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1.
Mats Hamberg 《Lipids》1998,33(11):1061-1071
[1-14C]α-Linolenic acid was incubated with a particulate fraction of homogenate of leaves of the meadow buttercup (Ranunculus acris L.). The main product was a divinyl ether fatty acid, which was identified as 12-[1′(Z),3′(Z)-hexadienyloxy]-9(Z), 11(E)-dodecadienoic acid. Addition of glutathione peroxidase and reduced glutathione to incubations of α-linolenic acid almost
completely suppressed formation of the divinyl ether acid and resulted in the appearance of 13(S)-hydroxy-9(Z), 11(E), 15(Z)-octadecatrienoic acid as the main product. This result, together with the finding that 13(S)-hydroperoxy-9(Z), 11(E), 15(Z)-octadecatrienoic acid served as an efficient precursor of the divinyl ether fatty acid, indicated that divinyl ether biosynthesis
in leaves of R. acris occurred by a two-step pathway involving an ω6-lipoxygenase and a divinyl ether synthase. Incubations of isomeric hydroperoxides
derived from α-linolenic and linoleic acids with the enzyme preparation from R. acris showed that 13(S)-hydroperoxy-9(Z), 11(E)-octadecadienoic acid was transformed into the divinyl ether 12-[1′(Z)-hexenyloxy]-9(Z), 11(E)-dodecadienoic acid. In contrast, neither the 9(S)-hydroperoxides of linoleic or α-linolenic acids nor the 13(R)-hydroperoxide of α-linolenic acid served as precursors of divinyl ethers. 相似文献
2.
[1-14C]Linolenic acid was incubated with homogenates of leaves from the aquatic plants Ranunculus lingua (greater spearwort) or R. peltatus (pond water-crowfoot). Analysis by reversed-phase high-performance liquid radiochromatography demonstrated the formation
of a new divinyl ether FA, i.e., 12-[1′(E), 3′(Z)-hexadienyloxy]-9(Z), 11(Z)-dodecadienoic acid [11(Z)-etherolenic acid] as well as a smaller proportion of ω5(Z)-etherolenic acid previously identified in terrestrial Ranunculus plants. The same divinyl ethers were formed upon incubation of 13(S)-hydroperoxy-9(Z), 11(E), 15(Z)-octadecatrienoic acid, a lipoxygenase metabolite of linolenic acid, whereas the isomeric hydroperoxide, 9(S)-hydroperoxy-10(E), 12(Z), 15(Z)-octadecatrienoic acid, was not converted into divinyl ethers in R. lingua or R. peltatus. Incubation of [1-14C]linoleic acid or 13(S)-hydroperoxy-9(Z), 11(E)-octadecadienoic acid produced the divinyl ether 12-[1′(E)-hexenyloxy]-9(Z), 11(Z)-dodecadienoic acid [11(Z)-etheroleic acid] and a smaller amount of ω5(Z)-etheroleic acid. The experiments demonstrated the existence in R. lingua and R. peltatus of a divinyl ether synthase distinct from those previously encountered in higher plants and algae. 相似文献
3.
Hamberg M Chechetkin IR Grechkin AN Ponce de León I Castresana C Bannenberg G 《Lipids》2006,41(5):499-506
3-Oxalinolenic acid (3-oxa-9(Z), 12(Z), 15(Z)-octadecatrienoic acid or (6(Z), 9(Z), 12(Z)-pentadecatrienyloxy)acetic acid)
was synthesized from 5(Z), 8(Z), 11(Z), 14(Z), 17(Z)-eicosapentaenoic acid by a sequence involving the C15 aldehyde 3(Z),
6(Z), 9(Z), 12(Z)-pentadecatetraenal as a key intermediate. Conversion of the aldehyde by isomerization and two steps of reduction
afforded 6(Z), 9(Z), 12(Z)-pentadecatrienol, which was coupled to bromoacetate to afford after purification by HPLC >99%-pure
3-oxalinolenic acid in 10–15% overall yield. 3-Oxalinolenic acid was efficiently oxygenated by soybean lipoxygenase-1 into
3-oxa-13(S)-hydroperoxy-9(Z), 11(E), 15(Z)-octadecatrienoic acid, and this hydroperoxide could be further converted chemically
into 3-oxa-13(S)-hydroxy-9(Z), 11(E), 15(Z)-octadecatrienoic acid and 3-oxa-13-oxo-9(Z), 11(E), 15(Z)-octadecatrienoic acid.
The 3-oxa-hydroperoxide also served as the substrate for the plant enzymes allene oxide synthase, divinyl ether synthase,
and hydroperoxide lyase to produce 3-oxa-12-oxo-10, 15(Z)-phytodienoic acid and other 3-oxa-oxylipins that were characterized
by MS, 3-Oxalinolenic acid was not oxygenated by 9-lipoxygenase from tomato but was converted at a slow rate into 3-oxa-9(S)-hydroperoxy-10(E),
12(Z), 15(Z)-octadecatrienoic acid by recombinant maize 9-lipoxygenase. Recombinant α-dioxygenase-1 from Arabidopsis thaliana catalyzed the conversion of 3-oxalinolenic acid into a 2-hydroperoxide, which underwent spontaneous degradation into a mixture
of 6,9,12-pentadecatrienol and 6,9,12-pentadecatrienyl formate. A novel α-dioxygenase from the moss Physcomitrella patens was cloned and expressed and was found to display the same activity with 3-oxalinolenic acid as Arabidopsis thaliana α-dioxygenase-1. Lipoxygenase-generated 3-oxa-oxylipins are resistant toward β-oxidation and have the potential for displaying
enhanced biological activity in situations where activity is limited by metabolic degradation. 相似文献
4.
Grechkin AN Ogorodnikova AV Gnezdilov OI Mukhtarova LS 《Chembiochem : a European journal of chemical biology》2007,8(18):2275-2280
The lipoxygenase pathway in sunflower roots was studied in vitro. A preliminary incubation of linoleic acid with 15 000 g supernatant of homogenate of sunflower roots (1.5-6 days after germination) revealed the predominant activity of 13-lipoxygenase. The exogenously added linoleic acid 13-hydroperoxide is further utilized through two competing pathways. One of them is directed towards formation of the ketodiene (9Z,11E)-13-oxooctadeca-9,11-dienoic acid. The second pathway, which is controlled by allene oxide synthase, leads to the formation of an alpha-ketol and a novel cyclopentenone, rac-cis-12-oxo-10-phytoenoic acid (12-oxo-PEA) via a short-lived allene oxide. Unexpectedly, the cyclopentenone 12-oxo-PEA is the predominant allene oxide synthase product. Identification of cis-12-oxo-PEA was confirmed by its UV, mass, (1)H NMR and 2D-COSY spectral data. The highest yield of 12-oxo-PEA is observed in very young roots (1.5-2 days after germination). The results of methanol-trapping experiments demonstrate that both 12-oxo-PEA and alpha-ketol are formed through the unstable allene oxide intermediate, (9Z)-12,13-epoxyoctadeca-9,11-dienoic acid, which is the primary product of allene oxide synthase. Since 12-oxo-PEA is a jasmonate congener, its biosynthesis in plants might be of physiological importance. 相似文献
5.
[1-14C]Linoleic acid was incubated with a whole homogenate preparation from potato stolons. The reaction product contained four
major labeled compounds, i.e., the α-ketol 9-hydroxy-10-oxo-12(Z)-octadecenoic acid (59%), the epoxy alcohol 10(S),11(S)-epoxy-9(S)-hydroxy-12(Z)-octadecenoic acid (19%), the divinyl ether colneleic acid (3%), and a new cyclopentenone (13%). The structure of the last-mentioned
compound was determined by chemical and spectral methods to be 2-oxo-5-pentyl-3-cyclopentene-1-octanoic acid (trivial name,
10-oxo-11-phytoenoic acid). Steric analysis demonstrated that the relative configuration of the two side chains attached to
the five-membered ring was cis, and that the compound was a racemate comprising equal parts of the 9(R), 13(R) and 9(S), 13(S) enantiomers. Experiments in which specific trapping products of the two intermediates 9(S)-hydroperoxy-10(E), 12(Z)-octadecadienoic acid and 9(S), 10-epoxy-10, 12(Z)-octadecadienoic acid were isolated and characterized demonstrated the presence of 9-lipoxygenase and allene oxide synthase
activities in the tissue preparation used. The allene oxide generated from linoleic acid by action of these enzymes was further
converted into the cyclopentenone and α-ketol products by cyclization and hydrolysis, respectively. Incubation of [1-14C]linolenic acid with the preparation of potato stolons afforded 2-oxo-5-[2′(Z)-pentenyl]-3-cyclopentene-1-octanoic acid (trivial name, 10-oxo-11, 15(Z)-phytodienoic acid), i.e., an isomer of the jasmonate precursor 12-oxo-10, 15(Z)-phytodienoic acid. Quantitative determination of 10-oxo-11-phytoenoic acid in linoleic acid-supplied homogenates of different
parts of the potato plant showed high levels in roots and stolons, lower levels in developing tubers, and no detectable levels
in leaves. 相似文献
6.
3,4-Dihydro-2H-benz[1,3]oxazin-2-ones 3 are obtained from 2-acyl(or aroyl)-cyanatobenzenes 2 and anisole. The reaction proceeds under Friedel-Crafts conditions via DIMROTH rearrangement. Compounds 2 , dissolved in diethyl ether, react with 1 in the presence of finely powdered KOH at ambient temperature leading to 8 . The structure of 8b is confirmed by X-ray structure analysis. (Z)-4-Ethylidene - 3,4 - dihydro -2H-benz[1,3] oxazin-2-one 9 is formed upon treatment of 2-cyanatopropiophenone 2b with diluted hydrochloric acid. The ethylene derivative 5 is obtained from 4 upon reaction with cyanogen bromide/triethyl amine. 相似文献
7.
Ching T. Hou Harold Gardner Wanda Brown 《Journal of the American Oil Chemists' Society》1998,75(11):1483-1487
Hydroxy fatty acids are important industrial materials. We isolated a microbial culture, Clavibacter sp. ALA2, which converts linoleic acid to many polyhydroxy fatty acids. Structures of the products were determined as: 12,13,17-trihydroxy-9(Z)-octadecenoic
(THOA, main product), 12-[5-ethyl-2-tetrahydrofuranyl]-7,12-dihydroxy-9(Z)-dodecenoic (ETDDA), and 12-[5-ethyl-2-tetrahydrofuranyl]-12-hydroxy-9(Z)-dodecenoic
(ETHDA) acid. The yield of THOA was 25% and the relative amount of the products were THOA/ETDDA/ETHDA =9:1.3:1. The structures
of the hydroxy unsaturated fatty acids resemble those of plant self-defense substances. 相似文献
8.
研究龙眼(Dimocarpus longan Lour.)果核的化学成分,采用硅胶柱色谱对龙眼果核石油醚提取物和体积分数95%乙醇提取物进行分离,并利用理化性质和光谱数据鉴定化合物的结构。从龙眼果核的提取物中分离得到一组混合神经酰胺(化合物1、2)和一组混合脑苷脂(化合物3~6),结构鉴定为Rel-(3S,4S,5S)-3-[(2'R)-2'-羟基二十二酰胺]-4-羟基-5-[(4″Z)-十四烷-4″-烯]-2,3,4,5-四氢呋喃(1)、Rel-(3S,4S,5S)-3-[(2'R)-2'-羟基二十四酰胺]-4-羟基-5-[(4″Z)-十四烷-4″-烯]-2,3,4,5-四氢呋喃(2)、1-O-(β-D-吡喃葡萄糖基)-(2S,3S,4R,8E)-2-(2'-羟基二十四酰胺)-8-十八烯-1,3,4-三醇(3)、1-O-(β-D-吡喃葡萄糖基)-(2S,3S,4R,8Z)-2-(2'-羟基二十四酰胺)-8-十八烯-1,3,4-三醇(4)、1-O-(β-D-吡喃葡萄糖基)-(2S,3S,4R,8E)-2-(2'-羟基二十二酰胺)-8-十八烯-1,3,4-三醇(5)、1-O-(β-D-吡喃葡萄糖基)-(2S,3S,4R,8Z)-2-(2'-羟基二十二酰胺)-8-十八烯-1,3,4-三醇(6)。 相似文献
9.
G. Aliotta P. Monaco G. Pinto A. Pollio L. Previtera 《Journal of chemical ecology》1991,17(11):2223-2234
Among the substances isolated from ethyl ether extract ofPistia stratiotes L., linoleic acid,-linolenic acid, (12R,9Z,13E,15Z)-l2-hydroxy- 9,13,15-octadecatrienoicacid, (9S,10E,12Z,15Z)-9-hydroxy-10,12,15-octadecatrienoic acid, -asarone, and 24S-ethyl-4,22-cholestadiene-3,6-dione were found to inhibit the growth of some microalgae in solid medium. Toxicity of -asarone on the growth of sensitive algal strains in liquid medium is discussed. 相似文献
10.
Gries R Khaskin G Clearwater J Hasman D Schaefer PW Khaskin E Miroshnychenko O Hosking G Gries G 《Journal of chemical ecology》2005,31(3):603-620
(Z, Z)-6,9-Heneicosadien-11-one (Z6Z9-11-one-21Hy) was identified as the major sex pheromone component of the painted apple moth (PAM), Teia anartoides (Lepidoptera: Lymantriidae), on the basis of (1) comparative gas chromatographic-electroantennographic detection (GC-EAD) analyses, GC-mass spectrometry (MS), high-performance liquid chromatography (HPLC)-MS, and HPLC-UV/visible spectroscopy of pheromone gland extracts and authentic standards; (2) GC-EAD analyses of effluvia of calling females; and (3) wind tunnel and field trapping experiments with a synthetic standard. In field experiments in Australia, synthetic Z6Z9-11-one-21Hy as a single component attracted male moths. Wind tunnel experiments suggested that a 4-component blend consisting of Z6Z9-11-one-21Hy, (6Z,9R,10S)-cis-9,10-epoxy-heneicosene (Z6-9R10S-epo-21Hy), (E, E)-7,9-heneicosadien-6,11-dione (E7E9-6,11-dione-21Hy), and 6-hydroxy-(E, E)-7,9-heneicosadien-11-one (E7E9-6-ol-11-one-21Hy) (all present in pheromone gland extracts) might induce more males to orient toward, approach, and contact the source than did Z6Z9-11-one-21Hy as a single component. Additional experiments are needed to determine conclusively whether or not Z6-9R10S-epo-21Hy, E7E9-6,11-dione-21Hy, and E7E9-6-ol-11-one-21Hy might be minor sex pheromone components of PAM. Moreover, attractiveness of synthetic pheromone and virgin PAM females needs to be compared to determine whether synthetic pheromone could replace PAM females as trap baits in the program to monitor eradication of exotic PAM in New Zealand. 相似文献
11.
Transannular Reactions of Cycloalkenes, Cycloalkadienes and Cycloalkatrienes. VIII. The Electrophilic Addition of Pseudohalogenes to Cycloocta-1(Z), 5(Z)-diene The reaction of cycloocta-1(Z), 5(Z)-diene 5 with chlorothiocyanate is described. The main process is the normal anti-addition to produce trans-5-chloro-6-thiocyanato-(Z)-cyclooctene 6 . In addition 2,6-dichloro-9-thiabicyclo [3.3.1] nonane 7 and 2,6-dithiocyanato-9-thiabicyclo[3.3.1] nonane 8 are obtained as products of a transannular reaction. 相似文献
12.
Satoshi Kubo Koh Hashida Tatsuhiko Yamada Shojiro Hishiyama Kengo Magara Masanori Kishino 《木材化学与工艺学杂志》2013,33(2):84-96
Abstract Guaiacylglycerol-β-guaiacyl ether (GG), which contains a predominant inter-unit linkage of lignin, could be converted into a corresponding glycerol type enol-ether (EE), 3-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)-2-propenol, by the heat treatment in ionic liquids. EE is believed to be the unstable intermediate of the lignin decomposition process under acidic and alkaline conditions. By contrast, EE could be isolated as a relatively stable compound from the reaction mixture of ionic liquids. EE was formed as a primary reaction product in all ionic liquids used in this research under the temperature conditions of 120°C, although the decomposition rate and secondary decomposition products of GG varied with the ionic liquid used. NMR data suggested that dehydration reaction of GG progressed stereospecifically and [Z] isomer was predominantly formed (stereoselectivety of [Z] is higher than 90%). 相似文献
13.
SEX PHEROMONE COMPONENTS OF THE SANDTHORN CARPENTERWORM, <Emphasis Type="Italic">Holcocerus hippophaecolus</Emphasis> 总被引:1,自引:0,他引:1
Extracts of female sex pheromone gland of the carpenterworm moth, Holcocerus hippophaecolus Hua, a pest of sandthorn, Hippophae rhamnoides L. were found to contain (E)-3-tetradecenyl acetate (E3-14:Ac), (Z)-3-tetradecenyl acetate (Z3-14:Ac), (Z)-7-tetradecenyl acetate (Z7-14:Ac), the corresponding alcohols, E3-14:OH, Z3-14:OH, Z7-14:OH, and (E)-9-tetradecenyl acetate (E9-14:Ac). Electroantennographic (EAG) analysis of these chemicals and their analogs demonstrated that Z7-14:Ac elicited the largest male EAG response, followed by E3-14:Ac. In field trials, traps baited with either Z7-14:Ac or E3-14:Ac alone caught no male moths, whereas a combination of these two components in a 1:1 ratio caught more males than control traps. Addition of Z7-14:OH and Z3-14:OH or the alcohols plus E9-14:Ac did not enhance trap catches. We conclude that the sex pheromone of H. hippophaecolusis composed of Z7-14:Ac and E3-14:Ac. Optimal ratios and doses of these two components, and the possible role of other minor components, remain to be determined. 相似文献
14.
发酵新鲜鸢尾香气成分分析 总被引:5,自引:1,他引:4
采用同时蒸馏萃取装置提取挥发油并用气相色谱-质谱联用仪对经发酵的新鲜鸢尾根茎挥发性香味化合物进行了分离和鉴定,分离并鉴定出 69个组分,占峰面积的 84 .24%,并用面积归一化法测定了各种成分的质量分数,其主要香气成分为:w( 3- 甲基 -2 -丁烯醛 ) =0. 14%、w〔(Z) 3 -己烯醛〕=0. 09%、w〔(Z)- 2 庚烯醛〕=0.07%、w〔(E) 2- 癸烯醛〕=0 .08%、w〔(E,E) -2, 4 -癸二烯醛〕=0 .06%、w(辛酸 ) =0. 52%、w(癸酸 ) =0 66%、w(十二酸) =0. 57%、w(2, 4 二羟基 3, 6 -二甲基苯甲酸) =0. 13%、w(十四酸) =7 .76%、w(十五酸 ) =0 .19%、w(1, 2- 苯二甲酸) =0 .14%、w(9- 十六碳烯酸) =0. 37%、w(十六酸 ) =11. 25%、w(十七酸 ) =0 .21%、w-〔(Z,Z) 9, 12 -十八碳二烯酸〕=26. 09%、w〔(E) 9 十八碳烯酸〕=9. 58%、w(蒿醇) =0. 20%、w(环橙花叔醇 ) =0 88%、w(1- 二十二醇) =0 .20%、w(2- 十四烷氧乙醇 ) =0. 15%、w(3, 7, 11 -三甲基- 2, 6- 十二碳二烯 1 醇 ) = 0 08%、w(蒿酮) =0 .04%、w〔1 ( 4 -羟基- 3- 甲氧苯基 )乙酮〕= 2 .69%、w〔4- ( 2, 5, 6, 6 -四甲基环己 1 烯基 )丁- 2- 酮〕=0. 12%、w(5 甲基α 紫罗兰酮) =1 .22%、w〔1- (3, 4- 二甲氧苯基) 乙酮〕=0. 47%、w(3, 5, 5- 三甲基 -2- 环己烯- 相似文献
15.
V. Spitzer F. Marx J. G. Maia K. Pfeilsticker 《European Journal of Lipid Science and Technology》1991,93(5):169-174
Four acetylenic fatty acids [11-octadecen-9-ynoic acid (E) (ximenynic acid), 11-octadecen-9-ynoic acid (Z), 9,11-octadecadiynoic acid and 13-octadecen-9,11-diynoic acid (E) (exocarpic acid)] were found in the seed oil of Curupira tefeensis (Olacaceae) as minor compounds. The mass spectra of the methyl esters (EI and CI mode), picolinyl esters and 4,4-dimethyloxazoline derivatives of these acids are discussed in detail. Furthermore the NMR data of 9,11-octadecadiynoic acid and 13-octadecen-9,11-diynoic acid are presented. 相似文献
16.
Crown Ether Substituted 1,4‐Distyrylbenzenes and their Complexation with Alkali Picrates The 1,4‐distyrylbenzenes 8 and 9 , which contain two crown ether units, each, were prepared by Wittig—Horner reactions. Their complexation tendencies with alkali picrates (Li—Cs) in water/dichloromethane were investigated. Potas sium ions give the strongest complexes. Generally monomo‐lecular 1:1‐complexes are formed; however, [K‐ 8 ] + [Pik]—, [K‐ 9 ]+ [Pik]— and [Rb‐ 8 ] + [Pik]— generate aggregates, for which a stairway structure is proposed. 相似文献
17.
Philipp Marx Angelo Romano Ignazio Roppolo Angela Chemelli Inge Mühlbacher Wolfgang Kern Sunny Chaudhary Thomas Andritsch Marco Sangermano Frank Wiesbrock 《大分子材料与工程》2019,304(12)
Tri(ethylene glycol) divinyl ether and the spiro‐orthoester 2‐((allyloxy)methy)‐1,4,6‐trioxospiro[4.4]nonane can be formulated in different ratios and crosslinked by thiol‐ene reactions. The spiro‐orthoester is used as anti‐shrinkage additive, enabling shrinkage reduction of up to 39%. Addition of a radical photoinitiator for the thiol‐ene reaction and a cationic photoinitiator for the double ring‐opening of the spiro‐orthoester enables dual‐curing for application in 3D‐printing. The formulation free of the spiro‐orthoester shows gelation during the printing process and, correspondingly, low resolution. The formulations containing the spiro‐orthoester exhibit higher resolutions in the range of 50 µm. The resins containing mixtures of tri(ethylene glycol) divinyl ether and the spiro‐orthoester show permittivities as high as 104. The dielectric loss factor of the resins is in the range of 0.5–7.6, and the conductivity in the range of 1.3?10?11 to 2.0?10?11 S cm?1. These high‐κ materials can be 3D‐printed by digital light processing for the next generation of electronic materials. 相似文献
18.
The total syntheses of 9(Z),12(E)- and 9(E),12(Z)-octadecadienoic acids have been carried out. A useful intermediate in both
syntheses, 8-bromo-octanoic acid, recently has become available from commercial sources. This compound has been used to expedite
the preparation of these isomers. The remaining carbon atoms were derived from propargyl alcohol along with either 1-heptyne
or acetylene and 1-bromopentane. Because the overall yield for each sequence was roughly 15% and there were no extraordinary
reaction conditions in any of the synthetic steps, the compounds could be prepared readily in multiple gram quantities. The
syntheses of the two compounds were supported by data from a variety of spectroscopic techniques. 相似文献
19.
Three species of brown algae,Laminaria sinclairii, L. saccharina andL. setchellii, have been investigated for the presence of oxylipins. From one,L. sinclairii, three new divinyl ether fatty acids have been characterized as methyl ester derivatives (methyl 12-[1′ (Z),3′(Z)-hexadienyloxy]-6(Z), 9(Z), 11(E)-dodecatrienoate, methyl 12-[1′ (Z), 3′ (Z)-hexadienyloxy]-9(Z), 11(E)-dodecatrienoate, and methyl 14-[1′ (Z),3′ (Z)-hexadienyloxy]-9(Z),11(E)-dodecadienoate, and methyl 14-[1′ (Z),3′(Z)-hexadienyloxy]-5(Z),8(Z),11(Z),13(E)-tetradecatetraenoate) by a variety of spectroscopic methods. In addition, one new [13(S)-hydroxy-6(Z),9(Z),11(E),15(Z)-octadecatetraenoic acid] and four known monohydroxy polyunsaturated fatty acids have been isolated from all three species
as their methyl ester derivatives. The occurrence of these compounds in brown algae strongly suggests that these organisms
possess an active lipoxygenase(s) with ω6 specificity.
A preliminary summary of this work was presented at the XIVth International Seaweed Symposium, Brest, France, August 1992
(10). 相似文献
20.
Two new fatty acid metabolites, 5(Z),7(E),9(E),14(Z),17(Z)-icosapentaenoic acid and 5(E),7(E),9(E),14(Z),17(Z)-icosapentaenoic
acid, have been isolated from the temperate red marine alga,Ptilota filicina (Ceramiales, Rhodophyta). The structures of these new compounds, isolated as their methyl ester derivatives, have been deduced
from detailed1H nuclear magnetic resonance (NMR),13C NMR and 2D-NMR analyses as well as comparisons to known compounds. 相似文献