwich panels bonding with copper interlayer. A reasonable isothermal solidification time was obtained when an effective diffusion coefficient was used. Based on lab experiments, the effects of plastic deformation on interlayer film thickness and isothermal solidification time were studied through theoretical calculation with the new model. The evolution of interlayer film thickness indicates a good agreement between the calculation and experimental measurement. The results show that the isothermal solidification time is obviously reduced due to the effect of plastic deformation. Furthermore, a new steel sandwich cooling panel for heat exchanger was fabricated by TLP diffusion bonding under 13.1% plastic deformation. The test results suggest that a steel sandwich panel of inequidistant fin structure can provide enhanced heat transfer efficiency.