共查询到20条相似文献,搜索用时 125 毫秒
1.
2.
3.
以Ba(OH)2.8H2O,Al(NO3)3.9H2O,TEOS为原料,采用溶胶-凝胶法制备BaO-Al2O3-SiO2三元系粉末,研究了不同因素对生成稳定溶胶和胶化时间的影响,用TG-DTA,XRD研究了溶胶-凝胶的热处理过程,用TEM观察了粉体的粒径。 相似文献
4.
5.
EXPERIMENTALINVESTIGATIONOFKINETICANDTRANSPORTPARAMETERSINAWALL-COOLEDFIXED-BEDREACTORZhen-MinCHENGandWei-KangYUAN(UNILABRese... 相似文献
6.
叠加定量气相色谱法测定吹苯残渣中的三苯含量王静华,王宏伟DETERMINATIONOFBENAENE,TOLUENBANDXYLENEINBLOWINGBENZENEREXIDUEBYADDRRIONQUANTTTATIVEMETHODOFGASCH... 相似文献
7.
8.
本文在研究了SBS/L/-PB/TEGDA(TMPTA)均相光敏体系对特定光源(低压汞灯,λ=254nm)发射光吸收的基础上,按剩余膜产率(Y)绘制出感光特性曲线(Y-t)确定出Y随L-PB和TEGDA(或TMPTA)用量变化的规律,求算了优选体系的量子产率,以剩余膜产率和灰梯度尺法测定了上述体系的相对感度。 相似文献
9.
10.
11.
《Propellants, Explosives, Pyrotechnics》2017,42(12):1410-1417
Two kinds of reduced sensitivity high explosive 1,3,5,7‐tetranitro‐1,3,5,7‐tetrazocane (RS‐HMX) with different particle sizes were selected to enhance the energy output and the mechanical properties of insensitive high explosive 1,3,5‐triamino‐2,4,6‐trinitrobenzene (TATB). Mechanical sensitivities, dynamic mechanical analysis, and non‐linear time dependent creep behaviors of TATB/HMX composites were investigated and discussed in relation to the structural characteristics. Compared with TATB/conventional HMX (C‐HMX) sample, both the impact and friction sensitivities of TATB/RS‐HMX were reduced. It revealed that TATB/fine grains RS‐HMX composites had the highest storage modulus and minimum steady‐state creep strain rate due to the increased coherence strength and the inhibited slide of the single layer of TATB crystal. The creep resistance also showed clear dependence on the particle size of RS‐HMX. The overall results indicated that RS‐HMX had good potential in high energetic, safe, and load‐bearing material applications. 相似文献
12.
采用溶剂/非溶剂法,在超声辅助的情况下,制备了TATB/HMX共晶炸药;探究了TATB/HMX共晶技术的影响因素;计算了TATB/HMX共晶炸药的理论密度和理论爆速;采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)和差示扫描热量法(DSC)对其进行表征和热分析,并测试了其撞击感度。结果表明,制备TATB/HMX共晶的最佳工艺条件为:以[Emim]Ac/DMSO为复合溶剂,TATB和HMX投料比(摩尔比)为3∶7,温度为80℃,搅拌速率为500r/min;与原料相比,TATB/HMX共晶分子在结构上发生改变;TATB/HMX共晶炸药颗粒大小约为2μm,形貌为六边形晶体;共晶炸药的热安定性优于原料HMX,其特性落高比原料HMX高74cm,撞击感度明显降低;理论密度为1.891g/cm~3,理论爆速为8.758km/s,表明其爆炸性能良好。 相似文献
13.
Looking for explosives for Low Vulnerability Ammunitions leads to an interest in explosive molecules less sensitive than the usual nitramines (RDX, HMX). If TATB is quite convenient in terms of sensitivity, its performance is too low. The researches described here are related to synthesis and use of NTO (nitrotriazolone), another insensitive molecule. The synthesis by nitration of TO (triazolone) is easy and the two steps from available starting materials have been optimized. A comparison of desensitivation of PBX either by TATB or by NTO have been made. The sensitivity levels were found equivalent while the detonation velocity of the NTO based PBX was slightly higher. Unfortunately in this case, the failure diameter would be larger. The last part relates to an extensive characterization in terms of performance and vulnerability to fast cook off, slow cook off, bullet impact, shock sensitivity and sympathetic detonation of a NTO and HMX based PBX. This PBX, B 2214, was one of the first examples of explosive composition showing no sympathetic detonation, even in 248 mm large diameter. 相似文献
14.
15.
V. V. Burtsev A. L. Mikhailov K. N. Panov A. V. Rudnev M. A. Syrunin 《Combustion, Explosion, and Shock Waves》2011,47(3):350-356
Detonation initiation in a composite explosive based on HMX and TATB loaded by a divergent shock wave was studied on a U-70
proton accelerator using proton radiography. Density distributions behind the initiating shock front at various times were
obtained. Detonation failure due to collision of shock and detonation waves was studied for a plastic-bonded TATB sample using
radiography. Characteristic features of the explosive transformation under shock-wave loading were determined from the images
obtained. 相似文献
16.
利用超声波法制备单质炸药TATB,用高频率超声波反应器,采用原位合成方法制备了钝感HMX/TATB混合炸药.讨论了反应时间、反应温度以及料比对合成TATB的影响.测试了混合炸药的压制成型性和耐热性能.结果表明,超声波法合成的TATB粒度为5~6μm,混合炸药中TATB的质量分数小于15%,降感效果明显,耐热性能良好;使... 相似文献
17.
多硝基吡啶类化合物的合成及应用研究进展 总被引:1,自引:0,他引:1
综述了2,6-二氨基-3,5-二硝基吡啶(ANPy)及其氧化物(ANPyO)、2,4,6-三氨基-3,5-二硝基吡啶(TANPy)及其氧化物(TANPyO)、2,4,6-三硝基吡啶(TNPy)及其氧化物(TNPyO)等多硝基吡啶类含能化合物的合成及应用研究进展。ANPyO的爆轰性能和安全性能与三氨基三硝基苯(TATB)接近,可作为高能钝感炸药;理论预测TANPy比TATB钝感;TNPyO具有良好的热稳定性和化学稳定性。预计这些多硝基吡啶类含能化合物在钝感炸药、低易损发射药和钝感推进剂领域中有良好的应用前景。 相似文献
18.
For a variety of reasons, including U.S. Federal law and improved safety, it is desirable to have insensitive munitions (IM). Although a variety of methods are available to reduce the sensitivity of munitions only changes to the high explosive (HE) itself result in increased safety during storage, transportation, handling, and deployment. As a result of this IM are almost always filled with fire resistant, shock resistant insensitive HE such as triaminotrinitrobenzene (TATB). The high cost of TATB has limited its use. In this study we examine 28 nitro‐aromatics, including TATB and five previously unpublished structures, in the solid state in order to identify forces that stabilize the HE. We show that the sum of forces involved in crystal packing (i.e. the estimated energy of stabilization) has a direct relationship to the observed sensitivity of nitro‐aromatic explosives. 相似文献
19.
Zhijian Yang Jinshan Li Bing Huang Shijun Liu Zhong Huang Fude Nie 《Propellants, Explosives, Pyrotechnics》2014,39(1):51-58
The insensitive high explosive 1,3,5‐triamino‐2,4,6‐trinitrobenzene (TATB) was selected for coating and desensitization of hexanitrohexaazaisowurtzitane (CL‐20), another high explosive, after surface modification. About 2 wt‐% polymer binder was adopted in the preparation process to further maintain the coating strength and fill the voids among energetic particles. The structure, sensitivity, polymorph properties, and thermal behavior of CL‐20/TATB by coating and physical mixing were studied. Scanning electron microscopy (SEM) and X‐ray photoelectron spectroscopy (XPS) results indicate that submicrometer‐sized TATB was compactly coated onto the CL‐20 surface with coverage close to 100 %. The core‐shell structure of CL‐20/TATB was confirmed by observation of hollow TATB shell from the CL‐20 core dissolved sample. X‐ray diffraction (XRD) analysis revealed that the polymorph of CL‐20 maintained ε form during the whole preparing process. Thermal properties were studied by thermogravimetry (TG) and differential scanning calorimeter (DSC), showing effects of TATB coating on the polymorph thermal stability and exothermic decomposition of CL‐20. Both the impact and friction sensitivities were markedly reduced due to the cushioning and lubricating effects of TATB shell. The preparation of explosive composites with core‐shell structure provides an efficient route for the desensitization of high explosives, such as CL‐20 in this study. 相似文献
20.
V. V. Burtsev V. A. Komrachkov A. D. Kovtun K. N. Panov A. V. Rudnev M. A. Syrunin 《Combustion, Explosion, and Shock Waves》2012,48(3):343-349
The initiation of detonation of plasticized TATB by shock loading using an initiator pressure charge of an HMX based explosive
was studied by radiography. In the experiments, the size of the initiator and the initial density of the TATB charge were
varied. During initiation of TATB detonation, part of the material did not react, forming so-called dark zones. As the process
goes on, the detonation wave bends around the dark zones, without initiating the material within them. The evolution of the
area of dark zones was compared for samples of different initial density and initiators of different sizes. The characteristic
boundaries and X−t diagrams of detonation front propagation under different loading conditions were constructed from images of the explosive
process. Density distributions behind a divergent detonation wave front at different times were obtained and analyzed. 相似文献