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向均聚聚丙烯(iPP)中添加α成核剂制备透明聚丙烯时,挤出过程设置不同挤出温度,以考察挤出温度对样品透光性能和力学性能影响的机理。测试了透光率和力学性能。结果表明,当挤出温度为230℃时可以获得透光率最佳的样品,这是由于温度高时α成核剂溶解度变大,成核密度变大,晶体尺寸减小所致;拉伸强度提高,断裂伸长率和冲击强度有所降低。 相似文献
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以均聚聚丙烯(PP)为基础树脂,通过加入成核剂生产透明PP片材专用树脂。探讨了成核剂的加入量及片材加工温度对片材透明性能的影响,确定PP片材最佳加工温度为230℃。成核剂的加入使PP的结晶度由 44.1%提高到51.4%,结晶温度、熔点等均有不同程度的提高。 相似文献
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透明聚丙烯性能的研究 总被引:7,自引:0,他引:7
采用偏光显微镜(PLM)、差示扫描量热仪(DSC)、毛细管流变仪和拉伸试验机对透明聚丙烯(PP)的结晶形态、热学、流变性、力学性能进行了研究。结果表明:与普通聚丙烯相比,透明聚丙烯不但光学性能得到改善,其他性能也有不同程度的提高,综合性能优于普通聚丙烯 相似文献
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竹纤维增强PP复合材料的研究 总被引:1,自引:1,他引:1
介绍了竹纤维增强聚丙烯(PP)复合材料的性能,初步探讨了竹纤维的处理、未处理以及纤维含量对增强PP的力学性能的影响因素。实验证明:与PP材料相比,添加竹纤维可使复合材料的力学性能有不同程度的改善,特别是对复合材料的冲击强度、拉伸强度及断裂伸长率影响较明显。 相似文献
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《国际聚合物材料杂志》2012,61(12):931-948
This work addresses the effect of organomodified layer double hydroxide (OLDH) on the properties of PP/LDH nanocomposites prepared by melt intercalation method using a single screw extruder with maleic anhydride grafted polypropylene (PP-g-MA) as a compatibilizer. For this, Ni-Al LDH was first prepared by the co-precipitation method at constant pH using their nitrate salts. The above synthesized pristine LDH was organically modified using sodium dodecyl sulphate (SDS) by the regeneration method. The structural and thermal properties of LDH and PP nanocomposites were performed by X-ray diffraction (XRD), FTIR spectroscopy, thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The influence of LDH loading on the mechanical and thermal properties of the nanocomposite was also investigated. The XRD results confirmed the formation of exfoliated PP/LDH nanocomposites. PP/LDH nanocomposites exhibited enhanced thermal stability relative to the pure PP. When 10% weight loss was selected as a point of comparison, the decomposition temperature of PP/LDH (5 wt%) nanocomposite was 15.3°C higher than that of pure PP. The DSC result indicated an increase in crystallization and melting temperature of the PP/LDH nanocomposites compared to pure PP. Overall, the mechanical properties of the PP/LDH nanocomposites increased with an increase in the LDH content. The maximum improvement of tensile strength, Young's modulus, flexural strength, and flexural modulus for the PP/LDH nanocomposite was found to be 11, 22.5, 28, and 22%, respectively, over neat PP. For comparison purposes, a nanocomposite with 5 wt% modified bentonite (PP/B5) was also prepared under the same operating condition and there was no significant improvement in mechanical properties (tensile strength and modulus). 相似文献
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Polypropylene was melt blended in a single screw extruder with thermo tropic Vectra B‐950 liquid crystalline polymer (copolyester amide) in different proportions in presence of 2% of EAA, ethylene‐acrylic acid copolymer (based on PP) as a compatibilizer. The mechanical properties of such compatibilized blends were evaluated and compared in respect of their Young's Modulii, Ultimate tensile strength, percent elongation at break, and toughness to those of Pure PP. The Morphology was studied by using a polarizing light microscope (PLM) and Scanning electron microscope (SEM). The Thermal characterization of these blends were carried out by differential scanning calorimeter (DSC).The mechanical properties under dynamic conditions of such compatibilized blends and pure PP were studied by dynamic mechanical analyzer (DMA). Mechanical analysis (Tensile properties) of the compatibilized blends displayed improvements in Modulii and ultimate tensile strength (UTS) of PP matrix with the incorporation of 2–10% of LCP incorporation. The development of fine fibrillar morphology in the compatibilized PP/LCP blends had large influence on the mechanical properties. Differential scanning calorimeter (DSC) studies indicated no remarkable changes in the crystalline melting temperature of the blends with respect to that of pure PP. However, an increase in the softening range of the blends over that of PP was observed. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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采用熔融共混法制备了PP/纳米SiO2复合材料,并通过力学性能测试、DSC分析以及材料断面形貌分析等手段,对增强增韧效果进行了研究。结果表明,加入纳米SiO2能提高了PP的结晶速率,使结晶度增大。当纳米SiO2的质量分数为2%时可使PP/nSiO2复合材料的缺口冲击强度提高2倍,拉伸强度稍微下降。 相似文献
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The effects of polypropylene (PP) and ultrasonic irradiation on the processing and mechanical properties of ultrahigh molecular weight polyethylene (UHMWPE) are studied. The results show that PP can effectively improve the fluidity and mechanical properties of UHMWPE. The Izod notched impact strength increases from 92 kJ/m2 for pure UHMWPE to 109.2 kJ/m2 for the blend of UHMWPE with 10 wt % PP. The Young's modulus increases from 528 MPa for pure UHMWPE to 1128 MPa when 25 wt % PP is contained in the blend, and the yield strength also rises when PP is added. The application of ultrasonic vibrations during extrusion can prominently decrease the die pressure and apparent viscosity of the melt, thus increasing the output of extrudate. An appropriate ultrasonic intensity and irradiation time can further promote the mechanical properties, while an overdose of irradiation destroys them. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2628–2632, 2003 相似文献
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ANN方法分析预测聚丙烯材料的力学性能 总被引:1,自引:0,他引:1
利用B-P人工神经网络(AJNN)对聚丙烯(PP)的力学性能进行了分析和预测。首先将PP材料接纯PP、共混和增韧及填充和增强PP等进行分类,并根据这些数据的特点建立B-P网络,然后用各类PP材料的组成和力学性能数据对网络进行学习训练,最后用“未知样品”的数据对网络进行验证。结果表明,所建立的网络能反映PP的力学性能特性,预测有一定的准确性,但不同类别的材料预测准确性不同。 相似文献