Kinetics of colour change of bamboo shoot slices during microwave drying

The effect of microwave power on colour change kinetics of bamboo shoot slices was investigated during microwave drying. Colour changes were quantified by tri‐stimulus Hunter L (whiteness/darkness), a (redness/greenness), and b (yellowness/blueness) system. These values were also used for calculation of total colour change (ΔE), chroma, hue angle, and browning index (BI). Microwave drying as expected changed colour parameters because of browning. The values of L and b decreased, while values of a and ΔE increased during drying. Mathematical modelling of colour change kinetics indicated that L, b, chroma and BI could be defined using a first‐order kinetic model, while a, ΔE and hue angle could be defined using a zero‐order kinetic model. Considering together colour deterioration and quality of dried bamboo shoot slices at higher power reveals the need of process standardisation for getting good quality product.     

The effect of heat treatment and starter culture on colour intensity and sensory properties of Kulek cheese

The effect of the heat treatment on colour intensity and sensory properties of Kulek cheese made from raw milk with (RS) or without starter culture (R) and heated milk with starter culture (HS) was investigated during ripening. Colour L, a and b values of Kulek cheeses were determined for both interior and surface. The values for cheese R were 82.4 and 74.5 for L, ?5.2 and ?5.5 for a, 31.0 and 34.7 for b interior and surface respectively. The equivalents for RS cheese were 82.8 and 75.7 for L, ?4.8 and ?5.0 for a, 31.0 and 34.0 for b. The values for HS cheese were 88.9 and 88.4 for L and ?3.3 and ?3.3 for a, 22.8 and 24.2 for b. L values (lightness) were the highest in cheeses made from heated milk while b and negative a values were the highest in cheeses made from raw milk. Aroma scores of raw and heat‐treated milk cheeses made with starter were not significantly different. The panelists scored cheeses made from raw milk without starter as the best in body and texture.     

Thermal degradation kinetics of anthocyanin and visual colour of plum puree

Thermal degradation kinetics of anthocyanin and visual colour (tristimulus L, a and b values) of plum puree were studied at selected temperatures (50–90 °C) for a residence time of 20 min. Results indicated that the thermal degradation of anthocyanin, tristimulus colour a value (representing redness) and L×a×b value (representing total colour) followed first-order reaction kinetics. The activation energy values for anthocyanin, red colour and total colour were 37.48, 25.86 and 30.68 kJ/mol respectively. Higher activation energy signified higher thermal sensitivity of anthocyanin during heat processing of plum puree. A linear relationship described well the variation of total visual colour (L×a×b) with anthocyanin content of plum puree during thermal processing.     

Comparison of Minolta colorimeter and machine vision system in measuring colour of irradiated Atlantic salmon

BACKGROUND: Minolta and machine vision are two different instrumental techniques used for measuring the colour of muscle food products. Between these two techniques, machine vision has many advantages, such as its ability to determine L*, a*, b* values for each pixel of a sample's image and to analyse the entire surface of a food regardless of surface uniformity and colour variation. The objective of this study was to measure the colour of irradiated Atlantic salmon fillets using a hand‐held Minolta colorimeter and a machine vision system and to compare their performance. RESULTS: The L*, a*, b* values of Atlantic salmon fillets subjected to different electron beam doses (0, 1, 1.5, 2 and 3 kGy) were measured using a Minolta CR‐200 Chroma Meter and a machine vision system. For both Minolta and machine vision the L* value increased and the a* and b* values decreased with increasing irradiation dose. However, the machine vision system showed significantly higher readings for L*, a*, b* values than the Minolta colorimeter. Because of this difference, colours that were actually measured by the two instruments were illustrated for visual comparison. Minolta readings resulted in a purplish colour based on average L*, a*, b* values, while machine vision readings resulted in an orange colour, which was expected for Atlantic salmon fillets. CONCLUSION: The Minolta colorimeter and the machine vision system were very close in reading the standard red plate with known L*, a*, b* values. Hence some caution is recommended in reporting colour values measured by Minolta, even when the ‘reference’ tiles are measured correctly. The reason for this discrepancy in colour readings for salmon is not known and needs further investigation. Copyright © 2009 Society of Chemical Industry     

Effects of dietary humate supplementation to broilers on performance,slaughter, carcass and meat colour

BACKGROUND: This experiment was designed to examine the effect of dietary humate supplementation primarily on pH and colour parameters of carcasses, breast fillets and drumsticks and, secondarily on performance and carcass characteristics in broilers. RESULTS: A total of 240 male broiler chicks (Ross‐308) were randomly allocated to four dietary treatments varying in supplemental humate level (0, 0.1, 0.2 and 0.3% for H₀, H₁, H₂ and H₃). Dietary humate supplementation did not affect performance traits and slaughter, hot carcass weights and yields. Carcass‐related variables (pH, L*, a*, b*, H* and C*) were responsive to the dietary treatments. The L*, a*, b*, and C* values for drumstick muscles were higher than those for breast muscles. Except for the L* value, meat colour parameters changed due to packaging. The a* value was higher and b* value was lower for vacuum packaged breast and drumsticks than for those aerobic packaged. Storage period affected colour parameters; while L*, b*, H* and C* values were higher for drumstick skin than for drumstick meat; the a* value was greater in drumstick meat than in skin. CONCLUSION: pH and colour parameters of carcasses, breast fillets and drumsticks of broilers were improved by dietary humate supplementation. However, responses of broiler performance and slaughter and carcass characteristics were minimal. Copyright © 2008 Society of Chemical Industry     

Development of a colour scale for colour evaluation of beef carcasses at 60 min post mortem

The pectoralis profundus muscles of 200 selected beef carcasses were measured to develop a standard colour scale for evaluating beef carcasses at the time of classification (approximately 60 min post mortem). Five lightness (L*) values were chosen ranging from 22 to 42 with intervals of five L* units. Corresponding a* and b* values were calculated. Based on regressions between the actual reflection spectra and the L*, a* and b* values, spectra of the five chosen colours for the colour scale were predicted. The L*, a* and b* values accurately predicted the reflection spectra. A paint company imitated the five reflection spectra. Spectra could not be matched exactly, without metamerism occuring. Therefore, the colour scale should be used with specific light sources. The scale is recommended in The Netherlands to classify the colour of beef, as a supplement of SEUROP‐system for conformation and fatness. © 1999 Society of Chemical Industry     

The use of bulgur as a meat replacement: bulgur‐sucuk (a vegetarian dry‐fermented sausage)

In this study, bulgur was used to produce a new sucuk (Turkish dry‐fermented sausage) as a vegetarian product. Yellow and black/brown bulgurs were mixed into the sucuk dough as fat and meat imitations respectively. Instead of animal fat, olive oil was used for lubrication. Nitrite and nitrate were not added to the recipe. The bulgur‐sucuk was ripened at 60–95% relative humidity and 18–25 °C over 15 days. During ripening, pH, moisture content and textural (hardness, adhesiveness, springiness, cohesiveness, gumminess, chewiness and resilience), sensory (flavour, colour, cutting and overall scores) and colour (Hunter L, a, b, yellowing index (YI), total colour difference, hue angle, chroma and browning index values) attributes were monitored. The pH and moisture content of the bulgur‐sucuk were 5.81 and 493 g kg^?1 respectively before ripening and decreased to 4.14 and 280 g kg^?1 during ripening. The colour values L, a, b and YI decreased significantly (P < 0.05) to 33.03, 7.67, 11.63 and 80.70 respectively during ripening. Some of these decreases in colour values were expected owing to the lack of nitrite and nitrate. All instrumentally measured textural properties of the bulgur‐sucuk increased significantly (P < 0.05) during ripening. From the results of the parameter measurements and sensory evaluations, bulgur appears to be suitable as a meat replacement when used in a dry‐fermented formulation. Copyright © 2006 Society of Chemical Industry     

Estimation of skin phototypes with optical parameters: an experimental study using newly developed fibre optic detection device

In an experimental study (October 2010 Mannheim Germany) with 99 Caucasian volunteers, the skin colour (L*, a*, b*) and the reflectance spectra of human skin were compared to the Fitzpatrick's sun‐reactive skin photo types (SPT). For this purpose, the skin colour and the reflectance spectra of human skin were determined using non‐invasive method with a newly developed fibre optic detection device. The device, based on reflectance spectroscopy, was designed and optimized using a commercial optical analysis Software. By means of the measured spectra of scattered light, the colour values and the absorption spectra of the skin were calculated. Neither any of the L*, a*, b* colour values nor any of the parameters of the absorbance spectra can be used alone to assess the skin type properly. Therefore, an ordinal logistic regression analysis was performed, using the statistical computing software r , to correlate the skin types with the measured optical parameters. It turned out that the detection device combined with the extended statistical analysis gives a better estimate of skin type in respect of the measured optical parameters than a procedure with only L*, a*, b* colour values. Even with the extended methodology, the procedure gives only a rough estimation of the skin type.     

Colour of post-harvest ripened and vine ripened tomatoes (Lycopersicon esculentum Mill.) as related to total antioxidant capacity and chemical composition

Greenhouse grown tomatoes (cvs ‘Durinta’, ‘Favorita’ and ‘Liberto’) were harvested green and vine ripe. Colour measurements and chemical analyses were performed on green, post‐harvest red and vine‐ripe fruits. Partial least square (PLS) regression was applied to predict the ferric reducing ability of plasma (FRAP) by means of colour measurements (L*, a* and b*). The PLS showed that 78% of the variation in colour were able to predict 74% of the variation in FRAP value. Chemical variables and colour variables together were able to predict 88% of the variation in FRAP by means of PLS regression. Linear regression showed a high negative correlation between high values of L*, b* and FRAP, and a high positive correlation between titratable acidity, a*, hue, a*/b*, soluble solids, vitamin C, dry matter and FRAP values. Thus, colour measurements of intact tomatoes can be used as a non‐destructive method to assess total antioxidant capacity of tomatoes.     

Modelling the biological variance of the yellow aspect of Granny Smith apple colour

BACKGROUND: The yellow aspect of colour is usually not considered for produce with a green‐to‐red or a green‐to‐yellow transition upon ripening. The magnitude of change is simply too small and, additionally, masked by a large variation. The colour of ‘Granny Smith’ apples, harvested from three orchards at two stages of maturity, was measured individually using the CIE L*a*b* system during storage in a regular atmosphere at three temperatures: 1, 4 and 10 °C. A model was developed based on a simplified mechanism, consisting of two consecutive reactions, to describe the development of the apple colour expressed as b* and L* values during storage. RESULTS: Monitoring individual apples made it possible to include and describe the biological variance of colour in batches of apples and to extract information on chilling injury, as a process active at 1 °C. All variations could be attributed to a single source related to the amount of yellowing compounds at the moment of harvest, indicating differences in state of maturity between individual apples. The obtained explained part (R²_adj), using nonlinear mixed effects regression analysis was well over 90% for all data combined over more than 3000 observations. CONCLUSION: Orchard location had a slight effect on the mean initial colour value, indicating differences in development stage, most probably due to differences in assessing the harvest date. The magnitude of the variation in these colour values was, however, the same for all three orchards. The behaviour of the green colour aspect (a* value) has been reported separately, as this represents the major change in perceived colour. The changes in b* and L* values are rather small, while the biological variation between the individual fruit is at least of the same magnitude. The model presented here is, as far as known, the first model on b* and L* values for green‐coloured products. Analysing b* and L* data using this model provides additional information with respect to the stage of maturity at harvest in a batch or for an orchard of Granny Smith apples. All the variation in the yellow colour aspects could be attributed exclusively to the initial level of yellow compounds. Copyright © 2010 Society of Chemical Industry     

Non-destructive and objective methods for the evaluation of the maturation level of olive fruit

The maturation level of two olive varieties (Olea europaea, cvs. Arbequina and Picual) was objectively evaluated using two non-destructive methods: checking the fruit firmness using a hand densimeter, and the skin colour with a portable colourimeter. These methods were compared with the Ripening Index (RI), habitually used by olive oil industry, and based on the subjective determination of skin and flesh colour. The values of skin colour [L*(b*–a*)/100] only monitor the olive maturation in both varieties, when the olive is losing its initial green colour, while fruit firmness is decreasing throughout the maturation process. Fruit firmness is directly related to RI and could be useful in objectively estimating the maturation level of the olives.     

Determination of optimum processing conditions for hot‐air roasting of hulled sesame seeds using response surface methodology

Sesame paste (tahin) is produced by milling hulled, roasted, sesame seeds. In this study, a hot‐air roasting process for the production of sesame paste was optimised by response surface methodology (RSM) over a range of air temperatures (120–180 °C) for various times (30–60 min). The colour parameters (L, a and b values), browning index (BI), hardness, fracturability and moisture content of the seeds were used as response parameters to develop predictive models and optimise the roasting process. Increases in roasting temperature and time caused increases in the a and b values and in the BI. The hardness and fracturability of seeds also decreased with increasing roasting temperature and time. The quadratic and linear models developed by RSM adequately described the changes in the colour values and textural parameters, respectively. The result of RSM analysis showed that all colour parameters and textural parameters should be used to monitor the roasting of sesame seeds in a hot‐air roaster. To obtain the desired colour and texture, the optimum roasting range for production of sesame paste was determined as 155–170 °C for 40–60 min. Copyright © 2006 Society of Chemical Industry     

Influence of pH on colour and iron content of peptide fractions obtained from bovine Hb concentrate hydrolysates

The effect of pH on colour and iron content (Fe) of peptide fractions obtained from bovine haemoglobin concentrate (BHC) hydrolysates was studied. Four hydrolysates were obtained using three enzymes: Protex‐6‐L (P), Fungal–Protease–Concetrate (FC) and Flavourzyme (F). BHC and its hydrolysates (P, FC, P + F, FC + F) were fractioned at pH 4.5, 7.0 and 9.5. Solubility and Fe from different fractions were measured. Correlations between CIELAB colour parameters and Fe from different fractions were analysed. The colour from different fractions varied from red to yellow (a* and b* positives). Lightness values (L*) ranged from twenty‐four to seventy. FC4.5 and FC + F4.5 fractions were the clearest and yellow (higher L*, b*, h), while BHC9.5 and P + F9.5 fractions had the lowest values of L*, b* and h. There was an inverse linear relationship between b* and L* parameters and Fe from fractions. This relationship could be associated with the pH of extraction. As pH increases Fe significantly increases and lower b* and L* values were obtained.     

Colour differences in paprika pepper varieties (Capsicum annuumL) cultivated in a greenhouse and in the open air

The quality of six paprika pepper varieties, cultivated in a greenhouse and in the open air, has been studied. There were differences in their paprika colours with regard to the total content of pigments (ASTA unities) and the quotient of the absorbance spectra values for red and yellow pigments (tint). Using colorimetric measurements, directly carried out on the surface of the ripe fruits, the varieties are clearly separated in the CIELAB space colour, depending on their growing conditions. The colorimetric coordinates a* and b* and quotient a*/b* of the ripe fruits, cultivated in greenhouse, allow to predict the total pigments concentration of the resulting paprika. For the cultivations in the open air, the fruit brightness (L*) and the chromatic quotient 2000×a*/L*×b* are the parameters which show best the correlation with the total content of the paprika pigments. The fruit colour change, from green to red, coincides in both growing conditions with the moment when the chlorophyll b concentration surpasses the a one. © 1998 SCI.     

Degradation Kinetics of Colour and Total Carotenoids in Jackfruit (Artocarpus heterophyllus) Bulb Slices During Hot Air Drying

The kinetics of colour and carotenoids degradation in jackfruit bulb slices was evaluated during hot air drying at 50, 60 and 70 °C. Visual colour as well as total carotenoids (TC) content was found to be influenced by the drying process. Tri-stimulus colour parameters such as Hunter L and b values decreased and a value increased during drying. The combination of Hunter L × b value was found to represent the colour change adequately. Degradation of TC and visual colour in terms of Hunter L × b value followed first-order reaction kinetics; however, zero-order reaction kinetics was found adequate to describe changes in total colour difference (TCD) and non-enzymatic browning (NEB). Dependence of the rate constant followed the Arrhenius relationship. The process activation energies (E _a) for Hunter L × b value, TCD, NEB and TC were 29.96, 27.21, 27.48 and 55.61 kJ/mol, respectively. Higher E _a for TC content indicated greater temperature sensitivity as compared with other colour parameters. Relationship of TC content and Hunter L × b value was found to be more consistent through regression analysis with R ² ≥ 0.979.     

Colour values of cooked top-round beef juices as affected by endpoint temperatures,frozen storage of cooked samples and storage of expressed juices

Juices from beef semimembranosus/adductor tissue, cooked to endpoint temperatures (EPTs) of 76, 78, 80, 82 and 84°C in a model heat-treating system, were evaluated for changes in CIELAB L*a*b*, chroma (C) and hue angle (H) values before and after storage of the cooked meat at -20°C for 3 weeks and after storage of the expressed juices under N₂ at 3°C for 72 h. Increases in EPTs altered all colour values of the juices. Lightness (L*) increased while yellowness (b*) decreased; redness (a*) and C decreased progressively while H increased toward the vertical axis. Storage of the expressed juices at 3°C under N₂ did not inhibit changes in a*, b*, C and H values. Regression coefficients of changes in relation to EPTs and time of storage of the expressed juices under N₂ were established. Storage of the cooked meats for 3 weeks at -20°C did not change any of the colour values of the juices. These data indicate that evaluations of cooked beef for doneness by colour of expressed juices must be performed immediately after expression of the juices before oxidation of the myoglobin pigments occurs. Storage of cooked meat at -20°C does not alter the colour of the juices, therefore, valid assays for doneness of meat in relation to juice colour can be made after frozen storage. © 1997 This article is a US Government work and, as such, is in the public domain in the United States of America     

Prediction of colour of European Emmental cheeses by using near infrared spectroscopy: a feasibility study

Near infrared (NIR) spectroscopy was used to predict colour of European Emmental cheese samples. Colour values (L, a and b) were measured on 20 Emmental cheese samples using a Hunter-lab D25-D-2 optical head in the system according to Hunter to determine L (brightness), a (green-red component) and b (blue-yellow component). The diffuse reflectance of the investigated cheeses was also determined by a Büchi NIR Lab N-200 spectrometer using a rotating measuring cell in the range of 1000–2500 nm. The best results for L-value (squared correlation coefficient (R ²) = 0.56, root mean square error of cross-validation (RMSECV) = 0.76, ratio of prediction deviation (RPD) = 1.89 and range error ratio (RER) = 7.91), a-value (R ² = 0.72, RMSECV = 0.15, RPD = 1.98 and RER = 7.6) and b-value (R ² = 0.82, RMSECV = 0.52, RPD = 2.56 and RER = 9.42) were obtained when the first 12 principal components (PCs) of the principal component analysis (PCA) applied on normalised NIR spectra were used. It can be concluded that NIR spectroscopy could be used to predict b-value. The a- and L-values can also be predicted from NIR technique with approximate quantitative prediction.     

Acrylamide in roasted barley grains: presence,correlation with colour and decrease during storage

We investigated the presence of acrylamide in roasted barley grains, and assessed the correlation between acrylamide concentration and colour, and also examined acrylamide decrease during storage. Acrylamide concentrations in 45 commercially available roasted barley grains were analysed. The mean and standard deviation were 0.24 and 0.08 mg kg^?1, respectively. The CIE colour parameter a* value had little correlation with acrylamide concentration in roasted barley grains; however, the L* and b* values showed correlations with acrylamide concentration in the grains, yielding a correlation coefficient of 0.42 and 0.40, respectively. Darker-coloured roasted barley grains with lower L* values may contain lower amounts of acrylamide. Although acrylamide concentration decreased by 40% in the grains, and decreased by 36% in the milled grains (teabag form) after 309 days of storage at room temperature a significant difference in the rate of acrylamide decrease was not observed between the grain and teabag forms. The data obtained in this study are of importance to the risk assessment and management of acrylamide exposure in Japan.     

Comparative effect of red yeast rice (Monascus purpureus), red beet root (Beta vulgaris) and betanin (E‐162) on colour and consumer acceptability of fresh pork sausages packaged in a modified atmosphere

Fresh pork sausages containing natural colorants, red yeast rice powder (Monascus purpureus; Frame^®) or a crude red beet root (Beta vulgaris) juice or commercial betanin (E‐162), at different concentrations, were packaged in an atmosphere containing 80% O₂ and 20% CO₂ and stored in the dark for 20 days. The following parameters were measured at 4 day intervals: instrumental colour (CIE L*, a*, b*, a*/b*, C* and h*), reflectance spectra, sensory discoloration (trained panel) and acceptability and willingness to purchase (habitual and non‐habitual consumer panels) under two different lighting displays (standard fluorescent and Promolux^® lamp). The use of colorants improved the colour properties of fresh pork sausages. Sausages with red yeast rice, red beet root juice and betanin had lower L* and h* and higher a* and a*/b* values than control samples. The colour properties of sausages with red beet root were the closest to control sausages, while sausages with red yeast rice had significantly lower b* values. Both natural colorants and betanin protected sausages from discoloration and extended acceptability and willingness to purchase by about 4 days, according to evaluation by habitual consumers under two different types of lighting display. Therefore, red beet root juice may be envisaged as the most suitable natural colorant for use in fresh pork sausages. Copyright © 2005 Society of Chemical Industry