共查询到19条相似文献,搜索用时 140 毫秒
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高性能、低成本锂离子电池隔膜的开发对于锂离子电池的技术进步与商业应用具有重要意义。本文从电池隔膜的性能要求出发,重点概述了液态多孔隔膜、半液态隔膜和全固态隔膜的结构特点、性能优劣及其制备技术,并展望了锂离子电池隔膜的研究方向和发展趋势。 相似文献
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V_2O_5具有容量高、循环稳定、易于制备成薄膜等特点,是全固态薄膜锂电池理想的正极材料。采用磁控溅射法,以V_2O_5为靶材制备了薄膜,研究了溅射气体Ar/O_2对薄膜结构、形貌及电化学性能的影响,优化了薄膜制备工艺。最终采用磁控溅射法依次沉积集流体薄膜、钒氧化物薄膜、固态电解质薄膜,真空热蒸发金属锂薄膜,成功制备了Al/V_2O_5/Li P ON/Li/Cu全固态薄膜锂电池。薄膜电池在1.7~3.4 V电压范围内,以10μA/cm~2恒电流充放电测试,电池比容量达到25μAh/cm~2,稳定循环超过500次。 相似文献
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ConventionalSOFCsareusuallyoperatedat 10 0 0℃ Duetoitshighoperationaltemperature ,thematerialsdemandinguponSOFCcomponentsarequitestringent Manyresearchersaregradu allyinterestedinintermediatetemperaturesolidoxidefuelcell(IT SOFC) [1-2 ] TherearetwopossibleapproachesforloweringtheoperatingtemperatureofSOFCs Thefirstistoreducethethicknessofelec trolyte ,forexampletheelectrolyteinanode supportedplanar typesinglecellisonly 2 0 μm Thesecondistodevelophigherconducti vityelectrolyte .Inth… 相似文献
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Arun Patil Vaishali Patil Ji-Won Choi Hyun-Jai Kim Bong-Hee Cho Seok-Jin Yoon 《Journal of Electroceramics》2009,23(2-4):230-235
Low cost anode materials having a high electrochemical efficiency have been critical in the success of thin film batteries that are applicable in ubiquitous environments as a portable energy source. Nichrome thin films are ideally suited for use in hybrid assemblies but their applications include precision integrated circuits in fields of telecommunications, instrumentation, power supplies, military and medical equipment where low noise and good power dissipation are required. With such a wide spectrum of applications, it is important to understand the electric behavior of the Nichrome alloy thin films by their microstructure. In this work, nanocrystalline films of nickel chromium alloys were deposited on alumina substrate by radio frequency (RF) magnetron sputtering technology. High purity nickel and chromium sputtering target were used for the deposition. First, aluminum was deposited on ceramic substrate acts as a current collector and over that NiCr was deposited by RF sputtering method. Both the layers were analyzed for structural and electrical properties using X-ray diffraction (XRD), energy dispersive X-ray analysis (EDS), atomic force microscopy (AFM), scanning electron microscopy (SEM) and cyclic voltammetry. The XRD peak confirms that deposited NiCr and Aluminum have tetragonal and cubic structures, respectively. The crystallite size was determined by full width at half maximum of XRD peaks. Structure, composition and the properties of the film are the major focus of this paper. Composition ratio between nickel and chrome obtained by EDS is 1:1. Particle size and microstructure of the film have been studied by SEM and AFM. Electrochemical properties of the films were analyzed. Reaction mechanism for the insertion and excretion is reported. After Lithium insertion and extraction the effect on the surface and structure of the thin film has been studied. The composition of equilibrium phases of NiCr as useful as attracting anode for the thin film battery. Nichrome on aluminum thin films as an anode has been attracted because it provides practical advantages including low cost production and competitive electrical performance. 相似文献
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Fukunori Izumida Rongbin Ye Koji Ohta Mamoru Baba Michiko Kusunoki 《IEEJ Transactions on Electrical and Electronic Engineering》2012,7(4):436-437
To use carbon nanotubes (CNTs) as anode material for the solid‐state thin‐film Li‐ion rechargeable battery, the tubes are preferred to be aligned perpendicular to a substrate and the CNT thin film to have a smooth surface. Using an Ar‐ion sputtering technique, we carried out the surface modifications of the CNT thin film prepared by the SiC surface decomposition method. In order to evaluate the surface modification, the surface and cross section of the modified CNT film were investigated by field‐emission scanning electron microscopy and atomic force microscopy. © 2012 Institute of Electrical Engineers of Japan. Published by John Wiley & Sons, Inc. 相似文献
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The high-field currents in poly-p-chloro-xylylene (PCPX) thin films are due to hole injection from anode metal and collision ionization. PPX thin films showed the negative temperature dependence of high-field currents. Since the chlorine atoms in PCPX thin films act as carrier scattering centers, high-field currents in PCPX thin films are suppressed in the low-temperature region. This paper discusses the high-field currents of PCPX/PPX composite thin films; these films are PCPX thin films (d < 150 nm) deposited on PPX thin films (d > 200 nm). They were strongly suppressed at room temperature, but not at low temperature. Therefore, PCPX/PPX composite thin films showed a remarkable negative temperature dependence of high-field currents. High-field currents were suppressed more in PCPX (60 nm)/PPX (230 nm) composite thin film than in PCPX (130 nm)/PPX (230 nm). This can be explained by the suppression of the hole injection from anode by homo space charge at the interface between PCPX/PPX. 相似文献
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硅基材料是新一代高容量锂离子蓄电池负极材料的典型代表,近年来已成为理论研究和应用研究的热点之一。综述了单质硅、硅-金属合金以及硅-碳复合材料作锂离子蓄电池负极材料最新研究成果,并对其今后研究和应用前景作了展望。纳米级硅薄膜具有大于3500mAh/g的超高可逆容量,有望用于微型锂离子蓄电池;硅-金属合金材料的研究正在由单相搀杂向多相搀杂的方向转移;而硅-碳复合材料能有效抑制硅的体积变化,在发挥高放电容量的同时能保持良好的循环特性,很有可能成为规模化生产的新一代负极材料。 相似文献
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LaNiO3 (LNO) thin films were prepared on Si (100) wafer by MOD method. Pb(Zr, Ti)O3 ferroelectric thin films and their compositionally graded thin films were prepared on LNO/Si (100) substrates by a modified sol–gel method. The composition depth profile of a graded film was determined by using a combination of Auger electron spectroscopy and Ar ion etching. The results confirmed that the processing method produces graded composition change. XRD analysis showed that the graded thin film possessed a composite structure of tetragonal and rhombohedral. The dielectric constant of the graded thin films was higher than that of each thin film unit, but the loss tangent was near to each other at 10 kHz. The temperature characteristics of the dielectric constant of the graded thin films at different frequencies showed three peaks and ferroelectric relaxor feature to some extent. Hysteresis loops showed that graded thin film had higher remanent polarization, smaller coercive field than each thin film unit. The pyroelectric coefficient of the graded thin films increased gradually with temperature, and was higher than that of each thin film unit. 相似文献