共查询到20条相似文献,搜索用时 62 毫秒
1.
2.
《新型炭材料》2015,(5)
以量大价廉的稻壳为原料,先后经Na OH脱硅处理、预氧化、磷酸活化,在无模板的情况下制备出介孔炭材料。Na OH脱硅处理可有效除去稻壳中的硅并破坏纤维素的晶体结构,脱硅过程中形成的孔隙亦有利于高比表面积和高中孔率介孔炭的制备。所制介孔炭比表面积和中孔率分别高达2 009 m2·g-1和90.8%。其在50 m A·g-1电流密度下的比电容达176 F·g-1,即使在1 000 m A·g-1的大电流下,其比电容仍保持在126 F·g-1,表现出优异的倍率能力。所制介孔炭具有良好的循环稳定性,在200·m A g-1电流密度下的比电容高达150 F·g-1,1 000次循环无容量衰减。稻壳基介孔炭在超级电容器领域具有良好的应用前景。 相似文献
3.
4.
高性能超级电容器用高比表面积、层次孔结构炭材料的简便制备(英文) 总被引:1,自引:0,他引:1
采用NaOH一步炭化-活化聚偏二氯乙烯(PVDC)简便制备出高比表面积、层次孔结构炭材料。该炭材料具有发达的微孔-中孔-大孔的层次孔结构,其比表面达到2 815 m·2g-1。独特的微结构使其在无机和有机电解液中都表现出高的比电容和优异的大电流性能。其在6 mol·L-1KOH电解液中以0.05 A·g-1电流充放电测得的比电容高达376F·g-1,电流密度增大到50A·g-1比电容还保持215 F·g-1。在有机电解液1 mol·L-1Et4NBF4/AN中的比电容也达到170 F·g-1(电流密度0.05 A.g-1),电流密度增大到20A·g-1比容量还保持124F·g-1。 相似文献
5.
热解柠檬酸镁或柠檬酸钡,制备了两种介孔炭(MgC或BaC),并将其用作双电层电容器电极材料。采用氮气吸附、扫描电子显微镜和傅里叶红外光谱对所制介孔炭进行表征。结果表明:所制介孔炭孔结构与柠檬酸盐所含金属阳离子有关。其中,BaC呈典型的双峰孔径分布,最可几孔径分别为3.8nm和15nm;而MgC的孔道主要是小尺寸的介孔或微孔。通过循环伏安、恒流充放电法测试所制介孔炭作为电化学电容器电极材料时的电化学性质。测试表明,在离子液体中MgC和BaC都具有很高的比电容值,分别达到180F.g-1和171F.g-1。其中,BaC的倍率性能良好,能量密度可达到53.3Wh.kg-1,最大功率密度为20kW.kg-1。BaC优良的电容特性主要归因于其孔径双峰分布的孔结构和亲水性表面化学性质。 相似文献
6.
本研究利用线性酚醛树脂体系,以溶胶-凝胶法在常压条件下制得有机气凝胶,并进一步碳化制备出碳气凝胶.研究发现,该碳气凝胶经过KOH活化后,具有微/介/大孔的分级孔结构,且比表面高达2091.87 m2·g-1.对材料进行电化学性能研究发现,其在1 A·g-1电流密度下,比电容为282.3 F·g-1.在600 W·kg-... 相似文献
7.
由于纯碳材料单一的双电层储能机理, 其比电容较低, 而赝电容材料可利用法拉第反应进行能量存储, 可以获得较高的比电容。作者利用软模板法制备出具有三维有序结构的介孔碳微球, 然后采用水热法制备氢醌改性的介孔碳微球。循环伏安和恒流充放电测试表明, 氢醌改性使得介孔碳微球不仅具有双电层电容, 而且具有赝电容。负载10wt%氢醌的介孔碳微球具有最大的比电容值, 当电流密度为0.5 A/g时, 其比电容值高达285 F/g; 当电流密度增大到10 A/g时, 其比电容值仍高达212 F/g, 表现出优异的倍率特性。这主要归因于氢醌以π-π堆叠方式负载在碳质介孔表面, 不仅提供了额外的赝电容, 而且提高了碳材料在水系电解液中的倍率特性。 相似文献
8.
通过简单的水热法以及后续热处理,成功合成介孔NiCo_2O_4微球。利用FESEM、TEM、XPS和电化学工作站对样品的表面形貌、元素价态和电化学性能进行表征。结果表明:合成的NiCo_2O_4拥有丰富的多孔纳米针状结构,表现出较高的比表面积。由于这种三维多孔纳米结构,当NiCo_2O_4微球作为电极材料时,展现出优异的电容特性,在1A·g-1的电流密度下比电容高达1 554F·g-1,而且当电流密度增加到20A·g-1时,电容保持率为87.5%。另外,在5A·g-1的电流密度下,经过2 000次的充放电循环后,比电容仍能保持初始电容的90.4%。良好的电化学性能表明,NiCo_2O_4微球是一种理想的超级电容器电极材料。 相似文献
9.
10.
11.
《International journal for numerical methods in engineering》2018,113(9):1488-1506
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method. 相似文献
12.
13.
Standards are the basis for production enterprises to organize production ex-factory inspection trade 《中国标准化(英文版)》2008,25(1):24-25
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.…… 相似文献
14.
A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa. 相似文献
15.
On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.…… 相似文献
16.
Zusammenfassung Bei der Gestaltung von Ernteprozessen — beispielsweise des Prozesses Mähdrusch, Körnertransport und -abnahme — als transportverbundene Fließarbeitsverfahren mit mindestens zwei verschiedenen Arbeitsmitteln gibt es einen großen Optimierungsspielraum. Solche Prozesse sind mehrstufige Bedienungsprozesse mit gemischter Anordnung der Bedienungseinrichtungen. Außerdem besitzen sie stark ausgeprägte räumliche Aspekte. Es wird vor allem gezeigt, welche Merkmale solcher Prozesse in Simulationsmodellen abgebildet sein müssen, welche Zielgrößen in Abhängigkeit von welchen Einflußgrößen unter Berücksichtigung welcher Prozeßbedingungen ermittelt werden sollten und wie der Bewertungsprozeß zur Ermittlung der gewünschten Informationen gestaltet werden muß. 相似文献
17.
C. Qihong W. Zhan‐Wen J. Yi J. Yehua L. Fei F. Hanguang 《Materialwissenschaft und Werkstofftechnik》2014,45(7):582-590
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill. 相似文献
18.
Dimiter Hadjistamov 《材料科学与工程:中英文B版...》2019,(2):56-65
The definition of the thixotropy is a decrease in viscosity with time in shear and a subsequent recovery of viscosity after the shear deformation is removed.We ... 相似文献
19.
《中国标准化(英文版)》2014,(4)
正Responding to ISO’s appeal for survey for the to-be-developed ISO Strategy Plan for 2016-2020,SAC hosted a special workshop over the needs and comments of various fi elds on June 8 in Beijing.The workshop was attended by ISO President-elect and Ansteel General Manager Zhang Xiaogang,SAC Vice-Administrator Yu Xinli,and 30 experts from 相似文献
20.
《中国标准化(英文版)》2014,(5)
正The review group of Asia Pacific Laboratory Accreditation Cooperation(APLAC)carried out a 4-day peer review of the proficiency testing provider(PTP)for China National Accreditation Service for Conformity Assessment(CNAS)from July 28 to 31,2014.CNAS passed the PTP review with excellent performance.Two senior peer reviewers of APLAC made a comprehensive,rigorous and detailed review of CNAS’s PTP accreditation activities,and made the on-spot inspection of the review groups in Shanghai and Shenzhen respectively. 相似文献