Residue strength,water absorption and pore size distributions of recycled aggregate concrete after exposure to elevated temperatures

In this paper, the effects of high temperature exposure of recycled aggregate concretes in terms of residual strengths, capillary water absorption capacity and pore size distribution are discussed. Two mineral admixtures, fly ash (FA) and ground granulated blast furnace (GGBS) were used in the experiment to partially replace ordinary Portland cement for concrete production. The water to cementitious materials ratio was maintained at 0.50 for all the concrete mixes. The replacement levels of natural aggregates by recycled aggregates were at 0%, 50% and 100%. The concretes were exposed separately to 300 °C, 500 °C and 800 °C, and the compressive and splitting tensile strength, capillary water coefficient, porosity and pore size distribution were determined before and after the exposure to the high temperatures. The results show that the concretes made with recycled aggregates suffered less deteriorations in mechanical and durability properties than the concrete made with natural aggregates after the high temperature exposures.     

The effect of mineral admixtures on the properties of high-performance concrete

The paper presents a laboratory study on the influence of two mineral admixtures, silica fume (SF) and fly ash (FA), on the properties of superplasticised high-performance concrete. Assessment of the concrete mixes was based on short- and long-term testing techniques used for the purpose of designing and controlling the quality of high-performance concrete. These include compressive strength, porosity, oxygen permeability, oxygen diffusion and chloride migration. Measurements were carried out after curing at 20% and 65% relative humidity up to the age of 1 yr. The results, in general, showed that mineral admixtures improved the properties of high-performance concretes, but at different rates depending on the binder type. While SF contributed to both short- and long-term properties of concrete, FA required a relatively longer time to get its beneficial effect. In the long term, both mineral admixtures slightly increased compressive strength by about 10%, but contributed more to the improvement of transport properties of concretes.     

Transport and mechanical properties of self consolidating concrete with high volume fly ash

This paper presents the transport and mechanical properties of self consolidating concrete that contain high percentages of low-lime and high-lime fly ash (FA). Self consolidating concretes (SCC) containing five different contents of high-lime FA and low-lime FA as a replacement of cement (30, 40, 50, 60 and 70 by weight of total cementitious material) are examined. For comparison, a control SCC mixture without any FA was also produced. The fresh properties of the SCCs were observed through, slump flow time and diameter, V-funnel flow time, L-box height ratio, and segregation ratio. The hardened properties included the compressive strength, split tensile strength, drying shrinkage and transport properties (absorption, sorptivity and rapid chloride permeability tests) up to 365 days. Test results confirm that it is possible to produce SCC with a 70% of cement replacement by both types of FA. The use of high volumes of FA in SCC not only improved the workability and transport properties but also made it possible to produce concretes between 33 and 40 MPa compressive strength at 28 days, which exceeds the nominal compressive strength for normal concrete (30 MPa).     

Mechanical performance of low cement reactive powder concrete (LCRPC)

The possibility of producing a reactive powder concrete (RPC) with low cement content was aimed in the scope of this study. Cement was replaced with class-C fly ash (FA) up to 60% for this purpose. Three different curing conditions (standard water curing, autoclave curing and steam curing) were applied to specimens. Two series of RPC composites were prepared with bauxite and granite aggregates. Mechanical properties such as compressive strength, splitting tensile strength, flexural strength and fracture energy of composites were investigated. Test results showed that, compressive strength of 200 MPa can be reached with low cement by using high-volume fly ash. Thermally treated specimens showed compressive strength beyond 250 MPa and high volume fly ash RPC have superior performance. Furthermore, compressive strength values reached up to 400 MPa with external pressure application during setting and hardening stages.     

Mechanical performance of low cement reactive powder concrete (LCRPC)

The possibility of producing a reactive powder concrete (RPC) with low cement content was aimed in the scope of this study. Cement was replaced with class-C fly ash (FA) up to 60% for this purpose. Three different curing conditions (standard water curing, autoclave curing and steam curing) were applied to specimens. Two series of RPC composites were prepared with bauxite and granite aggregates. Mechanical properties such as compressive strength, splitting tensile strength, flexural strength and fracture energy of composites were investigated. Test results showed that, compressive strength of 200 MPa can be reached with low cement by using high-volume fly ash. Thermally treated specimens showed compressive strength beyond 250 MPa and high volume fly ash RPC have superior performance. Furthermore, compressive strength values reached up to 400 MPa with external pressure application during setting and hardening stages.     

Use of OPC to improve setting and early strength properties of low calcium fly ash geopolymer concrete cured at room temperature

Most previous works on fly ash based geopolymer concrete focused on concretes subjected to heat curing. Development of geopolymer concrete that can set and harden at normal temperature will widen its application beyond precast concrete. This paper has focused on a study of fly ash based geopolymer concrete suitable for ambient curing condition. A small proportion of ordinary Portland cement (OPC) was added with low calcium fly ash to accelerate the curing of geopolymer concrete instead of using elevated heat. Samples were cured in room environment (about 23 °C and RH 65 ± 10%) until tested. Inclusion of OPC as little as 5% of total binder reduced the setting time to acceptable ranges and caused slight decrease of workability. The early-age compressive strength improved significantly with higher strength at the age of 28 days. Geopolymer microstructure showed considerable portion of calcium-rich aluminosilicate gel resulting from the addition of OPC.     

Compressive strength and drying shrinkage of fly ash-bottom ash-silica fume multi-blended cement mortars

This paper studies the physical properties, compressive strength and drying shrinkage of multi-blended cement under different curing methods. Fly ash, ground bottom ash and undensified silica fume were used to replace part of cement up to 50% by weight. Specimens were cured in air at ambient temperature, water at 25, 40 and 60 °C, sealed with plastic sheeting for 28 days. The results show that absorption and volume of permeable pore space (voids) of blended cement mortars at 28 day under all curing methods tend to increase with increasing silica fume replacement. The compressive strength of blended cement with fly ash and bottom ash was lower than that of Portland cement control at all curing condition while blended cement with silica fume shows higher compressive strength. In addition, the compressive strength of specimens cured with water increased with increasing curing temperature. The drying shrinkage of all blended cement mortar cured in air was lower than that of Portland cement control while the drying shrinkage of blended cement mortar containing silica fume, cured with plastic sealed and water at 25 °C was higher than Portland cement control due to pore refinement and high autogenous shrinkage. However, the drying shrinkage of blended cement mortar containing SF cured with water at 60 °C was lower than that of Portland cement control due to lower autogenous shrinkage and the reduced microporosity of C–S–H.     

A study on the effect of nano silica on compressive strength of high volume fly ash mortars and concretes

This paper presents the effect of nano silica (NS) on the compressive strength of mortars and concretes containing different high volume fly ash (HVFA) contents ranging from 40% to 70% (by weight) as partial replacement of cement. The compressive strength of mortars is measured at 7 and 28 days and that for concretes is measured at 3, 7, 28, 56 and 90 days. The effects of NS in microstructure development and pozzolanic reaction of pastes containing above HVFA contents are also studied through backscattered electron (BSE) image and X-ray diffraction (XRD) analysis. Results show that among different NS contents ranging from 1% to 6%, cement mortar containing 2% NS exhibited highest 7 and 28 days compressive strength. This NS content (2%) is then added to the HVFA mortars and concretes and the results show that the addition of 2% NS improved the early age (7 days) compressive strength of mortars containing 40% and 50% fly ash by 5% and 7%, respectively. However, this improvement is not observed at high fly ash contents beyond 50%. On the other hand, all HVFA mortars exhibited improvement in 28 days compressive strength due to addition of 2% NS and the most significant improvement is noticed in mortars containing more than 50% fly ash. In HVFA concretes, the improvement of early age (3 days) compressive strength is also noticed due to addition of 2% NS. The BSE and XRD analysis results also support the above findings.     

Comparison of ultrasonic wave reflection method and maturity method in evaluating early-age compressive strength of mortar

This paper focuses on the comparison between the ultrasonic wave reflection method and the widely known maturity method in their ability to evaluate compressive strength development of portland cement mortars. The experiments were conducted under laboratory conditions on cement mortars with different water–cement ratios (0.35, 0.5, 0.6) cured under different isothermal and non-isothermal conditions (15 °C, 25 °C, 35 °C, 15–35 °C). The results show that the application of the maturity method for accurate strength estimation requires the knowledge of the limiting strength of the mixture for the specific curing condition that is considered. It is not sufficient to base this estimation on the values of the limiting strength obtained from the calibration tests. The relationship between reflection loss and compressive strength was found to be independent of curing temperature. This finding is an important step towards establishing the wave reflection method as a non-destructive method for estimating early-age strength in cement-based materials.     

Influence of steam curing on the properties of concretes incorporating metakaolin and silica fume

In this paper, influence of steam curing on the compressive strength, ultrasonic pulse velocity, water sorptivity, chloride ion permeability, and electrical resistivity of metakaolin and silica fume blended concretes were investigated. A total of seven mixtures containing various combinations of Portland cement (PC), silica fume (SF), and metakaolin (MK) were produced with 400 kg/m³ of total cementitious materials content and with a constant water/binder ratio of 0.44. For each mixture, concrete samples were either standard-cured in water at 23°C or steam-cured at 70°C maximum temperature over 17 h curing period. Test results revealed that steam curing enhanced the 1-day compressive strength and ultrasonic pulse velocity while leading to reduced long term strength in line with earlier findings. At the end of the water sorptivity, chloride ion permeability, and electrical resistivity tests, it was found that the steam-cured concretes had higher water sorptivity and chloride ion permeability, and lower electrical resistivity values compared to the standard cured specimens. Use of SF and MK as cementitious materials remarkably decreased the water sorptivity and chloride ion permeability of concretes, irrespective of the curing condition.     

A study on reinforcement corrosion and related properties of plain and blended cement concretes under different curing conditions

This paper presents the results of an experimental investigation on the steel reinforcement corrosion, electrical resistivity, and compressive strength of concretes. Concretes having two different water–cement ratios (0.65 and 0.45) and two different cement contents (300 and 400 kg/m³) were produced by using a plain and four different blended portland cements. Concrete specimens were subjected to three different curing procedures (uncontrolled, controlled, and wet curing). The effect of using plain or blended cements on the resistance of concrete against damage caused by corrosion of the embedded reinforcement has been investigated using an accelerated impressed voltage setup. The resistivity of the cover concrete has been measured non-destructively by placing electrodes on concrete surface. The compressive strength, electrical resistivity, and corrosion resistance of the concretes were determined at different ages up to 180 days. The results of the tests indicated that the wet curing was essential to achieve higher strength and durability characteristics for both plain and especially blended cement concretes. The concretes, which received inadequate (uncontrolled) curing, exhibited poor performance in terms of strength and corrosion resistance.     

Optimization of concrete mixture with hybrid blends of metakaolin and fly ash using response surface method

This paper presents the experimental results of a research carried out on the strength and permeability related properties of high performance concretes made with binary and ternary cementitious blends of fly ash (FA) and metakaolin (MK). The replacement ratios for FA were 10% and 20% by weight of Portland cement and those for MK were 5% and 10%. Compressive strength, chloride permeability, water sorptivity, and water absorption properties of concretes were obtained in this study for different testing ages up to 90 days. The influences of fly ash, metakaolin, and testing age on the properties of concretes have been identified using the analysis of variance. The statistical based regression models and the response surface method with the backward stepwise techniques were employed in the multi-objective optimization analysis. That is carried out by maximizing compressive strength while minimizing chloride permeability, water sorptivity, and water absorption. It was observed that fly ash and especially metakaolin were very effective on the aforementioned properties of the concretes, depending mainly on replacement levels and duration of curing. The results indicated that the ternary use of fly ash and metakaolin with the approximate cement replacement values of 13.3% and 10% respectively has provided the best results for the testing age of 90 days, when the optimized strength and permeability based durability properties of the concretes are concerned.     

Compressive strength and chloride resistance of self-compacting concrete containing high level fly ash and silica fume

The influence of high-calcium fly ash and silica fume as a binary and ternary blended cement on compressive strength and chloride resistance of self-compacting concrete (SCC) were investigated in this study. High-calcium fly ash (40–70%) and silica fume (0–10%) were used to replace part of cement at 50, 60 and 70 wt.%. Compressive strength, density, volume of permeable pore space (voids) and water absorption of SCC were investigated. The total charge passed in coulombs was assessed in order to determine chloride resistance of SCC. The results show that binary blended cement with high level fly ash generally reduced the compressive strength of SCC at all test ages (3, 7, 28 and 90 days). However, ternary blended cement with fly ash and silica fume gained higher compressive strength after 7 days when compared to binary blended fly ash cement at the same replacement level. The compressive strength more than 60 MPa (high strength concrete) can be obtained when using high-calcium fly ash and silica fume as ternary blended cement. Fly ash decreased the charge passed of SCC and tends to decrease with increasing fly ash content, although the volume of permeable pore space (voids) and water absorption of SCC were increased. In addition when compared to binary blended cement at the same replacement level, the charge passed of SCC that containing ternary blended cement was lower than binary blended cement with fly ash only. This indicated that fly ash and silica fume can improve chloride resistance of SCC at high volume content of Portland cement replacement.     

Characterisation of ground hydrated Portland cement-based mortar as an additive to alkali-activated slag cement

The sustainable development of cement manufacturing requires extension of the raw material base, including large-tonnage waste. Hydrated mortar waste is a promising mineral resource for the production of Portland cements and alternative binders, such as alkali-activated slag cement. The influences of ground-hydrated mortar aged for 3 months on the properties of alkali-activated slag fresh and hardened pastes were performed. The results show that the properties are dependent on the concentration (2.5–60%), cement:sand ratio (1:1–3) and fineness (200–600 m²/kg) of the ground hydrated mortar; the alkali activator (sodium carbonate and sodium silicate); and the curing conditions (normal conditions and steam curing). The fresh paste properties that we considered in this study included the water requirement and the setting time; the hardened paste properties we considered were the water absorption, the density, and the compressive strength after 2, 7, 14, 28, 180 and 360 days of ageing. The ground hydrated mortar improved the early strength and the long-term strength of the alkali-activated slag paste and replaced the slag up to 50%. The factors that affecting the strength of the alkali-activated slag cement with ground hydrated mortar as an additive were, in order of influence, alkali activator type > curing conditions > cement:sand ratio > ground-hydrated mortar fineness.     

The role of 0–2 mm fine recycled concrete aggregate on the compressive and splitting tensile strengths of recycled concrete aggregate concrete

The aim of this study is to investigate the role of 0–2 mm fine aggregate on the compressive and splitting tensile strengths of recycled concrete aggregate (RCA) concrete with normal and high strengths. Normal coarse and fine aggregates were substituted with the same grading of RCAs in two normal and high strength concrete mixtures. In addition, to keep the same slump value for all mixes, additional water or superplasticizer were used in the RCA concretes. The compressive and splitting tensile strengths were measured at 3, 7 and 28 days. Test results show that coarse and fine RCAs, which were achieved from a parent concrete with 30 MPa compressive strength, have about 11.5 and 3.5 times higher water absorption than normal coarse and fine aggregates, respectively. The density of RCAs was about 20% less than normal aggregates, and, hence, the density of RCA concrete was about 8–13.5% less than normal aggregate concrete. The use of RCA instead of normal aggregates reduced the compressive and splitting tensile strengths in both normal and high strength concrete. The reduction in the splitting tensile strength was more pronounced than for the compressive strength. However, both strengths could be improved by incorporating silica fume and/or normal fine aggregates of 0–2 mm size in the RCA concrete mixture. The positive effect of the contribution of normal sand of 0–2 mm in RCA concrete is more pronounced in the compressive strength of a normal strength concrete and in the splitting tensile strength of high strength concrete. In addition, some equation predictions of the splitting tensile strength from compressive strength are recommended for both normal and RCA concretes.     

Lightweight geopolymer concrete containing aggregate from recycle lightweight block

In this research, the properties of lightweight geopolymer concrete containing aggregate from recycle lightweight block were studied. The recycle block was crushed and classified as fine, medium and coarse aggregates. The compressive strength and density with various liquid alkaline/ash ratios, sodium silicate/NaOH ratios, NaOH concentrations, aggregate/ash ratios and curing temperatures were tested. In addition, porosity, water absorption, and modulus of elasticity were determined. Results showed that the lightweight geopolymer blocks with satisfactory strength and density could be made. The 28-day compressive strength of 1.0–16.0 MPa, density of 860–1400 kg/m³, water absorption of 10–31% and porosity of 12–34%, and modulus of elasticity of 2.9–9.9 GPa were obtained. It can be used as lightweight geopolymer concrete for wall and partition.     

Mechanical properties of reactive powder concrete containing high volumes of ground granulated blast furnace slag

The mechanical properties (flexural strength, compressive strength, toughness and fracture energy) of steel microfiber reinforced reactive powder concrete (RPC) were investigated under different curing conditions (standard, autoclave and steam curing). Portland cement was replaced with ground granulated blast furnace slag (GGBFS) at 20%, 40% and 60%. Sintered bauxite, granite and quartz were used as aggregates in different series. The compressive strength of high volume GGBFS RPC was over 250 MPa after autoclaving. When an external pressure was applied during setting and hardening stages, compressive strength reached up to 400 MPa. The amount of silica fume can be decreased with increasing amount of GGBFS. SEM micrographs revealed the tobermorite after autoclave curing.     

Structure and strength of NaOH activated concretes containing fly ash or GGBFS as the sole binder

The influence of the concentration of the activating agent (4, 6, or 8 M sodium hydroxide solution), and activator-to-binder ratio (0.40, 0.50, or 0.60) on the compressive strengths, pore structure features, and microstructure of concretes containing Class F fly ash or ground granulated blast furnace slag (GGBFS) as the sole binder is reported. The starting material contents and the curing parameters (temperature and curing duration) are optimized to provide the highest compressive strengths. Statistical analysis of the compressive strength results show that the activator concentration has a larger influence on the compressive strengths of activated concretes made using fly ash and the activator-to-binder ratio influences the compressive strengths of activated GGBFS concretes to a greater degree. Activated fly ash concretes and pastes are found to be more porous and contains a larger fraction of pores greater than 10 μm in size as compared to activated GGBFS mixtures. The differences in the microstructure and the reaction products between activated fly ash and GGBFS pastes are detailed.     

An experimental study on optimum usage of GGBS for the compressive strength of concrete

This paper presents a laboratory investigation on optimum level of ground granulated blast-furnace slag (GGBS) on the compressive strength of concrete. GGBS was added according to the partial replacement method in all mixtures. A total of 32 mixtures were prepared in four groups according to their binder content. Eight mixes were prepared as control mixtures with 175, 210, 245 and 280 kg/m³ cement content in order to calculate the Bolomey and Féret coefficients (K_B, K_F). For each group 175, 210, 245 and 280 kg/m³ dosages were determined as initial dosages, which were obtained by removing 30 percent of the cement content of control concretes with 250, 300, 350, and 400 kg/m³ dosages. Test concretes were obtained by adding GGBS to concretes in an amount equivalent to approximately 0%, 15%, 30%, 50%, 70%, 90% and 110% of cement contents of control concretes with 250, 300, 350 and 400 kg/m³ dosages. All specimens were moist cured for 7, 14, 28, 63, 119, 180 and 365 days before compressive strength testing.The test results proved that the compressive strength of concrete mixtures containing GGBS increases as the amount of GGBS increase. After an optimum point, at around 55% of the total binder content, the addition of GGBS does not improve the compressive strength. This can be explained by the presence of unreacted GGBS, acting as a filler material in the paste.     

Compressive strength of ash-based geopolymers at early ages designed by Taguchi method

In the present work, compressive strength of ash-based geopolymers has been designed by Taguchi method at 2 and 7 days of water curing. Three factors including oven curing temperature (at 3 levels of 25, 70, and 90 °C), oven curing time (at 3 levels of 2, 4, and 8 h) and sodium hydroxide (NaOH) concentration (at 3 levels of 5, 8, and 12 M) were considered. By utilizing L9 Taguchi array, 9 series of experiments were conducted on the prepared specimens. The aluminosilicate source was a mixture of fly ash and rice husk ash while the alkali activating was done by a mixture of NaOH and sodium silicate solution. The obtained results were evaluated by analysis of variance (ANOVA) method to determine the optimum level of each factor. In all produced specimens, the optimum level of oven curing temperature was always 90 °C to achieve the highest compressive strength. Furthermore, the optimum strength was obtained by applying light and middle concentration of NaOH in approximately all specimens. Finally, the oven curing time was not an important factor to determine the compressive strength. To validate the accuracy of the optimum conditions suggested by ANOVA, compressive specimens were made and tested in accordance to the optimum conditions for each of 2 and 7 days water curing regimes. The compressive strength acquired from this situation was higher than those of proposed in initial 9 series of experiments for each of 2 and 7 days water curing regimes.